Products

ExxonMobil Exceed XP mLLDPE XP 7052RA

    • Product Name: ExxonMobil Exceed XP mLLDPE XP 7052RA
    • Factroy Site: Yudu County, Ganzhou, Jiangxi, China
    • Price Inquiry: sales8@ascent-chem.com
    • Manufacturer: Ascent Petrochem Holdings Co., Limited
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    Specifications
    HS Code 782533
    Density 0.9175 g/cm³
    Melt Index 0.5 g/10 min (190°C/2.16 kg)
    Melting Point 119 °C
    Vicat Softening Point 95 °C
    Tensile Strength At Yield 9.7 MPa
    Tensile Strength At Break 38 MPa
    Elongation At Break 600%
    1 Secant Modulus 180 MPa
    Dart Drop Impact 500 g
    Elmendorf Tear Strength Md 300 g
    Elmendorf Tear Strength Td 400 g
    Haze 7%
    Gloss 45 75

    As an accredited ExxonMobil Exceed XP mLLDPE XP 7052RA factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing ExxonMobil Exceed XP mLLDPE XP 7052RA is supplied in 25 kg polyethylene-lined bags, palletized and stretch-wrapped for industrial storage.
    Container Loading (20′ FCL) 20′ FCL containing palletized 25 kg bags of ExxonMobil Exceed XP mLLDPE XP 7052RA, shrink-wrapped and secured for ocean freight.
    Shipping ExxonMobil Exceed XP mLLDPE XP 7052RA is a nonhazardous polyethylene resin normally supplied as pellets in moisture-barrier bags or bulk containers. Ship as non-dangerous goods in dry, covered transport; avoid punctures, contamination, excessive heat, and direct sunlight. Keep packaging sealed, palletized, clean, and secure; follow SDS and local regulations.
    Storage Store ExxonMobil Exceed XP mLLDPE XP 7052RA in a cool, dry, well-ventilated warehouse, away from direct sunlight, heat, ignition sources, and strong oxidizers. Keep original bags or containers closed, dry, clean, and palletized; protect from moisture, contamination, UV exposure, and physical damage. Maintain good housekeeping and follow the supplier’s SDS and local storage regulations.
    Shelf Life Shelf life: typically 24 months from manufacture when stored in original packaging, dry, ventilated conditions, away from direct sunlight and heat.
    Application of ExxonMobil Exceed XP mLLDPE XP 7052RA

    Ethylene 1-hexene mLLDPE Exceed XP 7052RA with a melt index of 0.5 g/10 min (190°C, 2.16 kg, ASTM D1238-20) and density of 0.918 g/cm³ (ASTM D792-20) is processed on five-layer blown-film lines producing frozen vegetable and seafood packaging at web widths up to 1,800 mm, in the outer and core layers at 60 wt% to 80 wt%, with the balance consisting of a low-density polyethylene or C4-LLDPE letdown for bubble stability and melt strength. The downstream process is a three-layer blown-film coextrusion line with a die gap of 1.8 mm to 2.5 mm, a blow-up ratio maintained between 2.2:1 and 2.8:1, and melt temperatures between 188°C and 220°C. Frost-line height is typically positioned at 3–5 die diameters from the die face to preserve machine-direction tear strength while minimizing neck-in along the collapsing frame. Compliance for food contact frozen food packaging is governed by FDA 21 CFR 177.1520(c) for olefin polymers and EU Regulation 10/2011 with an overall migration limit of 10 mg/dm²; manufacturers also verify the grade against REACH and a Kosher certification when used in institutional food service. The terminal finished product types include pillow pouches, gusseted side-seal bags, and bag-in-box liners for individually quick-frozen vegetables, seafood, and frozen bakery items at film gauges from 30 µm to 70 µm. On production lines with 25:1 L/D grooved-feed extruders, a failure mode observed is moisture-related bubble pinholes when regrind surface moisture exceeds 0.1 wt%; sealed storage at ambient relative humidity below 60% is sufficient to avoid pre-drying, but open-floor silos with condensation cycles require desiccant dryers.

    What Governs Seal Initiation Temperature Below 105°C in High-Barrier Sealant Webs?

    Typically, high-barrier sealant webs produced on seven-layer and nine-layer coextrusion lines require XP 7052RA in the sealant layer at 20 wt% to 40 wt% when the layer also contains a lower-density hexene or butene LLDPE and a processing aid masterbatch at 0.5 wt% to 1.0 wt%; for demanding high-speed spouted pouch applications the sealant layer can carry up to 70 wt% XP 7052RA blended with a polyolefin plastomer, but the lower coefficient of friction may then require additional slip agent compensation. The downstream production process is a nine-layer blown film line with layer ratio control and a die gap of 1.5 mm to 2.0 mm, where the sealant layer is assigned a minimum thickness of 12 µm to maintain seal integrity on vertical form-fill-seal machines running above 45 m/min. Melt temperatures are held between 188°C and 232°C to avoid oxidative gel formation, and blow-up ratios range from 2.0:1 to 2.5:1 to minimize orientation-induced seal strength loss in the transversal direction. Relevant standards include EU Regulation 10/2011, Annex I food contact compliance, FDA 21 CFR 177.1520(c), and ASTM F88/F88M-21 for seal strength testing of flexible barrier materials. Terminal finished products include stand-up pouches, side-gusset pouches for dry foods and liquids, vacuum pouches for processed meat and cheese, and spout pouches for liquid foods. The limiting variable at thin sealant gauges is not resin degradation but hot tack strength; a sealant layer thinner than 10 µm can reduce heat-seal window width and generate channel leakers on high-speed lines, so seal initiation temperature should be re-qualified with the specific barrier core and adhesive tie layers rather than extrapolated from monolayer films. Published data for this specific seven-layer configuration with ethylene vinyl alcohol barrier layers remains limited, and seal strength values should be verified on the target line.

    Compliance and test method matrix for downstream scenarios
    Application scenarioStandard / codeApplied parameter
    Frozen food contact primary webFDA 21 CFR 177.1520(c); EU Regulation 10/2011Overall migration limit 10 mg/dm²
    High-barrier sealant webASTM F88/F88M-21; EU Regulation 10/2011Seal strength, sealant thickness 12 µm minimum
    Heavy-duty sack filmISO 21898:2021; ASTM D1709-16aDart drop impact, film thickness 80–200 µm
    Agricultural greenhouse filmEN 13206:2017; ISO 4593:2018; ASTM D1003-21Thickness tolerance, light transmission
    Stretch hood filmASTM D882-18; ASTM D1709-16a; ASTM D5748-95(2019)Tensile, dart drop, puncture resistance
    Poultry MAP lidding webASTM F1306-19; FDA 21 CFR 177.1520(c)Puncture resistance, food contact compliance
    Medical and liquid pouch overwrapISO 11607-1:2019; ISO 10993-5:2009; EU Regulation 10/2011Sterile barrier integrity, cytotoxicity

    Heavy-Duty Sack Extrusion: Melt Pressure Ceiling at 420 bar on Grooved-Feed 25:1 L/D Extruders

    A melt pressure ceiling of 420 bar is reached on 75 mm grooved-feed extruders when XP 7052RA is run at 10 wt% to 30 wt% in blends with high-density polyethylene or C4-LLDPE in heavy-duty sack film, and the 0.5 g/10 min low melt index requires barrier-screw design with a grooved-feed throat to maintain output without excessive shear heating. The production process is a three-layer blown-film line with a die gap of 2.0 mm to 2.8 mm, blow-up ratio 2.0:1 to 3.0:1, melt temperature 195°C to 240°C, and frost-line height maintained at 600 mm to 900 mm from the die face on a 350 mm die. Screw speeds above 110 rpm on 75 mm extruders may push melt pressure beyond 420 bar, increasing screen pack rupture risk, so a 60/100/60 mesh screen pack and a gear melt pump are specified when output targets exceed 450 kg/h. Compliance for heavy-duty packaging is anchored to ISO 21898:2021 for flexible intermediate bulk containers, ISO 527-3:2018 for tensile properties of film and sheet, and ASTM D1709-16a Method A for dart drop impact. Terminal finished product types include heavy-duty sacks for polymer resin, chemical powder, mineral filler, fertilizer, and FIBC liners with total film thickness from 80 µm to 200 µm. A known line failure is screw feed instability due to pellet slip when the grooved-feed throat temperature exceeds 60°C; feed throat cooling is required to maintain positive transport and prevent melt contamination at the feed port.

    When agricultural silage covers and greenhouse side curtains require multi-season UV durability, XP 7052RA is added at 15 wt% to 50 wt% of total formulation in the middle or outer layer of a three-layer blown coextrusion, with hindered amine light stabilizer and UV absorber packages at 0.5 wt% to 1.2 wt% to meet multi-year durability requirements under outdoor exposure. The production process uses a die diameter of 400 mm to 600 mm, die gap 1.8 mm to 2.4 mm, blow-up ratio 2.8:1 to 3.4:1, internal bubble cooling with automatic bubble diameter control, and melt temperature 180°C to 215°C. Compliance is governed by EN 13206:2017 for thermoplastic covering films for agricultural use, ISO 4593:2018 for thickness tolerance, and ASTM D1003-21 for light transmission and haze. The addition ratio of XP 7052RA in the outer layer is selected based on puncture resistance required for hail and wind; if inorganic anti-fog or anti-drip additives exceed 2 wt%, die lip oxidation and bubble instability can increase, and the line should be purged with a high-density polyethylene transition resin during shutdown to prevent crosslinked gel accumulation. Terminal finished product types include greenhouse covers, low tunnel films, silage bags, and baler ensiling films at thicknesses from 100 µm to 200 µm. The main material limitation is long-term UV stabilizer consumption; annual film returned from exposed installations should be tested for residual stabilizer by extraction chromatography rather than relying only on initial Xenon-arc QUV ratings.

    When Stretch Hood Mono-Webs Drop Below 40 µm, Frost-Line Height Becomes the Critical Control Variable

    Stretch hood mono-webs below 40 µm respond to frost-line height changes more than to melt temperature adjustments; XP 7052RA is introduced into the core layer at 20 wt% to 60 wt% to raise transverse direction tear resistance after stretching and to reduce hood blow-out failures on sharp pallet corners. The process is a three-layer high-draw blown film line equipped with a dual-lip air ring, internal bubble cooling, and collapse frame oscillation; die gap is set at 1.6 mm to 2.4 mm, blow-up ratio from 2.5:1 to 3.5:1, and frost-line height held at 4–6 die diameters to prevent excessive orientation in the machine direction. The low density of 0.918 g/cm³ and narrow molecular weight distribution produce a stable bubble at melt temperatures from 185°C to 220°C, but when film thickness falls below 40 µm, frost-line height becomes the main variable controlling dart tear and stretch recovery; a shift of more than one die diameter changes transverse direction elongation at break enough to affect stretch hood machine reliability. Compliance for load containment films uses ASTM D882-18 for tensile properties, ASTM D1709-16a for dart drop impact, and ASTM D5748-95(2019) for puncture resistance. Terminal finished products include stretch hoods for pallets of bottled beverages, gypsum board, insulation batts, and household appliances at typical film thicknesses of 30 µm to 80 µm. A processing limitation appears at transverse draw ratios above 300%; published data for this specific draw ratio condition with XP 7052RA is limited, but surface cling additive migration can become the dominant factor controlling coefficient of friction rather than the resin itself.

    Can a 0.918 g/cm³ mLLDPE Sealant Layer Reduce Puncture Failures in Poultry MAP Lidding Web Below 25 µm?

    Below 25 µm, modified atmosphere packaging lidding film on thermoformed trays of fresh poultry and processed meat uses XP 7052RA in the sealant layer at 10 wt% to 30 wt% with low-density polyethylene and ethylene vinyl acetate to maintain seal integrity while reducing puncture failures from bone edges and tray-to-tray abrasion. The production line is a three-layer coextruded blown film process running at 80 m/min to 120 m/min, with a die gap of 1.5 mm to 2.0 mm, blow-up ratio 2.0:1 to 2.5:1, and melt temperature 190°C to 225°C. The sealant web is generally supplied at 12 µm to 25 µm as part of a laminated or coextruded lidding structure; the lower melt index contributes high melt strength and permits thinner gauge without tunnel formation in the lamination nip. Food contact compliance is maintained under FDA 21 CFR 177.1520(c) and EU Regulation 10/2011, with ASTM F1306-19 used for slow-rate puncture penetration testing of flexible barrier films and ASTM F88/F88M-21 used for seal strength. Terminal finished products include lidding film for fresh poultry trays, vacuum pouches, and thermoformed tray lidding for processed meat and cheese. A formulation-related boundary appears above 50 wt% XP 7052RA in the sealant layer, where haze can rise due to crystalline morphology changes and contact clarity may become inadequate for fresh poultry display; for MAP lid stock below 25 µm, the addition is therefore normally held at or below 30 wt%. Puncture resistance data for specific multilayer configurations is limited and should be generated on the target line rather than taken from monolayer values.

    Liquid pouch and medical device overwrap converting lines run XP 7052RA as a sealant modifier at 15 wt% to 35 wt% in coextrusions with high-pressure LDPE and linear low-density polyethylene for blow-fill-seal and pouch overwrap applications requiring low gel count and controlled seal strength under aseptic filling conditions. The downstream production process is typically a three-layer blown-film line with a die gap of 1.4 mm to 2.0 mm, blow-up ratio 1.8:1 to 2.2:1, melt temperature 185°C to 215°C, and a clean-room-inspired handling protocol to minimize surface particulate. Compliance is anchored to ISO 11607-1:2019 for sterile barrier packaging, FDA 21 CFR 177.1520(c), EU Regulation 10/2011, and ISO 10993-5:2009 for in vitro cytotoxicity when the film is used as a direct medical device surface. Terminal product types include overwrap bags for pre-filled syringes, liquid pouch films for enteral nutrition, and protective barrier pouches for terminally sterilized instruments. The processing boundary is gel formation due to long residence time; start-up purges below 180°C or extended shutdowns with the screw rotating should be limited to prevent oxidized specks in medical-grade film. Published data for this specific downstream configuration with XP 7052RA is limited, and sterilization compatibility with ethylene oxide and gamma irradiation should be qualified per target cycle.

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    Certification & Compliance
    More Introduction

    ExxonMobil Exceed XP 7052RA is a metallocene-catalysed ethylene-1-hexene linear low-density polyethylene resin supplied in pellet form. The nominal density is 0.912 g/cm³ when tested according to ASTM D1505, and the melt index is 0.50 g/10 min when measured at 190 °C under a 2.16 kg load in accordance with ASTM D1238 and ISO 1133-1. The 1-hexene comonomer introduces short-chain branches of 4 carbon atoms along the polyethylene backbone. At an equivalent density, this longer branch length changes the tie-molecule population relative to a 1-butene copolymer and shifts the balance between low-temperature impact resistance and tear propagation.

    The molecular weight distribution of Exceed XP 7052RA is narrower than that of conventional Ziegler-Natta LLDPE resins. That distribution influences bubble stability, shear-thinning behaviour, and the relationship between extruder torque and output. The grade is used in monolayer and coextruded blown film structures for collation shrink film, freezer film, heavy-duty sacks, lamination film, and form-fill-seal packaging. The 7052RA designation is grade-specific; converters should verify lot-specific certificates of analysis for antioxidant and processing-aid levels before setting formulation records.

    Which Extrusion Boundaries Control Bubble Stability and Impact Retention?

    Blown film behaviour of XP 7052RA is governed by die gap, blow-up ratio, frost line height, melt temperature, and output rate. The material is not a direct drop-in replacement for a conventional C4-LLDPE on every line because the narrow molecular weight distribution reduces shear thinning. A suitable starting envelope is a die gap of 1.5–2.5 mm, a blow-up ratio of 2.0:1–3.0:1, and a melt temperature at the die of 190–240 °C. On high-stalk configurations, frost line height is typically held between 5 and 7 die diameters. If the frost line falls below 3 die diameters, quenching occurs before sufficient stress relaxation, and oscillating gauge bands or bubble instability can appear. If the frost line is raised above 8 die diameters, output benefit per tower height may decline and transverse-direction tear can increase because annealing in the bubble alters orientation.

    Die gaps below 1.5 mm can produce excessive die pressure on some spiral mandrel dies; the maximum die pressure stated on the die certificate must not be exceeded. During start-up, the adapter and die temperatures should be held at the lower end of the processing window, and output should be increased only after bubble symmetry is confirmed. Melt temperature should be monitored at the die exit because screw speed profiles developed for C4-LLDPE can push the melt toward 240 °C more rapidly with this resin. Gauge uniformity is measured by capacitance scanning or gravimetric film thickness methods; a stabilised bubble does not guarantee a fixed tolerance unless the die is centred and the air ring is balanced for the selected blow-up ratio.

    Mechanical performance of the converted film is not specified independently of fabrication conditions. A reference monolayer gauge of 25 µm at a 2.5:1 blow-up ratio, a 2.0 mm die gap, and a melt temperature of 210 °C provides one comparative basis. Under these conditions, tensile properties are determined by ASTM D882 with a crosshead speed of 500 mm/min, dart impact is tested by ASTM D1709 Method A, and Elmendorf tear is measured by ASTM D1922. Tear data are directional and reflect the anisotropic orientation imposed by bubble dynamics. When film gauge is reduced from 40 µm to 25 µm, dart impact energy does not decline linearly with thickness because the fracture zone beneath the dart consumes less material. Converters should generate a gauge–impact curve on the target line rather than extrapolate from a single thickness.

    Regulatory Compliance Matrix for Food Contact Conversion

    Food packaging use requires validation of the finished article under the applicable migration rules. The instruments listed below define the principal compliance framework; inclusion in this matrix does not replace converter-specific migration testing.

    InstrumentScopeCondition
    FDA 21 CFR 177.1520Olefin polymers in contact with foodFinished package must meet density, extraction, and end-use limitations specified in the regulation.
    Regulation (EU) No 10/2011Plastic materials and articles intended to come into contact with foodOverall migration and specific migration limits must be verified on the final film.
    Regulation (EC) No 1907/2006REACHMonomers and additives must be registered; the polymer itself is exempt from registration.
    Directive 2011/65/EURoHS recastRelevant only if film is incorporated into electrical or electronic equipment; not a packaging directive.

    Relative to conventional Ziegler-Natta C4-LLDPE, the difference is expressed as a shift in the gauge at which a package meets a given impact and tear specification. The 0.912 g/cm³ density of XP 7052RA gives a lower modulus than a 0.918 g/cm³ C4-LLDPE, while the hexene comonomer and metallocene architecture can provide a different dart impact response at equal gauge. In a non-optimised clinical replacement of a 50 µm C4-LLDPE film with a 35–40 µm XP 7052RA film, equivalent or improved dart impact may be observed, but the outcome is line-specific. Published data for this specific configuration is limited, and direct substitution must be confirmed by ASTM D1709 testing on the target blown film line.

    Start-up and shutdown procedures should include purging with an LDPE of 0.918–0.924 g/cm³ density and a melt index of 1.0–2.0 g/10 min to avoid stagnant material at the die lip. During brief stops, barrel and die temperatures should be held at the lower end of the processing window. If the line is stopped at melt temperature for more than 20–30 min, degradation in dead spots can form gel that appears later as film defects. Pre-drying is not normally required at ambient humidity below 60% RH; however, surface condensation on pellets stored in unheated silos can cause bubble instability and surface defects.

    In lamination structures, corona treatment is typically controlled to 38–42 dyn/cm when measured by ASTM D2578 wetting solutions. Treatment above 46 dyn/cm can create brittle surface oxidation layers that reduce heat seal strength. For sealant use, heat seal initiation is measured according to ASTM F1921 on the final sealant layer after surface treatment. A seal force curve generated on a benchtop sealer does not reproduce dynamic jaw pressure and dwell time on a packaging machine; therefore, the target line must be used for final seal specification.

    When Autoclave Sterilization Creates a Thermal Ceiling for Use

    The crystalline melting range of an 0.912 g/cm³ ethylene-1-hexene copolymer is lower than that of high-density polyethylene. Exposure to autoclave steam at 121 °C approaches the onset of crystalline melting; packages under stress can deform during heating. This resin is therefore not a direct substitute for polypropylene in retort applications. The same molecular features that reduce seal initiation temperature also place an upper thermal limit on the package. For applications requiring service above 110 °C, a higher-density or higher-melting resin should be selected.

    In frozen food end use at -40 °C, the film remains above the glass transition of the amorphous polyethylene phase and retains impact toughness. Suitability must nevertheless be established by ASTM D1709 at the intended service temperature. In collation shrink film, the grade is run in hot-air tunnel conditions where the film must shrink without losing package integrity; the tunnel temperature and dwell time are set to avoid over-shrinking the sealant layer and creating wrinkles. The operational boundary is the same for all polyolefins: the thermal and mechanical limits must be evaluated on the finished package under the intended distribution environment.

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