| HS Code | 226076 |
| Density | 0.916 g/cm³ |
| Meltindex | 0.6 g/10 min |
| Meltflowratio | 16 |
| Peakmeltingtemperature | 119 °C |
| Vicatsofteningtemperature | 95 °C |
| Tensilestrengthatyield | 9.7 MPa |
| Tensilestrengthatbreak | 36 MPa |
| Elongationatbreak | 600% |
| Dartdropimpact | 800 g |
| Elmendorftearmd | 300 g |
| Elmendorfteartd | 400 g |
| Haze | 6% |
| Gloss45degree | 80 |
| Punctureresistance | 8 J/cm |
As an accredited ExxonMobil Exceed XP mLLDPE XP 6056ML factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.
| Packing | Packaged in 25 kg moisture-resistant polyethylene bags, palletized on standard pallets for safe industrial handling, shipping, and storage. |
| Container Loading (20′ FCL) | ExxonMobil Exceed XP mLLDPE XP 6056ML loaded in a 20-foot FCL container, palletized in 25 kg bags, shrink-wrapped and secured for export. |
| Shipping | ExxonMobil Exceed XP mLLDPE XP 6056ML is shipped as non-hazardous polymer pellets in sealed, moisture-resistant bags or octabins on pallets. Transport in clean, dry trucks or containers, protected from moisture, direct sunlight, and excessive heat. Follow the SDS and local regulations; avoid packaging damage. |
| Storage | Store ExxonMobil Exceed XP mLLDPE XP 6056ML in a dry, clean, well-ventilated warehouse at ambient temperature. Keep sealed bags/pallets off the floor and away from direct sunlight, heat, moisture, odors, and incompatible chemicals. Avoid prolonged high temperatures and UV exposure. Use suitable handling equipment, protect packaging from damage/contamination, and follow first-in, first-out stock rotation. |
| Shelf Life | Shelf life is typically two years from date of manufacture when stored in original packaging, dry, cool conditions, away from direct sunlight. |
High-speed form-fill-seal lines converting ExxonMobil Exceed XP 6056ML into heavy-duty shipping sacks operate most predictably when the resin is coextruded as a core layer rather than run as a 100% monolayer. With a melt index of 0.50 g/10 min as determined by ASTM D1238 at 190°C/2.16 kg and a density of 0.916 g/cm³ per ASTM D1505, 6056ML contributes high dart impact and Elmendorf tear resistance but also raises extruder backpressure on grooved-feed blown film extruders with L/D ratios between 25:1 and 30:1. Typical starting formulations blend 20–30 wt% high-pressure LDPE with a melt index of 0.25–0.5 g/10 min into the outer layers to stabilize the bubble and reduce die lip roughness, while the core remains 60–70 wt% 6056ML. Die gaps are held between 2.0 mm and 2.5 mm at blow-up ratios of 2.5:1 to 3.0:1, with frost line heights typically maintained at 8–12 die diameters to prevent excessive transverse direction tear. On lines producing sacks of 80–120 µm, output is frequently limited by extruder motor load and melt temperature rather than bubble cooling capacity. Melt temperature leaving the die should not exceed 220°C because the metallocene resin has a narrow molecular weight distribution and no long-chain branching to dissipate shear. The converted sack, after corona treatment to 38–42 mN/m per ASTM D2578, is printed, gusseted, and sealed on FFS jaw or band sealers. Seal strength measured by ASTM F88 is sensitive to erucamide slip migration, so slip dosage is kept below 1,200 ppm in the seal layer when high seal integrity is required. Pre-drying is not routinely required for 6056ML; however, if bulk silos are stored at ambient temperature and transferred into a warmer extruder room with relative humidity above 60%, surface condensation can occur and should be removed by circulating dry air at 60–70°C for 2–3 hours before processing. Regulatory compliance for food-contact industrial packaging references FDA 21 CFR 177.1520 and EU Regulation (EU) No 10/2011; food-contact status does not extend to non-polyethylene tie layers or masterbatch carriers unless separately evaluated.
Greenhouse film formulations based on 6056ML are designed for multi-season exposure, but the resin itself contains no UV stabilization; the weathering package must be compounded in a separate step or added via masterbatch at the extruder throat. A 36-month service life in a Mediterranean or subtropical climate is normally addressed with a combined stabilizer system containing 0.30–0.60 wt% hindered amine light stabilizer and 0.10–0.30 wt% benzotriazole or triazine UV absorber. The film is typically coextruded in three layers at 150–200 µm total thickness, with the external layer receiving the highest HALS loading because it is exposed to UV radiation, rain, and pesticide condensation. Processing on blown film lines with a 2.0–2.5 mm die gap and a blow-up ratio of 2.0:1 to 2.5:1 is recommended because 6056ML has lower melt strength than LDPE and can become unstable at high blow-up ratios. Elongation retention after weathering is assessed by ISO 4892-2 Xenon arc exposure followed by tensile testing per ISO 527-3; a greenhouse film is generally considered serviceable if longitudinal and transverse elongation at break remain above 50% of the original value after 3,000 hours of accelerated weathering. Pesticide contact imposes an additional boundary condition: sulfur-containing and halogenated pesticides accelerate nickel-quencher-free HALS systems, so films intended for pesticide-intensive cultivation should use a sulfur-resistant stabilizer package or a thicker external layer. Calcium carbonate filler above 5 wt% is avoided because it reduces UV stabilizer effectiveness and shortens screen pack life in extruders with melt filtration. End-use certification for greenhouse film used in the EU falls under EN 13206, which requires minimum tensile, tear, and elongation values, and the film must not contain substances that exceed REACH restrictions.
Extrusion of 25–40 µm silage bale wrap from 6056ML is usually configured as a three-layer blown film because monolayer structures with the resin’s 0.50 g/10 min melt index generate excessive backpressure on conventional single-layer dies and lose cling uniformity under winder tension variations. The core layer, comprising 70–80 wt% of the film, uses 6056ML for puncture resistance. The outer cling layers contain polyisobutylene at 0.5–2.0 wt% or an EVA-based cling masterbatch, but PIB migration into the core is deliberately minimized by keeping the core layer free of tackifier. Blown film processing for silage wrap requires a low frost line and a high blow-up ratio of 2.5:1 to 3.0:1 to balance machine-direction and transverse-direction tear. The die gap is typically 1.8–2.5 mm, and internal bubble cooling is used above 120 kg/h throughput to prevent bubble flutter. Puncture resistance is characterized by ASTM D5748, which applies a rotating probe to the film; this test correlates with the film’s ability to survive stalk stubble when bales are wrapped on side-arm wrappers. For black/white silage wrap, the white outer layer is filled with 6–9 wt% titanium dioxide or a combination of titanium dioxide and calcium carbonate, but carbon black must not be included in the inner cling layer because it can interfere with PIB tack development. Film stretch on wrapping machines is performed at 50–70% pre-stretch; at these ratios, 6056ML-based wrap retains tensile force without the extreme yield behavior of some conventional LLDPE grades. A critical boundary is cold-weather application: at ambient temperatures below 5°C, PIB migration slows, and cling force measured by a slide resistance test may fall below the level required to prevent layer unwinding, so the cling layer should be enriched with PIB or a lower-molecular-weight tackifier. No pre-drying of 6056ML is normally required, but condensation on resin pellets after outdoor storage should be prevented because surface moisture can create melt defects at the die lip. Food-contact compliance is not relevant to this end use, but the film must comply with REACH and the materials used in silage film must not release substances harmful to livestock under national agricultural film regulations.
When 6056ML is coextruded as the sealant web in laminated frozen food packaging, the critical performance parameters are seal initiation temperature, hot tack strength, and resistance to flex cracking at freezer temperatures. In a typical three-layer blown or cast coextrusion, the sealant web uses 5–7 wt% of an ethylene-alpha-olefin plastomer to lower seal initiation to approximately 95–105°C; the 6056ML-rich layer provides high dart impact after lamination to a barrier film of PET, BOPP, or metallized PET. The air side of the sealant web is corona treated to 38–40 mN/m and laminated with solventless polyurethane adhesive at 1.5–2.0 g/m² coat weight. Solventless systems are preferred because the low surface energy of metallocene polyethylene can resist water-based adhesives, leading to green tack failure. Laminated pouches for frozen seafood or prepared foods are subjected to flex-crack testing after low-temperature conditioning at -20°C; the 6056ML-based sealant web resists pinhole formation better than conventional LDPE-rich webs when measured by Gelbo flex testing. Hot tack testing per ASTM F1921 is used on vertical form-fill-seal lines to establish minimum jaw speed. Because 6056ML has a narrow comonomer distribution, hot tack strength remains useful across a seal temperature window of 110–150°C, but published data for this specific configuration is limited. The food-contact status of the sealant web is anchored to FDA 21 CFR 177.1520 and EU Regulation (EU) No 10/2011, but the overall laminate is only compliant if the adhesive and barrier film are also compliant. Operational boundaries include avoiding over-treatment above 44 mN/m on the sealant surface, which can increase adhesion to the back side of the opposite film during storage and cause blocking. Slip and antiblock packages must be formulated at the lower end of their ranges to preserve seal strength.
Stretch hood film for pallet unitization is produced at 60–100 µm thickness in three layers, with 6056ML selected for the core layer when high puncture resistance and stretch force retention are required. The outer layers are usually ethylene-vinyl acetate or ULDPE-rich cling layers containing 0.5–1.5 wt% glycerol mono-oleate or PIB as the cling agent. The 6056ML core occupies 60–80 wt% of the total structure. Blown film lines for stretch hood film run with a blow-up ratio of 2.0:1 to 2.5:1 and a die gap of 2.0–2.5 mm. The low melt index of 6056ML requires a barrel temperature profile from 180°C at the feed throat to 210°C at the die, but the die head is kept below 215°C to avoid free radical degradation of the cling additives. Cold-weather tension retention is evaluated by ASTM D5458, which measures stretch film cling and stretch force after conditioning at -10°C to -20°C. Stretch hood machines apply film at up to 100% transverse stretch and 50–70% machine-direction stretch, so the film must avoid localized thinning at the pallet corners. 6056ML contributes to corner puncture resistance but its higher melt viscosity reduces line throughput on small extruders. A common production bottleneck occurs when extruder screw speed is raised to meet output targets, causing melt temperature to exceed 220°C and producing gel formation or die lip deposit; grooved-feed barrier screws with a mixing section at the discharge end are preferred. Cling layer distribution is asymmetric by design: the outer cling surface is corona treated to 36–38 mN/m, lower than the inward-facing cling surface, to prevent unwinding on high-speed hooders. No food-contact use is implied for industrial stretch hood film, but REACH and RoHS compliance apply to packaging placed on the EU market.
| Regulation/Standard | Scope | Applicability to 6056ML-based films |
|---|---|---|
| FDA 21 CFR 177.1520 | Olefin polymers for food contact | Applicable when the film is used in contact with food under the regulation’s prescribed conditions; final approval is article-specific |
| EU Regulation (EU) No 10/2011 | Plastic materials and articles intended to come into contact with food | Overall migration limit 10 mg/dm² under assigned simulants; compliance is established on the finished film |
| REACH 1907/2006 | Registration, evaluation, authorization, and restriction of chemicals | No SVHC above 0.1 wt% reportable threshold in the resin as supplied, per safety data sheet |
| RoHS 2011/65/EU | Restriction of hazardous substances in electrical equipment | Packaging is outside the direct scope; test targets for Pb, Hg, Cd, Cr(VI), PBB, and PBDE are not expected in the resin |
| EN 13206 | Thermoplastic films for use in agriculture and horticulture | Only applicable to greenhouse and low-tunnel films; requires declared values for tensile, tear, and UV elongation retention |
Coextruded bag-in-box liners for edible oil, dairy concentrates, and aseptic liquid packaging use 6056ML as the inner sealant layer because the grade’s resistance to environmental stress cracking and low extractable profile reduce flex-cracking failures during transport. A five-layer cast or blown structure typically comprises a barrier layer of EVOH or polyamide, two tie layers, and a sealant layer containing 80–100 wt% 6056ML. The sealant layer is maintained at 20–40 µm of a 100–150 µm total liner thickness. Cast coextrusion of 6056ML at 0.50 g/10 min melt index is feasible only when the die and feedblock are designed for medium-viscosity metallocene resins; otherwise, layer-to-layer viscosity mismatch with EVOH can produce flow instabilities and wavy interface defects. Seal integrity for liquid liners is validated by ASTM F88 heat-seal strength after steam sterilization or hot-fill conditions. The sealant layer is sealed to itself at 130–160°C, but slip and antiblock additions must remain below 1,000 ppm to avoid lowering seal burst strength. Food-contact compliance for the 6056ML sealant layer is based on FDA 21 CFR 177.1520 and EU Regulation (EU) No 10/2011; the final liner must also satisfy overall migration testing under simulant D2 or D1 depending on the product type. An operational limitation is the need to avoid excessive melt residence time in cast film barrels because metallocene resins with a narrow molecular weight distribution can develop localized gel accumulation at the feedblock if temperatures exceed 230°C. The film is tested for pinhole resistance and seal burst according to ASTM F2054; target values are product-specific and must be derived from the filling line’s mechanical stress profile. For aseptic applications, the liner must also pass hydrogen peroxide compatibility testing and retain seal integrity after hot-fill and cold-chain distribution cycles.
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ExxonMobil Exceed XP mLLDPE XP 6056ML is a hexene-1-based metallocene-catalysed linear low-density polyethylene supplied as pelleted resin for blown film extrusion. The product is typically characterized by a nominal density of 0.916 g/cm³ when tested under ASTM D1505 and a nominal melt index of 0.55 g/10 min when tested under ASTM D1238 at 190 °C/2.16 kg. Lot-to-lot variation should be checked against the certificate of analysis; density may vary by ±0.002 g/cm³ and melt index by ±0.05 g/10 min without altering the intended film conversion. The grade is used in multilayer food packaging, heavy-duty sacks, form-fill-seal webs, collation shrink, and lamination sealant layers. It carries a standard slip and antiblock package suitable for high-speed packaging equipment, but the exact additive formulation is defined in the manufacturer’s product specification.
The narrow molecular weight distribution and uniform short-chain branching of the metallocene catalyst system produce lower shear thinning than a conventional Ziegler-Natta C6-LLDPE of the same density and melt index. As a result, melt pressure at the die may be higher, and bubble stability is more sensitive to blow-up ratio and frost-line control. The melt temperature at the adapter is normally held between 195 °C and 230 °C. Temperatures below 190 °C may produce unmelts and optical defects, while temperatures above 250 °C may initiate oxidative degradation and increase gel count. Die gap settings between 1.5 mm and 2.5 mm are commonly used; die gaps below 1.2 mm can create excessive shear heating and visible melt fracture. The blow-up ratio is typically set between 2.0:1 and 3.5:1; higher ratios may destabilize the bubble because of the relatively low melt strength of linear metallocene resins. Internal bubble cooling dew point is often controlled between 5 °C and 15 °C to shorten the frost line and improve cooling. Single-screw extruders with 24:1 to 30:1 L/D and barrier screws are generally sufficient for this grade. Grooved feed sections may improve solids conveying but can raise melt temperature if not cooled. Pre-drying is not routinely required when the resin is stored in sealed packaging at ambient relative humidity below 60%. If sacks are opened in humid environments, surface moisture may cause bubble pinholes; drying at 70–80 °C for 2–4 h in a desiccant dryer is a common corrective action.
In a three-layer packaging line configured with a 400 mm annular die, 2.0 mm die gap, and internal bubble cooling, 6056ML is often placed in the sealant layer at 15–25% of total film thickness. When processed at a melt temperature of 210 °C, film haze measured under ASTM D1003 typically remains below 10%; lower melt temperatures can increase haze through incomplete melting or residual crystallinity. Seal initiation temperature is evaluated on laboratory heat-seal equipment under ASTM F1921 or ASTM F2029. Metallocene grades of this class generally initiate sealing approximately 8–12 °C lower than conventional C6-LLDPE of equal density and melt index. This differential allows incremental line-speed gains on vertical form-fill-seal machines, provided the seal jaw dwell time is not reduced below 0.3 s and the jaw temperature is profiled to avoid burn-through at the film overlap. The lower seal initiation temperature also reduces energy demand at the seal bars. For lamination or surface printing, corona treatment should be adjusted to a wetting tension between 38 mN/m and 44 mN/m before gravure or flexographic ink application.
Differences from other products arise primarily from catalyst architecture and comonomer type. Relative to a conventional Ziegler-Natta C6-LLDPE of density 0.916 g/cm³ and melt index 0.55 g/10 min, 6056ML typically exhibits lower n-hexane extractable fraction, lower seal initiation temperature, improved dart drop impact per unit gauge, and better optical uniformity. However, the same metallocene architecture may reduce melt strength and bubble stability at very high blow-up ratios. Compared with a metallocene C4-LLDPE of similar density and melt index, the hexene-1 comonomer in 6056ML generally shifts the impact-tear balance toward higher puncture resistance and improved low-temperature ductility. The magnitude of the shift depends on film gauge, tie-layer selection, frost-line height, and additive package; published data for this specific comparative configuration is limited and should be generated on the target line.
| Property | Typical value | Test method |
|---|---|---|
| Density, resin | 0.916 g/cm³ | ASTM D1505 |
| Melt index | 0.55 g/10 min | ASTM D1238 |
| Melting peak temperature | 114 °C | ASTM D3418 |
| Vicat softening point | 104 °C | ASTM D1525 |
| Tensile strength at yield, MD/TD | 10.5/10.2 MPa | ASTM D882 |
| Tensile strength at break, MD/TD | 55/52 MPa | ASTM D882 |
| Elongation at break, MD/TD | 460/580% | ASTM D882 |
| Dart drop impact, F50 | 1100 g | ASTM D1709A |
| Elmendorf tear strength, MD/TD | 220/300 g | ASTM D1922 |
| Haze | 8% | ASTM D1003 |
Blending with LDPE to improve bubble stability may be acceptable at addition rates up to 20 wt%, but higher levels tend to reduce dart drop impact and seal performance. Use of reprocessed 6056ML at loadings above 10–15 wt% can increase gel counts and should be verified by optical inspection under ASTM D1003. In multilayer structures, 6056ML is frequently used as the sealant or core layer rather than as the outer abuse layer; the outer layer may be a higher-density LLDPE or HDPE to increase stiffness and thermal resistance.
Heavy-duty sack film production typically targets gauge between 80 µm and 200 µm. In such structures, 6056ML is run as the core or inside layer; the outside layer may be a higher-density LLDPE or HDPE for stiffness and downgauging. Dart drop impact measured under ASTM D1709A and Elmendorf tear under ASTM D1922 are used as release criteria. On many converting lines, one specimen is taken every 500 kg of resin consumed; a drop in F50 below 900 g at 25 µm equivalent may indicate contamination, insufficient melting, or poor dispersion of the slip/antiblock package. Low-temperature drop tests at -20 °C are applied for frozen food and industrial sacks. The uniform comonomer distribution of the metallocene hexene grade lowers the ductile-to-brittle transition compared with conventional C4-LLDPE, although the extent of the shift depends on tie-layer thickness and frost-line height. For heavy-duty use, pre-drying at 70–80 °C is required if the resin has been stored in unheated warehouses at relative humidities above 60%. Adding polymer processing aid masterbatch at 0.02–0.05 wt% may be necessary to reduce die lip buildup after extended runs; the exact level is determined by screw design, die condition, and processing history.
Regulatory documentation for food-contact use requires confirmation against the manufacturer’s compliance document. The resin is generally stated to comply with U.S. FDA 21 CFR 177.1520 (c) 3.2a and European Union Regulation (EU) No 10/2011 when the final film meets overall migration limits under EN 1186. For specific food types, users must verify compliance with the appropriate simulant as prescribed in EU 10/2011, particularly fatty-food simulant D2. REACH registration is maintained by the manufacturer; the resin is not expected to contain intentionally added substances of very high concern above 0.1 wt%. The RoHS Directive 2011/65/EU is not directly applicable to food packaging but may apply to packaging components used in electrical and electronic products. Processors should obtain the current product stewardship and food-contact certificates before qualifying 6056ML for commercial applications.