| HS Code | 421994 |
| Melt Index | 1.0 g/10 min (190°C/2.16 kg) |
| Density | 0.918 g/cm³ |
| Melting Point | 119 °C |
| Vicat Softening Temperature | 96 °C |
| Tensile Strength At Yield | 9.7 MPa |
| Tensile Strength At Break | 31 MPa |
| Elongation At Break | 600% |
| Flexural Modulus | 210 MPa |
| Dart Drop Impact | 300 g |
| Elmendorf Tear Strength Md | 200 g |
| Elmendorf Tear Strength Td | 350 g |
| Haze | 7% |
| Gloss 45 | 65 |
| Coefficient Of Friction | 0.20 |
As an accredited ExxonMobil Exceed mLLDPE 1018MK factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.
| Packing | ExxonMobil Exceed mLLDPE 1018MK supplied in 25 kg polyethylene-lined bags, palletized; each pallet contains 1,000 kg (40 bags). |
| Container Loading (20′ FCL) | ExxonMobil Exceed mLLDPE 1018MK in 25 kg polyethylene bags, palletized, loaded into a 20′ FCL; approximately 22 MT net weight. |
| Shipping | ExxonMobil Exceed mLLDPE 1018MK is shipped as non-hazardous polyethylene resin pellets in moisture-resistant 25 kg bags, bulk bags, or bulk trucks/railcars. Transport in clean, covered vehicles. Store dry, away from heat, sunlight, moisture, contamination, and ignition sources. No special DOT/IMDG/IATA hazardous classification. |
| Storage | Store ExxonMobil Exceed mLLDPE 1018MK in a cool, dry, well-ventilated area, away from direct sunlight, heat, sparks, flames, and strong oxidizers. Keep original containers closed and off the floor to prevent moisture, dust, and contamination. Avoid prolonged UV exposure. Do not store near food or incompatible materials. Follow local regulations and the supplier’s safety data sheet. |
| Shelf Life | No specific shelf life; stable under normal storage conditions. Store cool, dry, well-ventilated, in original packaging away from direct sunlight. |
Across 65 mm single-screw blown film lines with a 30:1 L/D barrier screw and a 250 mm spiral mandrel die, Exceed 1018MK is processed at melt temperatures from 199°C to 215°C for heavy-duty industrial sacks and FIBC inner liners. The resin has a nominal density of 0.918 g/cm³ and a melt index of 1.0 g/10 min at 190°C/2.16 kg determined by ISO 1133-1. In 70/30 and 80/20 blends of Exceed 1018MK with fractional-melt LDPE, the die gap is set from 1.8 mm to 2.3 mm. Blow-up ratio is maintained between 2.5:1 and 2.8:1, and frost line height is held at 6 to 8 die diameters. Screw speeds on 65 mm extruders typically range from 60 rpm to 90 rpm, with melt pressure upstream of the screen changer kept below 350 bar to reduce gel formation and melt-temperature overtemperature. Finished film thickness ranges from 50 µm to 150 µm, depending on sack size and filling speed. Heavy-duty sack specifications require dart drop impact testing per ASTM D1709, Elmendorf tear per ASTM D1922, and tensile properties per ASTM D882. Converters frequently qualify an 80 µm film with a minimum dart drop F50 of 800 g for chemical packaging. Actual values depend on the LDPE fraction, the LDPE density, and the lot-specific slip and antiblock package. Compliance for industrial chemical liners includes REACH Regulation (EC) No 1907/2006 and amine-free process-aid declarations. The main processing boundary is that a die gap below 1.5 mm may raise die-lip shear stress above the critical range for metallocene melt fracture, producing surface roughness on the inner sack wall. Finished products include heavy-duty shipping sacks for polymer compounds, FIBC inner liners, and flat-bottom valve bags used in construction chemical filling.
Because slip-agent migration becomes measurable at deep-freeze temperatures, seal windows are validated on production film after 72 h ageing at -20°C, not on laboratory film conditioned at room temperature. That procedural constraint determines whether a three-layer blown film containing Exceed 1018MK can be certified for IQF vegetable and frozen seafood packaging. The core layer is typically 60 wt% of the structure, the outer layer is high-clarity LDPE, and the seal layer is a 1018MK-rich formulation with a low-seal-initiation polyolefin plastomer. Melt temperature is controlled between 193°C and 204°C. Die gap is set at 1.8 mm. Blow-up ratio is 2.5:1. Film thickness is set from 40 µm to 70 µm depending on bag size and fill speed. Seal strength is measured per ASTM F88/F88M-21 after a dwell time of 0.5 s and a jaw pressure of 0.3 MPa. Hot-tack performance is measured per ASTM F1921 on vertical form-fill-seal lines. Coefficient of friction against stainless steel is measured per ISO 8295 after conditioning at -20°C. Food-contact compliance is validated under FDA 21 CFR 177.1520 and Commission Regulation (EU) No 10/2011, with migration testing performed under frozen-food use conditions. The medium-slip formulation allows transport through horizontal form-fill-seal machinery, but slip agent migrates gradually to the surface. Low-temperature storage retards further migration, so the kinetic coefficient of friction measured after 72 h may differ from the value at 24 h. Converters therefore set film-to-metal friction specifications only after conditioning at -20°C for the planned shelf-life interval. A known boundary is that anti-fog additives added for frozen vegetable films may compete with slip-agent migration and alter the seal initiation curve measured by ASTM F88/F88M-21. Finished goods are frozen vegetable pouches, IQF fruit bags, and seafood block overwraps.
A five-layer blown film structure is configured with Exceed 1018MK in the 70 wt% core and polyolefin elastomer skins when finished silage bale wrap must survive puncture from maize stalk ends and prolonged UV exposure. On a five-layer oscillating haul-off line, individual extruders are set to give a layer ratio of 1:1:3:1:1. The two outer skins contain a UV stabilizer masterbatch based on a HALS/UV-absorber system; the core and sub-skin layers carry the load-bearing Exceed 1018MK phase. Feedblock and spiral mandrel die temperatures are held at 199°C to 210°C. Die gap is 2.0 mm. Blow-up ratio ranges from 2.3:1 to 2.7:1. Finished bale wrap is produced at 25 µm to 40 µm. Accelerated weathering is assessed by ISO 4892-2 cycles at 0.55 W/m² at 340 nm; acceptance is normally based on retention of tensile elongation at break after 2000 h. Puncture resistance is tested by a low-speed puncture probe and by field tear initiation on bale wrappers. The UV package addition is set by final film thickness and expected field residence time; typical masterbatch loadings in the outer skins start at 8 wt% and may exceed 12 wt% for multi-season films. Published data for this specific five-layer configuration is limited, so field validation on the target bale wrapper is required before commercial qualification. Exceed 1018MK is not recommended as an oxygen-barrier silage layer without a polyamide or EVOH core because the polyolefin backbone provides only limited oxygen resistance. The terminal products are round-bale silage wrap, square-bale cover sheeting, and temporary silage pit liners.
Extrusion lamination of metallized polyester to a polyethylene sealant web places two conflicting demands on the resin: melt strength for draw-down and low seal-initiation temperature for package sealing. The use of Exceed 1018MK as a sealant layer in laminated pouches therefore occurs predominantly as a blend with autoclave LDPE of melt index 4 g/10 min to 8 g/10 min. A typical blend is 30 wt% Exceed 1018MK and 70 wt% LDPE. The blend is processed on an extrusion coating laminator equipped with a 90 mm single-screw extruder, an air gap of 100 mm to 200 mm, and a chill roll maintained at 15°C to 20°C. Melt temperature at the die is set from 280°C to 305°C to reduce neck-in. Line speed is limited by draw resonance; commercial lines running this class of blend typically begin at 80 m/min and adjust based on edge bead quality. The resulting sealant layer is corona treated to a surface tension of 42 mN/m to 48 mN/m before lamination to aluminum foil or metallized polyester film. Lamination bond strength is determined by ASTM F904, and seal strength is measured according to ASTM F88/F88M-21. Seal temperatures from 100°C to 130°C are validated because the metallocene phase contributes to seal initiation below the melting point of the LDPE fraction. Compliance is required under FDA 21 CFR 177.1520 for dry food contact and under EU Regulation (EU) No 10/2011 for export packaging. The main limitation is that neat Exceed 1018MK does not provide the draw-down stability of LDPE at high line speed; a blend content above 50 wt% may cause edge instability and unacceptable neck-in. Finished products include dry-mix pouch laminations, single-serve beverage sachets, and lidstock sealant layers for condiment cups.
The condition under which haze retention is achievable is a three-layer structure in which the Exceed 1018MK core is protected by EVA skin layers carrying anti-fog and UV stabilizer concentrates. Greenhouse film produced at 80 µm to 200 µm on a three-layer blown film line uses a layer distribution of 1:2:1. The core is 100 wt% Exceed 1018MK; the skins are EVA with vinyl acetate content from 9 wt% to 14 wt%. Blow-up ratio is set at 2.0:1 to 2.4:1. Die gap is 2.0 mm to 2.5 mm. Melt temperatures are limited to 180°C to 195°C in the skin extruders to avoid EVA degradation and 195°C to 205°C in the core extruder. Haze and total luminous transmittance are measured by ASTM D1003-21. The anti-fog package is added to the inner skin only; its migration to the film surface is monitored by condensation testing under simulated greenhouse conditions. The UV package is added to the outer skin. For multi-season greenhouse film, the outer skin loading of HALS-based masterbatch is raised, and tensile retention after ISO 4892-2 weathering becomes the critical specification. The presence of medium antiblock in Exceed 1018MK modifies initial haze; greenhouse films requiring very low haze may need a separate clarity grade or a second metallocene resin without antiblock. This is a specific operational boundary: 1018MK is suited to greenhouse film where a balance of toughness and handling is more important than the lowest possible haze. Finished products include tunnel covers, greenhouse cladding, and low-tunnel row covers.
Pallet stretch-hood applications select Exceed 1018MK because the resin contributes dart impact resistance and tensile yield to a film that must recover elastically around a loaded pallet after being heated and stretched. In a three-layer blown film line with a 250 mm die and internal bubble cooling, the structure is produced at 60 µm to 120 µm. The outer skins contain a polyolefin elastomer and Exceed 1018MK in a 1:1 ratio, while the core is 100 wt% Exceed 1018MK. Extruder temperatures are set between 190°C and 205°C. Blow-up ratio is 3.0:1 to 3.5:1 to balance transverse direction stretch and machine direction modulus. The film is converted on stretch-hood machinery that pre-stretches the hood by 80% to 110% before application. Holding force is measured by load retention testing, and mechanical properties are evaluated by ASTM D882 for tensile modulus and ASTM D1709 for impact at low gauge. Compliance for industrial packaging is based on REACH Regulation (EC) No 1907/2006; food-contact status is not applicable to most pallet hoods. The limitation is that the medium-slip package may reduce film-to-film friction below the level needed for stable pallet stacking. Converters may adjust the slip package or add an antiblock concentrate at the hopper to tune coefficient of friction. Finished products are pallet stretch hoods for bagged cement, brick packs, and chemical drums.
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ExxonMobil Exceed mLLDPE 1018MK is a metallocene-catalyzed linear low-density polyethylene resin supplied for blown film, cast film, and extrusion coating applications. The numerical portion of the grade designation, 1018, corresponds to a nominal melt index of 1.0 g/10 min at 190°C under 2.16 kg load and a nominal density of 0.918 g/cm³. The suffix MK identifies the supplied additive package, which may include slip and antiblock agents; the exact slip and antiblock concentrations are lot-specific and listed on the certificate of analysis. The base polymer is generally categorized as an ethylene-hexene mLLDPE, although full comonomer disclosure should be confirmed against the safety data sheet and product specification. The metallocene catalyst system generates a narrower molecular weight distribution and more homogeneous short-chain branching than conventional Ziegler-Natta LLDPE of similar melt index and density. These structural features affect die pressure, shear thinning, bubble stability, seal initiation, dart impact, tear, and optical haze. Typical end uses include general-purpose packaging films, agricultural films, lamination films, and sealant layers in flexible packaging. Because the resin does not exhibit the pronounced shear thinning of high-pressure LDPE, extrusion lines may require die gap or melt temperature adjustment to avoid melt fracture.
| Parameter | Standardized method | Nominal value |
|---|---|---|
| Melt index | ASTM D1238 / ISO 1133-1:2022, 190°C, 2.16 kg | 1.0 g/10 min |
| Density | ASTM D1505 / ISO 1183-1 | 0.918 g/cm³ |
| Melting peak | ASTM D3418 / ISO 11357-3 | approximately 119°C |
| Physical form | visual inspection | pellets |
| Antioxidant and processing additive package | internal specification; lot certificate of analysis | as supplied |
These values define the inbound resin specification but do not alone predict film performance. Melt index measured under 2.16 kg is a single-point rheological parameter and does not capture the reduced shear thinning of the narrow molecular weight distribution. Density is determined on compression-moulded specimens after conditioning at 23°C. The melting peak is referenced to a standard heating rate, and the exact endotherm position may shift by 1°C to 2°C depending on heating rate and production campaign. Users should verify lot-specific values before setting extrusion profiles.
In blown film conversion, the practical upper output rate for Exceed 1018MK is often limited not by extruder drive but by melt fracture at the annular die lip and bubble instability in the haul-off region. The narrow molecular weight distribution inherent to metallocene catalysis reduces the shear-viscosity dependence on shear rate. A conventional Ziegler-Natta LLDPE with the same 1.0 g/10 min melt index may show a greater viscosity reduction at die-lip shear rates of 500 s⁻¹ to 1500 s⁻¹. Consequently, the mLLDPE may generate higher die pressure and a lower critical shear rate for sharkskin at the same die gap and melt temperature. Production-scale lines with 45 mm to 75 mm barrier screws at L/D ratios of 24:1 to 30:1 commonly set melt temperatures between 190°C and 220°C. Published data for this specific configuration is limited; line trials often require widening the die gap from 1.5 mm to 2.0 mm or from 2.0 mm to 2.5 mm and increasing die temperature by 5°C to 10°C to lower shear stress at the lip. If surface haze and melt fracture cannot be resolved by thermal adjustments, fluoropolymer processing-aid addition may be evaluated, but the MK package may already contain processing aid; duplicate addition should be avoided unless verified by trial.
Bubble stability is governed by melt strength and extensional strain-hardening. Unlike high-pressure LDPE with long-chain branching, the mLLDPE has comparatively weaker extensional viscosity growth at high deformation rates. At blow-up ratios above 2.5:1 or frost-line heights beyond 1.0 m, bubble sway and draw resonance can occur unless auxiliary internal bubble cooling or stabilizing cages are used. The common industrial practice is to blend 10 wt% to 20 wt% high-pressure LDPE into the mLLDPE to restore bubble stability and improve shear thinning. However, each 10 wt% LDPE addition may shift optical and seal-initiation properties. Blend optimization should therefore include film tensile measured per ASTM D882, dart impact per ASTM D1709A, coefficient of friction per ASTM D1894, and melt index after blending per ASTM D1238.
Seal initiation, optics, and extractables diverge from Ziegler-Natta LLDPE because comonomer incorporation is more statistically uniform. In conventional LLDPE, the broader distribution of short-chain branches broadens the crystallite thickness distribution, pushing the onset of sealing toward higher temperatures and increasing the fraction of low-molecular-weight material available for migration. In Exceed 1018MK, the density of 0.918 g/cm³ and homogeneous branching generally produce lower seal initiation and hot-tack onset when measured on vertical form-fill-seal equipment. The relevant test methods are ASTM F1921 for seal initiation temperature and hot tack, ASTM F88 for seal strength, ASTM D1003 for haze, ASTM D2457 for gloss, and ASTM D1894 for coefficient of friction. The MK additive package may alter blocking and slip characteristics; blocking force can be measured per ASTM D3354, and wetting tension after corona treatment can be checked per ASTM D2578.
Compared with other Exceed suffix grades based on a similar base polymer, Exceed 1018MK should not be treated as a drop-in replacement solely on the basis of density and melt index. The additive package modifies surface friction, blocking, and possibly processing-aid response. A change from one suffix to another should be validated on the target packaging line using the applicable film test matrix. Quantitative catalyst residue limits are not ordinarily published in single-page datasheets; extractives compliance is instead demonstrated on the finished article under the intended use conditions.
| Film characteristic | Exceed 1018MK mLLDPE | Ziegler-Natta LLDPE | High-pressure LDPE | Primary test method |
|---|---|---|---|---|
| Molecular weight distribution | narrow; polydispersity index often below 3.0 | broad; polydispersity index often 4.0 to 6.0 | broad, with long-chain branching | gel permeation chromatography; internal specification |
| Shear thinning at die-lip rates | moderate to low | moderate | strong | capillary rheology |
| Seal initiation temperature at equal density | lower | higher | lower to comparable dependent on density | ASTM F1921 |
| Dart impact at 25 µm | high, validated by ASTM D1709A | moderate | moderate to low | ASTM D1709A |
| Haze in thin film | low to moderate depending on additives | moderate to high | low | ASTM D1003 |
| Bubble stability at blow-up ratio above 2.5:1 | lower without LDPE blending | moderate | high | blown-film trial |
When Exceed 1018MK is placed as the innermost sealant layer in a coextruded barrier structure, the layer adjacent to the product is typically 15 µm to 30 µm thick in a total film of 50 µm to 120 µm. The core may be polyamide, ethylene-vinyl alcohol, or high-density polyethylene, with tie layers of maleic anhydride-grafted polyolefin. The mLLDPE sealant layer generally provides lower seal initiation temperature and better sealing through wet meat or powder contamination than an HDPE sealant layer, while the outer structure supplies stiffness and oxygen barrier. Interlayer adhesion is typically measured by 180° peel according to ASTM D1876 or ISO 11339; absolute adhesion values depend on tie resin chemistry and corona treatment. If the mLLDPE skin is corona-treated to 38 mN/m to 42 mN/m per ASTM D2578 before lamination or printing, oxidation products can lower surface tension over time; lamination should be performed within a time window determined by trial. For high-speed form-fill-seal operations, hot-tack strength measured per ASTM F1921 is a more relevant predictor of package integrity than ambient seal strength alone.
On a three-layer line with 50 mm skin extruders and an 80 mm core extruder, the mLLDPE skin melt pump should be operated with a melt temperature not exceeding 220°C to limit head-pressure variation. If the skin layer is starved or cooled at the die lip, gauge uniformity measured by ASTM D374 can degrade. In blown film coextrusion, the bubble may be less stable because the mLLDPE skin has lower melt strength than an HDPE core; reducing blow-up ratio to 2:1 to 2.5:1 and maintaining gear-pump-controlled layer distribution may improve layer uniformity.
Resin storage should be maintained at ambient temperatures below 50°C and protected from direct sunlight. Polyethylene is not hygroscopic and generally does not require predrying; however, condensation on cold pellets moved into a warm, humid plant can cause hopper bridging and feed-rate variation. If the resin has been stored below dew point, allow it to equalize in closed sacks or use hopper-carrier purging with dry air. Prolonged exposure to temperatures above 70°C accelerates antioxidant consumption and may reduce oxidative-induction time measured by ASTM D3895. Sustained melt temperatures above 240°C for more than 5 min should be avoided unless nitrogen purge protects the feed throat and hopper; residence time at these temperatures can generate oxidation products that cause gels and organoleptic shifts. The safety data sheet should be reviewed for composition and regulatory information. For food-contact applications, the final article is typically assessed under 21 CFR 177.1520 for olefin polymers in contact with food in the United States and under Regulation (EU) No 10/2011 in the European Union. Specific migration testing is formulation-specific and must be performed on the finished package under the intended food simulant, time, and temperature conditions. REACH and RoHS status should be confirmed through the supplier’s regulatory bulletin or safety data sheet.
Cast film and extrusion coating lines can process Exceed 1018MK without the bubble stability constraints of blown film. Melt temperature is often set 10°C to 20°C higher in cast film to reduce draw resonance, but the narrow molecular weight distribution may still require die-gap adjustment. Extrusion coating onto paper or aluminum foil should be evaluated for adhesion because the absence of polar functionality limits direct adhesion to aluminum and paper; corona treatment or adhesion promoters are required. For lamination applications, the lower density contributes to sealability but may require higher chill-roll temperature to control curl.