| HS Code | 427957 |
| Polymertype | Very Low Density Polyethylene (VLDPE) |
| Catalyst | Metallocene |
| Comonomer | Butene |
| Density | 0.920 g/cm3 |
| Meltindex | 1.0 g/10 min (190°C/2.16 kg) |
| Meltingpoint | 119 °C |
| Crystallizationtemperature | 103 °C |
| Vicatsofteningpoint | 95 °C |
| Brittlenesstemperature | < -70 °C |
| Tensilestrengthatyield | 9.0 MPa |
| Tensilestrengthatbreak | 34.0 MPa |
| Elongationatbreak | 600% |
| Secantmodulus1percent | 172 MPa |
| Hardnessshored | 50 |
| Dartdropimpact | 300 g |
| Elmendorftearmd | 200 g |
| Elmendorfteartd | 400 g |
| Haze | 7% |
| Gloss | 65% |
As an accredited ExxonMobil Enable VLDPE 2010CB factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.
| Packing | Packaged in 25 kg polyethylene-lined woven bags, 55 bags per pallet; each pallet contains 1,375 kg for bulk handling. |
| Container Loading (20′ FCL) | ExxonMobil Enable VLDPE 2010CB loaded in a 20′ FCL container, packed in bags on pallets, stowed and secured for ocean shipment. |
| Shipping | ExxonMobil Enable VLDPE 2010CB is typically shipped as dry resin pellets in sealed moisture-barrier bags, boxes, or bulk containers. Use standard freight; protect from moisture, heat, sunlight, and contamination; avoid package damage; store cool, dry, and ventilated; follow the SDS and local regulations. |
| Storage | Store ExxonMobil Enable VLDPE 2010CB in a cool, dry, well-ventilated area away from direct sunlight, heat, sparks, flames, and strong oxidizers. Keep containers closed and labeled, and protect resin from moisture, dust, and contamination. Prevent pellet spills and follow the supplier SDS and local regulations. |
| Shelf Life | Typical shelf life is 2 years from manufacture when stored unopened in original packaging under dry, ambient conditions. |
Within vertical form-fill-seal converted frozen vegetable packaging, the sealant layer is subjected to repeated thermal impulses during the sealing process, typically reaching contact temperatures of 85°C to 120°C and then cooling under product weight before the pouch is case-packed. A metallocene very-low-density polyethylene such as Enable 2010CB, with density 0.902 g/cm³ and melt index 1.0 g/10 min measured to ASTM D1238-20, provides an earlier seal initiation onset and a wider hot-tack plateau than a conventional butene LLDPE of equivalent melt index, which reduces rejected packages during high-speed VFFS conversion. The food-contact compliance framework for this application is governed by FDA 21 CFR 177.1520(c) for olefin polymers and by EU 10/2011, Article 17, with an overall migration limit of 10 mg/dm²; converters typically require an updated REACH SVHC declaration covering the compounded grade. In a representative three-layer blown-film structure, the sealant layer is formulated with 70-100 wt% Enable 2010CB, with the balance selected from a low-density polyethylene or a fractional-MI LLDPE to adjust tack and gouge resistance, while the core layer comprises 40-60 wt% of the total film thickness using an octene LLDPE for puncture resistance. The film is produced on an internal bubble cooling blown-film line with 75-mm grooved-feed extruders at L/D 30:1, a dual-lip air ring, die gap 2.0-2.4 mm, blow-up ratio 2.2-2.8:1, and frost line height controlled to 4-6 die diameters; the bubble is held above the air-ring lock point to prevent melt fracture in the VLDPE layer. Finished pouches in the 400-750 g capacity range for frozen peas, maize, and spinach are converted at 60-80 packages/min, with seal strength verified to ASTM F88/F88M-21 and channel leaks detected to ASTM F1929-15.
In tandem extrusion coating of aluminium foil and metallised PET snack laminates, Enable 2010CB is melt-pumped through a deckled slot die and oxidised at the die exit with ozone to generate polar carbonyl species that promote adhesion to the metal surface. The lower density and narrow composition distribution of the metallocene VLDPE allow coating weight reductions of 2-4 g/m² relative to LDPE in some structures, but the melt curtain must be maintained within ±5°C of the target melt temperature because neck-in and edge-bead variation become unacceptable with larger thermal drift on a 90-mm single-screw extruder of L/D 30:1. The polymer coating is normally run neat at 100 wt% Enable 2010CB, or as an 80/20 blend with LDPE when lower melt tension is required for wide-web stability; coat weight is specified at 20-35 g/m² on a substrate of aluminium foil or metallised PET at 7-12 μm. The coating line operates at melt temperature 290-315°C, chrome chill-roll temperature 15-20°C, and line speed 150-300 m/min, with the substrate pre-treated by corona discharge to 42-48 dynes/cm. Food-contact compliance is assessed under FDA 21 CFR 177.1520(c) for the polyolefin layer and under EU 10/2011, Article 17, with an overall migration limit of 10 mg/dm², while specific migration limits for additives carried in the compounded grade are verified against the Union list. Finished packages include three-side-seal stick packs for roasted snacks and lidding films for thermoformed PP or PET trays, where seal strength is measured to ASTM F88/F88M-21 and hot tack to ASTM F1921/F1921M-14.
| Regulatory or test framework | Code or clause | Measured parameter | Relevance to 2010CB snack laminate sealant |
|---|---|---|---|
| US FDA olefin polymer food-contact | 21 CFR 177.1520(c) | Extractables under end-use conditions | Condition-specific compliance for lidding and stick-pack sealant layer |
| EU plastics food-contact | EU 10/2011, Article 17 | Overall migration | ≤ 10 mg/dm² |
| US seal strength | ASTM F88/F88M-21 | Peak seal force | Verification after lamination and VFFS conversion |
| US hot tack | ASTM F1921/F1921M-14 | Hot seal strength | Sealing window before laminate delamination |
Machine-direction edge tear in high-speed cast pallet-wrap film is controlled by the short-chain branching distribution and density of the ethylene copolymer; lowering the sealant-layer resin density to 0.902 g/cm³ with Enable 2010CB shifts puncture failure from brittle crack propagation to ductile elongation under ASTM D5748-95(2012). In five-layer cast stretch film, 2010CB is typically added to the two outer A layers at 10-30 wt% of the layer recipe, with the balance an octene or hexene LLDPE, while the C core remains a high-strength hexene LLDPE at 30-40 wt% of the total structure, giving an overall 2010CB addition of 2-10 wt% in the finished film. The cast process uses a slot die gap of 2-3 mm, melt temperature 240-270°C, chill-roll temperature 18-25°C, and line speed 300-600 m/min; machine film is pre-stretched to 200-300% before wrapping. On production lines running VLDPE-containing formulations, batch-to-batch melt index drift above 0.1 g/10 min alters chill-roll release and can induce telescoping, so at least one driven auxiliary roll and a taper tension profile of 40-60% across the roll width are required. Compliance for secondary packaging is anchored to EN 13698-1 for pallet-wrap film dimensional and performance classification, with REACH Annex XVII restricted-substance screening and an SVHC declaration required when wrapped pallets enter EU food-manufacturing areas; direct food-contact compliance is not needed unless the film is used as a primary food contact overwrap. Finished products include 12-35 μm machine pallet wrap and hand wrap, where puncture resistance is measured to ASTM D5748-95(2012) and cling is quantified to ASTM D5458-95(2012).
In a terminally sterilised barrier pouch, the VLDPE sealant layer must retain a seal strength above 1.5 N/15 mm after exposure to 25-50 kGy gamma irradiation; radiation-induced free-radical recombination in the amorphous region of Enable 2010CB can produce localised crosslinking and a measurable reduction in elongation at break if the stabiliser package is not formulated for radiation tolerance. Published data for this specific 2010CB configuration under all sterilisation dose rates is limited, so end users must verify post-irradiation seal strength and delamination resistance on their own converting line. For a three-layer cast coextruded pouch, the sealant layer is formulated with 70-100 wt% Enable 2010CB, with the outer abuse layer compounded from HDPE or polypropylene; when a peelable seal is not required, the sealant layer can be run neat at 100 wt%. Slot-die cast film is produced in an ISO 14644-1 Class 8 cleanroom, with melt temperature 210-250°C, die gap 1.5-2.0 mm, and film gauge 40-80 μm. Lidding film for PETG trays is heat-sealed at 120-150°C with 0.3-0.7 MPa seal pressure and 0.5-1.5 sec dwell. The finished sterile barrier system is validated to ISO 11607-1:2019 and ISO 11607-2:2019; seal strength is measured to ASTM F88/F88M-21; dye penetration integrity is tested to ASTM F1929-15; radiation sterilisation dose is established under ISO 11137-1:2006/Amd 1:2018; and biocompatibility screening follows ISO 10993-5:2009 and ISO 10993-10:2010. Finished packages include double-pouch sterile barrier systems for surgical kits, catheter pouches, and lidding films for PETG or polystyrene trays; the material is not recommended for primary liquid-drug containers requiring multi-year shelf-life because post-sterilisation long-chain branching can lower impact strength at -20°C.
Below -20°C, polypropylene homopolymer parts show a ductile-to-brittle transition in injection-moulded weld lines and living hinges; the addition of a metallocene VLDPE with density 0.902 g/cm³ and melt index 1.0 g/10 min creates a secondary rubbery phase that absorbs impact energy without the high glass-transition penalty of ethylene-propylene rubber. In automotive interior and appliance compounds, Enable 2010CB is added at 10-30 wt% by dry blending with PP homopolymer and 0.05-0.15 wt% processing stabiliser before compounding; below 10 wt% the low-temperature impact improvement is marginal, while above 30 wt% the tensile modulus of unfilled systems can fall sufficiently to alter part deflection under load. Compounding is performed on a co-rotating twin-screw extruder with L/D 40:1, screw speed 300-600 rpm, barrel temperatures 180-220°C, and a strand pelletiser; dispersion is improved when the PP and 2010CB pellets are fed together at the main throat rather than side-stuffed, because side-stuffing can induce phase inversion if the melt seal is lost at the feed port. Automotive interior compounds are screened to VDA 277 for total volatile organic compound emissions, ISO 3795 or FMVSS 302 for horizontal burn rate, and REACH Annex XVII restricted-substance limits; no direct food-contact claim applies in this segment. Finished parts include pillar trim, door panel inner carriers, battery covers, and appliance housings, where notched Izod impact is measured to ASTM D256-10(2018) at -30°C and Charpy impact to ISO 179-1:2010. Published data for this specific 2010CB-modified PP configuration is limited; end users should conduct a design-of-experiments study on their own compounding line to establish the exact impact-modulus balance and injection-moulding shrinkage envelope.
For form-fill-seal sacks used to package polymer granules, mineral fillers, and pet food, the film must withstand automated drop testing after filling at 25-50 kg gross mass; Enable 2010CB is preferentially placed in the core layer to increase impact and puncture resistance without reducing the external surface coefficient of friction required on sack-converting mandrels. A standard three-layer FFS film of 120-180 μm thickness uses a core layer containing 20-40 wt% Enable 2010CB blended with a high-strength hexene or octene LLDPE, while the two outer layers are HDPE-rich and contain 10-20 wt% LLDPE for seal strength and abrasion resistance. Blown-film production employs a three-layer internal bubble cooling line with die gap 2.0-2.5 mm, blow-up ratio 1.8-2.4:1, and gusseted reel winding; the lower melt stiffness of the VLDPE-containing core requires a die lip temperature 5-8°C lower than the LLDPE-rich outer layers to avoid bubble sag and gauge bands. Industrial packaging is assessed for drop resistance to ISO 7965-2:1993, trouser tear to ISO 6383-2:1983, and dart impact to ASTM D1709-15a; REACH and CLP hazard classification apply to the filled goods rather than the sack film itself unless direct food contact is claimed. Finished sacks are converted on FFS lines at 1,800-2,200 sacks/hour and are used for free-flowing granular products, where the 20-40 wt% core addition improves drop performance at stack heights from 3-5 m.
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