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Exelene PP Homopolymer H3500

    • Product Name: Exelene PP Homopolymer H3500
    • Factroy Site: Yudu County, Ganzhou, Jiangxi, China
    • Price Inquiry: admin@ascent-chem.com
    • Manufacturer: Ascent Petrochem Holdings Co., Limited
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    Specifications
    HS Code 679252
    Density 0.90 g/cm³
    Melt Flow Rate 35 g/10 min (230°C, 2.16 kg)
    Tensile Strength At Yield 36 MPa
    Elongation At Yield 10%
    Flexural Modulus 1400 MPa
    Izod Impact Strength Notched 23 C 3.2 kJ/m²
    Rockwell Hardness R100
    Vicat Softening Temperature 155 °C
    Heat Deflection Temperature 0 45 Mpa 105 °C
    Melting Point 165 °C

    As an accredited Exelene PP Homopolymer H3500 factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing Exelene PP Homopolymer H3500 is packaged in 25 kg multi-wall paper bags with a polyethylene liner for safe handling and moisture protection.
    Container Loading (20′ FCL) 20' FCL: 25kg PP woven bags, approximately 1000 bags, 25 metric tons per container, palletized and shrink-wrapped for safe transit.
    Shipping Exelene PP Homopolymer H3500 ships as non-hazardous polypropylene resin in moisture-proof PP/PE-lined woven bags, palletized and stretch-wrapped for stability. Use covered, dry, well-ventilated containers. Avoid exposure to rain, excessive heat, or direct sunlight during transit and storage to preserve product quality and prevent bag damage.
    Storage Store Exelene PP Homopolymer H3500 in a cool, dry, well-ventilated area, away from direct sunlight, heat, and ignition sources. Keep containers tightly sealed to prevent moisture pickup and contamination. Avoid generating dust; use proper grounding to prevent static discharge. Follow manufacturer guidelines and maintain good housekeeping during storage.
    Shelf Life Store in original packaging, cool and dry, away from sunlight and heat. Shelf life is typically 12 months from date of delivery.
    Application of Exelene PP Homopolymer H3500

    In thin-wall injection moulding of food-contact containers, melt flow consistency at a nominal MFR 3.5 g/10 min (ASTM D1238, 230 °C/2.16 kg) directly governs the minimum achievable wall thickness and demoulding cycle time for transparent tubs and cups. Compliance with FDA 21 CFR 177.1520(c)2.1 and EU Regulation No 10/2011 (overall migration limit 10 mg/dm²) is maintained when the stabilised homopolymer is processed with a pre-compounded additive package consisting of 0.25 wt% sorbitol-based clarifying agent (e.g., Millad NX 8000), 0.08 wt% primary phenolic antioxidant, 0.08 wt% phosphite secondary antioxidant, and 0.05 wt% calcium stearate as acid scavenger. The formulation is dry-blended and fed directly into a high-speed injection moulding machine equipped with a general-purpose screw of L/D 22:1, maintaining barrel temperature zones from 210 °C (feed) to 245 °C (nozzle), with hot-runner manifold set at 235 °C and mould temperature held at 25–30 °C to accelerate solidification and achieve haze levels below 15 % on 1.2 mm wall sections. Pre-drying at 80 °C for 2 hours is mandatory only when resin has been exposed to ambient relative humidity above 60 % for more than 24 hours; failure to observe this results in surface silver streaks on the finished sidewalls. Terminal products include microwave-safe dessert beakers with snap-on lids, stackable dairy cups tolerant of hot-fill temperatures up to 95 °C, and rectangular meal-prep containers that withstand repeated dishwasher cycles without crazing when processed with this specific nucleated homopolymer system.

    How Does H3500 Extruded Sheet Respond to Large-Area Thermoforming Stress?

    Extruded sheet from H3500 exhibits a pronounced tendency to sag when heated above the crystalline melting point during the forming cycle; mitigating this requires blending the base homopolymer with 3 wt% of a high-melt-strength polypropylene grade grafted with long-chain branches, whose branching index measured by intrinsic viscosity ratio yields an RSI value of 1.8 at 190 °C. This modification elevates the zero-shear viscosity to approximately 12 000 Pa·s, thereby restricting sheet deformation under its own weight during the 30–45 second radiant heating phase. Direct food-contact sheet intended for chilled-meal trays must additionally conform to the same FDA 21 CFR 177.1520 and EU 10/2011 migration thresholds, with specific migration limits for the clarifying agent validated by EN 1186 total immersion testing in 3% acetic acid and 50% ethanol simulants. Sheet extrusion is performed on a single-screw extruder with a barrier screw profile (L/D 30:1) fitted with a flat die having a 1.5 mm lip gap, and a three-roll polishing stack temperature profile of 80/90/80 °C to produce 0.8–1.5 mm gauge sheet with a thickness tolerance of ±0.03 mm. Thermoforming employs a plug-assisted process using aluminium tooling heated to 110 °C, with plug speed profiling that delays material contact to avoid precooling marks on translucent polypropylene. Final article inspection under ASTM D2582 puncture propagation tear resistance ensures that tray corners withstand transport stress without splitting; typical end products include compartmentalised meal trays, bakery clamshells, and tamper-evident lidding base foils for modified-atmosphere packaging.

    Heavy-Duty Logistics Pallets and Crate Moulding

    Production of returnable logistics pallets demands a melt with adequate high-shear fluidity to replicate rib patterns of 2.5 mm nominal wall thickness across a 1 200 × 1 000 mm footprint. H3500 formulated with 0.2 wt% organic nucleating agent, 0.10 wt% hindered phenolic antioxidant, 0.10 wt% phosphite stabiliser, and 3 wt% carbon black masterbatch for UV resistance delivers a flexural modulus exceeding 1 600 MPa (ISO 178), sufficient to pass ISO 8611-1:2011 static top-deck deflection tests with less than 12 mm deformation under a 1 000 kg distributed load. Injection moulding is performed on a 2 200-tonne hydraulic clamping unit equipped with sequential valve-gated hot runners; fill time is constrained to 4.5 seconds to prevent premature freeze-off at the extremities of the cavity, after which a three-stage packing pressure profile (70 MPa for 8 s, 50 MPa for 12 s, 30 MPa for 10 s) compensates for the 1.6–1.8% volumetric shrinkage during crystallisation. Process audits on production lines reveal that a mould temperature deviation exceeding ±4 °C from the 35 °C setpoint increases scrap rates due to underfill at the pallet’s corner blocks, a failure mode traceable to reduced flow length. Terminal products encompass nestable distribution crates for beverage bottles, three-runner rackable pallets for automated warehousing, and collapsible fruit bins that endure 10 000 dynamic compression cycles according to ASTM D4169 truck transport simulation without weld-line fracture.

    When a washing machine tub manufacturer transitions from 20% talc-filled PP to a nucleated homopolymer formulation to eliminate post-moulding machining of seal contact surfaces, the dimensional stability requirements demand a shrinkage tolerance band within ±0.05 mm per 100 mm of part length. The H3500-based compound is loaded with 0.30 wt% ultrafine sodium benzoate nucleator (CAS 532-32-1), 0.08 wt% primary antioxidant, 0.08 wt% secondary antioxidant, and 0.10 wt% glycerol monostearate antistatic agent to suppress dust adhesion on finished surfaces. Compliance with IEC 60335-1:2020 clause 30.2.3 is demonstrated by a glow-wire ignition temperature (GWIT) of 775 °C on a 2.0 mm plaque, while the ball pressure test at 125 °C (IEC 60695-10-2) leaves an indentation diameter under 2.0 mm, confirming dimensional integrity during spin drying at residual heat. Moulding takes place on a 650-tonne toggle-clamp injection machine with a two-cavity hot-runner tool; melt temperature is controlled to 230 ± 3 °C because deviations outside this window alter crystallisation kinetics sufficiently to produce anisotropic differential shrinkage that manifests as out-of-roundness exceeding 0.15 mm on the tub rim — a critical defect during automated bearing insertion. Packing pressure is set to 85 MPa for 6 seconds followed by 20 seconds of cooling at 40 °C mould temperature, generating a spherulite size distribution fine enough to maintain a notched Izod impact of 4.5 kJ/m² (ISO 180/1A) at 23 °C. Field data from assembly plants indicates that tubs moulded without nucleator sacrifice 0.8 dB(A) in spin-cycle noise damping due to micro-void coalescence at the bearing housing interface — a failure mode eliminated by the nucleated H3500 formulation. Final products extend to top-loading washer outer tubs, front-loader base frames, and refrigerator compressor mounting plates, all subject to 100 000 cycle endurance validation under unbalanced load.

    Characteristically, under-bonnet components such as fan shrouds and battery trays fabricated from H3500 require continuous-use thermal resistance at 105 °C without load-bearing deflection exceeding 0.5 mm over 1 000 hours. The stabilisation system is elevated to long-term heat-aging requirements by incorporating 0.25 wt% hindered phenolic antioxidant, 0.15 wt% phosphite, and 0.10 wt% thio-ester synergist, yielding an oxidative induction time (OIT) exceeding 40 minutes at 200 °C per ISO 11357-6. Before compounding, the resin must be purged of residues from previous polyamide batches, as cross-contamination at levels as low as 0.02 wt% catalyses thermo-oxidative chain scission during melt processing. Volatile organic compound and fogging emissions are controlled within VDA 278 limits (VOC < 50 µg/g, FOG < 250 µg/g) when purging protocols and the specified antioxidant blend are employed; deviation from this blend via substitution with low-cost recycled additives has been documented to elevate acetaldehyde levels above the 3 µg/g odour-rejection threshold measured by VDA 270 B3 olfactory evaluation. Injection moulding is executed on a 350-tonne hydromechanical clamp with a hot-runner system kept at 240 °C maximum to preclude residence-time-induced degradation; fill speeds are profiled to maintain a melt-front velocity of 120 mm/s through the 1.8 mm nominal wall sections of a fan shroud, preventing flow hesitation marks that act as stress concentrators under engine-compartment vibration. Mould temperature is maintained at 50 °C via pressurised water units to produce a surface gloss of 85 GU at 60° without sink marks opposite ribs. Terminal products include engine cooling fan shrouds tested to ISO 6603-2 puncture impact at -30 °C, lead-acid battery containment trays where acid-spill resistance is verified by IEC 62660-3 immersion test, and air-intake resonators that demand a 30% glass-fibre-reinforced variant for creep resistance at 120 °C peak soak — a grade-blending approach mapped to H3500 as a carrier resin.

    Extrusion-Grade H3500 Sustains 4 Bar Hydrostatic Pressure at 60 °C

    Single-screw extrusion lines with a barrier screw design (L/D 33:1) process H3500 into corrugated drainage pipes at a melt temperature window of 210–225 °C, monitored by melt pressure transducers positioned before the screen changer to avoid pressure spikes above 320 bar that indicate excessive screw recovery loading. The compound is dry-blended with 2.5 wt% carbon black masterbatch of 50 nm primary particle size for UV stabilisation and 0.10 wt% processing stabiliser package, and fed into a grooved-barrel extruder to ensure adequate conveying without pre-compression bridging at the intake throat. Pipe conformity to ASTM D4101 cell classification PP0110B is verified through ISO 1167-1:2006 long-term hydrostatic strength testing, with representative specimens sustaining a hoop stress of 4.0 MPa in water at 60 °C for 1 000 hours without brittle failure, while the same formulation passes the DIN 8078 chemical resistance immersion in 5% sodium hydroxide and 10% sulphuric acid for 168 hours with a weight change under 0.5%. During downstream corrugator forming, the vacuum calibration sleeve is set to -0.30 bar and the haul-off speed is synchronised to the melt output to achieve an inner diameter ovality below 2%. Any interruption in the vacuum supply beyond 15 seconds causes immediate collapse of the semi-molten tube, requiring a full line purge — an operational boundary that demands redundant vacuum pumps and accumulator tanks in continuous production campaigns. Finished products cover underground land-drainage piping with socket-and-spigot jointing, laboratory chemical waste conduits, and double-wall culvert systems where the outer corrugated shell provides ring stiffness exceeding 8 kN/m² as per ISO 9969, while the inner liner maintains hydraulically smooth flow coefficients.

    Regulatory Compliance Matrix for H3500 Downstream Applications
    Application Sector Standard / Regulation Key Test Condition Performance Criterion
    Food-contact moulding & sheet FDA 21 CFR 177.1520(c)2.1EU 10/2011 OML, simulants A/B/D2, 40 °C/10 days ≤ 10 mg/dm²
    Domestic appliance structural IEC 60335-1:2020 cl.30IEC 60695-11-10 Glow-wire 750 °C, GWITBall pressure 125 °C No persistent flame > 2 sIndentation ≤ 2.0 mm
    Automotive interior/under-bonnet VDA 278:2011VDA 270:2018 Thermodesorption 90 °COdour evaluation 80 °C VOC < 50 µg/gOdour grade ≤ 3.0
    Industrial logistics pallet ISO 8611-1:2011ASTM D4169-16 Top deck static loadDynamic compression Deflection ≤ 12 mm at 1 000 kg
    Extruded drainage pipe ISO 1167-1:2006DIN 8078 Hoop stress 4.0 MPa, 60 °C No burst 1 000 h
    Representative Property Profile of H3500 Formulations
    Property (Test Method) Neat H3500 +0.25% Clarifier +3% HMS-PP
    Melt flow rate (ISO 1133, 230 °C/2.16 kg) 3.5 g/10 min 3.8 g/10 min 2.6 g/10 min
    Tensile yield strength (ISO 527-2) 35 MPa 38 MPa 33 MPa
    Flexural modulus (ISO 178) 1 500 MPa 1 750 MPa 1 400 MPa
    Notched Charpy impact (ISO 179, 23 °C) 4.0 kJ/m² 3.2 kJ/m² 5.5 kJ/m²
    Heat deflection temp. (ISO 75-2, 0.45 MPa) 110 °C 118 °C 105 °C
    Optical haze (ASTM D1003, 1 mm) 55 % 11 % 62 %
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    Certification & Compliance
    More Introduction
    Exelene PP Homopolymer H3500 is a high-flow, nucleated polypropylene grade engineered for thin-wall injection moulding applications where rapid filling, fast cycle times, and elevated stiffness are required. The melt mass-flow rate (MFR) of 35 g/10 min (ISO 1133-1:2022, 230 °C/2.16 kg) places it in the upper-mobility tier of the homopolymer portfolio, enabling consistent cavity replication in multi-impression tooling with wall sections as low as 0.45 mm. Typical production sectors include rigid food-contact packaging, caps and closures, laboratory consumables, and medical device components. Unlike random copolymer or impact-modified alternatives, H3500 delivers the intrinsic crystallinity of a homopolymer backbone—translated into tensile modulus and heat deflection temperature advantages—while a tailored nucleating package accelerates solidification kinetics and narrows the half-crystallisation time.

    How Does Melt Flow Rate Govern Thin-Wall Filling?

    The MFR measured at 230 °C under a 2.16 kg load per ISO 1133-1:2022 determines the pressure drop per unit flow length and dictates the feasible flow length-to-wall thickness ratio. On a 200 tonne all-electric Arburg 720 S injection press fitted with a 25 mm barrier screw and a 32-cavity cold runner mould, spiral flow length data collected at 800 bar hydraulic pressure and a melt temperature of 235 °C show that H3500 fills a 1 mm-thick channel to a distance of 450 mm before freeze-off, compared to 310 mm for a non-nucleated homopolymer with an MFR of 11 g/10 min. The low shear-thinning exponent (power-law index 0.32 at apparent shear rates between 10³ s⁻¹ and 10⁴ s⁻¹) means that filling is proportionally less sensitive to gate velocity, but the material’s thermal diffusivity and the narrow processing window between solidification onset (128 °C peak crystallisation temperature) and degradation threshold (260 °C) require precise barrel profiling. Recommended set-points: feed zone 200 °C, compression 230 °C, metering 240 °C, with a nozzle temperature of 245 °C. Residence times exceeding 5 min at 250 °C initiate chain scission, evidenced by a shift in MFR upwards by 2–4 g/10 min and yellowing. High-flow propensity also elevates the risk of drool in open-nozzle configurations; a positive shut-off nozzle or valve-gated hot runner with a gate diameter below 1.2 mm is essential to maintain shot consistency.

    Mechanical Property Thresholds for Stacking Rigidity

    Property values derived from injection-moulded specimens conditioned for 40 h at 23 °C and 50 % RH establish the stiffness envelope that differentiates H3500 from other Exelene PP grades. In tensile testing according to ASTM D638-14 (Type I specimens, test speed 50 mm/min), the homopolymer returns a yield stress of 34 MPa and a tensile modulus of 1 750 MPa, figures that exceed typical random copolymer grades by approximately 25 % and 35 %, respectively. Flexural modulus measured under ASTM D790-17 (span‑to‑depth ratio 16:1, 1.3 mm/min) averages 1 550 MPa, conferring the stacking rigidity required for thin-wall containers that must carry a top load of 250 N without buckling. Conversely, notched Izod impact strength per ASTM D256-10 at 23 °C is limited to 2.5 kJ/m², declining to 1.2 kJ/m² at 0 °C, which underscores the material’s low‑temperature brittleness. The table below compares these values with a lower‑flow homopolymer (H1100, MFR 11 g/10 min), a random copolymer (RP340N, MFR 25 g/10 min, ethylene content approx. 3.5 wt%), and an impact copolymer (IP540N, MFR 45 g/10 min, ethylene‑propylene rubber phase 18 wt%).
    Property H3500 H1100 RP340N IP540N
    Tensile modulus (ASTM D638) 1 750 MPa 1 800 MPa 1 300 MPa 1 450 MPa
    Flexural modulus (ASTM D790) 1 550 MPa 1 600 MPa 1 100 MPa 1 250 MPa
    Heat deflection temperature, 0.455 MPa (ASTM D648) 105 °C 108 °C 85 °C 95 °C
    Notched Izod, 23 °C (ASTM D256) 2.5 kJ/m² 3.0 kJ/m² 6.5 kJ/m² 12.0 kJ/m²
    Shrinkage (flow × transverse, ISO 294-4) 1.4 % × 1.6 % 1.5 % × 1.7 % 1.8 % × 1.8 % 1.2 % × 1.4 %
    The data illustrate the trade‑off between load‑bearing capacity and ductility. For dry‑packed consumables stored at ambient temperature, the higher stiffness of H3500 translates into a 12 % reduction in wall thickness relative to RP340N while maintaining equivalent top‑load performance, as validated in compression tests per ASTM D2659-16 on 500 ml cylindrical containers. However, when cold‑chain integrity is required, the impact copolymer IP540N becomes mandatory; H3500 exhibits brittle failure in drop‑impact trials at −20 °C with a 50 % bruceton‑protocol failure height below 30 cm.

    When Crystallisation Kinetics Dictate Cooling Time

    A nucleating agent raises the peak crystallisation temperature (Tc) from approximately 115 °C (non‑nucleated homopolymer) to 128 °C as measured by differential scanning calorimetry at a cooling rate of 10 K/min (ISO 11357-3:2018). The shift widens the gap between mould temperature and solidification point, accelerating the shell‑layer formation and reducing the required hold‑pressure time. On a 350‑tonne KraussMaffei hydraulic machine running a 24‑cavity 28 mm beverage cap mould, the cycle time was trimmed from 8.5 s to 7.2 s when substituting a non‑nucleated homopolymer with H3500, while maintaining a part mass standard deviation below 0.08 g. The nucleated morphology also raises the Vicat softening point (VST A50, ISO 306) to 153 °C, affording an additional margin against deformation during hot‑fill operations at 85 °C. Processors must, however, anticipate that the faster crystallisation increases residual stresses in thick‑walled sections, as evidenced by an increase in warpage of 0.5 mm on a 3 mm‑thick plaque over a 200 mm span. Mould temperature uniformity within ±2 °C becomes non‑negotiable; a single unbalanced cooling circuit can produce differential crystallinity sufficient to amplify post‑mould warpage. Gamma sterilisation at a dose of 25 kGy induces minimal discolouration and retains over 90 % of original tensile elongation at break when evaluated according to ISO 11137-2, provided the stabiliser package is designed for radiation resistance. Published data for this specific configuration in H3500 is limited, but tests on analogous high‑flow homopolymers exhibit post‑irradiation oxidative induction time (OIT, ISO 11357-6, 200 °C) of 12 min, sufficient for single‑use medical devices. The near‑total absence of extractable ethylene‑based fractions simplifies compliance with USP <661.1> plastics physicochemical test panels, as only trace oligomers migrate into aqueous and hydrocarbon simulants. The following compliance matrix captures the relevant regulatory landscape.
    Regulation Scope Status / Condition
    FDA 21 CFR 177.1520(c) 1.1a Olefin polymers for food contact Conformant; hot‑fill conditions up to 100 °C, not for cooking
    EU 10/2011 (Commission Regulation) Plastic materials in contact with food Overall migration <10 mg/dm²; specific migration of antimony <0.04 mg/kg
    USP Class VI Biological reactivity for plastics Passes systemic injection, intracutaneous, and implantation tests
    REACH (EC) 1907/2006 Registration, Evaluation, Authorisation Substance registered, SVHC content <0.1 wt%
    RoHS Directive 2011/65/EU Restriction of hazardous substances Conformant; lead, mercury, cadmium, hex‑Cr, PBBs, PBDEs below limits

    Differential Shrinkage in Complex Geometries

    In‑mould shrinkage anisotropy, quantified by ISO 294-4, results from the flow‑induced orientation of polymer chains that persists through the crystallisation front. H3500 produces a parallel‑to‑flow shrinkage of 1.4 % and a transverse‑to‑flow value of 1.6 %, yielding a differential of 0.2 percentage points. This mismatched contraction can cause doming or saddle‑shaped distortion in large‑format lids. A production trial involving a 1 200 mm × 800 mm coffin‑box lid moulded on a 1 300‑tonne Engel Duo press showed that relocating the film gate from the geometric centre to the end‑of‑fill edge and adopting a sequential valve‑gate opening profile reduced flatness deviation from 3.8 mm to 1.1 mm. Random copolymer RP340N, despite its lower stiffness, generates a near‑isotropic shrinkage of 1.8 % in both directions due to its lower overall crystallinity and more uniform crystal orientation, making it the preferred choice for flatness‑critical applications such as transparent stationery folders, albeit at a cost of reduced heat resistance. Storage in high‑humidity environments above 60 % RH leads to surface moisture adsorption up to 0.08 wt%, which may generate splay defects and surface cracking during injection. Pre‑drying in a desiccant dryer at 80 °C for 2 h brings residual moisture below 0.02 %. Material incompatibilities include prolonged contact with strong oxidising agents and amine‑based mould‑release sprays, which can catalyse thermo‑oxidative degradation within the barrel and cause inter‑batch variability in melt viscosity. The product must not be blended with acetal resins or PA66 in recycling streams, as the thermal degradation products of these polymers compromise the stabiliser package of H3500, leading to acid‑catalyzed chain scission during subsequent heat histories.
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