| HS Code | 983374 |
| Material | Polyamide 12 (PA12) |
| Color | Natural |
| Odor | Slight characteristic odor |
| Density | 1.01 g/cm³ |
| Bulk Density | 0.40 g/cm³ |
| Melting Point | 178 °C |
| Average Particle Size D50 | 50 µm |
| Tensile Strength | 40 MPa |
| Elongation At Break | 300 % |
| Shore Hardness D | 70 |
| Water Absorption 24h | 0.30 % |
| Vicat Softening Temperature | 170 °C |
As an accredited Evonik VESTOSINT® 2155 natural color Polyamide 12 factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.
| Packing | Packaged in 20 kg multi-wall paper sacks with polyethylene liner; natural color polyamide 12 powder for coating applications. |
| Container Loading (20′ FCL) | 20′ FCL loading of Evonik VESTOSINT® 2155 natural polyamide 12 powder: clean, dry container, secure palletized bags, prevent moisture and damage. |
| Shipping | VESTOSINT® 2155 natural Polyamide 12 ships as non-hazardous powder in moisture-protective bags or drums. Keep sealed, dry, and away from ignition sources to prevent static discharge. Store below 40°C, protect from humidity, and ensure clean, ventilated transport. Standard freight is suitable; avoid rough handling to preserve particle integrity. |
| Storage | Store VESTOSINT® 2155 in its original, tightly sealed container in a cool, dry area away from direct sunlight and heat sources. Protect the polyamide powder from moisture and humidity, as dampness can affect flow and coating performance. Maintain ambient storage temperatures and avoid exposure to incompatible chemicals. Properly stored, it retains its properties for its specified shelf life. |
| Shelf Life | Shelf life is typically 2 years when stored in original, unopened packaging in a cool, dry place. |
In dishwasher rack coating lines, the replacement of PVC plastisol with VESTOSINT® 2155 natural color Polyamide 12 powder is driven by the requirement to eliminate phthalate plasticizers and reduce volatile organic compound emissions during cure. The powder is dry-blended with 0.2–0.5 wt% of a hydrophobic fumed silica flow aid to maintain constant fluidization in an air-fluidized bed with a lithium chloride dew-point control set to -20 °C or lower. Wire racks fabricated from 4–6 mm diameter low-carbon steel are degreased in an aqueous alkaline bath at 60–70 °C, rinsed, pickled, and phosphated to a coating weight of 2.5–4.5 g/m² zinc phosphate. The preheat oven is operated at 330–360 °C for 6–12 min depending on wire gauge; the lower thermal mass of cutlery basket wire imposes an upper temperature limit of 345 °C to prevent metal warpage. Immersion in the fluidized bed lasts 3–8 s, yielding a fused dip layer of 300–450 μm after post-heat curing at 180–200 °C for 8–12 min. Terminal products include dishwasher baskets, cup trays, and cutlery reservoirs that must withstand 5,000 wash cycles under EN 50242 with pH 12.5 alkaline detergent at 75 °C. Compliance is documented against EN 60335-2-5, REACH Regulation (EC) 1907/2006, and FDA 21 CFR 175.300 for indirect food-contact coatings.
Process failure modes observed on high-rack lines include edge starvation, where the 300 μm minimum coating thickness falls below 250 μm at cut-wire ends when part withdrawal from the fluidized bed exceeds 0.3 m/s. The post-heat cure must remain above the crystalline melting range of PA 12 at 176 °C but below 210 °C; oxidative yellowing of natural-color PA 12 begins at continuous forced-air oven temperatures above 220 °C. Finished coatings are qualified for 1,000 h neutral salt spray without red rust on zinc-phosphated steel when tested according to ISO 9227. The coating also undergoes thermal shock testing from 75 °C wash water to 20 °C rinse water for 1,000 cycles, with no loss of adhesion greater than 5% of the coated area. Because natural-color VESTOSINT® 2155 contains no pigment masking effects, batch-to-batch discoloration is used as an early indicator of melt-temperature drift or contaminated virgin powder. Rework powder generated from overspray is limited to ≤10 wt% of fresh material because repeated heat input raises the carboxylic acid end group concentration and narrows the fusion window.
For spring-steel clamp programs, the use of VESTOSINT® 2155 natural color PA 12 as a topcoat over zinc-flake or zinc-nickel basecoats is evaluated because PA 12 provides a low-friction surface and prevents metal-to-metal contact noise while retaining clamp force. The powder is applied at 100 wt% as supplied after conditioning for 4 h at 80 °C when storage relative humidity exceeds 60%. Addition ratios in dry-blend lines include 0.1–0.3 wt% of fumed alumina to stabilize tribo-charging in electrostatic spray systems that operate with a voltage of 60–90 kV and a powder output of 80–150 g/min. Spring-steel parts are preheated to 160–200 °C before spraying, not to the higher temperatures used in fluidized-bed processing, to avoid tempering hardened spring steel above its metallurgical relaxation threshold. The applied layer is fused at 210–230 °C for 10–15 min, producing a final coating thickness of 80–200 μm on clamp inner surfaces. Terminal products include constant-tension band clamps, turbocharger clip brackets, and brake hose spring clips.
Qualification for underhood spring clamps is anchored to ISO 9227 neutral salt spray testing for 720 h on zinc-flake coated substrates, with no red rust at scribe and no blistering greater than 2 mm creep. Interior fasteners are tested for fogging per DIN 75201, with a gravimetric condensate limit of <2 mg on glass plates. The production part approval process is controlled under IATF 16949:2016, including dimensional capability after coating because a 200 μm layer can affect torque retention on threaded clamp housings. The processing window for preheat temperature is ±5 °C on fully automated lines; below 155 °C the powder fails to fuse, and above 205 °C the zinc-flake basecoat can blister. Electrostatic application over coated spring steel is not intended to replace all secondary corrosion protection systems; a chromium-free zinc-flake or zinc-nickel base layer remains mandatory for corrosion resistance under red-rust test conditions.
Medical device coating lines that process non-implantable surgical instruments and clamping devices use VESTOSINT® 2155 natural color PA 12 powder after an abrasive blasting step that raises the substrate surface roughness to Ra 3.2–6.3 μm on AISI 316L stainless steel. The powder is applied at 100 wt% solids; no solvent, catalyst, or reactive diluent is permitted in the biocompatibility validation batch. Coating thickness is controlled to 150–300 μm on instrument handles, locking levers, and knobs. After preheating to 250–300 °C in a convection oven, the heated parts are immersed in a fluidized bed for 2–6 s or sprayed with a high-voltage electrostatic gun in a Class 8 cleanroom. The cure cycle is 190–210 °C for 10–20 min, chosen to keep the coating above its melting range while avoiding thermal discoloration of the natural-color surface. Terminal products include forceps rings, retractor handles, and torque wrench grips for reusable surgical trays.
Biocompatibility documentation for the coated instruments is generated under ISO 10993-5:2009 for cytotoxicity with an elution test on L929 mouse fibroblasts, and ISO 10993-10 for skin sensitization. Depending on the end-user risk class, the material may also be supported by a USP 88 Class VI certificate from the resin producer. The coating line operates under ISO 13485:2016 documented process validation with IQ/OQ/PQ; addition levels of rework powder are limited to 0–15 wt% of virgin powder because repeated heat cycles raise the carboxylic acid end group concentration and shift melt flow outside the validated range. The 150 μm minimum thickness is not sufficient to mask sharp edges or burrs; therefore medical parts require edge rounding before coating. The use limit is restricted to disinfection and low-temperature steam sterilization at 121 °C; repeated autoclave cycles above 134 °C may alter crystallinity and reduce impact resistance.
| End-use scenario | Compliance anchor | Thickness range | Application process |
|---|---|---|---|
| Dishwasher racks | EN 60335-2-5; FDA 21 CFR 175.300 | 300–450 μm | Preheat 330–360 °C, fluidized-bed dip, post-cure 180–200 °C |
| Automotive clamps | ISO 9227; DIN 75201; IATF 16949:2016 | 80–200 μm | Preheat 160–200 °C, electrostatic spray, fuse 210–230 °C |
| Medical instruments | ISO 10993-5:2009; USP 88; ISO 13485:2016 | 150–300 μm | Abrasive blast Ra 3.2–6.3 μm, preheat 250–300 °C, cure 190–210 °C |
| Food machinery guides | EU 1935/2004; EU 10/2011; FDA 21 CFR 177.1500 | 250–500 μm | Phenolic primer 5–10 μm, electrostatic spray 70–100 kV, cure 210–230 °C |
| Drinking-water valves | NSF/ANSI 61; UBA W270; KTW-BWGL | 250–400 μm | Primer 20–40 μm, fluidized-bed dip 3–7 s, cure 180–200 °C |
| Textile rollers | ISO 527-2; ASTM D4060; ISO 868 | 200–400 μm | Preheat 260–300 °C, electrostatic spray, cure 190–210 °C |
Conversion of stainless steel guide rails from hard chrome electroplating to PA 12 powder coating is typically initiated when a processing line experiences repeated wear of UHMWPE inserts or when chrome plating baths generate hexavalent chromium waste. VESTOSINT® 2155 natural color PA 12 is applied as a 100 wt% powder, with optional dry blending of 0.1–0.2 wt% fumed silica only if the powder feed hopper shows bridging at relative humidity above 60%. Steel rails are ground to a profile of Ra 2.5–5.0 μm, degreased, and primed with a thin phenolic adhesion layer at 5–10 μm before electrostatic spray application at 70–100 kV. The powder layer is cured at 210–230 °C for 10–15 min to produce a final thickness of 250–500 μm, depending on the wear allowance. Terminal products include guide rails, star wheels, filler screws, and conveyor rollers for bakery, beverage, and meat processing lines.
Food-contact compliance is documented under EU Regulation 1935/2004, Commission Regulation (EU) 10/2011 with migration testing according to OM 2 conditions, and FDA 21 CFR 177.1500 for nylon resins intended for repeated food-contact use. Cleaning-agent resistance is verified with 2% sodium hydroxide and 2% peracetic acid at 80 °C for 100 h; published data for this specific chemical exposure on natural-color PA 12 coatings is limited, so post-cleaning adhesion is tested using ISO 2409 cross-cut tape pull after each batch. The processing boundary includes a continuous surface temperature limit of 80 °C for dry food contact and 60 °C for steam-cleaned lines. At thicknesses above 500 μm, cooling rate after cure must be slowed to 5–10 °C/min to prevent internal stress cracking at weld seams. Hard chrome replacement is not recommended for cutting-edge contact zones because PA 12 cannot withstand the point-load abrasion of metal-to-metal shear.
Within the drinking-water fitting sector, organic powder coatings are qualified against material-specific migration and organoleptic test batteries before they are accepted on brass or stainless steel valve bodies. VESTOSINT® 2155 natural color PA 12 is applied over a zinc phosphate or epoxy primer base at a thickness of 250–400 μm, with the powder itself used at 100 wt% solids. The primer layer, typically 20–40 μm, seals the metallic substrate and prevents dezincification of brass under stagnant low-pH water. Heated valve bodies enter a fluidized bed at 290–340 °C; immersion time is 3–7 s, after which cure proceeds at 180–200 °C for 10–15 min. The terminal products include check valve housings, ball valve stems, coupling sleeves, and vented tap connectors.
Regulatory documentation includes NSF/ANSI 61 Section 9 for mechanical plumbing devices, the German KTW-BWGL recommendation for drinking water contact, and UBA W270 microbial growth testing. The diffusion-controlled migration threshold requires thickness monitoring because contaminant release scales with film thickness under stagnant water conditions; therefore the 400 μm upper limit is treated as a compliance boundary unless supplemental migration tests are performed on the finished component. Continuous service temperature of the coated valve bodies is limited to 80 °C for water under 10 bar; applications above 85 °C require thermal cycling validation because PA 12 absorbs up to 1.4 wt% water and the glass transition shifts. Rework powder is limited to ≤10 wt% of virgin material because recycled powder increases the surface area for low-molecular-weight fraction migration. The coating is not applied to threaded surfaces that require machined metal-to-metal sealing.
Polyamide 12 powder is applied to steel roller cores in the fiber processing sector where yarn tension and static dissipation are controlled. VESTOSINT® 2155 natural color PA 12 is used at 100 wt% powder without solvent-borne primers when the steel core is first grit-blasted to a surface profile of Ra 4.0–6.0 μm. Roller cores are preheated to 260–300 °C, coated by electrostatic spray or fluidized-bed immersion, and cured at 190–210 °C for 10–15 min. The final coating thickness is held between 200 μm and 400 μm to balance flexibility with wear resistance. Terminal products include draw rollers, guide rollers, and tension bars on ring spinning and texturing frames.
Mechanical property verification is anchored to ISO 527-2 for tensile modulus, ISO 868 for Shore D hardness, and ASTM D4060 with CS-10 wheels at 1,000 g load for 5,000 cycles. Published data for this specific roller configuration is limited, so acceptance limits are established internally after each roller build. The coating is not recommended for roller surface temperatures above 70 °C under continuous high yarn tension because creep can reduce dimensional stability. The natural-color grade carries no processing dyes and is selected when optical contamination control is critical in white and undyed fiber runs.
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Evonik VESTOSINT® 2155 natural color Polyamide 12 is an unpigmented, free-flowing powder produced by hydrolytic polymerization of laurolactam, followed by cryogenic grinding and air classification. The grade belongs to the VESTOSINT® coating-powder range and is specified for fluidized bed dip coating and electrostatic spray application onto metal substrates that require a fused semicrystalline polyamide 12 layer without carbon black or colorant interference. Lot release testing according to DIN EN ISO 60 and ISO 8130-1 controls bulk density and sieve fraction. Typical bulk density is 0.42–0.48 g/cm³, and the laser-diffraction median particle size is controlled at approximately 50 µm; these values are representative and must be confirmed against the current certificate of analysis. The natural pigmentation state preserves the intrinsic dielectric strength and surface resistivity of polyamide 12, which is relevant for electrical insulators, sensor housings, and dishwasher-basket coatings.
The crystalline melting peak is measured at 176–180 °C by ISO 11357-3, and the glass transition is near 45 °C by ISO 11357-2. The polymer chain contains a lower amide-group density than polyamide 6 or polyamide 66, which holds water absorption at saturation to approximately 1.4% under ISO 62 and limits hygroscopic dimensional change in humid service. The 176–180 °C melting peak is lower than the 260 °C melting point of polyamide 66 and permits coating of heat-sensitive aluminum substrates without exceeding artificial aging temperatures. On compression molded void-free sheets, Shore D hardness is 70–75 per ISO 868, tensile strength at yield is 43–48 MPa per ISO 527-2, and elongation at break is 150–250%. Notched impact strength at 23 °C is 5–8 kJ/m² per ISO 179-1/1eA.
| Property | Standard | Typical range | Remarks |
|---|---|---|---|
| Bulk density | DIN EN ISO 60 | 0.42–0.48 g/cm³ | No anti-caking additive |
| Particle size d50 | ISO 13320-1 | 45–55 µm | Air classification |
| Particle size d90 | ISO 13320-1 | 80–100 µm | Oversize controlled |
| Melting peak | ISO 11357-3 | 176–180 °C | Second heat |
| Viscosity number | ISO 307 | 190–210 mL/g | Solvent per manufacturer method |
| Density of fused film | ISO 1183-1 | 1.01–1.03 g/cm³ | Void-free compression molded sheet |
| Water absorption at saturation | ISO 62 | 1.4% | 23 °C, water |
| Shore D hardness | ISO 868 | 70–75 | 15 s delay |
| Tensile strength at yield | ISO 527-2 | 43–48 MPa | 50 mm/min |
| Elongation at break | ISO 527-2 | 150–250% | Specimen type 1A |
The primary process difference between VESTOSINT 2155 natural and carbon-black-filled VESTOSINT grades is the absence of conductive or colorant particles. In filled grades, carbon black can reduce the volume resistivity of the fused film to 10³–10⁶ Ω·cm, whereas the natural grade typically retains volume resistivity above 10¹⁴ Ω·cm at 23 °C and 50% relative humidity. This difference is decisive for insulating clips, bus bars, and sensor housings where surface leakage current must remain below 1 µA at 500 V test voltage. The natural grade also shows dielectric strength in the range 20–30 kV/mm on void-free films of 300 µm thickness when tested according to IEC 60243-1. Filled grades may shift the dielectric loss factor at 1 MHz by more than 0.02, which is not acceptable for resonance circuits and capacitive sensing elements.
Compared with low-viscosity PA12 powders, VESTOSINT 2155 natural builds higher film thickness per dip and retains edge cover on sharp wire goods. Low-viscosity grades produce smoother films below 200 µm but are more prone to drip-off and edge pullback on vertical wire goods. Where a pinhole-free coating of 300–600 µm on dishwasher baskets is required, the higher melt viscosity of VESTOSINT 2155 natural reduces drain-off and sag. The viscosity number of 190–210 mL/g per ISO 307 places this grade in the higher-viscosity portion of the VESTOSINT coating-powder range. Compared with polyamide 11 powder, polyamide 12 exhibits a slightly broader melting interval and lower water absorption at saturation; both facts require adjustments in preheat and post-cure when substituting one powder for the other.
On production-scale fluidized bed lines, carbon-steel wire goods are preheated in convection or induction ovens to 250–300 °C before immersion in the air-fluidized powder. Preheat below 240 °C produces incomplete sintering at the substrate interface, visible as low gloss and poor peel adhesion. Preheat above 320 °C initiates thermo-oxidative yellowing of the natural grade, especially when oven oxygen concentration exceeds 5%. The immersion time of 4–10 s yields a fused film thickness of 250–500 µm on wire diameters of 3–6 mm. The fluidizing air must be dried to -20 °C dew point or lower; moisture in the powder increases the minimum film-formation temperature and creates microbubbles at the substrate-film interface. Post-fusion is performed at 180–200 °C for 8–12 min in a recirculating air oven. Oven profiling by differential scanning calorimetry (ISO 11357-3) is used to confirm complete fusion; published data for this specific configuration is limited, so each line must be validated with first-off part cross-sections.
Fluid bed pressure drop across the porous plate is typically maintained between 50 cm and 80 cm water column, and bed level is held constant within ±10% to avoid variations in powder density at the part surface. Coating lines use 316L stainless steel fluidizing chambers and diaphragm air vibrators to prevent rat-holing and dead zones. Substrate preparation on hot-rolled steel requires degreasing followed by abrasive blasting to Sa 2.5 per ISO 8501-1 with a surface profile of Rz 40–75 µm according to ISO 4287. On stainless steel, oxidative discoloration during preheat can inhibit wetting; a passivation or alumina-grit roughening step at 0.5 MPa is often inserted before coating to prevent peel failure in service. Adhesion is then verified by cross-cut classification 0–1 per ISO 2409 on a 250 µm film.
A common production failure on automated dishwasher-basket lines is edge pullback after post-cure, caused by molten-film contraction on sharp corners. Maintaining the substrate preheat in the upper portion of the 250–300 °C window and limiting immersion time to 4–6 s reduces this defect. Conversely, film porosity above 2% by image analysis on cross-sections arises when the substrate temperature falls below 240 °C or when the fluidizing air dew point rises above 0 °C. Such porosity lowers dielectric strength and increases moisture penetration during dishwasher alkaline wash cycles.
Electrostatic spray application of VESTOSINT 2155 natural to sensor housings and electrical insulators uses corona charging guns set at 70–90 kV with a powder flow rate of 100–200 g/min. Transfer efficiency declines sharply when the powder moisture content exceeds 0.15% because back-ionization and spitting disrupt the powder cloud. Powder stored above 60% relative humidity should be dried at 80 °C for 4 h in a desiccant-air dryer to bring moisture below 0.10%. The unpigmented grade is selected over carbon-black-filled grades for high-frequency sensor housings because filled grades can shift the dielectric loss factor at 1 MHz by more than 0.02; this shift is not acceptable for resonance circuits and capacitive sensing elements. Particle-size distribution is equally critical: if the d90 exceeds 100 µm, first-pass transfer efficiency on thin edges falls below 40% on flat vertical surfaces, while if the d50 falls below 35 µm, the powder is prone to impact fusion in the feed hose and to excessive dust generation.
Corona spray lines with reclaim systems must maintain the overspray fraction below 30% of the total powder feed because the recirculated fraction experiences repeated tribo-charging and can develop a shifted charge-to-mass ratio. High-voltage measurements on the part surface are typically in the range 50–90 µC/kg; deviations from this range indicate improper grounding or worn electrodes. Faraday cage areas on complex sensor housings are coated by reducing gun voltage to 40–60 kV and increasing powder cloud turbulence, which prevents thick-edge deposits that crack during oven fusion.
| Test or requirement | Condition | Result or status |
|---|---|---|
| REACH Regulation (EC) No 1907/2006 | Registration of monomer and polymer | Registered; confirm tonnage band with safety data sheet |
| RoHS Directive 2011/65/EU Annex II | Homogeneous material thresholds | Cadmium 0.01%; lead 0.1%; mercury 0.1%; hexavalent chromium 0.1%; PBB 0.1%; PBDE 0.1% |
| FDA 21 CFR 177.1500 | Nylon resins for food contact | Base resin listed; end-use migration testing required under 21 CFR 177.1500(c) |
| ISO 9227 neutral salt spray | 300 µm film on phosphate-treated steel | 1000 h scribe creep ≤3 mm; published data for this exact grade is limited |
| IEC 60243-1 dielectric strength | 300 µm void-free sheet | 20–30 kV/mm |
| ISO 2409 cross-cut adhesion | 250 µm film on blasted steel | Classification 0–1 |
Because post-cure oxidation controls porosity and dielectric loss, the fusion oven temperature must be balanced against carbonyl-index growth. The natural PA12 film develops microporosity if the coalescence time is too short; porosity above 2% by image analysis lowers dielectric strength below 15 kV/mm and increases moisture uptake in service. If the post-cure temperature exceeds 200 °C or the residence time exceeds 12 min, thermo-oxidative degradation raises the carbonyl index and yellows the natural film. This is measured by infrared spectroscopy; a carbonyl-index increase of more than 0.05 relative to the virgin powder is grounds for process rejection. For parts exposed to hot aqueous media above 80 °C, PA12 undergoes gradual hydrolysis; tensile strength may decline by more than 20% after 5000 h immersion in water at 80 °C. VESTOSINT 2155 natural is therefore not recommended for continuous immersion service in hot water or strong mineral acids without a protective topcoat or alloy-specific testing.
The powder is incompatible with amine-based coupling agents above 0.5 wt% and with transition-metal pigments above 2 wt%, both of which accelerate thermo-oxidative degradation during fusion. Storage in unopened bags below 30 °C and 60% relative humidity is required; after 24 months, the powder should be re-screened through a 125 µm sieve to remove any humidity-induced agglomerates. On twin-screw compounding lines with 34:1 L/D ratio, if VESTOSINT 2155 natural is used as a powder feedstock rather than as a coating, feeding through a side-stuffer at zone 6 is required because main-hopper bridging occurs at bulk densities below 0.40 g/cm³. This restriction is not specific to the 2155 natural grade but applies to all PA12 coating powders with similar bulk density.