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ETEC (EnvisionTEC) ETEC HTM140 DLP High Temperature Mold Material

    • Product Name: ETEC (EnvisionTEC) ETEC HTM140 DLP High Temperature Mold Material
    • Factroy Site: Yudu County, Ganzhou, Jiangxi, China
    • Price Inquiry: admin@ascent-chem.com
    • Manufacturer: Ascent Petrochem Holdings Co., Limited
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    Specifications
    HS Code 222975
    Material Type Photopolymer
    Technology DLP
    Color Amber
    Density 1.12 g/cm³
    Viscosity 350 mPa·s at 25°C
    Heat Deflection Temperature 140 °C
    Tensile Strength 50 MPa
    Tensile Modulus 2,400 MPa
    Elongation At Break 3%
    Flexural Strength 80 MPa
    Flexural Modulus 2,500 MPa
    Hardness 85 Shore D
    Layer Thickness 25–100 µm
    Critical Energy 10 mJ/cm²
    Penetration Depth 0.15 mm
    Water Absorption 0.3%
    Shrinkage 0.5%

    As an accredited ETEC (EnvisionTEC) ETEC HTM140 DLP High Temperature Mold Material factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

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    Certification & Compliance
    More Introduction

    ETEC HTM140 is a filled photopolymer resin formulated for digital light processing additive manufacturing of high-temperature mold inserts, thermoforming tools, and thermally loaded fixtures. The product is intended for ETEC/EnvisionTEC DLP platforms operating in the 385–405 nm projector wavelength band and is supplied as a low-viscosity dispersion that transitions from a green printed state to a rigid, high-heat-deflection polymer network after washing and post-cure. Manufacturer-published typical data list a heat deflection temperature of 140 °C at 0.45 MPa when tested in accordance with ASTM D648. Tensile elongation at break remains below 10%, and Shore D hardness falls in the 85–90 range, indicating a high-modulus, low-ductility response. Compared with unfilled prototype resins in the same printer family, such as E-Model or PIC 100, whose published HDT values are generally below 60 °C, HTM140 shifts the service window upward for short-run tooling but reduces fracture tolerance and requires tighter process control.

    What Operational Boundaries Constrain HTM140 in Injection Tooling Applications?

    Injection tooling produced from HTM140 is qualified for short-run inserts where melt-contact temperature and clamp pressure remain within the material’s compressive strength and thermal stability limits. Tooling trials on small-tonnage injection machines with clamp force settings between 300 kN and 800 kN have shown that insert survival is often governed by thermal gradients near the gate rather than by peak cavity pressure alone. Because the filled photopolymer exhibits lower thermal conductivity than tool steel or aluminum, heat does not dissipate rapidly from the cavity wall. Published data for filled photopolymer systems generally place thermal conductivity in the range of 0.2–0.5 W/m·K. This lower heat transfer slows cycle time and raises the local surface temperature at the gate. As a result, processing guidelines limit continuous mold surface contact to approximately 120 °C for sustained duty, while cycle time is typically extended 1.5–3× relative to equivalent steel tooling unless conformal cooling channels are printed directly into the mold body. Thin ribs and sharp corner transitions should be avoided unless supported by a metal bolster, because crack initiation at these locations occurs before bulk thermal softening.

    Rheologically, HTM140 behaves as a filled suspension rather than a homogeneous monomer solution. The dispersed filler phase raises heat deflection temperature but also produces shear-thinning behavior and can settle during idle vat periods. The manufacturer’s recommended layer thickness is usually 50 µm or 100 µm, with the finer layer setting used where maximum green strength and surface resolution are required. Before each build, the resin must be reconditioned by vat agitation or manual stirring; settling during overnight shutdowns changes local viscosity and can produce layer-to-layer density variation. Build chamber temperature should be maintained within the recommended processing window. Thermal excursion below 18 °C raises viscosity and disrupts recoating, while excursion above 35 °C can accelerate dark polymerization and produce vat film fouling. These control points are particularly relevant on top-down DLP systems where the printed surface is immersed in resin and a wiper blade passes across a constrained meniscus after each exposure cycle.

    When HTM140 Replaces Aluminum or Filled Epoxy Tooling Boards in Thermoforming Tools, Which Design Rules Apply?

    Thermoforming and vacuum-forming tools made from HTM140 replace machined aluminum or epoxy board where intermediate surface temperatures and low thermal mass are required. The resin permits rapid digital fabrication of curved tool faces, vacuum channels, and low-volume production aids. However, the material’s localized bearing strength is lower than metallic equivalents. Toggle clamps, alignment pins, and ejector points should be backed by a steel bolster or embedded insert because point loads can exceed the resin’s local bearing capacity. Manufacturer case studies describe HTM140 tools used with polycarbonate and ABS sheet at surface temperatures up to 100 °C, with tool campaigns limited to avoid accumulated thermal fatigue. Edge radii below 3 mm are generally avoided unless the geometry is reinforced, because repeated heating and cooling initiate cracks at sharp corners. Vacuum hole drilling after printing requires low cutting speeds and coolant-free machining to prevent melt-smear and microcracking around hole perimeters. Carbide drill bits with 90–120° point geometry are recommended for producing clean apertures in the cured polymer without delaminating printed plies.

    Post-print cleaning and mold-release selection are chemically constrained. Green parts are washed in isopropyl alcohol or a glycol-ether solvent to remove uncured resin. Extended solvent contact beyond 10 min can produce edge swelling and reduce critical feature accuracy. After washing, parts are dried and post-cured in a UV flood chamber followed by an optional thermal post-cure. The cured surface is compatible with water-based mold releases and silicone-free demolding agents. Solvent-based releases containing strong ketones or chlorinated species can attack the polymer matrix and should be avoided. Because the material is hygroscopic at elevated relative humidity, pre-drying at 40–50 °C for 4–6 h is recommended before exposing tooling to high-humidity shop air to minimize dimensional drift during use.

    Thermal Fatigue, Post-Cure Shrinkage, and Vat-Settling Control Points

    Thermal fatigue appears on HTM140 tool faces as microcrack networks after repeated cycling from ambient to 100–120 °C. The mechanism is driven by differential expansion between the filled polymer surface and reinforcing supports rather than by bulk softening alone. Support structures should be placed on non-functional tool surfaces, and the CAD model should taper transitions from thick flanges to thin walls to redistribute thermal strain. Post-cure shrinkage is anisotropic. Published dimensional studies for filled DLP resins report aggregate linear shrinkage in the range of 0.1–0.3%, with the Z-axis generally exhibiting higher shrinkage than X/Y because of layerwise polymerization. Compensation factors are applied in slicing software and verified on a first-article tool before production geometry is finalized. Vat settling is controlled by continuous agitation during builds longer than 2 h. Printers without automated vat stirring require periodic interruption and manual re-dispersion, which can produce visible knit lines in the tooling surface if not managed. The thermal post-cure temperature window is typically held to a tolerance of ±5 °C around the specified setpoint; excursions outside that window create gradient conversion and measurable warpage in unsupported sections.

    High-Temperature Mold Material Classification Under ASTM D648 and ISO 75

    The material is classed as a high-temperature mold material on the basis of heat deflection temperature and not as a continuous-service engineering thermoplastic. Reporting of mechanical and thermal properties follows the standard designations listed in the table below. Batch certificates should be consulted for lot-specific values, because filler dispersion and post-cure protocol influence final properties.

    Property or Compliance Category Standard Designation Typical Reporting Condition
    Heat deflection temperature ASTM D648-18 / ISO 75-1:2020 0.45 MPa flatwise
    Tensile properties ASTM D638-14 / ISO 527-2:2022 10 mm/min crosshead speed
    Flexural properties ASTM D790-17 / ISO 178:2019 Three-point loading, 16:1 span-to-depth ratio
    Hardness ASTM D2240-15 / ISO 868:2003 Shore D, 15 s dwell
    Regulatory status REACH EC 1907/2006; RoHS 2011/65/EU Per SDS and compliance certificate

    Crack Propagation Along Layer Boundaries in High-HDT DLP Inserts

    Layer boundaries in HTM140 tooling act as preferred paths for crack propagation when tensile stress is applied normal to the build plane. The effect is more pronounced than in unfilled DLP resins because the stiff filler phase increases modulus but does not arrest interlayer fracture. Tooling designers commonly orient the mold face away from the platform and incline the part 15–30° relative to the Z-axis to avoid placing layer boundaries perpendicular to major tensile stress. In printed conformal cooling channels, wall thickness should be at least 2 mm to prevent coolant leakage through interlayer microcracks. Channel diameters as small as 1.5 mm can be produced, but pressure testing of printed channels is required before use in injection tooling. Failure observed on production-scale equipment most often occurs as gate-area erosion, thin-rib breakage during demolding, or corner cracking after repeated thermal cycling rather than bulk thermal collapse. Published data for high-cycle shot counts with this specific tooling configuration is limited; short-run campaigns should be qualified empirically on production geometry before scale-up.

    Compared with cast urethane or epoxy tooling boards, HTM140 offers a direct digital workflow that eliminates machining handwork and permits curved internal cooling geometry. However, the material has lower continuous service temperature than metal-filled epoxy tooling boards and lower fracture toughness than machined aluminum. In contrast to metal powder bed fusion tooling, HTM140 can be produced on lower-cost DLP hardware within a working day for small inserts, but it is not intended for high-volume injection production. Used as a bridge tooling resin, HTM140 is positioned between general-purpose DLP prototyping materials and metal tooling: it provides a higher thermal ceiling than unfilled resins but introduces filler settling, anisotropic shrinkage, and interlayer crack sensitivity that require disciplined build preparation and post-cure control.

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