| HS Code | 804354 |
| Material Type | Acrylonitrile Styrene Acrylate (ASA) |
| Polymer Structure | Amorphous thermoplastic |
| Density | 1.07 g/cm³ (typical) |
| Tensile Strength | 40–50 MPa (typical) |
| Flexural Modulus | 2.0–2.5 GPa (typical) |
| Notched Izod Impact Strength | 100–200 J/m (typical) |
| Heat Deflection Temperature | 85–95 °C at 1.8 MPa (typical) |
| Vicat Softening Temperature | 95–105 °C (typical) |
| Glass Transition Temperature | Approximately 105 °C |
| Mold Shrinkage | 0.4–0.7% (typical) |
| Water Absorption | Low; approximately 0.1–0.3% (typical) |
| Uv Weathering Resistance | Excellent |
| Chemical Resistance | Good to dilute acids and alkalis; limited resistance to many solvents |
| Flammability Rating | UL94 HB (typical) |
| Processing Method | Injection molding |
| Melt Processing Temperature | 230–260 °C (typical) |
| Drying Temperature | 80–90 °C (typical) |
As an accredited EnCom Polymers ASA factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.
| Packing | EnCom Polymers ASA is packaged in 25 kg moisture-resistant multiwall paper bags, palletized and stretch-wrapped for secure industrial storage and transport. |
| Container Loading (20′ FCL) | EnCom Polymers ASA loaded in a 20′ FCL container, securely palletized, dry, and protected under standard chemical shipping conditions. |
| Shipping | EnCom Polymers ASA is shipped as non-hazardous polymer pellets and is not regulated for transport under DOT, IMDG, or IATA. Use clean, dry, sealed containers; protect from moisture, direct sunlight, and contamination; store at ambient temperature. Follow the SDS and applicable local regulations. |
| Storage | Store EnCom Polymers ASA in a cool, dry, well-ventilated area, away from direct sunlight, heat, ignition sources, and incompatible materials. Keep containers tightly closed, labeled, and off the floor to prevent moisture pickup and contamination. Avoid dust generation, use appropriate PPE, and follow the SDS and local regulations. |
| Shelf Life | EnCom Polymers ASA typically has a 24-month shelf life when stored unopened in dry, ambient conditions away from sunlight and moisture. |
When unpainted exterior trim is specified for long-term UV exposure without an in-line painting step, EnCom Polymers ASA is processed by injection moulding with melt temperatures controlled between 240°C and 252°C. Pellets are pre-dried at 80°C for 3–4 h in a desiccant dryer with a dew point not higher than -30°C. Residual moisture above 0.05% produces silver streaking on mirror housings and B-pillar appliqués. Barrel profiles rise in 10°C increments from the feed throat to the metering zone. The nozzle temperature is set at the lower end of the melt range to reduce drool. Mould temperature is held between 50°C and 70°C. Back pressure is limited to 0.5–1.0 MPa. Screw speed is selected to avoid a recovery delay greater than 80% of cooling time. Tensile properties are checked to ASTM D638-14 at 50 mm/min. Flexural modulus is determined to ISO 178:2019 at 2 mm/min. Typical unfilled ASA values fall at 40–50 MPa tensile strength and 2,200–2,600 MPa flexural modulus. Notched Charpy impact to ISO 180:2019 at 23°C is reported between 5 kJ/m² and 15 kJ/m². The exact grade-dependent value is confirmed from the certificate of analysis before tool trial approval.
Mirror housings, cowl grilles, tailgate spoilers, and roof ditch mouldings are manufactured without primer or topcoat. This removes the paint line bottleneck and eliminates volatile organic compound emissions. The visible surfaces are qualified to SAE J2527:2017 xenon-arc exposure at 0.55 W/m² irradiance at 340 nm. OEM test plans typically require 1,500–2,500 kJ/m² total exposure. Gloss retention at 60° incident angle is measured to ISO 2813:2014. Total colour change is measured to ISO 7724 or ASTM D2244-21. A ΔE value under 3.0 is commonly used as acceptance. Black ASA grades resist chalking because the UV stabiliser package is distributed through the melt rather than applied as a surface coating. Surface defects such as gate blush and knit-line gloss difference are controlled by gate position and melt front temperature. On a 1,200 kN press, a mirror housing with a projected area of 150 cm² and a cavity pressure of 35 MPa demands 525 kN clamp force. This margin prevents flash at the parting line.
Thermal degradation is the main process conflict in high-UV grades. Residence time above 252°C for more than 10 min causes yellowing. The practical processing window is narrow on small-shot moulding machines where the barrel holds several cycles of material. Moulders select a shot size between 40% and 70% of barrel capacity. Injection speed is set to fill the cavity in 1.0–2.5 s. Too high a shear rate raises melt temperature at the gate by 15–30°C. Too low an injection speed freezes the flow front and increases weld-line visibility. Regrind from sprues and runners is limited to 10–20 wt% in visible black trim. Repeated heat history increases melt flow rate by 2–4 g/10 min when measured to ISO 1133-1:2022 at 220°C/10 kg. This MFR shift alters filling pressure and can move the weld-line position in multi-gated cowl grilles. Production-scale twin-screw compounding on a co-rotating extruder with L/D of 40:1 disperses the UV package, but lot-to-lot stabilizer dispersion is verified by purge colour and gloss retention coupons.
A three-layer capstock structure typically comprises an EnCom Polymers ASA top layer, a regrind core, and a white or recycled PVC substrate. The ASA layer is metered at 0.2–0.5 mm thickness over the PVC core. Coextrusion is performed on conical twin-screw or parallel twin-screw lines with melt pumps on the capstock extruder. Die lip melt temperature for the ASA capstock is maintained between 195°C and 215°C. PVC substrate melt temperature is kept between 185°C and 200°C. A mismatch above 20°C creates interfacial waviness. The melt pump is operated at 5–15 rpm depending on line speed. Line speeds for window profiles typically run from 2.5 m/min to 6.0 m/min. The die is designed with a pre-land section to prevent ASA from cooling before contact with PVC. A vacuum calibrator sets the outer skin before the profile enters the cooling tanks. The first cooling bath is held at 15–25°C to control shrinkage. Excessive cooling shock causes gloss reduction and residual stress at the ASA/PVC interface. Weatherability of the extruded profile is verified by EN 12608-1:2016 for window profiles. Colour change is assessed to ISO 4892-2:2013 and ASTM D3679-17 for vinyl siding. Terminal products include window profiles, door co-extrusions, fascia boards, and siding. Corner welding of window profiles is performed at 240–260°C on single-head or four-head welding machines. The ASA capstock must remain fused to the PVC substrate during the weld cycle. Poor layer adhesion leads to edge delamination after corner cleaning. The capstock layer must withstand knife blade machining without chipping. Impact resistance of the finished profile is tested to ASTM D4226-19 or EN 477. The PVC substrate absorbs most of the impact. The ASA skin contributes colour retention and gloss stability. Dimensional stability is influenced by coefficient of linear thermal expansion. ASA expands at roughly 0.08–0.10 mm/m°C. PVC expands at roughly 0.05–0.07 mm/m°C. This differential is managed by layer thickness ratio. Unsuitable layer ratios cause bowing in dark-coloured profiles. Dark brown or black capstock reaches surface temperatures of 70–85°C under direct sunlight. Heat build-up is measured with a pyrometer during qualification. Batch-to-batch viscosity variation is controlled by melt flow testing to ISO 1133-1:2022. Capstock grades are supplied in the 4–9 g/10 min MFR range at 220°C/10 kg. Lower MFR grades improve surface hardness. Higher MFR grades reduce die pressure. Coextruders balance this against the PVC flow.
Published water absorption data for unfilled ASA after 24 h at 23°C according to ISO 62:2008 are approximately 0.30–0.35%. The low moisture uptake reduces swelling in spa collars, pool step treads, and RV exterior mouldings. Resistance to chlorinated water is evaluated by immersion to ISO 175:2010 in 5% sodium hypochlorite at 23°C for 168 h. Acceptance limits for tensile retention and colour shift are defined by the OEM because published data for continuous EnCom-specific grades is limited. ASA is selected over polycarbonate in these applications because of better environmental stress crack resistance in chlorinated water. It is not resistant to concentrated acids, esters, ketones, or aromatic solvents. Warranty replacement has been linked to contact with acetone-based cleaners on RV trim. The material is therefore specified with a restricted cleaning protocol. Thermoformed spa shells use ASA sheet with a cap layer of acrylic for gloss. The ASA layer provides impact toughness and UV stability. The acrylic cap gives chemical resistance and depth of colour. Twin-sheet forming is used for spa shells. Sheet temperatures are typically 185–205°C at the forming station. High-temperature forming beyond 210°C causes surface haze in ASA-rich layers. Male and female moulds are temperature controlled between 40°C and 65°C. Demoulding at too high a temperature produces sink marks around mounting bosses. Marine hatch frames and swim platform panels are injection moulded rather than thermoformed. The tooling must include generous radii of at least 0.5 mm to avoid stress concentration. Fastener torque is limited by the bearing strength to ISO 604:2002 compressive tests. Over-tightening a stainless bolt against a moulded boss can cause stress cracking after extended exposure. The use of brass inserts is preferred for removable covers. This reduces cyclic stress on the ASA matrix. UV protection in marine exposure is verified by ISO 4892-3:2016 fluorescent UV lamps. Chalking is evaluated by ASTM D4214-07 or by gloss change to ISO 2813:2014. Terminal products include spa skirts, pool filter housings, RV side vents, and washdown panels. These parts carry no contact with potable water in most designs. Potable water contact requires separate national certification.
In outdoor telecom enclosure tooling, gate vestige and weld-line orientation govern impact retention after outdoor ageing. EnCom Polymers ASA is moulded in wall thicknesses from 3.0 mm to 5.5 mm for active antenna housings, junction boxes, and remote radio unit covers. The tooling is typically a single-drop cold runner or a hot runner with valve gates. Gate size is kept at 0.75–1.00 mm wall thickness ratio to avoid jetting. Filling speed is set to achieve a flow-front velocity constant enough to keep the melt front above the freeze layer. Holding pressure is maintained until gate freeze is complete. Gate freeze time is calculated from cavity pressure decay curves rather than assumed. Rib thickness is limited to 0.5–0.6 of the nominal wall. Boss wall thickness is limited to 0.6 of nominal wall. Sink marks under bosses are controlled by adding a gate vestige or gas counter-pressure. Corners are radiused at 0.5 mm minimum. Weld lines are repositioned behind mounting ribs. The parts are supplied with UV protection sufficient for a UL 746C F1 rating at the specified minimum thickness. Flame ratings for unfilled ASA are typically UL 94 HB. Flame-retardant versions may reach UL 94 V-0 at specified thicknesses, but the specific grade must be confirmed against the current UL Yellow Card. Glow-wire requirements for unattended appliances are covered by IEC 60695-2-11. At 650°C or 750°C, the plaque must not ignite or must self-extinguish within the defined time. The following compliance matrix is typical for electrical outdoor enclosure qualification.
| Segment | Standard or Code | Test Method | Parameter | End-Use Acceptance |
|---|---|---|---|---|
| Outdoor telecommunication housing | UL 746C | UL 746C UV and water immersion programme | F1 rating | Pass F1 at 3.0 mm minimum thickness |
| Electrical enclosure flame rating | UL 94 | UL 94 small flame | Flame class | HB or V-0 as per grade Yellow Card |
| Long-term thermal index | UL 746B | Mechanical with impact | RTI mechanical | Grade-specific Yellow Card value |
| Glow wire end product | IEC 60695-2-11 | Glow wire | Ignition and self-extinguish | 650°C or 750°C per product standard |
Published data for the specific EnCom FR configuration may be limited. The UL Yellow Card should be checked for minimum thickness and colour restrictions. Dark colours often need a lower thickness to pass F1. The heat ageing portion of UL 746B uses tensile impact retention as the failure criterion. The unaged values are established from ASTM D638-14 and ISO 178:2019. A common bottleneck in production lines is screw recovery time for FR grades. Flame retardant additives can increase melt viscosity. Screw speed is reduced. The melt temperature is kept below 230°C if the package is thermally sensitive. If the melt temperature is too low, filling pressure rises and knit lines become brittle. A practical barrel profile for FR ASA starts at 195°C at the feed zone and ends at 225°C at the nozzle. Screw recovery time must not exceed 90% of cooling time. Back pressure is raised slightly to 0.5–1.2 MPa to improve dispersion of the flame retardant. Too high a back pressure can shear the package and lower flame resistance. Terminal products include 5G antenna covers, solar inverter housings, and outdoor disconnect switch enclosures.
The shift away from painted ABS in lawn and garden chassis components introduces UV performance and tooling demands. EnCom Polymers ASA is used for lawn mower shrouds, snow thrower panels, tractor hoods, and power tool housings. The key specification is colour retention under SAE J2527:2017 or ISO 4892-2:2013. Typical exposure targets are 1,000–2,000 kJ/m² at 340 nm depending on OEM warranty. Change of colour is measured to CIEDE2000 in ASTM D2244-21. A total colour shift below 3.0 is used for non-show surfaces. Gloss retention at 60° is checked to ISO 2813:2014. Red and orange grades are more sensitive to pigment fade and require overlay studies. In moulded multi-colour mower decks, the dark ASA outer shell encloses a structural polypropylene core. Fasteners are set through the ASA skin. Boss strength is verified with ASTM D3763-18 instrumented puncture at 2.5 m/s. The sheet-rib proportion is designed to avoid surface read-through. Ribs are placed at least 1.5 mm below the outer surface. Gas-assisted injection is applied to thick tube handles. This reduces pack pressure and warpage. Mould temperature is raised to 65–80°C on show surfaces to increase gloss. On textured surfaces, lower mould temperature is used. Weld lines around handle bosses are moved by changing gate location. Processing regrind is limited to 20 wt% in black deck shells. The melt flow ratio is checked to ISO 1133-1:2022 at 220°C/10 kg. Repeated recycling at higher levels lowers tensile elongation. Elongation at break is measured to ASTM D638-14. A drop in elongation below 5% indicates degradation. Field failure in snow thrower panels occurs when a cold impact at -30°C triggers a brittle fracture. Low-temperature notched impact is therefore tested to ISO 180:2019 at -30°C. Values vary by grade. The grade should be selected from low-temperature impact data rather than room-temperature data.
Kitchen appliance fascias manufactured from EnCom Polymers ASA are specified for non-food-contact external panels. The parts include washing machine control facias, dryer front panels, and refrigerator door end caps. Heat resistance is quantified by ISO 306:2022 Vicat softening temperature method B50. Unfilled ASA normally falls between 96°C and 105°C. Deflection temperature under load is tested to ISO 75-2:2020 method A at 1.8 MPa. Typical values are 80–95°C. These limits are below those of mineral-filled polyamide but sufficient for external appliance surfaces. The key ageing test is thermal storage at 80°C for 1,000 h. Colour difference is measured to ASTM D2244-21. The acceptance limit is often ΔE < 2.0 after ageing. Gloss retention to ISO 2813:2014 at 60° must remain above 70%. High-gloss fascias require class-A mould surfaces with Diamond polished SPI-A1 finish. Mould release agents are excluded because they migrate and cause haze. Mould temperature is controlled between 60°C and 80°C. Melt temperature is held between 245°C and 255°C. Lower melt temperatures create cold slug marks on large surfaces. Higher melt temperatures cause yellowing around the hot runner nozzle. Fill time for a fascia panel is 1.5–3.0 s. Pack pressure is profiled to reduce gate blush. The gate is hidden behind a control knob or badge. Chemical resistance to household cleaners is tested by ISO 175:2010. Substances include diluted dishwash, glass cleaner, and isopropanol at 10% concentration. No cracking is allowed after 168 h at 23°C. ASA is incompatible with strong alkali oven cleaners and paint strippers. These are excluded from end-use instructions. Batch-to-batch gloss variation is controlled by pigment dispersion. This is verified on a calibrated gloss meter before production release.
For large-format additive manufacturing systems, published data for EnCom Polymers ASA filament is limited compared with injection moulding grades. The most relevant process window is a nozzle temperature of 250–260°C, a bed temperature of 100–110°C, and a heated chamber at 50–70°C. Drying is performed at 80°C for 4 h. Moisture above 0.05% produces popping at the nozzle and poor interlayer fusion. Layer height is set to 0.15–0.25 mm. Print speeds are lower than ABS because ASA has stronger melt strength and can pull on corners. Part warpage is reduced by a brim or raft. Tensile properties are anisotropic. XY-direction specimens tested to ASTM D638-14 Type IV are considerably stronger than Z-direction specimens. Published data for z-layer strength varies with chamber temperature and print speed. For industrial pellet-fed large-format machines, ASA is dried to 0.02% moisture and extruded through a 6.0–10.0 mm nozzle. The melt temperature at the screw is held below 250°C. Layer time must be long enough to allow the preceding layer to cool below the heat distortion temperature. If the layer remains above 90°C, the next layer causes sag on unsupported overhangs. Support material is removed. Annealing of printed parts at 80–90°C for 2 h reduces locked-in stress. Dimensional change during annealing is anisotropic. The part must be fixtured if tolerances are below 0.5% of nominal dimension. Terminal products include low-volume outdoor trim, jigs, and replacement covers where UV resistance is required. The printed part is not a direct substitute for an injection moulded production grade. Destructive testing of a coupon printed in the same build orientation as the final part is advised before qualification.
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