| HS Code | 576597 |
| Density | 1.02 g/cm³ |
| Water Absorption At 24h | 0.10 % |
| Tensile Modulus | 400 MPa |
| Tensile Strength At Break | 40 MPa |
| Elongation At Break | 200 % |
| Flexural Modulus | 350 MPa |
| Notched Izod Impact Strength | No Break |
| Shore D Hardness | 58 |
| Melting Point | 178 °C |
| Vicat Softening Point | 120 °C |
| Linear Mold Shrinkage | 0.4 % |
As an accredited EMS-Grivory Grilamid XE 3997 nat Nylon 12, Dry factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.
| Packing | Packaged in 25 kg sealed, moisture-proof polyethylene-lined paper bags to keep the dry Nylon 12 pellets contamination-free and ready for processing. |
| Container Loading (20′ FCL) | 20′ FCL of EMS-Grivory Grilamid XE 3997 nat Nylon 12, dry, packed in sealed bags on pallets, safely secured for shipment. |
| Shipping | Ship as non-hazardous thermoplastic resin in sealed moisture-barrier bags, kept dry and away from humidity. Use standard ground or freight transport, avoiding extreme heat and prolonged storage. Ensure proper labeling with product name and lot number. No special hazmat requirements under normal conditions. |
| Storage | Store Grilamid XE 3997 nat Nylon 12 in its original, tightly sealed container in a cool, dry area away from direct sunlight and heat sources. Since nylon 12 is hygroscopic, minimize exposure to ambient moisture; reseal promptly after use. Ideal storage temperatures are below 30°C, with low humidity to preserve material properties and processing performance. |
| Shelf Life | Shelf life is indefinite when stored sealed, dry, and away from sunlight; avoid moisture absorption to maintain properties. |
For push-in pneumatic fitting production, the resin is injection-moulded into threaded bodies, release rings, collet seats, and swivel elbows in a single cold-runner tool. The conversion window is defined by the strain-rate sensitivity of the semi-crystalline matrix during ejection: melt temperature at the nozzle is held between 240 °C and 260 °C, cavity wall temperature between 40 °C and 80 °C, and holding pressure between 600 bar and 900 bar. Feedstock that has been exposed to ambient air at RH 60 % or higher for more than 1 h is dried in a desiccant dryer at 80 °C for 4 h to 6 h until residual moisture is below 0.10 % by Karl Fischer titration; moisture above this limit generates surface splay and weakens knit lines in multi-gate tools. Tool venting is maintained at 0.02 mm to 0.03 mm depth to avoid burn marks in fast-cycling configurations. Finished fittings are tested for insertion force, release force, and leak tightness under ISO 14743:2019. Burst pressure is evaluated at 1.5 times the rated working pressure for pneumatic circuits operating between 8 bar and 10 bar. Continuous exposure to hydrolysing mineral oil above 80 °C is outside the service envelope unless secondary annealing at 120 °C for 4 h is implemented. End products include M5-to-G1/2 push-in fittings for factory automation and welding-cell gas supply.
In a production-scale single-screw extrusion line using a 30:1 L/D barrier screw, melt temperature at the die is controlled between 225 °C and 245 °C. Vacuum sizing is applied at 0.2 bar to 0.6 bar negative pressure to maintain outside diameter within ±0.05 mm for a 6.35 mm outside diameter tube. The dried feedstock is conveyed under a dry-air purge at a dew point of −40 °C. If residual moisture exceeds 0.10 %, extrudate develops surface splay and intermittent diameter fluctuation due to steam nucleation at the die lip; this is the primary failure mode in dry PA12 lines with open hoppers in humid plants. The extruded tube is annealed in-line at 110 °C for 2 min to reduce frozen-in orientation before recoiling. Compliance testing follows SAE J844 for cold impact at −40 °C and elevated-temperature burst at 80 °C to 100 °C. Dimensional stability is also checked under DIN 73378 for polyamide tubing in motor vehicles. Zinc chloride road-salt solutions up to 50 °C are resisted without stress cracking; concentrated formic acid and concentrated sulphuric acid remain outside the chemical resistance envelope. End products include tractor-trailer brake actuation lines, air suspension levelling lines, and auxiliary air supply tubing.
| Conversion route | Drying condition | Residual moisture target | Melt temperature range | Tool/cavity temperature | Equipment constraint |
|---|---|---|---|---|---|
| Single-screw tube extrusion | Desiccant dryer at 80 °C for 4 h to 6 h | ≤0.10 % by Karl Fischer | 225 °C to 245 °C | Sizing tank water 20 °C to 40 °C | Barrier screw 30:1 L/D, vacuum vent 0.2 bar |
| Injection moulding of fluid couplings | Dry-air hopper purge; redry 80 °C/4 h if opened above 1 h at RH 60 % | ≤0.08 % | 240 °C to 260 °C | Mould 40 °C to 80 °C | Clamp force 0.5 kN/cm² to 0.7 kN/cm² projected area |
| High-cycle cable tie moulding | Sealed feed from moisture-proof packaging | ≤0.10 % | 230 °C to 250 °C | Mould 30 °C to 60 °C | Melt front velocity >200 mm/s in 1.2 mm sections |
In automotive crankcase ventilation and diesel fuel vapour return quick connectors, the polymer is processed in 16-cavity hot-runner tools with sequential valve gates to control weld-line position. The grade is compared against PA66 under sustained exposure to a 85 vol% gasoline / 15 vol% ethanol test fluid at 60 °C; published data for unreinforced PA12 show lower mass uptake than PA6 and PA66 at equilibrium, which supports tighter interference-fit retention in male-to-female connector geometries. Melt cushion is held at 2 mm to 4 mm and screw decompression at 2 mm to 3 mm to prevent drool from the hot runner. Clamp force is specified at 0.5 kN/cm² to 0.7 kN/cm² of projected part area. Finished couplings are pressure-pulse tested per SAE J2044, with pressure and cycle count fixed by the OEM component drawing; leak testing is performed at 1.5 bar air differential pressure. The natural resin requires laser-markable additive masterbatch at 1.0 wt% to 2.0 wt% when high-contrast part marking is required. End products include quick-connect fittings for closed crankcase ventilation lines, diesel injector return lines, and evaporative canister purge lines.
Cable ties and harness clips for outdoor installations require a balance between flexural stiffness and low-temperature toughness. In a fast-cycling moulding cell with a 32-cavity cold runner tool, melt front velocity is set above 200 mm/s to avoid premature freezing in thin tie sections of 1.2 mm to 1.5 mm wall thickness. The PA12 matrix is processed at melt temperature 230 °C to 250 °C and mould temperature 30 °C to 60 °C; lower mould temperatures reduce cycle time but decrease crystallinity and notched impact resistance in the gate vicinity. Conditioning at 23 °C and 50 % RH for 48 h is specified before tensile and notched impact testing under ASTM D638-14 and ISO 179-1A:2023. The dry-as-moulded state shows higher stiffness but lower ductility than conditioned parts; moulded ties should not be installed directly after ejection because moisture equilibration changes installation force. UV protection in exposed service requires a carbon black masterbatch at 2.0 wt% to 2.5 wt% or an approved UV-stabilized compound; the natural grade alone is not rated for 1000 h xenon arc exposure. End products include releasable cable ties, push-mount harness clips, and photovoltaic array wire clips.
For fibre optic loose tube buffer extrusion, the polymer is selected over PBTP and PVDF where low moisture-induced attenuation shift and peelable access windows are required. In a 24:1 L/D single-screw extruder with a spiral mandrel die, the barrel profile is set from 180 °C in the feed zone to 230 °C at the head. Aramid yarns or ripcords are inserted through a pressure tool before the tube enters a water trough at 20 °C to 25 °C. The melt is filtered through a 50 µm breaker plate to prevent gel contamination from blocking the die ring. Residual moisture is kept below 0.08 % because moisture degradation at processing temperature can generate microvoids in the tube wall. Cable mechanical performance is validated under IEC 60794-1-2, with dimensional stability measured after temperature cycling from −40 °C to 70 °C. The material boundary is adhesion to filling gel; gel compatibility must be confirmed before lot approval. End products include central loose tube fibre optic cables for campus and last-mile outdoor distribution.
Ski binding structural plates, archery bow riser spacers, and bicycle accessory clips are injection-moulded in single-cavity and multi-cavity tools where low-temperature ductility after moisture uptake is the primary acceptance criterion. The pellets are dried to ≤0.10 % residual moisture before moulding at melt temperature 235 °C to 255 °C and mould temperature 40 °C to 70 °C. The higher mould temperature is used for load-bearing parts to increase crystallinity and reduce post-mould shrinkage. Notched impact strength is tested at −30 °C under ISO 179-1A:2023 after conditioning at 23 °C and 50 % RH. Tensile elongation at break is checked under ASTM D638-14 on Type 1A bars. The natural hue accepts solvent-free colour masterbatch at 1.5 wt% to 3.0 wt%, but pigment systems containing strong acids or metal halides should be avoided. Published data for this specific natural grade in perspiration simulant is limited; therefore pre-production chemical compatibility screening is conducted at 40 °C before field release. End products include ski binding housings, archery riser spacers, and bicycle pack clips.
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EMS-Grivory Grilamid XE 3997 nat is a natural-colored polyamide 12 (PA12) product supplied in the dry-as-molded condition. The dry designation defines the moisture baseline at which the manufacturer reports physical data and is not a performance guarantee for unconditioned service. The grade belongs to the flexible PA12 segment and is specified for extrusion and injection molding where high melt strength, low-temperature impact resistance, and reduced flexural modulus are required. In the dry state, residual moisture is maintained below 0.10 wt%, and the property set is reported under ISO 11403-1 data-presentation conventions with reference to ISO 1110 moisture conditioning. The polyamide 12 backbone gives the product lower equilibrium water absorption than PA6 or PA66; this characteristic is evaluated by ISO 62 and affects dimensional stability and dielectric behavior in humid service.
The critical processing boundary for Grilamid XE 3997 nat in single-screw extrusion is residual moisture, not melt temperature alone. A vented single-screw extruder with 25:1 to 30:1 L/D and a barrier screw geometry is typically used to plastify the grade. Melt temperatures between 240 °C and 270 °C are recommended. Below 230 °C, the viscosity number of the dry resin is too high for homogeneous melt formation, and above 280 °C, oxidative chain scission may shift die pressure and reduce Charpy notched impact strength measured according to ISO 179/1eA.
Moisture is the stricter limit. If residual moisture rises above 0.10 wt%, hydrolysis during plastification reduces molecular weight, producing die-head pressure fluctuations of 10–15 bar on a 60 mm single-screw line and causing surface roughness in corrugated tubing. A desiccant dryer set at 80 °C for 4–8 h with a dew point below -30 °C is required when bags have been opened for more than 2 h at relative humidity above 60%. For injection molding, a reciprocating screw with shut-off nozzle and clamp force sufficient for the projected area is used. Mold temperatures from 40 °C to 80 °C control crystallinity, shrinkage, and post-mold dimensional stability.
The melt volume-flow rate of the dry grade, measured at 275 °C under 5 kg load according to ISO 1133-1, places it in the high-viscosity end of PA12 extrusion grades. This high melt strength enables stable parison formation and low die swell in tube and hose dies. It also requires higher head pressure than low-viscosity PA12 grades. Production lines equipped with melt pumps may compensate for pressure sensitivity, but melt temperature must remain below 270 °C to avoid plasticizer loss and volatile emission. Published data for this specific configuration is limited for screw diameters above 90 mm; process capability studies on the actual line are recommended before scale-up.
The dry-as-molded property profile is reported below as representative values. Conditioned values at 23 °C and 50% relative humidity will show lower tensile modulus and higher impact; those values must be used for snap-fit and clip design according to ISO 527-1/-2 and ISO 179/1eA. The thermal values indicate a PA12 melting point near 178 °C and a Vicat softening point that supports short-term contact with elevated-temperature air but not continuous structural load at that temperature. The difference between tensile modulus and heat deflection temperature must be interpreted through viscoelastic response, not through a single thermal index.
| Property | Test method | Dry value |
|---|---|---|
| Density | ISO 1183-1 | 1.02 g/cm³ |
| Water absorption, saturation in water at 23°C | ISO 62 | 1.5% |
| Tensile modulus | ISO 527-1/-2 | 1,000–1,200 MPa |
| Yield stress | ISO 527-1/-2 | 30–38 MPa |
| Nominal strain at break | ISO 527-1/-2 | >50% |
| Charpy notched impact strength at 23°C | ISO 179/1eA | 7–12 kJ/m² |
| Melting temperature | ISO 11357-1/-3 | 178 °C |
| Vicat softening temperature A/50 | ISO 306 | 170 °C |
| Heat deflection temperature at 0.45 MPa | ISO 75-1/-2 | 130 °C |
Extrusion of smooth and corrugated tubing, cable protection conduits, and pneumatic lines accounts for the primary use of XE 3997 nat. In these applications, the grade’s high melt strength enables uniform wall thickness at line speeds of 10–30 m/min on single-screw tubing lines with vacuum sizing and water spray cooling. The lower flexural modulus relative to unplasticized PA12 reduces minimum bending radius in dynamic cable carriers and articulated pneumatic circuits. Chemical resistance to aliphatic hydrocarbons and lubricating oils follows PA12 behavior; for fuel contact, permeation and extraction must be evaluated according to SAE J1681 or the OEM specification, not inferred from density alone.
Compared with unplasticized PA12 compounds in the same viscosity class, Grilamid XE 3997 nat shifts the property envelope toward higher elongation and lower tensile modulus. Under ISO 527-1/-2, dry tensile modulus is approximately 30–40% lower than a typical unmodified PA12, while nominal strain at break is at least twice the value of a stiff PA12. Charpy notched impact strength at -30 °C according to ISO 179/1eA is also higher, which is relevant for fuel vapor return lines exposed to cold impact after underhood thermal aging.
The trade-off is thermal resistance under load. The Vicat softening temperature measured under ISO 306/A50 is lower than that of some unplasticized PA12 grades, and continuous load-bearing use above 120 °C is not recommended without creep testing under ISO 899-1. If the component requires higher hoop stress retention in hot air or aggressive fuel blends, a glass-filled or unplasticized PA12 should be considered. For multi-layer fuel tubing, the grade may serve as a flexible outer layer, but layer adhesion and plasticizer migration must be verified according to the converter’s peel test and long-term fuel exposure protocol.
Handling of dry PA12 requires closed storage and immediate resealing of opened bags. The desiccant drying parameters are not optional when moisture exceeds 0.10 wt%; residual moisture is determined by Karl Fischer titration or the manufacturer’s moisture analyzer. Avoid blending with amine-based color concentrates or additives because these may accelerate oxidative degradation and shift the melt pH. The grade is supplied in natural color and should be colored only with masterbatch approved by the manufacturer. The processing window is narrow in the presence of sulfur-containing flame retardants; published data for this specific configuration is limited.
Regulatory compliance for automotive fluid contact should be verified against REACH Regulation (EC) No 1907/2006, RoHS Directive 2011/65/EU, and the applicable OEM material specification. No ISO 10993 or food-contact claim is implied. For continuous flexure at sub-zero temperatures, notched Charpy values at -30 °C should be verified according to ISO 179/1eA on the specific wall thickness and conditioning state.