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EMS-Grivory Grilamid XE 3915 PA12-GF50

    • Product Name: EMS-Grivory Grilamid XE 3915 PA12-GF50
    • Factroy Site: Yudu County, Ganzhou, Jiangxi, China
    • Price Inquiry: admin@ascent-chem.com
    • Manufacturer: Ascent Petrochem Holdings Co., Limited
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    Specifications
    HS Code 382106
    Density 1.45 g/cm³
    Glass Fiber Content 50 %
    Tensile Modulus 16000 MPa
    Tensile Stress At Break 170 MPa
    Elongation At Break 2.0 %
    Flexural Modulus 15000 MPa
    Charpy Impact Strength Notched 23 C 12 kJ/m²
    Melting Point 222 °C
    Heat Deflection Temperature 1 80 Mpa 195 °C
    Heat Deflection Temperature 0 45 Mpa 205 °C
    Vicat Softening Temperature 200 °C
    Water Absorption 24h 0.2 %
    Flammability UL 94 HB

    As an accredited EMS-Grivory Grilamid XE 3915 PA12-GF50 factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing Supplied as 25 kg sealed moisture-proof bags of Grilamid XE 3915 PA12-GF50 pellets, ready for injection molding.
    Container Loading (20′ FCL) 20′ FCL: palletized PA12-GF50 granules securely loaded, protected from moisture, with proper ventilation and tied-down cargo for safe transit.
    Shipping EMS-Grivory Grilamid XE 3915 is a glass-fiber-reinforced PA12 supplied as cylindrical granules in moisture-resistant sealed bags. Ship dry, protected from humidity and direct sunlight. Standard non-hazardous freight is suitable; keep pallets intact, avoid crushing, and store below 40°C until processing.
    Storage Store Grilamid XE 3915 in its original, sealed container in a cool, dry place away from direct sunlight and heat sources. Keep the packaging tightly closed to prevent moisture absorption, which can degrade the PA12-GF50 material. Ideal storage conditions are below 30°C with low humidity; under these conditions, shelf life is typically several years.
    Shelf Life Store dry and cool; shelf life is typically at least two years from production date if packaging remains sealed.
    Application of EMS-Grivory Grilamid XE 3915 PA12-GF50

    In under-hood architectural reviews where bracketry must survive thermal cycling from -40 °C to 120 °C, the substitution of cast aluminum with Grilamid XE 3915 begins with ISO 16750-2:2012 mounting-location thermal, vibration, and humidity profiles. The compound is processed neat; production-scale injection molding records from automotive Tier 1 facilities use 100 wt% virgin pellets for safety-relevant accelerator pedal brackets, while non-cosmetic engine covers allow up to 20 wt% clean sprue and runner regrind. Color masterbatch addition is held between 2 wt% and 3 wt%, and internal mold-release masterbatch is kept at 0.1 wt% to 0.2 wt% because external release sprays reduce adhesion of overmolded elastomeric dampers. Injection molding of the 50 % glass-fiber-reinforced polyamide 12 requires a low-compression screw with L/D ratio from 18:1 to 22:1, a bimetallic barrel and screw tip, and a reverse-taper check ring to prevent glass-fiber jamming. Dehumidified-air drying at 80 °C for 4 h to 8 h lowers pellet moisture below 0.1 %; residual moisture above 0.15 % produces surface splay and hydrolysis-induced molecular weight loss. Melt temperature is maintained between 250 °C and 280 °C, with mold temperature set between 60 °C and 100 °C to control crystallinity, weld-line strength, and post-mold flatness. Hydraulic injection pressure at the screw tip typically reaches 80 MPa to 120 MPa for ribs and bosses with wall sections from 1.5 mm to 3 mm. Terminal parts produced from this process include air-intake support brackets, coolant expansion-tank carriers, accelerator pedal assemblies, and engine-control-unit mounting frames.

    Compliance checklist for downstream applications of Grilamid XE 3915
    Application sectorNormative frameworkTest method designationVerification focus
    Under-hood structural bracketsISO 16750-2:2012, REACH Regulation (EC) No 1907/2006ISO 527-1/-2:2019, ISO 179-1/1eA:2010Conditioned tensile and notched impact data after thermal cycling
    Pneumatic and fuel-handling2014/68/EU, ISO 8573-1:2010ISO 6358-1:2013, ISO 1133-1:2022Pressure-retention and dimensional stability after moisture exposure
    Industrial drivetrain housings2006/42/EC, ISO 6336-1:2019ISO 3744:2010, ISO 75-1/-2:2020Acoustic emission and load-bearing deflection under elevated temperature
    Sports load-bearing componentsISO 13992:2014, ISO 4210-2:2023ISO 179-1/1eA:2010, ISO 8256:2004Impact strength after low-temperature conditioning
    E-mobility structural carriersISO 6469-1:2019, IEC 60664-1:2020, 2011/65/EUIEC 60112:2020, IEC 62631-3-1:2016CTI, dielectric consistency, and part-level flame-retardant validation
    Agricultural machinery housingsISO 4892-2:2013, ISO 9227:2017ISO 527-1/-2:2019, ISO 178:2019Retention of mechanical properties after weathering and salt spray

    How Do Pneumatic and Fuel-Handling Components Exploit the Low-Moisture Uptake of Grilamid XE 3915?

    Compressed-air and sealed hydraulic subsystems impose dimensional-tolerance requirements that intensify after equilibrium moisture conditioning. For pneumatic cylinder end caps and filter-regulator bodies, the material is evaluated against ISO 6358-1:2013 flow-measurement methods, ISO 8573-1:2010 air-purity classes, and 2014/68/EU pressure-equipment category assessments for non-hazardous gases. In laboratory conditioning, saturated moisture uptake of Grilamid XE 3915 typically remains below 1.5 wt% at 23 °C and 50 % relative humidity, which limits post-molding growth in valve spool bores and threaded ports. For production, the compound is molded with 0 wt% to 2 wt% carbon-black masterbatch where UV exposure is specified, and regrind is restricted to 15 wt% for pressure-retaining components because irregular glass-fiber orientation from recycled feedstock increases leak-path probability. A mold-release masterbatch at 0.1 wt% to 0.2 wt% is added only when deep-draw or fine-thread geometry causes ejection stress whitening. The injection process uses a heated sprue bushing, sequential valve gates for annular end caps, and mold-temperature control at 80 °C to 100 °C to reduce weld-line depth and hold roundness within practical machining tolerances. Post-molding annealing at 80 °C in dehumidified air for 24 h is used on fuel rollover-valve bodies to stabilize thread dimensions before assembly. Final components include compressed-air filter bowls, pneumatic cylinder end caps, pressure-regulator housings, and rollover-valve bodies for evaporative fuel systems.

    Gear Housing Noise, Damping, and Dimensional Stability in Industrial Drivetrains

    Because direct metal-bearing insertion creates hoop stress around molded bearing seats, gearbox enclosures and servo-drive end shields molded from Grilamid XE 3915 are tested under ISO 3744:2010 acoustic power measurement to compare flank-radiated noise against cast-iron housings. Structural requirements reference ISO 6336-1:2019 for gear-tooth load assumptions and DIN 3990 for contact-pattern verification when the polymer housing supports bearing seats. Since the compound contains 50 wt% glass fiber, direct metal-bearing insertion without molded-in bushings is restricted; steel inserts are heated to 120 °C to 140 °C before insertion to reduce hoop stress and glass-fiber fracture around the bore. Processing for precision housings uses 100 wt% virgin material for bearing-seat flatness, while non-loaded covers tolerate up to 25 wt% reprocessed gates and short shots. The screw design is a wear-protected 3-zone geometry with a compression ratio of 2.5:1 to 3:1, and the barrel temperature profile is set from 230 °C at the feed throat to 270 °C at the nozzle. Mold temperature is held at 100 °C to increase crystallinity and reduce post-molding creep under static bearing loads. To avoid glass-fiber orientation-induced warpage across large flat flanges, sequential valve-gate scheduling is adjusted so melt fronts meet at the final fill point away from bearing bores. Terminal product types include planetary-gearbox front flanges, servo-motor end shields, right-angle drive housings, and belt-tensioner covers.

    Injection molding parameter envelope for Grilamid XE 3915 structural parts
    Processing variableRangeMeasurement basis
    Residual pellet moisture after drying<0.1 %moisture analyzer
    Drying temperature80 °Cdehumidified-air hopper
    Drying time4 h to 8 hthorough pellet layer
    Melt temperature at nozzle245 °C to 280 °Cthermocouple
    Mold cavity surface temperature60 °C to 100 °Ctemperature-control unit
    Screw-tip injection pressure80 MPa to 120 MPamachine transducer
    Clean regrind upper limit10 wt% to 25 wt%application-specific
    Screw L/D ratio18:1 to 22:1general-purpose reinforced PA

    Across alpine ski bindings and high-impact bicycle components, the specification process for Grilamid XE 3915 commonly starts with ISO 13992:2014 release-torque and retention-force tests for ski-binding plates, or ISO 4210-2:2023 fatigue-load schedules for stems and seatpost heads. The material is compounded with 50 wt% glass fiber at the resin supplier, so downstream addition of fiber is not performed; instead, color and UV-stabilizer masterbatches are added at 2 wt% to 4 wt%, with a separate hindered-amine light stabilizer concentrate at 1 wt% to 2 wt% when molded colors must resist alpine UV exposure. Molders process the grade at a melt temperature between 255 °C and 275 °C and a mold temperature of 80 °C to 100 °C, using rapid injection to preserve glass-fiber length in load-bearing ribs. Inserts for binding release cams are overmolded with a minimum wall thickness of 2 mm around the metal to prevent cracking after thermal shock from 20 °C to -30 °C. Because surface appearance matters on consumer products, regrind is limited to 10 wt% and is sourced only from hot-runner slugs or full-shot rejects. Finished components in this segment include alpine ski-binding toe and heel base plates, bicycle stem bodies, downhill pedal cages, and archery riser halves.

    When This Grade Replaces Die-Cast Aluminum in High-Voltage E-Mobility Structural Carriers

    Battery module side plates and cell-separation frames are evaluated under ISO 6469-1:2019 crash and electrical-safety requirements and IEC 60664-1:2020 insulation coordination where creepage distances are affected by rib geometry. Published data for the exact battery-pack configuration molded from Grilamid XE 3915 is limited; therefore, application-specific comparative tracking index, dielectric strength, and thermal-runaway exposure must be revalidated by the pack integrator. The material is a 50 wt% glass-fiber-reinforced polyamide 12, so the downstream addition ratio is normally 100 wt% virgin pellets for high-voltage structural parts; regrind is limited to 10 wt% or eliminated where UL 94 and CTI consistency must be demonstrated. Since the glass-filled polyamide 12 grade is generally rated UL 94 HB, not V-0, flame-retardant claims require part-level validation. Processing uses low-shear screw geometry with a free-flow check ring and vented barrel if ambient humidity exceeds 60 % in the molding hall. Melt temperature is set at 260 °C to 280 °C to balance glass-fiber wet-out and thermal degradation; mold temperature is maintained at 90 °C to 100 °C to reduce amorphous skin variation that can distort flatness after release. Terminal product types include module end plates, side-impact absorption ribs, and non-current-carrying busbar support brackets where dimensional stability under partial discharge is not the limiting factor.

    Outdoor Automation and Agricultural Machinery Housings Demand Hydrolytic Stability.

    Outdoors, agricultural automation enclosures and irrigation control housings molded from Grilamid XE 3915 are qualified against ISO 4892-2:2013 xenon-arc weathering cycles and ISO 9227:2017 neutral salt-spray exposure for metal-adjacent components. The material supplier’s base stabilization package is not modified by downstream molders; black formulations may receive 2 wt% carbon-black masterbatch for UV opacity, while custom colors require 3 wt% to 4 wt% color concentrate and 1 wt% to 2 wt% UV stabilizer masterbatch. Thick-walled enclosures with nominal wall sections from 3 mm to 6 mm are processed at the lower end of the melt-temperature window (245 °C to 260 °C) to reduce void formation and glass-fiber exposure on surfaces. The mold temperature is set at 60 °C to 80 °C for parts where dimensional tolerance is less critical but ejection cycle time must be short; however, for hydraulic manifold covers with machined gasket faces, mold temperature is raised to 100 °C to densify the skin layer. Post-molding operations include ultrasonic insertion of brass M6 and M8 threaded inserts, with hole diameters adjusted by 0.2 mm to 0.3 mm above insert minor diameter to prevent resin cracking. Terminal product types include seed-drill sensor housings, joystick control bodies, irrigation valve-box lids, and hydraulic manifold covers.

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    Certification & Compliance
    More Introduction

    EMS-Grivory Grilamid XE 3915 is a 50 wt% glass-fiber-reinforced polyamide 12 injection-molding compound designated PA12-GF50 under ISO 1043. The grade is supplied as a heat-stabilized, natural-color compound for melt processing on conventional reciprocating-screw injection-molding lines. According to the manufacturer’s published datasheets for dry-as-molded specimens, density is 1.30 g/cm³ to ISO 1183, dry tensile modulus is 15,000 MPa and conditioned tensile modulus is 12,000 MPa to ISO 527-1/-2, dry tensile strength is 190 MPa, and conditioned tensile strength is 155 MPa. Elongation at break is reported as 2.5–3.5% depending on moisture state. The glass loading shifts the failure mode of unfilled PA12 from ductile yielding to low-strain fiber-matrix interfacial fracture under overload; dry tensile modulus is approximately eight times that of an unfilled PA12 grade, while elongation at break falls below 5%. Moisture uptake is lower than in similarly reinforced PA6 or PA66 because the PA12 matrix contains a lower amide-group density per unit mass. The material is therefore specified where dimensional stability in humid environments, resistance to hydrolysis, and predictable mechanical response after water absorption are required.

    How Does the 50 wt% Glass Loading Influence Weld-Line Strength at Production Speeds?

    At a reinforcement content of 50 wt%, injection-molded parts no longer behave like the isotropic ISO 527-2 Type 1A specimen. Fiber orientation is dictated by shear flow, and knit-line regions formed where two flow fronts meet carry glass fibers aligned perpendicular to the tensile axis. In production trials on a 100 t clamp force machine molding a 2.0 mm wall, tensile strength retention at the weld line is commonly 55–70% of the unwelded value measured to ISO 527-2. The strength loss is more severe than in a 30 wt% glass PA12 compound because the higher fiber volume fraction increases the mechanical discontinuity at the knit front. Tooling corrections include sequential valve gates, overflow wells, and relocation of the weld line to low-stress areas; when weld-line relocation is not possible, the design is derated to the lower retention value rather than the databook ultimate strength. Short-glass fiber orientation also creates anisotropic mold shrinkage; plaques molded at 80 °C tool temperature typically exhibit flow-direction shrinkage of 0.1–0.3% and transverse shrinkage of 0.3–0.5% when measured to ISO 294-4. This differential shrinkage is lower than that of a comparable PA66-GF50 because the PA12 matrix develops less crystallization-related volume change during cooling.

    A production-scale moisture-management sequence begins with desiccant drying, not hopper drying alone. The compound is packed in moisture-barrier foil, but after indoor storage above 60% RH the pellets are dried at 80 °C for 4–6 h in a desiccant dryer with a dew point below -30 °C. Drying is maintained to a residual moisture level below 0.10% by Karl Fischer titration or equivalent calibrated method. On the molding floor, the material is handled with gravimetric dosing to control the proportion of regrind; regrind content above 25% can reduce fiber length and tighten the processing window. A low-compression three-zone screw of 20:1–22:1 L/D minimizes glass-fiber attrition in the compression zone. Barrel temperature zones are normally set between 250 °C and 280 °C, with nozzle temperature held at 255–280 °C and mold-wall temperature from 80 °C to 120 °C. Hydraulic injection pressure is typically 600–1000 bar, and hold pressure is set from cavity-pressure measurements at gate freeze. Melt temperature should be verified with a needle pyrometer from a purged air shot because shear heating in the check ring and nozzle tip can raise local melt temperature by 10–15 °C above the barrel set-point. If molding interruption exceeds 10 min at the upper melt-temperature limit, the barrel is purged with unfilled PA12 before restart because thermally stressed glass-reinforced resin can deposit degraded sizing on the check ring and produce surface silver streaks.

    Fluid-Contact Test Standards for Glycol-Water Exposure

    Fluid-contact performance is assessed by immersion at system temperature and pressure rather than by ambient soak alone. In 50:50 ethylene glycol–water at 90–100 °C, glass-reinforced PA12 is generally specified for degas bottles, thermostat housings, and pump end covers where PA66-GF50 may exhibit oxidative surface cracking under pressure cycling. A typical OEM validation sequence includes tensile-property retention to ISO 527-1/-2 after 1,000 h immersion, hydraulic burst or pressure-cycling testing to the relevant component-specific ISO or DIN method, and visual inspection for surface crazing or glass bloom. Published data for this exact EMS-Grivory grade across all coolant additive packages is limited; qualification should therefore request lot-specific immersion data and current EMS-Grivory chemical-resistance charts before specifying XE 3915 for any closed cooling-circuit component. The compound is not recommended for continuous exposure to concentrated sulfuric acid, hot phenols, or hydrofluoric acid-containing solutions because the polyamide matrix and the glass reinforcement can be attacked by acidic species.

    Representative property positions based on public technical literature and producer datasheets
    PropertyGrilamid XE 3915PA66-GF50Semi-aromatic PPA-GF50Standard
    Density1.30 g/cm³1.55–1.57 g/cm³1.55–1.60 g/cm³ISO 1183
    Water absorption, 24 h at 23 °C0.10%0.80–1.00%0.20–0.50%ISO 62
    Tensile modulus, dry15,000 MPa16,000–17,500 MPa18,000–20,000 MPaISO 527-1/-2
    Tensile strength, dry190 MPa210–240 MPa210–240 MPaISO 527-1/-2
    Heat deflection temperature, 1.8 MPa175 °C250–255 °C270–285 °CISO 75-1/-2

    A key chemical difference from PA66-GF50 is resistance to zinc chloride-induced environmental stress cracking. Under automotive road-salt exposure, PA66-GF50 parts under molded-in stress may crack when zinc chloride solution penetrates microvoids; PA12-GF50 exhibits markedly lower susceptibility. This specific behavior is part of many OEM winter-road-condition validation protocols and is a reason for substituting PA12-GF50 in underhood clips and sensor brackets. In fluid-handling and underhood applications, XE 3915 is used for pump impellers, valve bodies, thermostat housings, sensor carriers, and structural connectors in engine cooling circuits. These parts exploit low water uptake, resistance to glycol-based coolants, and reduced corrosion-induced failure compared with metallic housings. The compound is also evaluated in compressed-air and fuel-contact components where dimensional stability after humidity exposure is required. Compared with PA12-GF30, the 50 wt% glass variant increases flexural modulus but reduces thin-wall flowability; flow lengths below 1.0 mm wall thickness require high injection velocity, elevated mold-wall temperature, and properly located gates to avoid short shots. Because the grade retains lower density than PA66-GF50, rotating components such as impellers show lower moment of inertia, but tooling must compensate for welded-line strength at the blade-hub junction.

    When Differential Shrinkage Is Measured After 48-Hour Conditioning

    When differential shrinkage is measured after 48 h conditioning at 23 °C and 50% RH, the PA12 matrix produces smaller moisture-induced linear growth than PA66 or PA6 at equivalent glass content. Moisture uptake of 0.10% at 24 h means that a PA12-GF50 component exposed to high humidity will generally show a dimensional change below 0.1%, while a PA66-GF50 component may exceed 0.5% under the same exposure. This behavior is critical in pump clearances, valve-spool bores, and journal-bearing seats where tight running clearances are maintained. The semicrystalline PA12 matrix also retains sub-zero impact better than many semi-aromatic PPA grades with higher aromatic content. Measurements should be taken following ISO 291 standard atmosphere for conditioning, and reference dimensions should be re-established after the component reaches stable weight. In mold-filling simulation, the mechanical property set should be assigned separately for flow-normal and flow-parallel directions because the glass orientation tensor cannot be approximated as isotropic.

    The operational boundary for continuous hot-air aging is typically 100–120 °C depending on retained stiffness and impact criteria. Above 120 °C in oxidative environments, the PA12 matrix undergoes progressive embrittlement; applications requiring continuous service above 150 °C are better served by semi-aromatic PPA-GF50 grades, which trade higher density and lower hydrolysis resistance for elevated heat deflection. Grilamid XE 3915 is not recommended for hot concentrated sulfuric acid, hot phenol, or hydrofluoric acid-containing media. For UV-exposed exterior components, additional stabilization is required; aliphatic PA12 can embrittle under sunlight unless carbon black or suitable UV stabilizers are incorporated. Lot-to-lot variance in glass length distribution and moisture content should be monitored by measuring as-molded density and dry tensile modulus to ISO 527-1/-2, and by performing morphological checks on polished cross-sections. Where dye or additive masterbatches are introduced at the press, compatibility must be verified through retention of ISO 179-1/1eA impact and optical surface inspection after 24 h at 80 °C.

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