| HS Code | 861945 |
| Product | EMS-Grivory Grilamid LVX-50H black 9230 |
| Material | PA12-GF50 (Polyamide 12, 50% glass fiber reinforced) |
| Color | Black 9230 |
| Density | 1.58 g/cm³ |
| Glass Fiber Content | 50% |
| Tensile Modulus | 16000 MPa |
| Tensile Strength At Break | 200 MPa |
| Elongation At Break | 2% |
| Charpy Impact Strength Notched 23 C | 18 kJ/m² |
| Charpy Impact Strength Unnotched 23 C | 70 kJ/m² |
| Melting Point | 178 °C |
| Heat Deflection Temperature At 1 8 Mpa | 170 °C |
| Heat Deflection Temperature At 0 45 Mpa | 175 °C |
As an accredited EMS-Grivory Grilamid® LVX-50H black 9230 PA12-GF50 factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.
| Packing | EMS-Grivory Grilamid LVX-50H black 9230 is supplied in 25 kg sealed, moisture-proof polyethylene bags, labeled with batch details. |
| Container Loading (20′ FCL) | 20′ FCL: palletized bags of Grilamid LVX-50H black 9230 PA12-GF50, securely loaded and braced for safe transport. |
| Shipping | Grilamid® LVX-50H black 9230 is supplied as moisture-protected sealed pellets. Ship in clean, dry containers or original packaging, avoiding excessive heat and humidity. Non-hazardous per transport regulations; handle with standard industrial care. Keep upright, protect from damage, and store away from direct sunlight to preserve material quality during transit. |
| Storage | Store Grilamid® LVX-50H black 9230 (PA12-GF50) in its original, unopened packaging in a cool, dry, well-ventilated area away from direct sunlight, heat sources, and moisture. Keep containers tightly sealed to prevent water absorption. Ideal storage temperature is below 30°C. Avoid prolonged exposure to humidity, which can degrade performance. Handle with care to prevent dust contamination. |
| Shelf Life | Store dry, cool, and sealed; Grilamid LVX-50H black 9230 remains stable for at least two years under recommended conditions. |
Automotive underhood thermal management systems impose continuous exposure to hot aqueous glycol and cyclic thermal gradients between -40 °C and 130 °C, which eliminates many glass-reinforced aliphatic polyamides because of hydrolysis and dimensional instability. Grilamid LVX-50H black 9230 is a 50 wt% glass-filled PA12 injection moulding compound, and it is used for coolant flanges, thermostat housings and EGR cooler end caps where threaded attachment features must retain torque after thermal cycling. In pressure-bearing parts the formulation addition ratio is normally 100% virgin compound, with sprues and runners reintroduced at a maximum regrind let-down of 20–30 wt% only after de-dusting and re-drying; any material exposed to coolant leakage for more than 24 h is excluded from rework. The material is dried in a desiccant dryer at 80 ± 5 °C to a residual moisture of ≤0.05 wt% because residual moisture above this threshold degrades hydrolytic stability at processing temperatures and increases splay on moulded surfaces. Production injection moulding of these components uses bimetallic barrels and wear-resistant screw flights because of the abrasive 50% glass-fibre loading; melt temperatures are maintained between 260 °C and 280 °C, mould temperatures are held at 80–100 °C, hold pressure is set at 80–120 MPa, and screw L/D ratio is selected in the 20:1–24:1 range to manage fibre-length retention. Process capability requirements are aligned with IATF 16949. Compliance is anchored to ISO 16396-2 for polyamide moulding materials and ISO 527-1/-2 for tensile property validation after conditioning; automotive processors additionally verify cooling-fluid compatibility by immersion testing under ISO 175 in a 50:50 ethylene glycol/water mixture at 130 °C for 1,000 h, followed by a torque-retention check on threaded bosses. Terminal product types produced from this grade include coolant flanges, thermostat housings, heater-core quick connectors and EGR cooler end caps.
In electric vehicle battery enclosures, die-cast aluminium is replaced only when the polymer composite simultaneously provides specific stiffness, creep resistance at 70–85 °C, and sufficient Charpy impact resilience to survive crush and vibration loads without electrical short-circuit risk through broken brackets. The PA12-GF50 compound achieves this by combining a high fibre-volume fraction with the low moisture affinity of the PA12 matrix; after conditioning at 23 °C and 50% relative humidity, the material absorbs approximately 0.4–0.6 wt% water, which is markedly lower than PA66-GF50 and reduces dimensional change at battery-pack bolting interfaces. Formulation addition ratios for mass-production battery peripheral parts allow 20–25 wt% clean regrind from sprue and runner systems in non-critical cable-clamp and bracket bodies, whereas busbar retention rails and cantilevered module mounts are run from 100% virgin material; all feed streams are pre-dried at 80 °C to ≤0.05% moisture and conveyed under dry air. If silo storage humidity exceeds 60% relative humidity, drying time is extended from 4 h to 8–12 h. The production process is injection moulding on an electric or hydraulic machine with clamp force calculated from projected area at 0.5–1.0 kN/cm² to maintain flatness of plate geometries; sequential valve-gated hot runners are used to reposition weld lines away from high principal stress regions, and screw back pressure is held at 50–80 bar to homogenize glass distribution without excessive fibre fracture. Mould temperatures between 90 °C and 120 °C are typical for plate surfaces requiring low fibre read-through and high geometric repeatability. Compliance is assessed under RoHS Directive 2011/65/EU Annex II and REACH Regulation (EC) No 1907/2006 for SVHC content; the compound carries a UL 94 HB classification at recommended thickness, but it is not a UL 94 V-0 grade and must be separated from direct arc or spark sources. Mechanical acceptance criteria are referenced to ISO 527-1/-2, ISO 178, and ISO 179/1eA for notched Charpy. Terminal product types include battery module end-plate retainers, busbar support rails, high-voltage cable clamps, and service-disconnect bracket housings.
Industrial compressed-air manifold blocks require dimensional stability under pressure pulsation and resistance to compressor oil mist to justify replacing extruded aluminium. The PA12-GF50 compound is selected for ported manifolds and solenoid valve islands operating at working pressures up to 1.6 MPa and temperature cycles between -20 °C and 60 °C; the long-chain aliphatic matrix resists hydrolysis by warm condensate and maintains thread strength in repeated assembly. Published data for this specific fluid-power configuration is limited, so burst-pressure validation is performed on the finished port geometry rather than extrapolated from raw material tensile data. The formulation addition ratio for standard pneumatic manifold bodies is 100% virgin material at the thread bosses and sealing faces, with a maximum 20 wt% regrind fraction permitted only in non-pressure-bearing covers and blanks; all material is dried at 80 ± 5 °C for 4–8 h to a moisture ceiling of 0.05 wt% before processing. Injection moulding of thick manifold sections with 1/8–1/2 inch port features uses melt temperatures of 255–270 °C and mould temperatures of 80–100 °C; gate locations are moved to the thickest bosses to avoid jetting at thread core pins and to minimise weld lines at sealing ribs. Screw rotational speed is limited to 80–150 rpm to reduce fibre attrition. Compliance is anchored to ISO 4414:2010 for pneumatic fluid power systems and ISO 8573-1:2010 for compressed air quality classes; material testing follows ISO 527-1/-2 and ISO 179/1eA, while pressure-life testing is conducted at 1.25× maximum working pressure for 500,000 cycles under square-wave load. Terminal product types include manifold blocks, pneumatic valve islands, FRL brackets and ported adapter plates.
| Application area | Standard designation | Test condition / processing parameter | Material acceptance criterion |
|---|---|---|---|
| Automotive underhood coolant components | ISO 16396-2; ISO 175; IATF 16949 | 50:50 ethylene glycol/water at 130 °C for 1,000 h | No leak path, no thread cracking, torque retention after immersion |
| EV battery peripheral mounting components | RoHS 2011/65/EU; REACH 1907/2006; UL 94 HB; ISO 179/1eA | Notched Charpy at 23 °C; UL thickness ≥1.5 mm | No brittle failure at assembly; no SVHC report |
| Industrial pneumatic manifold systems | ISO 4414:2010; ISO 8573-1:2010; ISO 527-1/-2 | 1.25× rated working pressure, 500,000 cycles | No fatigue cracking or leak at ported interfaces |
Water-meter housing bodies produced from unreinforced PA66 often exceed tolerance after saturation because of equilibrium moisture uptake; the PA12 matrix in the compound reduces this drift and allows tighter metering chamber tolerances without overmoulding metal reinforcement. In non-potable water and industrial metering applications, the material is moulded into housings and pump components exposed to water at 5–40 °C and intermittent pressure spikes up to 2.0 MPa. Compliance testing for this segment includes ISO 62 for water absorption, ISO 527-1/-2 for tensile properties after conditioning, ISO 178 for flexural modulus, and ISO 9080 for hydrostatic design basis where the housing functions as a pressure-retaining component; processors are cautioned that potable-water approvals such as NSF/ANSI 61 or KTW are not automatically conferred by the raw material and must be validated on the final assembly. The formulation addition ratio in water-contact bodies is limited to 15–20 wt% regrind for impeller hubs and pump casings, and 25 wt% maximum for non-load-bearing meter covers; all regrind is dried together with virgin material at 80 °C to a moisture level of ≤0.05 wt% before moulding. Production is typically injection moulding with an oil-heated mould maintained at 100–120 °C to minimize surface porosity at sealing grooves; packing pressure is held at 80–100 MPa until gate freeze, and cooling time for a 2.5 mm wall is set at 25–35 s to avoid post-demoulding dimensional recovery. Gate location is placed at the thick hub section and away from the metering chamber to orient glass fibres circumferentially rather than axially along sealing faces. Terminal product types include industrial water-meter housings, submersible pump impeller hubs, valve bodies and flow-sensor housings.
When loading frequency exceeds 2 Hz in orthotic frame injection moulding, weld lines and glass-accumulation zones are exposed to microcrack initiation even when monotonic tensile values are acceptable. The PA12-GF50 compound is applied in serial and custom ankle-foot orthosis side struts, ski touring binding frames and cycling shoe chassis where specific stiffness must be paired with fatigue endurance and low density. For load-bearing orthotic elements, the formulation addition ratio is 100% virgin material; regrind is excluded from the load path because process heat history increases fibre scission and reduces fatigue scatter. If a colour masterbatch is used, it is limited to 1.0–1.5 wt% and must employ a PA12 carrier because incompatible carriers lower impact toughness. The material is dried at 80 ± 5 °C to ≤0.05% moisture; injection moulding uses melt temperatures of 260–280 °C, mould temperatures of 80–110 °C, and high injection velocity with controlled pack to move the weld line toward a low-stress edge identified by mould-filling simulation. Post-moulding annealing at 100–120 °C for 2–4 h reduces residual stress in thick sections and improves dimensional stability. Compliance is based on ISO 527-1/-2, ISO 178, and ISO 179/1eA; where the orthotic device is placed on the market in the EU, the finished product must additionally meet Medical Device Regulation (EU) 2017/745, including ISO 10993-5 for cytocompatibility unless the component is separated from skin by a liner. Terminal product types include PA12-GF50 orthotic side struts, ski touring binding frames, and high-stiffness cycling shoe plates.
Across high-cycle pick-and-place end-of-arm tooling, the unsprung mass of each gripper finger multiplies motor load and limits cycle acceleration; replacing steel with the compound reduces mass while the 50% glass reinforcement maintains bending stiffness in thin cross-sections. The material is processed into gripper fingers, structural links and adapter plates used on robots with payload capacities of 3–25 kg, where impact against fixtures and occasional cutting-fluid mist are the main stressors. Compliance for this robotic tooling segment is referenced to ISO 10218-1:2011 and ISO 10218-2:2011 for robot system design, with material acceptance via ISO 527-1/-2, ISO 178 and ISO 179/1eA; because the compound is not intrinsically conductive, electrostatic discharge safety must be evaluated separately for EOAT used near sensitive electronics. The formulation addition ratio is 100% virgin material for fingers and load-bearing links, with up to 20 wt% regrind in non-critical clamp bodies after drying at 80 °C to ≤0.05% moisture. Injection moulding of these parts requires hardened check rings and screw tips because the high glass loading accelerates wear; melt temperature is kept at 260–280 °C and mould temperature at 80–100 °C, while gas-assisted moulding is avoided because gas injection in glass-filled PA12 can create anisotropic hollow sections with unpredictable fibre orientation and reduced bending strength. Terminal product types include gripper fingers, end-of-arm tooling structural links, quick-change tooling plates and palletising clamps.
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EMS-Grivory Grilamid® LVX-50H black 9230 is a heat-stabilized 50 wt% glass-fiber-reinforced polyamide 12 injection molding and extrusion compound. The generic designation is PA12-GF50 under ISO 1043-1; the black 9230 suffix denotes the color concentrate and lot reference system, not a separate polymer modification. Published dry-as-molded data from the manufacturer’s technical datasheet report density of 1.45 g/cm³ per ISO 1183 and tensile modulus of 14,000 MPa per ISO 527-1/-2. The product sits between unreinforced PA12, with its low moisture uptake and chemical resistance, and stiffer 50 wt% glass-filled compounds based on PA66 or PPA that demand higher drying and melt temperatures.
At 50 wt% loading, discontinuous E-glass filaments produce mechanical anisotropy dominated by flow orientation. Tensile modulus rises from roughly 1,400–1,600 MPa for dry unfilled PA12 to 14,000 MPa, while tensile elongation at break falls to 3.0%. The modified product retains only a fraction of unfilled PA12’s snap-fit abuse capacity; outer-fiber strains in snap geometries should remain below 1.5% to avoid brittle interface cracking between the PA12 matrix and sized glass surfaces. Notched Charpy impact is 20 kJ/m² at 23 °C per ISO 179/1eA, while unnotched Charpy impact is 90 kJ/m² per ISO 179/1eU. Relative to PA12-GF30, stiffness increases from approximately 8,000 MPa to 14,000 MPa, but elongation drops and melt viscosity rises; hot-runner pressure drop therefore increases at equivalent wall thickness.
The following table consolidates the single-point values most often used for initial design comparison. Specimens are dry-as-molded at 23 °C and 50% RH unless otherwise noted; conditioned values for stiffness and strength are lower after moisture equilibrium.
| Property | Typical value | Test standard |
|---|---|---|
| Density | 1.45 g/cm³ | ISO 1183 |
| Tensile modulus, dry | 14,000 MPa | ISO 527-1/-2 |
| Tensile stress at break, dry | 180 MPa | ISO 527-1/-2 |
| Tensile elongation at break, dry | 3.0% | ISO 527-1/-2 |
| Charpy notched impact strength, 23 °C | 20 kJ/m² | ISO 179/1eA |
| Charpy unnotched impact strength, 23 °C | 90 kJ/m² | ISO 179/1eU |
| Melting point, DSC | 178 °C | ISO 11357-1/-3 |
| Heat deflection temperature, 1.8 MPa | 170 °C | ISO 75-1/-2 |
| Heat deflection temperature, 0.45 MPa | 175 °C | ISO 75-1/-2 |
| Vicat softening temperature, VST/B50 | 175 °C | ISO 306 |
| Water absorption at saturation, 23 °C | 1.2% | ISO 62 |
| Mold shrinkage, flow/transverse | 0.1–0.3% / 0.3–0.6% | ISO 294-4 |
Material preparation before compounding or molding begins with moisture extraction. A closed-loop desiccant dryer with a dew point of -40 °C is maintained at 80 °C for 4–12 h until residual moisture falls below 0.10 wt%. Hydrolysis during plastication becomes irreversible when residual moisture exceeds 0.15 wt% at the feed throat; visible splay, loss of melt strength, and a drop in notched impact strength are common production-line failure indicators. Conveying from dryer to feed throat is kept below 15 min when shop-floor relative humidity exceeds 60%.
Compounding of the 50 wt% chopped glass into PA12 is performed on co-rotating twin-screw extruders with L/D ratio from 36:1 to 44:1. Glass is side-fed after polymer melting to limit fiber attrition; vacuum venting at -0.08 MPa removes volatiles. Screw speeds above 400 rpm increase fiber breakage and reduce notched impact strength. At the injection press, nozzle melt temperature is set between 240 °C and 280 °C; thin-wall sections use the upper bound, while thick sections are limited to the lower bound to minimize thermal degradation. Mold-wall temperature is selected from 60 °C to 100 °C. At mold temperatures below 60 °C, the non-isothermal skin freezes before glass-fiber orientation can relax, increasing flow-to-transverse shrinkage asymmetry. Injection pressure typically reaches 80–140 MPa, with back pressure from 3–7 MPa and screw rotation speeds from 50–150 rpm. Screws, check rings, and nozzles hardened for glass-filled compounds are required; standard nitrided screws exhibit accelerated wear on production lines running high glass loadings.
Hot-runner residence time should not exceed 10 min; beyond this, PA12 molecular weight reduction produces black specks near the gate and brittle weld lines. Valve-gate hot runners with full-round channels of 3–6 mm diameter minimize glass-fiber breakage. Fiber attrition in small gates below 1 mm thickness reduces tensile strength at weld lines. Screw geometry should use a low compression ratio between 2.0:1 and 2.5:1; high compression screws generate excessive torque and glass attrition. Gas venting in the cavity is set at 0.01–0.03 mm depth. Inadequate venting increases burn marks and weld-line weakness, especially in vented-pin cold-runner systems.
Direct substitution is not thermodynamically neutral. PA66-GF50 typically shows higher dry heat deflection, often in the range of 245–250 °C at 1.8 MPa per ISO 75-1/-2. PA12-GF50 has a dry HDT/A near 170 °C, which restricts continuous underhood exposure where metal-adjacent surface temperatures exceed 150 °C. The conversion is justified when the failure mode is not thermal softening but environmental stress cracking from zinc chloride road salts, methanol-containing fuel blends, or long-term coolant exposure. PA12 has significantly lower saturated water uptake than PA66; for reinforced grades, the practical difference in equilibrium moisture is approximately 1.2% versus 4.5–5.5% depending on coupon thickness and glass-matrix adhesion. Lower moisture absorption reduces hygroscopic swell and property loss in wet compartments, but mechanically loaded weld lines require destructive testing under ISO 527-1/-2 after conditioning because published data for this specific configuration is limited.
Compared with PPA-GF50, the PA12-GF50 grade processes in a lower melt-temperature window of 240–280 °C instead of 320–350 °C, and mold temperature remains 60–100 °C instead of 120–150 °C. The tradeoff is thermal: PPA-GF50 retains load-bearing capacity at higher continuous-use temperatures, while PA12-GF50 remains limited by the 170 °C HDT/A. The PA12 grade is therefore assigned to fluid-line connectors, sensor housings, and manifold components rather than engine-mounted structural brackets exposed to sustained high heat.
PA12-GF50 retains the low aliphatic hydrocarbon permeability of PA12, but glass fibers reduce the effective diffusion path only modestly because permeation occurs through the amorphous PA12 phase. For fuel-system connectors, permeative emissions are assessed at system level under vehicle SHED protocols rather than on the raw material alone. Chemical resistance is governed by the PA12 matrix: aromatic chlorinated solvents, strong mineral acids, phenols, and concentrated formic acid degrade the polymer, while acetone, aliphatic hydrocarbons, diesel, zinc chloride solutions, and glycol-water mixtures are generally tolerated under low internal stress. Resistance to environmental stress cracking is measured under ISO 22088-3 or ASTM D1693 with injection-molded coupons; the glass-fiber phase tends to reduce ESC crack growth relative to unfilled PA12 only when fiber orientation is not normal to the imposed tensile strain.
Dimensional stability is anisotropic. Mold shrinkage parallel to flow is 0.1–0.3%, transverse 0.3–0.6% per ISO 294-4. Post-mold moisture uptake can add 0.05–0.15% linear expansion in the thickness direction. Parts requiring ±0.05 mm flatness over 100 mm length are evaluated with warpage simulation and conditioned dimensional audits; published data for this specific configuration is limited. Regulatory status is lot-dependent. Unfilled PA12 grades may be considered for food-contact use under FDA 21 CFR 177.1500 or EU 10/2011, but the glass-fiber content and black 9230 pigmentation require explicit manufacturer certification before such use is claimed.
Typical uses are injection-molded quick connectors, pneumatic couplings, fuel-system flanges, filter housings, pump impellers, sensor bodies, and industrial manifold blocks. The grade is selected where PA6-GF50 shows unacceptable moisture-induced dimensional change or where acetal-based alternatives fail in alkaline or fuel-alcohol environments. In electrical and electronic applications, the 170 °C HDT/A is below lead-free reflow peak temperatures of 260 °C; therefore the material is not suitable for soldered surface-mount carriers. For structural brackets exposed to cyclic loading, design allowables use conditioned tensile modulus and account for weld-line strength retention below base material values; part-specific fatigue validation remains mandatory.