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EMS-Grivory Grilamid LV-65H FWA nat Nylon 12, 65% Glass Fiber Filled, Dry

    • Product Name: EMS-Grivory Grilamid LV-65H FWA nat Nylon 12, 65% Glass Fiber Filled, Dry
    • Factroy Site: Yudu County, Ganzhou, Jiangxi, China
    • Price Inquiry: admin@ascent-chem.com
    • Manufacturer: Ascent Petrochem Holdings Co., Limited
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    Specifications
    HS Code 966083
    Product EMS-Grivory Grilamid LV-65H FWA nat Nylon 12, 65% Glass Fiber Filled, Dry
    Condition Dry
    Glass Fiber Content 65%
    Density 1.66 g/cm³
    Water Absorption 24h 0.20%
    Tensile Modulus 20000 MPa
    Tensile Strength At Break 220 MPa
    Elongation At Break 2%
    Flexural Modulus 19000 MPa
    Charpy Impact Strength Notched 23 C 8 kJ/m²
    Charpy Impact Strength Unnotched 23 C 60 kJ/m²
    Melting Point 220 °C
    Heat Deflection Temperature 1 80 Mpa 200 °C
    Volume Resistivity 1E14 ohm·cm
    Dielectric Strength 30 kV/mm

    As an accredited EMS-Grivory Grilamid LV-65H FWA nat Nylon 12, 65% Glass Fiber Filled, Dry factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing Supplied in 25 kg moisture-proof sealed polyethylene-lined bags, dry, with product identification and lot traceability, on shrink-wrapped pallets.
    Container Loading (20′ FCL) 20′ FCL container loading for dry nylon 12 granules, 65% glass fiber filled, palletized bags, secure, moisture-protected, full container load.
    Shipping Grilamid LV-65H is supplied as moisture-sensitive nylon 12 pellets in sealed, dry packaging. Ship in standard dry containers or trucks, protected from rain and humidity. No hazardous goods classification required. Store below 50°C, keep bags sealed, and avoid prolonged exposure to moisture before processing.
    Storage Store in a cool, dry area in its original sealed container to prevent moisture absorption, which can degrade the nylon 12 matrix. Keep away from direct sunlight, heat sources, and UV exposure. Maintain temperatures below 30°C. Ensure good ventilation and protect from physical damage, dust, and contamination. Proper handling preserves mechanical properties and processing performance.
    Shelf Life Shelf life is typically 2 years when stored in original, unopened packaging in a cool, dry place.
    Application of EMS-Grivory Grilamid LV-65H FWA nat Nylon 12, 65% Glass Fiber Filled, Dry

    At the injection molding cell for high-pressure gaseous-fuel connector bodies, EMS-Grivory Grilamid LV-65H FWA nat Nylon 12 with 65 wt% glass fiber loading replaces lower-modulus PA12 in the flange area where bolt-retention force and creep resistance control leak-tightness after thermal cycling. The feedstock is dried to a residual moisture content of ≤0.10 wt% using a desiccant dryer with a dew point of ≤-30 °C and an air temperature of 80 °C for 4–8 h, verified by ISO 15512:2019. Lot-to-lot variability is controlled at receiving by melt volume-flow rate measurement under ISO 1133-1:2022 at 275 °C with a 2.16 kg load, and by ash content per ISO 3451-1 to confirm the 65 wt% glass loading. Industry compliance for the finished connector bodies is documented against SAE J2044 for automotive quick-connect interfaces where the design retains a liquid-fuel connection; compressed hydrogen vehicle fuel system components are validated against the applicable sections of UN ECE R134 or ANSI/CSA HGV 3.1 only when specified by the OEM, because low-temperature burst and permeation requirements are system-level and not material-specific. Formulation addition ratio for the pressure shell is 100 wt% virgin compound; reprocessed sprue-and-runner material from the same grade may be incorporated up to 20 wt% of the total shot weight only in non-pressure-retaining retention features, after demonstrating at least 90% tensile strength retention relative to virgin material according to ISO 527-2. The production process uses a conventional hydraulic injection molding machine with a screw L/D of 20:1–24:1, a compression ratio of 2.0:1–2.5:1, and a shut-off nozzle to avoid drool from the high glass content. Melt temperature is controlled to 260–280 °C, mold surface temperature to 80–100 °C, and injection velocity is profiled to maintain a flow-front velocity below 300 mm/s at the gate to limit glass-fiber orientation anisotropy. Holding pressure is set at 60–80 MPa until gate freeze, and cooling time is derived from part-wall temperature decay rather than a fixed timer. Terminal product types include rigid quick-connect bodies for compressed natural gas and hydrogen fuel systems, flange retention clips, sender unit locking collars, and fuel-line bracket inserts that require dimensional stability under hood temperature excursions.

    What Limits Gate Freeze Time in Pneumatic Valve Manifolds Produced from 65% Glass-Reinforced PA12?

    The conversion of pneumatic valve manifold blocks from die-cast aluminium to EMS-Grivory Grilamid LV-65H FWA nat is governed less by inline viscosity than by the solidification rate at the heavily glass-loaded gate land, where freeze-off begins when the melt at the gate interface drops below the crystallization onset of PA12. Compliance for the assembled component is defined under ISO 4414:2010, while the compressed-air supply is filtered and dried to a pressure dew point of ≤3 °C consistent with ISO 8573-1:2010 class 2 for dry indoor pneumatic systems. Formulation addition ratio is 100 wt% dry compound at the machine hopper; regrind may be reintroduced at ≤25 wt% only if the granulate passes a dust-content screen of 0.5 wt% maximum fines below 0.25 mm to avoid screw-bridging at the feed throat. Production-scale equipment includes a twin-channel hot runner with sequential valve-gate control, a mold temperature unit maintaining 85–100 °C on the moveable and fixed halves, and cavity pressure sensors in each manifold body cavity to switch from injection to holding at 400–500 bar cavity pressure. Injection is performed at a melt temperature of 265–285 °C, with screw back pressure kept low at 2–5 MPa to minimize glass fiber attrition. The primary processing conflict is that the gate land must remain molten long enough to transmit holding pressure into the thick bosses, while excessive barrel residence time above 300 s causes surface splay and loss of notched Charpy impact strength measured by ISO 179-1/1eA. End-product types from this process include modular pneumatic valve manifold blocks, filter/regulator/lubricator housing bases, actuator end caps, and porting plates with machined O-ring grooves requiring flatness of ≤0.10 mm across a 200 mm sealing face.

    Because the 65 wt% short-glass reinforcement in EMS-Grivory Grilamid LV-65H FWA nat drives anisotropic mold shrinkage, with typical values for highly glass-filled PA12 of 0.10%–0.40% depending on flow direction when measured on ISO 294-4:2018 plaques, high-voltage interlock housing tooling requires separate insert dimensions for cores perpendicular to flow. Regulatory screening for electrical enclosure sub-components follows IEC 60664-1:2020 for creepage and clearance design, and the material may be assessed for flammability according to UL 94 at the final part thickness; published data for this specific configuration is limited, so the supplier datasheet and a first-article flammability test at the minimum production wall thickness form the acceptance record. Feedstock formulation ratio in thin-wall housing production is 100 wt% natural compound; if color identification is required, only a PA12-based black masterbatch is added at ≤1.5 wt%, and the final mechanical property set is re-verified because even low pigment loadings alter gloss and can reduce weld-line tensile strength. The downstream production process uses an all-electric injection molding machine with a 40 mm screw, segmented feed zones set from 240 °C at the throat to 275 °C at the nozzle, and a mold temperature of 90–105 °C to reduce post-mold warpage. After molding, parts are placed on a constrained cooling fixture for 20 min and then conditioned at 23 ± 2 °C and 50 ± 10% relative humidity for 48 h before dimensional inspection on a coordinate measuring machine. Terminal product types include high-voltage interlock connector bodies, electric vehicle battery management unit housings, sensor mounting frames, and industrial control enclosure structural inserts in which thread-forming screw bosses must survive repeated assembly torque.

    ApplicationNormative referenceTest fluid / conditionRequired evidence
    Gaseous-fuel connector bodiesSAE J2044, UN ECE R134, ISO 527-2Fuel C, -40 °CTensile strength retention ≥90%
    Pneumatic manifold blocksISO 4414:2010, ISO 8573-1:2010Compressed air dew point ≤3 °CFlatness ≤0.10 mm
    Electrical housingsIEC 60664-1:2020, UL 941,000 V creepage, minimum wall thicknessCTI per IEC 60112:2020; flame class at final thickness
    Fuel sender flangesSAE J1681, ASTM D543-21Fuel C + 10% ethanol at 80 °CTensile strength retention after 1,000 h
    Hydraulic manifoldsISO 175:2010, ISO 178Mineral oil at 85 °CFlexural modulus retention after 1,000 h
    Pump wear ringsISO 175:2010, ISO 899-2, NSF/ANSI 61 if potableWater-glycol at 60 °CDimensional stability; short-term creep rupture

    Fuel System Sending Unit Flanges and Ethanol Exposure Limits

    Fuel system sending unit flanges molded from EMS-Grivory Grilamid LV-65H FWA nat use the low equilibrium moisture regain of PA12, measured by ISO 62:2008, to resist dimensional shift during continuous immersion in gasoline-ethanol blends; however, qualification must include aggressive alcohol service rather than routine gasoline exposure alone. Industrial compliance for this component class is anchored by SAE J1681 surface-discoloration and fuel-resistance screening, supplemented by ASTM D543-21 immersion in Fuel C and in Fuel C containing 10% ethanol, with tensile properties after immersion measured according to ISO 527-2. The formulation addition ratio for the sealing flange body is 100 wt% virgin dry compound; regrind from the same grade is limited to ≤20 wt% of shot weight and is prohibited from the weld-line region around the connector boss because the Charpy notched impact strength measured by ISO 179-1/1eA becomes the limiting acceptance criterion. Downstream production uses a multi-cavity hot-runner mold with a hydraulically sequenced valve gate, a mold temperature of 85–95 °C, and a melt temperature of 265–280 °C; the injection profile is slowed through the flange perimeter to prevent jetting at the sealing lip and to maintain glass-fiber orientation parallel to the sealing surface. After ejection, flanges are annealed at 100 ± 5 °C for 1 h in a circulating-air oven to relieve hoop stress, then leak-tested with helium at 100 kPa differential pressure. Terminated part categories include fuel pump mounting flanges, sending unit closure plates, fuel line retainer sockets, and tank access covers, all of which require low creep under clamp load after 1,000 h at 80 °C. Operational boundary: continuous exposure to methanol blends above 15 vol% or to aggressive sour gasoline with peroxide species is outside the known industrial dataset for this material and should require supplementary testing on molded plaques before production release.

    When Hydraulic Manifold Flatness Must Remain Below 0.15 mm After 85°C Oil Aging

    When hydraulic manifold flatness must remain below 0.15 mm after 85 °C oil aging, EMS-Grivory Grilamid LV-65H FWA nat is processed with substantially longer cooling time than unreinforced PA12 because the 65 wt% glass phase raises both thermal conductivity and the internal residual stress locked into thick bosses. Compliance documentation for the material in oil-contacting service uses ISO 175:2010 for resistance to mineral oil at 85 °C and ISO 178 for flexural modulus after immersion, with aging periods extended to 1,000 h to expose the approach to equilibrium. Formulation addition ratio remains 100 wt% virgin material for first-shot parts; regrind may be reintroduced at ≤15 wt% only when the molded part passes the dimensional acceptance protocol after thermal cycling, because the glass fiber length reduction in recycled material shifts anisotropic shrinkage. The production route uses an injection molding machine with a screw L/D of 22:1, a melt temperature of 270–285 °C, and a mold temperature of 90–105 °C; cavity pressure is held at 500–600 bar until the gate cools below the PA12 recrystallization temperature, which is estimated from differential scanning calorimetry rather than assumed from standard cooling tables. After molding, hydraulic manifold blanks are clamped between stress-relief plates and held at 95 ± 5 °C for 2 h, then flatness is measured on a granite surface plate using a dial indicator with 0.01 mm resolution after 24 h conditioning. End products include hydraulic valve adapter plates, pump inlet manifolds, oil filter mounting flanges, and solenoid valve mounting blocks, all of which require CNC-machined O-ring grooves and flat sealing surfaces. The material is unsuitable for hydraulic systems using phosphate-ester fire-resistant fluids unless the OEM confirms compatibility by long-term exposure data; aggressive additive packages containing alkaline components should be excluded from validation testing.

    Thermoplastic pump wear rings and bearing cages molded from this compound use the low saturated moisture regain of PA12 to maintain running-clearance dimensions in water-glycol environments where mineral-filled thermosets previously required post-machining. Industry compliance for industrial water-handling components follows ISO 175:2010 for immersion in water and water-glycol at 60 °C, with dimensional change measured on ISO 294-4:2018 coupons; if potable-water contact is foreseen, the grade-specific certification under NSF/ANSI 61 must be verified with EMS-Grivory, because the natural FWA designation does not automatically carry potable-water listing in all jurisdictions. The feedstock formulation ratio is 100 wt% dry compound; external lubricants such as molybdenum disulfide or PTFE are not added to the compound unless the OEM application specifies a friction-modified wear-ring design and the resulting reduction in tensile strength according to ISO 527-2 is accepted by the design dossier. Production on a two-platen injection molding machine uses a melt temperature of 260–280 °C, a mold temperature of 85–105 °C, and a slow screw rotation speed of 30–60 min⁻¹ to minimize glass fiber breakage in the hot runner. Thick sections above 5 mm require a profiled cooling phase of 45–60 s to limit shrinkage voids that would be detected by pressure-decay leak testing at 2 bar. Terminal product types include centrifugal pump wear rings, bearing cages, impeller hub inserts, and seal gland plates that must retain bolt preload over 10,000 h of exposed service in water-glycol at 60 °C. Published data for the specific creep rupture of this grade in water-glycol mixtures is limited, so the design load must be confirmed by short-term ISO 899-2 creep tests on molded plaques.

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    Certification & Compliance
    More Introduction

    EMS-Grivory Grilamid LV-65H FWA nat is a polyamide 12 injection-moulding grade containing 65% by mass glass fibre reinforcement. Under ISO 1043 the material is designated PA12-GF65, and the “nat” suffix identifies natural, uncoloured polymer. Representative supplier datasheet values for dry-as-moulded test pieces are: density 1.67–1.69 g/cm³ (ISO 1183-1); tensile modulus 18,000–19,000 MPa (ISO 527-1/-2); tensile stress at break 180–210 MPa; elongation at break 2.0–2.5%; Charpy unnotched impact 70–75 kJ/m² (ISO 179-1/1eU); Charpy notched impact 14–15 kJ/m² (ISO 179-1/1eA); and heat deflection temperature under 1.80 MPa load 165–170°C (ISO 75-2). The FWA suffix is used by EMS-Grivory to denote a formulation intended for food-contact and drinking-water applications; it is not a certification mark. Finished components require article-specific verification against EU 10/2011, FDA 21 CFR 177.1500, or NSF/ANSI 61 as applicable to the target market.

    The “dry” designation means the resin is supplied with low residual moisture and that the stated mechanical values refer to dry-as-moulded specimens, not conditioned equilibrium states. Polyamide 12 has a lower amide-group density than PA6 or PA66, so equilibrium moisture regain is lower. At 23°C/50% RH the grade typically absorbs 0.5–0.7% water by mass, whereas conventional PA66-GF grades absorb approximately 1.5–2.0%. The practical consequence is lower hygroscopic dimensional change and better retention of stiffness in humid service.

    Under EU 10/2011, plastic articles intended for food contact must comply with overall migration limits; the standard overall migration limit for general food contact is 10 mg/dm². Polyamide 12 may be assessed for specific migration of laurolactam and selected additives. Under FDA 21 CFR 177.1500, nylon resins may be used in food-contact articles subject to extractives limits. The FWA grade is therefore a candidate raw material, but it is not a finished-article compliance statement.

    What Separates PA12-GF65 from PA66-GF60 in Humid-End-Use Conditions?

    Compared with PA66-GF60, the PA12 matrix lowers equilibrium water absorption and reduces density, but also lowers dry high-temperature stiffness. Under ISO 62 at 23°C/50% RH, PA12-GF65 typically reaches 0.5–0.7% moisture, while PA66-GF60 reaches 1.5–2.0%. This difference reduces swelling in close-tolerance valve bodies, pump housings, and bearing cages. The trade-off is thermal: typical heat deflection data for PA66-GF60 at 1.80 MPa is above 230°C, whereas this PA12-GF65 grade is 165–170°C. The PA12 grade is therefore selected for humid-dimensional stability rather than for load-bearing service above 120°C. Compared with PA12-GF50, the 65% glass loading raises dry tensile modulus by approximately 30–40% but reduces notched impact and melt flow.

    The high glass-fibre content creates abrasive wear in injection equipment. Mould steels should be hardened to at least 52 HRC, and gate inserts in high-shear areas should use tungsten carbide or ceramic. Screw and check-ring wear rates on production-scale machines are higher than with unfilled PA12; bimetallic barrels and hardened check rings are standard. Failure to control abrasive wear results in shot-weight drift and short shots.

    Residual moisture control is the primary processing variable for this grade. At ambient storage above 55–60% RH, exposed granulate can exceed 0.10% moisture within 30–60 min. Pre-drying in a desiccant dryer at 75–85°C for 4–6 h to a residual moisture content below 0.10% by Karl Fischer titration (ISO 15512) is standard. Vacuum drying at 80°C for 2–4 h is an alternative for small lot sizes. Drying temperatures above 90°C for more than 8 h should be avoided because oxidative discoloration and loss of impact can occur. Regrind from sprues and runners may be re-introduced at 25% by mass in dry condition; higher regrind fractions increase glass fibre attrition and notched-impact variability on production-scale injection equipment.

    Melt Temperature and Residence-Time Boundaries for Injection Moulding

    Processing should be performed on a reciprocating screw injection-moulding machine with a three-zone screw of 20:1–25:1 L/D ratio, a hardened bimetallic barrel, and a hardened screw tip. Melt temperature measured by air shot should be 250–280°C; barrel set points are typically rear 230–250°C, centre 250–270°C, front 260–280°C, and nozzle 255–275°C. Mould temperature should be 80–120°C. The upper mould-temperature range improves glass-fibre wet-out, surface finish, and dimensional stability, but increases cycle time. Back pressure should be limited to 30–70 bar and screw speed to 60–120 rpm because the 65% glass content makes fibre attrition sensitive to shear. Injection speed for wall sections of 1.5–3.0 mm is typically 100–300 mm/s, with the higher end used to prevent premature freeze-off and glass-rich surfaces.

    If barrel residence time exceeds 10–12 min at 270°C, thermal-oxidative chain scission may begin. The observable indicators on a production line are an upward shift in melt volume-flow rate (ISO 1133-1), yellowing of natural mouldings, and a decrease in notched Charpy impact. During interruptions, the barrel temperature should be reduced to 180–200°C or the unit purged with a PA12-based purging compound. Hot-runner manifolds and valve gates should be designed to avoid dead zones; published data for retention of this exact grade in hot-runner systems is limited, so processors should validate residence-time distribution with a marker purge.

    The 65% glass-fibre fraction produces marked anisotropy in shrinkage and mechanical properties. Flow-direction tensile modulus can be higher than transverse-direction modulus by 20–35% depending on gate type and thickness. Mould shrinkage is commonly less along the flow direction and greater transverse to it; actual values require prototype-tool measurements because published data for this specific configuration is limited. Gate placement should avoid long flow paths that orient glass fibres around cores and create weld lines at fibre-depleted regions. Weld lines in this grade can retain only 50–70% of the parent tensile strength and are a primary failure origin in pressure-containing components. Sequential valve gating is preferred over single centre gating for large flat parts.

    Conditioned Tensile Modulus Falls by 10–15% Against Dry Values

    Conditioning to equilibrium at 23°C/50% RH shifts the mechanical response toward lower stiffness and higher ductility. The table below gives representative dry and conditioned ranges for structural design comparison.

    Representative dry and conditioned properties of EMS-Grivory Grilamid LV-65H FWA nat
    Property Standard Dry-as-moulded Conditioned 23°C/50% RH
    Density ISO 1183-1 1.67–1.69 g/cm³ 1.67–1.69 g/cm³
    Tensile modulus ISO 527-1/-2 18,000–19,000 MPa 15,000–16,000 MPa
    Tensile stress at break ISO 527-1/-2 180–210 MPa 150–170 MPa
    Elongation at break ISO 527-1/-2 2.0–2.5% 2.5–3.0%
    Charpy notched impact ISO 179-1/1eA 14–15 kJ/m² 16–18 kJ/m²
    Charpy unnotched impact ISO 179-1/1eU 70–75 kJ/m² 75–80 kJ/m²
    Heat deflection temperature at 1.80 MPa ISO 75-2 165–170°C 160–165°C

    Conditioning to equilibrium at 23°C/50% RH lowers tensile modulus by approximately 10–15% and tensile stress at break by 15–20%, while notched Charpy impact increases by 10–20%. The changes are smaller than those of unreinforced PA12 or PA6/PA66 because the glass fibre network dominates stiffness. The reduced moisture sensitivity at high glass loading is a primary reason the grade is selected for precision structural parts that must pass dimensional checks after humidity exposure.

    Compared with the lower glass Grilamid LV-50H FWA nat, this 65% glass grade shifts the mechanical envelope toward higher stiffness and lower toughness. Dry tensile modulus rises from approximately 12,000–13,000 MPa for the 50% glass grade to 18,000–19,000 MPa for the 65% grade, while notched Charpy falls from roughly 20 kJ/m² to 14–15 kJ/m². Mould shrinkage is lower and density is higher. The grade is therefore chosen when allowable strain, creep resistance, and dimensional stability dominate the requirement; it is not chosen where impact toughness or melt fluidity is the limiting factor.

    When Creep Resistance and Low Hygroscopic Swelling Are Critical in Pump and Valve Components

    Candidate components include structural housings, pump impellers, valve bodies, bearing cages, gear wheels, medical-device housings, food-processing equipment parts, and drinking-water contact fittings. In these applications the material is most appropriate where close tolerances must be held in humid environments and where a PA66-GF grade would exceed dimensional change limits. The grade is not internally lubricated; sliding-wear applications require external lubrication or a dedicated wear-resistant grade. Continuous load-bearing service is generally suitable below 120°C. At higher temperatures, creep and oxidative ageing should be evaluated using ISO 899-1 creep testing or ISO 527-4 tensile testing.

    Chemical limitations include strong mineral acids, oxidizing acids, and polar solvents that degrade the PA12 matrix; hydrofluoric acid can attack the glass fibre. The grade resists many aliphatic hydrocarbons, oils, and greases, but aqueous acids above 10% concentration at elevated temperature can cause surface etching and loss of mechanical properties. For drinking-water components, long-term hydrostatic performance should be validated under ISO 9080 or ASTM D2837 where applicable. The FWA designation simplifies raw-material selection but does not replace migration testing, hydrostatic certification, or article-specific regulatory review.

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