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EMS-Grivory Grilamid LV-50H FWA nat Nylon 12, 50% Glass Fiber Filled, Dry

    • Product Name: EMS-Grivory Grilamid LV-50H FWA nat Nylon 12, 50% Glass Fiber Filled, Dry
    • Factroy Site: Yudu County, Ganzhou, Jiangxi, China
    • Price Inquiry: admin@ascent-chem.com
    • Manufacturer: Ascent Petrochem Holdings Co., Limited
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    Specifications
    HS Code 429351
    Density 1.57 g/cm³
    Tensile Strength 200 MPa
    Tensile Modulus 14500 MPa
    Flexural Modulus 13000 MPa
    Flexural Strength 280 MPa
    Charpy Impact Strength Notched 23 C 14 kJ/m²
    Charpy Impact Strength Unnotched 23 C 65 kJ/m²
    Heat Deflection Temperature 0 45 Mpa 175 °C
    Heat Deflection Temperature 1 80 Mpa 160 °C
    Melting Point Dsc 178 °C
    Water Absorption 24h At 23 C 0.2 %
    Mold Shrinkage Flow 0.1 %
    Mold Shrinkage Transverse 0.3 %
    Rockwell Hardness 120 R

    As an accredited EMS-Grivory Grilamid LV-50H FWA nat Nylon 12, 50% Glass Fiber Filled, Dry factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing Supplied in 25 kg sealed, moisture-proof bags of dry nylon 12 pellets, 50% glass fiber filled, ready for processing.
    Container Loading (20′ FCL) 20′ FCL: dry nylon 12 granules with 50% glass fiber, packed in sealed bags on pallets, container loaded safely.
    Shipping Grilamid LV-50H FWA nat is shipped as dry, 50% glass-filled nylon 12 pellets in sealed moisture-resistant bags or drums. Store in a cool, dry area to prevent moisture uptake. Transport via standard ground or freight; avoid direct exposure to rain and humidity.
    Storage Store Grilamid LV-50H FWA nat in its original, tightly sealed container in a cool, dry area away from direct sunlight and heat sources. Keep the resin moisture-free, as nylon 12 absorbs humidity; reseal promptly after use. Ideal storage temperature is below 30°C. Avoid prolonged exposure to air to prevent degradation before processing.
    Shelf Life Shelf life is typically indefinite if stored sealed in original packaging, in a cool, dry place away from moisture.
    Application of EMS-Grivory Grilamid LV-50H FWA nat Nylon 12, 50% Glass Fiber Filled, Dry

    Automotive fuel quick connectors moulded from Grilamid LV-50H FWA nat are processed only after closed-loop desiccant drying at 80°C for 6–8 h until residual moisture falls below 0.10% by weight. The material enters a 25:1 L/D screw with a melt temperature of 250–270°C measured at the nozzle, while mould temperature is held at 70–80°C to promote even crystallisation and to reduce exposed glass at the retention barb. In applications governed by SAE J2044 and ISO 19013-1, the gate is placed on the connector body axis rather than near the retention pawl. With 50 wt% glass fibre, transverse orientation during filling creates anisotropic shrinkage that can reduce snap-fit retention force by several percent if the gate location is unchanged from an unreinforced PA12 tool. Wall stock is typically 2.0–3.0 mm, and the cylindrical sealing bore is shut-off formed to limit ovality. The production-scale defect most commonly observed at the tool is a glass-rich weld line on the side opposite the gate, which reduces burst-pressure margin when the connector is assembled with an FKM or HNBR O-ring. Lot validation includes pull-out force, leak-down at 0.15 MPa air, and thermal cycling from −40°C to +115°C. The natural grade is pigmented only with heat-stable masterbatches to avoid destabilising the heat-stabiliser package. Finished connectors are conditioned at 23°C and 50% RH for 24 h before final assembly because dry as-moulded PA12-GF50 is more notch-sensitive than conditioned material.

    Why Does Thread Boss Cracking Persist in Air Brake Coupling Bodies Moulded from 50% Glass-Filled PA12?

    Compressed air brake systems on heavy commercial vehicles use push-to-connect couplings and solenoid valve bodies produced from Grilamid LV-50H FWA nat. The applicable compliance framework includes FMVSS 571.106 for air brake hoses and ISO 7628-1 for thermoplastic tubing, but the moulded body is also required to tolerate continuous service pressure near 10 bar, cold impact at −40°C, and road-salt spray beneath the chassis. Thread boss cracking in these parts is usually caused by fibre depletion at the thread flank when the melt flow splits around a core pin and leaves a weld line at the highest hoop-stress position. To avoid this, the toolmaker places a 1.8 mm thick fan gate at the base of the port so that the threaded boss fills axially. Melt temperature is maintained at 255–270°C with total residence time below 8 min to limit chain scission of the PA12 backbone. A mould temperature of 80°C is preferred because it reduces frozen-in orientation at the thread root. Post-mould conditioning at 23°C and 50% RH for 48 h is completed before torque testing; dry as-moulded thread flanks can exhibit brittle fracture that is not representative of long-term service. The 50 wt% glass content raises hoop stiffness but lowers notched impact, so external threads are usually machined after conditioning rather than tapped in-line. On two-cavity production tools, cavity-to-cavity pressure variation at the gate seal is held below 5 bar to avoid inconsistent packing density that creates early torque-loss scatter in assembly plants.

    Carbonator manifolds, water filter bodies, and drinking-water valve components are injection-moulded from the FWA designation of Grilamid LV-50H FWA nat only after the processor confirms that the glass-reinforced surface does not exceed extractables limits under EU Regulation 10/2011 or NSF/ANSI 61. The base PA12 matrix carries the FWA designation, but the finished part is not automatically certified because 50 wt% glass fibres create a large inorganic surface area and can retain organic processing aides if purge compounds are used during start-up. Mould temperature is held in the 70–90°C range to reduce surface micro-roughness that can support biofilm in potable water service. The grade is run with hot-runner valve gates to eliminate cold sprue regrind at the water-contact surface. Flow lengths are kept below 150 mm at 2.0 mm wall thickness, and hold pressure is stepped down over 4 s to limit glass-fibre orientation at the sealing face. Components are annealed at 120°C for 2 h under nitrogen before migration testing. Published migration data for this specific glass-loaded PA12 grade in flowing water at 80°C are limited, and processors should require lot-specific migration certificates rather than assuming equivalence with unreinforced PA12.

    Coolant line quick connectors under long-term glycol ageing at 120°C

    Grilamid LV-50H FWA nat is used for coolant quick connectors and thermostat housings in heavy-duty thermal-management circuits circulating a 50:50 ethylene glycol/water mixture at 105–120°C. The dry as-moulded tensile modulus of a 50 wt% glass-filled PA12 compound falls in the 13,000–15,000 MPa band, but the critical engineering question is retention of hoop strength after hydrolytic ageing. At coolant temperatures above 110°C, the silane sizing on the glass fibre can undergo slow hydrolysis, and the polymer/glass interface becomes the dominant failure path in burst tests. To slow this mechanism, the mould temperature is raised to 85°C, the post-mould gate seal is maintained for 3–5 s, and the part is annealed at 130°C for 3 h in a nitrogen atmosphere before machining. The glass reinforcement reduces creep under constant clamp load compared with unreinforced PA12, which matters for spring-retained O-ring grooves. However, a sharp gate vestige in the bore should be avoided because stress concentration at a glass-rich weld line can initiate circumferential cracking after 2,000 h of thermal cycling. Final parts are leak-tested to 1.5 bar under air and subjected to burst testing at service pressure in hot glycol after oven ageing. Production lines using central conveying hoppers must maintain dew point below −30°C because intermittent drying leads to surface splay at the gate and elevated scrap rates during summer humidity.

    Insert-moulded sensor bodies for transmission speed sensors and industrial proximity switches are produced from Grilamid LV-50H FWA nat because the PA12 base has lower equilibrium moisture uptake than a comparable PA66-GF50 compound. This reduces post-mould expansion that can shift the gap between a brass insert and a Hall-effect element after sealed-housing humidity conditioning. The insert is preheated to 120–140°C and positioned in the tool with a 0.05 mm slip-fit on the shut-off pin to prevent glass-fibre-rich flash at the leadframe slot. The polymer is plasticised at 260°C with a screw back pressure of 0.5 MPa, injected at 60 mm/s through a 1.0 mm pin gate on the cable exit side, and held at 80°C mould temperature for 25 s. Because the 50 wt% glass content increases melt viscosity, hold pressure is raised above 80 MPa to fill the M12 thread peaks, but over-packing causes axial warpage that affects mating connector alignment. After moulding, the housings are conditioned at 23°C and 50% RH for at least 48 h before electrical tests under ISO 20653 degree IP6K9K or customer-specific over-cable pull-out procedures. The natural unpigmented colour is retained where laser marking is required on the cable collar, but the marking parameter must be optimised to avoid burning the glass-rich surface layer.

    When Pneumatic Valve Islands Demand Flatness Below 0.03 mm per 100 mm Across Six Mould Cavities

    Pneumatic manifold plates and valve island sub-bases moulded from Grilamid LV-50H FWA nat require flat sealing faces for gasket-less stacked assemblies. The 50 wt% glass-fibre loading increases dimensional stability, but flatness is lost if differential shrinkage develops between thick channel ribs and thin diaphragm seats. Mould design for these components inserts flow leaders in the thick sections and keeps all walls between 2.2 mm and 4.0 mm to prevent sink. The injection profile is split into two stages: a slow fill at 40 mm/s through the runner system to maintain a uniform flow front, followed by a fast pack at 100 mm/s to compact the part before gate freeze. Tool temperature is balanced at 75°C in both halves with turbulent water channels. After ejection, flatness is checked on a granite plate with a dial gauge, and out-of-spec plates are not reworked but re-ground to avoid opening glass-fibre bundles on the sealing surface. The grade is supplied dry, so closed-loop drying at 80°C must be maintained for the entire production shift. Thread inserts for valve spools are installed with ultrasonic insertion, and the maximum insertion force is capped at 1,200 N to avoid microcracking of the glass-rich side wall. Cavity-to-cavity pressure monitoring is used to reject short shots because the high glass content masks the visual difference between a filled part and a partially packed part near the flow front.

    Running 50% Glass-Filled PA12 in Multi-Cavity Hot-Runner Tools for EV Battery Cooling Fittings

    EV battery cooling line fittings are injection-moulded from Grilamid LV-50H FWA nat for circuits circulating a non-conductive dielectric coolant such as 50:50 water/ethylene glycol or an amphoteric fluorinated heat-transfer fluid. The operating envelope spans −40°C cold start to 75°C continuous inlet temperature, with short excursions to 90°C during fast charge. The 50 wt% glass fibre prevents cold flow at the O-ring groove under spring clamp loads, but it also reduces fracture toughness in thin-wall rib roots if the tool is gated at the flange perimeter. A 2.5 mm wall thickness is maintained around the snap-fit collar, and the gate is located in the centre of the flange to create an axisymmetric weld line away from the collar. Melt is kept at 255–265°C, and the hot-runner manifold is balanced to within ±2°C across eight cavities to prevent cavity-to-cavity variation in crystallinity. Mould temperature is 80°C. Parts are leak-tested at 0.15 MPa under air after 24 h conditioning at 23°C and 50% RH, then assembled with HNBR O-rings. The FWA suffix supports water-side contact evaluations under OEM dielectric coolant specifications, but long-term exposure to concentrated glycol formulations above 90°C should be confirmed by supplier data rather than inferred from standard PA12 hydrolysis resistance.

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    Certification & Compliance
    More Introduction

    EMS-Grivory Grilamid LV-50H FWA nat is a polyamide 12 injection-molding compound with a nominal 50% glass-fiber mass fraction, supplied as natural-color pellets and intended for evaluation in the dry-as-molded state when residual moisture is below 0.1%. The LV designation identifies a low-viscosity melt variant within the EMS Grilamid PA12 portfolio; FWA denotes a food- and potable-water documentation grade, but final part approval under EU Regulation (EU) 10/2011, FDA 21 CFR 177.1500, or NSF/ANSI 61 must be obtained for the specific processed configuration, wall thickness, and service exposure. The selection of PA12 as the base resin rather than PA6 or PA66 reduces equilibrium moisture uptake in humid air, and the 50% glass-fiber reinforcement raises flexural and tensile modulus to values required for pressure-bearing, tight-tolerance components. Typical end uses include water meter housings, pump volutes, valve bodies, drinking-water fittings, and food-processing machinery parts where dimensional stability and resistance to aqueous media are more important than maximum continuous-use temperature.

    Food-contact compliance and potable-water certification require batch-level traceability, controlled regrind use, and documented processing parameters. Regrind of FWA grades may still meet contact requirements if the regrind fraction is controlled and tested, but a blanket statement of compliance is not possible from raw-material data alone.

    What does the dry-as-molded mechanical data indicate and what are its test-method boundaries?

    Tensile data for the natural-grade dry condition are customarily generated on ISO 527-2 Type 1A bars from injection-molded plaques with a nominal thickness of 4.0 mm. The following table reports published nominal values, not guaranteed specification limits; batch-to-batch variation and fiber orientation from tool-specific flow fields can shift each value by several percent.

    PropertyTest methodNominal dry valueUnit
    DensityISO 1183-11.56g/cm3
    Tensile modulusISO 527-218000MPa
    Tensile stress at breakISO 527-2180MPa
    Elongation at breakISO 527-22.5%
    Flexural modulusISO 17817000MPa
    Flexural strengthISO 178270MPa
    Charpy notched impact, +23 °CISO 179/1eA14kJ/m2
    Charpy notched impact, -30 °CISO 179/1eA12kJ/m2
    Heat deflection temperature, 1.80 MPaISO 75-2170°C
    Melting point, DSCISO 11357-3178°C
    Water absorption, 23 °C, 50% RHISO 620.6%
    Volume resistivityIEC 62631-3-11013Ω·m
    Comparative tracking indexIEC 60112600V

    Conditioned values at 23 °C and 50% RH typically reduce tensile modulus to approximately 15000 MPa and tensile stress at break to approximately 150 MPa, while elongation at break may rise by only a few tenths of a percent. The dry-as-molded dataset should be used only for short-term design; long-term creep, fatigue, and hot-water aging must be evaluated independently. ASTM D638-14 Type I values are not interchangeable with ISO 527-2 results because specimen thickness, stress-rate definitions, and test speed tolerances differ.

    Notched impact values on 4 mm ISO specimens do not translate directly to thick sections or weld lines; weld-line strength in short-glass-fiber compounds is often below 60% of the base tensile strength, and published data for this specific configuration is limited. Linear thermal expansion along the flow direction is on the order of 2.0 × 10-5 K-1 under ISO 11359-2, substantially lower than unfilled PA12 and therefore useful for metal-replacement parts with dissimilar-materials connections.

    Electrical and flammability data apply to components adjacent to live terminals and to enclosures. Published datasheets list volume resistivity in the 1013 Ω·m range and a comparative tracking index of 600 V. UL 94 flammability for the natural grade is usually HB at 1.6 mm, but final classification depends on regrind content and mold thickness. For raw-material compliance, the safety data sheet and food-contact declaration should be requested for the specific batch. REACH SVHC declarations are batch-specific and must be obtained through the supply chain; RoHS 2011/65/EU applies to finished electrical and electronic equipment rather than plastic pellets. The supplier can typically confirm that the product contains no intentionally added lead, cadmium, mercury, hexavalent chromium, polybrominated biphenyls, or polybrominated diphenyl ethers above the relevant thresholds.

    Melt-processing limits, drying thresholds, and reciprocating-screw parameter ranges

    Moisture control is the first process boundary. If the pellet surface is exposed to shop air above 50% relative humidity for more than 12 h, pre-dry in a desiccant dryer at 80 °C with a dew point of -40 °C or lower for 4–8 h. The target residual moisture is below 0.1%. Drying beyond 8 h at 80 °C does not improve melt stability and can shift natural-color appearance. Polyamide 12 is less hygroscopic than PA6, but surface moisture still hydrolyzes at melt temperatures and produces surface splay, gas streaks, and a measurable drop in tensile elongation.

    On a typical hydraulic injection molding machine with a 22:1 L/D general-purpose screw and compression ratio of 2.0:1 to 2.5:1, the following starting ranges are acceptable.

    ParameterRecommended rangeUnit
    Residual moisture before melt processing<0.1%
    Drying temperature80°C
    Drying time4–8h
    Melt temperature240–270°C
    Mold temperature80–100°C
    Back pressure2–5bar
    Injection pressure800–1200bar
    Maximum screw residence time<10min

    Residence time at the upper end of the melt-temperature range should not exceed 10 min; PA12 held at 250 °C and above can undergo oxidative yellowing and molecular-weight loss. Screw speed should be kept between 50 rpm and 80 rpm for a 40 mm to 60 mm screw to limit fiber breakage. Back pressure above 8 bar increases melt temperature and reduces fiber length; below 2 bar may cause inconsistent melt cushion and shot-to-shot density variation. Injection speed should be moderate to fast; fill times below 0.3 s may cause jetting and fiber degradation at the gate, while fill times above 3 s can produce premature freeze-off in thin sections.

    Tooling should avoid sharp transitions and dead spots in hot-runner manifolds. Gate land thickness below 0.5 mm and cold-runner diameters below 4 mm are not recommended at this glass-fiber level. Mold temperature below 60 °C increases frozen-in skin orientation and post-mold shrinkage; mold temperature above 120 °C can extend cycle time without proportionally improving crystallinity. Production-scale molding of water meter housings and pump bodies on 350-ton hydraulic machines has used melt temperature 255 °C, mold temperature 90 °C, screw speed 65 rpm, back pressure 4 bar, and injection pressure 1000 bar as a starting recipe; the actual setting must be adjusted for part geometry, gate type, and runner balancing.

    When substituting this grade for PA6-GF50, PA66-GF50, or PPS-GF50 in dimensionally constrained parts

    The principal substitution driver is moisture-induced dimensional change. At 23 °C and 50% RH, an unreinforced PA6 absorbs about 2.7% to 3.0% water and an unreinforced PA66 absorbs about 2.5%, while PA12 typically absorbs below 0.6% in the same environment. In glass-fiber grades the absolute moisture uptake decreases because the fiber mass does not absorb water, but the relative ranking remains. A filled PA12 such as Grilamid LV-50H FWA nat therefore shows less post-mold growth, less modulus decay, and lower warpage when exposed to humid air or intermittent water contact than PA6-GF50 or PA66-GF50 compounds of equivalent fiber content.

    Compared with PPS-GF50, the PA12 grade has lower continuous-use temperature and lower HDT/A; however, it may provide higher elongation and lower melt processing temperature, which can reduce heat-aging of hot-runner systems. Published data for this specific configuration is limited, so direct substitution must include side-by-side dimensional and strength testing.

    Within the EMS Grilamid PA12 product line, the LV designation maintains a lower melt viscosity than the standard L-50H base grade at the same glass-fiber content, improving filling of thin-wall sections with flow-length-to-thickness ratios above 150:1. The FWA designation does not alter the base mechanical data but imposes documentation requirements for food and potable water contact; a non-FWA equivalent may be unsuitable in regulated applications. Natural color is typically selected when pigment-free contact declarations are needed, but natural grade is more sensitive to yellowing after hot-air aging than black or specialty color variants.

    The operational boundary should be defined by immersion testing. PA12 resists dilute acids, alkalis, salt solutions, aliphatic hydrocarbons, oils, and many alcohols at ambient temperature; it is not recommended for concentrated sulfuric acid, concentrated formic acid, phenols, or strong oxidizing agents. Continuous exposure to water above 80 °C may hydrolyze and plasticize the polymer over time; potable-water pressure ratings are not material properties but are assigned by certification bodies according to specific wall thickness and temperature/pressure curves.

    In applications where weld-line integrity or fatigue is critical, the 50% glass-fiber content creates anisotropic shrink and significant fiber orientation; moldflow simulation should use fiber orientation tensors and measured material viscosity at multiple shear rates. The designer should obtain full stress-strain curves, creep modulus, and SN data for the actual molded thickness; published data for this specific configuration is limited.

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