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EMS-Grivory Grilamid LV-50H FWA black 9225 Nylon 12, 50% Glass Fiber Filled, Dry

    • Product Name: EMS-Grivory Grilamid LV-50H FWA black 9225 Nylon 12, 50% Glass Fiber Filled, Dry
    • Factroy Site: Yudu County, Ganzhou, Jiangxi, China
    • Price Inquiry: admin@ascent-chem.com
    • Manufacturer: Ascent Petrochem Holdings Co., Limited
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    Specifications
    HS Code 253120
    Density 1.58 g/cm³
    Glass Fiber Content 50%
    Water Absorption 24h 0.2%
    Tensile Modulus 17000 MPa
    Tensile Stress At Break 185 MPa
    Tensile Strain At Break 3%
    Flexural Modulus 15500 MPa
    Charpy Impact Strength Notched 23 C 15 kJ/m²
    Charpy Impact Strength Unnotched 23 C 110 kJ/m²
    Melting Temperature 178 °C
    Heat Deflection Temperature 1 80 Mpa 170 °C

    As an accredited EMS-Grivory Grilamid LV-50H FWA black 9225 Nylon 12, 50% Glass Fiber Filled, Dry factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing Supplied as 25 kg net in sealed, moisture-proof foil bags, vacuum-packed to keep Nylon 12 dry and contamination-free.
    Container Loading (20′ FCL) 20′ FCL container loaded with EMS-Grivory Grilamid LV-50H FWA black 9225 Nylon 12, 50% glass fiber filled, dry.
    Shipping This product ships as a non-hazardous granular resin. It is packaged in moisture-resistant, sealed bags and should be kept dry during transit. Avoid exposure to rain or humidity, as moisture absorption affects quality. Standard truck freight is suitable; store in a cool, dry place immediately upon receipt.
    Storage Store Grilamid LV-50H FWA black 9225 in its original, unopened, moisture-proof packaging in a cool, dry area away from direct sunlight and heat sources. Maintain ambient temperatures around 20–25°C. Keep containers tightly sealed to prevent moisture absorption; if partially used, reseal immediately. Avoid exposure to humidity, condensation, and prolonged UV, which can degrade the glass-filled nylon.
    Shelf Life Shelf life is typically 2 years from manufacture when stored sealed, dry, and cool in original packaging.
    Application of EMS-Grivory Grilamid LV-50H FWA black 9225 Nylon 12, 50% Glass Fiber Filled, Dry

    In fuel delivery and evaporative emission systems, a 50 wt% glass-reinforced polyamide 12 is specified where three failure modes—fuel swell retention-force decay, thermal oxidative embrittlement at weld lines, and salt-spray stress cracking at metallic overmoulded inserts—must be suppressed simultaneously. The fuel-specific compliance envelope for this application is anchored to SAE J2044 for quick-connector insertion and pull-off forces after exposure to Fuel C, CE10, and 85% ethanol/15% water, to SAE J2260 for dimensional and permeation performance in rigid connector bodies that join multi-layer fuel tubing, and to ISO 9227 neutral salt spray for metal-insert overmoulding validation. Underhood thermal ageing is benchmarked at 1,000 h at 125 °C in forced-air ovens, with retention-force testing performed after ageing because oxidised glass-fibre sizing at the surface can change latch-finger friction. The formulation addition ratio at the moulding machine is 0% further glass reinforcement; the grade is supplied as a ready-to-mould compound with a 50% glass fibre loading fixed at the compounding stage and verified by ISO 3451-1 ash content. Reclaimed sprues and runners are limited to 20% by mass for non-pressure-bearing geometries and are excluded from SAE J2044 retention-latch features because regrind lot-dependent notched impact at −40 °C cannot be predicted from dry 23 °C Charpy data. Downstream production is injection moulding on a reciprocating screw machine with an L/D ratio of 20:1 and a low compression ratio of 2.0:1 to 2.5:1 to limit fibre breakage; predrying is executed at 80 °C for 4–8 h in a dew-point-controlled dryer at −30 °C until residual moisture is below 0.10% by ISO 15512 Method B. Melt temperature is maintained between 220 °C and 250 °C, mould temperature between 80 °C and 100 °C, and gate design uses tab or submarine gates of 80–100% nominal wall thickness to avoid jetting while weld lines are positioned away from latch root radii. Tensile modulus is spot-checked at 16,000–17,000 MPa per ISO 527-2 in dry as-moulded condition to detect anomalous fibre breakage from aggressive screw recovery. Moulded part numbers for this sector include SAE J2044 fuel quick connectors, fuel pump mounting flanges, fuel sender unit flanges, evaporative emissions canister fittings, injector retention clips, and fuel filter end caps.

    What Limits Certification of Potable Water Contact Valve Bodies Made from PA12-GF50?

    Certification of potable water contact valve bodies made from 50% glass-reinforced PA12 is limited less by tensile strength than by oligomeric nylon 12 migration and glass-fibre sizing exudation into standing water at 60 °C and 80 °C. The applicable regulatory matrix includes EU 10/2011 with its most recent amendment for plastic food-contact materials, FDA 21 CFR 177.1500 for nylon 12 resins, NSF/ANSI/CAN 61 for component-specific potable water contact, and DVGW W270 for microbial growth resistance on wetted surfaces; the last two are finished-part listings, not pellet-level certificates. No further glass fibre is added downstream; the supplied compound already contains 50% glass fibre by mass per ISO 3451-1. If custom colour cannot be avoided for non-black components, a PA12-carrier masterbatch is used at no more than 2.0% by mass because higher letdown shifts total migration into the range where EU 10/2011 verification must be repeated on finished parts. Downstream production requires a mould temperature of 90–100 °C, not the lower end of the general PA12 window, to develop a crystalline surface layer with reduced amorphous fraction; hold pressure is set at 50–70 MPa hydraulic and the wetted cavity is polished to SPI A2 to prevent glass-fibre protrusion after mould wear. Gate location and sequencing are used to keep knit lines out of o-ring sealing grooves and diaphragm support webs because knit-line retention of hygienic surface finish deteriorates after 500 CIP cycles when the first flow front has frozen prematurely. The sector’s finished part range covers multi-port water valve bodies, residential and commercial water meter housings, reverse osmosis membrane housing end caps, drinking water pump volute inserts, and irrigation control valve bodies.

    When a glass-filled PA12 manifold replaces sand-cast 6061-T6 aluminium in compressed air circuits operating at 10 bar, the component must be redesigned around anisotropic tensile modulus and fatigue crack propagation at moulded-in brass thread inserts, not simply substituted by geometry. Pneumatic system safety is validated under ISO 4414:2010, and pressure-containing parts are subjected to a burst test at 1.5× design pressure after ageing at 80 °C in dry air; published multi-lot fatigue data for this exact 50% glass PA12 configuration in compressed air manifolds is limited, so each gate position must be re-validated. Production uses the pellet without letdown of additional reinforcement; the pellet stock contains 50% glass fibre by mass per ISO 3451-1, and the black 9225 already contains carbon black and heat stabiliser. Regrind addition is kept below 10% for pressure-boundary walls and is prohibited in threaded features because fibre length distribution in regrind reduces Charpy notched impact at 23 °C by a non-linear but measurable amount. The production process is injection moulding with preheated brass inserts at 150 °C to minimise differential shrinkage stress, back pressure of 2–5 bar, screw speed of 60–80 rpm, and a barrel profile from 220 °C to 245 °C. Post-mould machining of port threads is avoided because exposed glass fibres create leak paths along thread flanks; instead, moulded threads or ultrasonically inserted helicoils are used. Representative moulded components are pneumatic manifold blocks, cylinder end caps, pressure regulator bodies, FRL filter/regulator/lubricator bowls, and compressed air distribution blocks.

    Application scenarioNormative referenceCritical test conditionTerminal part types
    Fuel delivery and evaporative emissionsSAE J2044, SAE J2260, ISO 9227Pull-off force after Fuel C, CE10, and 85% ethanol/15% water; 1,000 h at 125 °C; neutral salt sprayQuick connectors, fuel pump flanges, sender flanges, canister fittings, injector retention clips
    Potable water contactEU 10/2011, FDA 21 CFR 177.1500, NSF/ANSI/CAN 61, DVGW W270Migration in standing water at 60 °C and 80 °C; microbial growth resistance on wetted surfacesValve bodies, water meter housings, RO housing end caps, pump volute inserts
    Compressed air and pneumaticsISO 4414:2010Burst at 1.5× design pressure after 80 °C air ageingManifold blocks, cylinder end caps, regulator bodies, FRL bowls
    Food processing equipmentEU 1935/2004, EU 10/2011, FDA 21 CFR 177.1500CIP immersion in 2–3% sodium hydroxide and 200–400 ppm sodium hypochlorite at 60 °CPump housings, filter plates, dispenser valve bodies, brew unit frames
    Laboratory fluidicsISO 10993-12, ISO 10993-18Extractables in acetonitrile, methanol, and dilute buffers at 20–60 °CHPLC manifolds, pump head housings, selector valve bodies, probe holders
    Outdoor enclosure hardwareUL 746C, IEC 60529, RoHS 2011/65/EU, REACH EC 1907/2006UV and chloride fog exposure; IP65 or IP66 ingress after assemblyLatches, hinge brackets, cable management brackets, inverter handles

    Food Processing Pump Housings and Filtration Plates With a Fixed 50% Glass-Reinforced PA12 Matrix

    Food processing pump housings and filtration plates made from this grade are exposed to cleaning-in-place agents containing sodium hydroxide at 2–3% and sodium hypochlorite at 200–400 ppm at 60 °C; chemical resistance is validated by part-level immersion testing because glass-fibre sizing may be hydrolysed at the surface and produce a slightly matte finish that must be controlled for drainability. The relevant compliance framework is EU 1935/2004 for food-contact materials, EU 10/2011 for plastic migration, and FDA 21 CFR 177.1500 for nylon 12; 3-A Sanitary Standards apply to finished equipment and are the responsibility of the equipment builder after assembly. The processing recipe does not add glass; the 50% fibre content is fixed at the pellet stage and verified by ISO 3451-1. Regrind is excluded from food-contact surfaces because regrind source tracking cannot guarantee absence of non-food-contact contaminants, and migration testing would need to be repeated per lot. The production process uses injection moulding with wall thicknesses of 3–6 mm, a mould temperature of 90 °C, and an injection-compression or staged packing profile to suppress sink marks in thick bosses and flange areas; gate sizes are increased to ≥80% of the local wall thickness to prevent early freeze-off of the glass-filled melt. Finished components in this category are rotary lobe pump housings, filter plate segments, beverage dispenser valve bodies, coffee machine brew unit frames, and sanitary flange adapters.

    When Laboratory Fluid Manifolds Must Resist Acetonitrile, Methanol, and Dilute Buffers Without Leaching Plasticisers

    Laboratory and diagnostic fluid manifolds moulded from 50% glass-reinforced PA12 are chosen when the fluid path must resist acetonitrile, methanol, and dilute phosphate or acetate buffers at 20–60 °C without plasticiser leaching; because the grade contains no plasticiser, extractables are limited to nylon oligomers and possible glass sizing components. For diagnostic instrument fluid paths, extractables are prepared and evaluated according to ISO 10993-12 and ISO 10993-18 only at the finished-device level; the pellet itself is not an ISO 10993 certified medical grade. The fluid-path formulation remains unmodified at the moulding machine; the 50% glass loading is fixed per ISO 3451-1, and no flame-retardant masterbatch is added because halogen-free purity of the fluid path must be preserved. Regrind addition is limited to 10% by mass for non-fluid-path structural supports and is not used in the analytical flow path because microvoids from regrind can create carryover sites. Production is injection moulding with tight tolerance tooling cut to ±0.05 mm on sealing faces, mould steel hardened to 52 HRC, and mould temperature 90–100 °C to stabilise post-mould dimensions before machining of any port faces. The part catalogue for this fluid path includes HPLC manifold bodies, pump head housings, eluent selector valve bodies, filter end caps, and sample probe holders for diagnostic instruments.

    Chloride Fog and UV Exposure Decide Whether a 50% Glass-Reinforced PA12 Latch Body Survives Without a Secondary Coating

    In outdoor telecommunication enclosures installed within 5 km of coastal shorelines, latch handles and hinge brackets are subjected to chloride fog, 90% RH, and cyclic UV exposure; black 9225 provides carbon black UV screening, but the part-level outdoor weatherability classification must be validated under UL 746C for polymeric outdoor enclosures. The applicable material compliance set includes RoHS 2011/65/EU and REACH EC 1907/2006; ingress performance of the assembled enclosure is tested according to IEC 60529 IP65 or IP66, not by the resin alone. No further reinforcing filler is introduced after pellet supply; the 50% glass fibre content is fixed by ISO 3451-1, and no external UV masterbatch is used because the carbon black package in black 9225 already screens the polymer matrix. Regrind addition is allowed up to 20% by mass for non-aesthetic interior brackets but is reduced to 10% for visible latch surfaces due to gloss variation. The downstream production process is injection moulding with wall sections of 2–3 mm, mould temperature 80–90 °C, and mechanical interlock features designed with draft angles of 1.5–2.0° to avoid textured surface drag. Commonly moulded articles are telecommunication enclosure latch handles, hinge brackets, cable management brackets, photovoltaic inverter handles, and rooftop antenna mounting brackets.

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    Certification & Compliance
    More Introduction

    EMS-Grivory Grilamid LV-50H FWA black 9225 is a heat-stabilised polyamide 12 injection moulding compound containing 50% glass fibre by mass and supplied in the dry state. The FWA designation denotes grades formulated for food-contact and drinking-water applications, subject to current approval certificates, while black 9225 is the colour identification. The grade occupies the high-stiffness end of the EMS-Grivory Grilamid PA12 portfolio. In the dry as-moulded condition, the material combines a published density of 1.56 g/cm³ measured to ISO 1183-1 with tensile modulus and strength values substantially above unfilled PA12. The glass fibre content reduces equilibrium moisture uptake relative to unreinforced PA12 because the hygroscopic polyamide mass fraction is lower; however, the same reinforcement also reduces elongation at break and increases notch sensitivity. Applications for the black 9225 version are typically injection-moulded water-meter housings, drinking-water fittings, pump components, filter bodies, and structural parts requiring dimensional stability under humid or submerged service conditions. The material must be processed from the dry condition, and re-drying is required after exposure to ambient humidity because residual moisture above process limits causes hydrolytic degradation and surface defects.

    Why Does Residual Moisture Content Govern Melt Preparation?

    Conditioning of the granulate before plastication is a primary process control. Polyamide 12 absorbs water from humid air, and the same mechanism that produces the low saturated water uptake of PA12 still permits sufficient surface moisture during storage to create defects at melt temperatures. Published EMS-Grivory processing guidance for Grilamid LV grades identifies a maximum residual moisture content of 0.10% by mass before injection moulding. In production-scale dry-air drying systems, failures are most frequently observed when the dew point of the air supply is too high, when the desiccant bed is saturated, or when the hopper throat is not sealed. A dryer with a dew point of -40 °C or lower, an air temperature of 80 °C, and a residence time of 4–12 h is used depending on the moisture history of the sack. Moisture analysis by ISO 15512 is recommended for incoming lots after storage at ambient conditions. If the granulate is processed above 0.10% moisture, the resulting hydrolysis reduces molecular weight; observable defects include surface splay, silver streaks, gas burn marks at vent locations, and measurable loss of Charpy notched impact strength. The drying operation is not a cosmetic step: it determines whether the final moulding retains the dry mechanical property envelope. Plasticising temperatures should be held between 250 °C and 280 °C. Short residence time is recommended because glass-filled PA12 can degrade if held at 280 °C for more than 5 min. Mould temperature should be maintained between 80 °C and 120 °C; the upper portion of this range is selected for dimensional stability and lower post-mould shrinkage, while the lower portion may be used where demoulding constraints dominate.

    In the dry as-moulded state, the short-term mechanical and thermal profile is defined by the reinforcing glass fibre rather than by the PA12 matrix alone. The following table summarises typical published dry-condition values for the black 9225 colour; variability between production lots and injection moulding conditions should be expected. Specimen preparation is by injection moulding to ISO 294-4; mechanical tests are carried out at 23 °C unless otherwise noted. The values are not certificate minima and must be confirmed against the current EMS-Grivory datasheet.

    PropertyTest methodTypical dry valueUnit
    DensityISO 1183-11.56g/cm³
    Tensile modulusISO 527-1/-215 000MPa
    Tensile stress at breakISO 527-1/-2180MPa
    Elongation at breakISO 527-1/-23.0%
    Charpy notched impact strength, 23 °CISO 179/1eA15kJ/m²
    Charpy unnotched impact strength, 23 °CISO 179/1eU85kJ/m²
    Melting temperature, DSCISO 11357-1/-3178°C
    Heat deflection temperature, 1.8 MPaISO 75-2170°C
    Heat deflection temperature, 0.45 MPaISO 75-2178°C
    Coefficient of linear thermal expansion, parallelISO 11359-20.15 × 10⁻⁴K⁻¹
    Coefficient of linear thermal expansion, perpendicularISO 11359-20.70 × 10⁻⁴K⁻¹
    Mould shrinkage, parallelISO 294-40.1%
    Mould shrinkage, perpendicularISO 294-40.5%
    Water absorption, saturation in water at 23 °CISO 620.9%

    Anisotropic Shrinkage in 50% Glass-Fibre-Reinforced Polyamide 12

    Shrinkage in fibre-reinforced PA12 is directionally dependent. When the melt enters a mould cavity, glass fibres orient preferentially parallel to the flow direction. This orientation restricts volumetric contraction along the orientation axis; transverse to flow, the polyamide matrix contracts more freely. The result is an anisotropic shrinkage field that cannot be corrected by a single mould scale factor. Published shrinkage ranges for LV-50H FWA black 9225 measured on ISO 294-4 plaques are 0.1% parallel to flow and 0.5% perpendicular to flow in the dry as-moulded state. In a rectangular housing with a centrally located gate, this difference may produce warp and out-of-round conditions. Mould tools for this grade are typically dimensioned using flow-dependent compensation: the parallel shrinkage value is applied to features aligned with the fill path, while the transverse value is applied to cross-flow features. Melt and mould temperature variations shift these values. Higher mould temperatures, particularly at 120 °C, increase crystallinity and generally reduce post-mould shrinkage but may increase as-moulded shrinkage. Lower mould temperatures, near 80 °C, can reduce cycle time but may increase post-mould growth and dimensional variability. For production-scale moulds, the effect of the cooling circuit and gate size must be validated with a pilot mould, because published shrinkage values are geometry-dependent and do not replace cavity-specific measurements.

    When 50% Glass Loading Compromises Weld-Line Ductility

    At 50% glass fibre content, the mechanical continuity of a knit line is limited by fibre orientation and matrix depletion at the converging flow front. Weld-line regions show lower tensile strength and an even greater reduction in notched impact ductility than bulk material. In short-glass-reinforced polyamide injection mouldings, weld-line tensile strength retention relative to the bulk value is commonly in the range 40–60%. Published data for this specific configuration is limited and must be verified by testing moulded plaque weld lines to ISO 527-1/-2. The H heat stabilisation package does not restore weld-line ductility. Mould designers should position gates to move weld lines away from pressure-bearing sealing faces, snap-fit arms, or impact-loaded ribs. When weld lines cannot be avoided, local runner design, sequential valve gating, or modification of the injection speed can improve knit-line strength. For fluid-handling parts in drinking-water service, weld lines must be checked for pressure integrity and long-term creep resistance under hot-water exposure; a visual inspection of the knit line is not sufficient to establish component compliance.

    The FWA suffix identifies the grade for food-contact and drinking-water applications within the EMS-Grivory approval framework. Typical component applications for black 9225 are water-meter housings, hot-water manifolds, valve bodies, pump impellers, filter housings, and fittings for beverage-dispensing equipment. These applications are selected because PA12 exhibits lower saturated water absorption than PA6 or PA66. The 0.9% water absorption value to ISO 62 for LV-50H is below comparable glass-filled PA66 grades. Fluid-contact compliance must be confirmed against the current certificate register for the exact grade, colour, and extraction conditions. The FWA designation does not exempt the processor from end-article testing where national drinking-water regulations require batch release. The black 9225 pigment can be used in contact with potable water only when the relevant approval letter for the specific production site and colour lot remains valid.

    What Distinguishes LV-50H From Adjacent Glass-Filled PA12 Grades?

    Differences between LV-50H FWA black 9225 and adjacent PA12 products are defined primarily by glass loading. Relative to unfilled PA12, the 50% glass fibre grade raises dry tensile modulus from approximately 1 400 MPa to 15 000 MPa, reduces elongation at break from a high-strain value to 3.0%, and increases density from approximately 1.01 g/cm³ to 1.56 g/cm³. Relative to a 30% glass fibre PA12 injection moulding grade, the step to 50% loading raises stiffness and heat deflection temperature but reduces impact ductility and increases the anisotropic shrinkage differential. The comparative table below presents representative dry values from public EMS-Grivory product data; exact values depend on colour, moisture state, and forming conditions. These differences define the three grades as separate design tools rather than drop-in substitutes.

    PropertyTest methodUnfilled PA12 dryPA12 GF30 dryLV-50H GF50 dry
    DensityISO 1183-11.01 g/cm³1.23 g/cm³1.56 g/cm³
    Tensile modulusISO 527-1/-21 400 MPa8 500 MPa15 000 MPa
    Tensile stress at breakISO 527-1/-245 MPa130 MPa180 MPa
    Elongation at breakISO 527-1/-2>50%3.0%3.0%
    Charpy notched impact strength, 23 °CISO 179/1eA5 kJ/m²14 kJ/m²15 kJ/m²
    Heat deflection temperature, 1.8 MPaISO 75-255 °C160 °C170 °C
    Water absorption, saturation in water at 23 °CISO 621.5%1.1%0.9%

    Alongside thermal drying, plasticating hardware must accommodate 50% glass fibre reinforcement. Production-scale injection moulding of LV-50H FWA black 9225 is carried out on machines with wear-protected barrels and screws; bimetallic or hardened flight coatings are specified because glass fibre abrasion accelerates screw and check-ring wear. Typical back pressure settings are kept low to moderate because excessive back pressure increases fibre breakage and reduces final tensile modulus. A shut-off nozzle prevents drool at melt temperatures of 250 °C to 280 °C. Venting depths of 0.01–0.02 mm on the runner and at the last-fill locations prevent burn marks; insufficient venting of a 50% glass-filled melt can produce visible gas tracks at the flow front. Injection speed is set to fill the cavity without jetting. High speed is preferred for thin sections, but it can increase shear heating and induce polymer degradation at the nozzle. Holding pressure and time must be sufficient to compensate for the rapid solidification of high-glass-fraction melts. Components moulded from this grade are demoulded with uniform release; mould release agents are not recommended because they can interfere with drinking-water approvals and subsequent welding or bonding operations.

    In drinking-water and food-contact equipment, the combination of low water uptake, high stiffness, and regulatory-grade formulation makes LV-50H FWA black 9225 suited to multifunctional housings that replace metal assemblies. The limiting operational boundary is impact demand. At 50% glass loading, components are stiff but brittle relative to unfilled PA12, and snap-fit deflections must be designed below the 3.0% dry elongation at break. Where repeated impact or high strain after water saturation is expected, an unfilled or lower-glass PA12 grade may be required. In hot-water systems, continuous service temperature and pressure lifetime must be validated to the applicable national standard; short-term HDT values to ISO 75-2 do not substitute for long-term hydrostatic testing.

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