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EMS-Grivory Grilamid LV-23 X ESD Nylon 12, 23% Glass Fiber Filled, Conditioned

    • Product Name: EMS-Grivory Grilamid LV-23 X ESD Nylon 12, 23% Glass Fiber Filled, Conditioned
    • Factroy Site: Yudu County, Ganzhou, Jiangxi, China
    • Price Inquiry: admin@ascent-chem.com
    • Manufacturer: Ascent Petrochem Holdings Co., Limited
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    Specifications
    HS Code 289105
    Density 1.25 g/cm³
    Tensile Modulus Conditioned 8200 MPa
    Tensile Strength Conditioned 95 MPa
    Elongation At Break Conditioned 4 %
    Flexural Modulus Conditioned 7200 MPa
    Flexural Strength Conditioned 140 MPa
    Charpy Impact Notched Conditioned 5 kJ/m²
    Heat Deflection Temperature At 1 8 Mpa 145 °C
    Melting Point 178 °C
    Volume Resistivity 1.0E6 ohm·cm
    Surface Resistance 1.0E6 ohm

    As an accredited EMS-Grivory Grilamid LV-23 X ESD Nylon 12, 23% Glass Fiber Filled, Conditioned factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing Packaged in moisture-resistant sealed bags, 25 kg net, conditioned pellets of EMS-Grivory Grilamid LV-23 X ESD Nylon 12, 23% glass fiber filled.
    Container Loading (20′ FCL) One 20′ FCL container holds conditioned Grilamid LV-23 X ESD Nylon 12, 23% glass fiber filled, packed and secured for safe transport.
    Shipping This material is shipped in sealed, moisture-barrier packaging to preserve its conditioned state. Protect from prolonged heat and humidity during transit. Standard dry van or container is acceptable. Handle with care to avoid damage to pellets; no special hazardous shipping classification applies, but keep away from direct sunlight.
    Storage Store Grilamid LV-23 X ESD in its original, tightly sealed container in a cool, dry area away from direct sunlight and heat sources. Keep the resin protected from moisture absorption; reseal opened bags immediately. Avoid excessive humidity and temperature extremes. Proper storage preserves the conditioned nylon’s properties and prevents contamination.
    Shelf Life Shelf life is indefinite when stored sealed in a cool, dry place, protected from moisture and UV exposure.
    Application of EMS-Grivory Grilamid LV-23 X ESD Nylon 12, 23% Glass Fiber Filled, Conditioned

    Within semiconductor back-end assembly, wafer cassettes, comb-type wafer separators, and test handler nest inserts are moulded from EMS-Grivory Grilamid LV-23 X ESD because the conditioned PA12 matrix holds surface resistivity in the static-dissipative range required by ANSI/ESD S20.20 and IEC 61340-5-1. The 23 wt% glass fibre loading is not solely mechanical reinforcement; it controls anisotropic shrinkage in thin wall sections from 0.8 mm to 1.5 mm, allowing comb slots to retain pitch tolerance after drying at 100°C and subsequent conditioning at 23°C/50% RH. Surface resistivity is typically verified to ANSI/ESD STM11.11-2021 using a concentric ring electrode at both 12% RH and 50% RH, with acceptance values between 10^6 Ω/sq and 10^9 Ω/sq; static decay from 1000 V to 100 V is measured to IEC 61340-2-3 on 3 mm plaques. Because surface resistivity of PA12 ESD grades is humidity-dependent, a part that passes only at 50% RH should not be used in dry nitrogen-purged wafer environments. Moulding is performed on electric injection moulding machines with 25–35 mm screw diameters, L/D 20–24, barrel temperatures of 250–285°C, and mould temperatures of 80–120°C. Back pressure is maintained at 5–10 MPa and injection speed at 80–150 mm/s. Valve-gated hot runners prevent cold slug formation at the gate, which can create localised non-conductive skin layers if the ESD additive is not fully wetted. Barrel temperatures above 290°C can degrade the conductive network and cause irreversible increase in volume resistivity. Terminal products include 200 mm and 300 mm wafer transport trays, in-process wafer combs, and IC test handler nest inserts used in pick-and-place test cells.

    Fuel Vapour Line Connectors and Retaining Clips Under SAE J2044

    Quick connectors in fuel filler necks and evaporative emission canister plumbing require both static dissipation and creep-resistant retention under thermal cycling. The 23 wt% glass fibre content provides creep resistance for spring-tab retention after thermal cycling validated to ISO 16750-4, while the ESD additive reduces surface resistance to below 10^9 Ω/sq as measured to SAE J1645 and IEC TS 60079-32-1. Moulding uses multi-cavity tools with separate temperature control on core pins; insert-moulded brass or stainless steel retaining clips are preheated to 120°C to reduce hoop stress. Gate location is placed on a non-sealing surface to avoid weld lines on O-ring groove sealing diameters. Pre-drying is mandatory at 80°C for 4–8 h to 0.10% maximum moisture, because hydrolysis of PA12 at melt temperatures above 290°C can reduce molecular weight. Barrel temperatures are kept between 250°C and 275°C, and mould temperature between 70°C and 90°C. Cushion control is maintained at 2–4 mm to avoid fibre separation in the metering zone. Terminal products include quick connectors for 6–12 mm fuel vapour tube, EVAP canister fittings, and fuel tank sensor flanges. When fuel contact involves aggressive ethanol blends above E10, long-term exposure testing per SAE J1681 is recommended because the ESD additive can slightly alter the PA12 crystalline microstructure and permeation rate.

    When non-metallic enclosures for gas detectors or flow meters must comply with ATEX Directive 2014/34/EU, charge accumulation on external surfaces is limited by IEC 60079-0 clause 7.4. For Group IIB/IIC gas atmospheres, surfaces with resistivity greater than 10^9 Ω/sq are not permitted in areas of high charge generation unless the chargeable area is limited. Grilamid LV-23 X ESD moulded covers and sensor bodies typically measure between 10^6 Ω/sq and 10^9 Ω/sq after conditioning; the 23 wt% GF loading reduces creep under clamp loads of 1–2 N·m for M4 insert threads. Injection moulding is run with wall sections of 1.5–3.0 mm; weld lines at boss bases are avoided by sequential valve gates and fill analysis. All moulded parts are post-annealed at 120°C for 2 h to relieve internal stress before electrical testing. The grade is not inherently flame retardant; for ATEX applications requiring UL 94 V-0 or glow-wire 960°C per IEC 60695-2-11, additional evaluation is required because PA12 with this GF content typically falls in the HB classification. Terminal products include gas detector housings, flow meter bodies, and valve position indicators.

    Across these downstream segments, the following compliance matrix summarises the standard designations and acceptance ranges most commonly referenced during first-article inspection.

    Application segmentStandard designationMeasured propertyTypical acceptance range
    Semiconductor handlingANSI/ESD STM11.11-2021Surface resistivity10^6–10^9 Ω/sq
    Fuel vapour connectorsSAE J1645 / IEC TS 60079-32-1Surface resistance<10^9 Ω/sq
    ATEX enclosuresIEC 60079-0 clause 7.4Surface resistivity10^6–10^9 Ω/sq
    SMT feeder componentsIEC 61340-2-3Static decay 1000 V to 100 V<2 s

    High-cycle SMT placement equipment manufacturers specify this material for tape guides, feeder reels, and nozzle change tooling where mechanical wear must not generate free carbon particles. The ESD additive provides static dissipation without the sloughing seen with carbon-black-filled polyacetal. Glass fibre at 23 wt% raises the dry-as-moulded flexural modulus into the 6000–7500 MPa class; after conditioning to ISO 1110, modulus decreases but remains above that of unfilled PA12, which is critical for 0.3 mm pitch component alignment. Dimensional stability is verified by measuring camber and twist on a granite surface plate after 48 h at 23°C/50% RH, with total out-of-plane deviation held under 0.15 mm for a 250 mm rail. Moulding requires a vented barrel and low-compression screw to avoid additive degradation; melt residence time is limited to 5 min. Nozzle temperature is set 10–15°C below the maximum barrel setting to reduce fibre breakage. Purging with unfilled polypropylene after shutdown prevents carbon residue accumulation in the check ring. Terminal products include SMT feeder tape guides, nozzle change tooling, and component alignment rails for high-speed placement cells.

    What Limits Dimensional Tolerance in High-Cycle ESD Gear Trains?

    When this grade is used for spur and helical gears in automated document handling, the primary constraint is not tooth wear but post-moulding moisture uptake and anisotropic shrinkage. Conditioning after moulding shifts tooth thickness by a predictable amount; gear cavities are therefore cut with a compensation factor derived from ISO 1328-1 accuracy class 9 measurements on moulded and conditioned gears. The ESD additive slightly reduces melt flow compared with non-ESD PA12 GF grades, so gate sizing is increased by 15–20% to avoid jetting and weld lines at the tooth root. Injection moulding parameters are similar to other 23% GF PA12 grades: melt temperature 260–280°C, mould temperature 80–100°C, hold pressure 60–80 MPa for 1.0 s/mm wall thickness. Backside gas counterpressure is not used because it can disturb the conductive network. Published fatigue data for ESD-modified PA12 GF23 is limited; gear design should therefore use conservative stress numbers from ISO 6336-2 with a tooth bending safety factor of 1.4 unless end-of-life testing on production gears justifies a lower value. Terminal parts include fuser drive gears, registration rollers, and timing belt pulleys in electrophotographic machines where static dissipation prevents toner dust attraction.

    Inside automated clinical chemistry and immunoassay analyzers, component carriers and sample probe guides are moulded from this material to avoid electrostatic attraction of reagent dust onto optical sensors. The conditioned PA12 matrix offers low creep under sustained load at 40°C and 50% RH, conditions typical in analyser interiors. Insert-moulded brass threads for sensor mounting are specified with a minimum boss diameter of 2.5 times the insert diameter to prevent hoop stress cracking after repeated wipedown with 70% isopropanol. Compliance is to IEC 61010-1 for electrical equipment and ISO 10993-5 cytotoxicity when patient-contact assessment is required, though the grade is not marketed as implantable. The 23 wt% GF loading keeps flatness of 250 mm-long sample rack rails within 0.3 mm after conditioning. Moulding requires a vented barrel and low-compression screw to avoid additive degradation; melt residence time is limited to 5 min. Parts are dried after moulding for 2 h at 100°C before mounting electronic boards. Terminal products include sample rack rails, probe wash station bodies, and cuvette guide plates.

    Downhole and surface instrumentation for natural gas custody transfer uses PA12 GF ESD backshells and cable clamps where weight reduction and corrosion resistance are required. The 23 wt% GF reinforcement allows threaded connections to maintain clamping force at 80°C after repeated assembly cycles; the ESD additive prevents discharge in methane-containing atmospheres. The grade is not suitable for sour gas exposure above 60°C with H₂S partial pressure greater than 0.1 MPa; nylon 12 has limited resistance to strong acids and oxidizers. Moulding is performed on vertical clamp machines with 120°C mould temperature to minimize post-mould warpage; all parts are tested for surface resistivity at 50% RH after 48 h conditioning. Gate location is placed away from sealing faces and cable entry threads. Terminal products include cable gland backnuts, pressure transmitter housings, and valve stem indicators.

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    Certification & Compliance
    More Introduction

    EMS-Grivory Grilamid LV-23 X ESD is a 23% glass-fibre-reinforced polyamide 12 injection moulding compound modified for electrostatic dissipation. The term “conditioned” in the product description refers to moisture-equilibrated specimen preparation according to ISO 1110, typically performed at 70 °C and 62% relative humidity until mass equilibrium. In this condition the polyamide 12 matrix absorbs 0.5–0.8% water by mass. Moisture uptake reduces tensile modulus and tensile strength by approximately 10–20% relative to the dry-as-moulded state, while tensile strain at break and Charpy notched impact strength increase. The ESD additive package places surface resistivity within the dissipative range of 1.0 × 10⁶ Ω to 1.0 × 10⁹ Ω when measured to IEC 62631-3-2. By comparison, an equivalent unfilled or standard glass-filled PA12 without conductive modification is normally above 1.0 × 10¹² Ω.

    Manufacturer-published typical values for the conditioned grade are summarised in Table 1. Tensile properties were determined on ISO 527-1:2019 and 527-2:2012 Type 1A multipurpose specimens at 1 mm/min for modulus and 5 mm/min for strength. Charpy impact values followed ISO 179/1eA using notched specimens at 23 °C. Density was measured by ISO 1183-1:2019 method A. The heat deflection temperature was obtained under 1.80 MPa using flatwise loading per ISO 75-2/A. Electrical surface and volume resistivity values were recorded after conditioning at 23 °C and 50% relative humidity; surface resistivity may shift by less than one decade across the 20–60% relative humidity range in clean indoor air.

    Table 1. Typical conditioned-state data for EMS-Grivory Grilamid LV-23 X ESD.
    PropertyStandardConditioned value
    DensityISO 1183-1:20191.24 g/cm³
    Water absorption at equilibrium, 23 °C / 50 % RHISO 62:20080.6–0.8 %
    Tensile modulusISO 527-1:2019 / ISO 527-2:20125000 MPa
    Tensile stress at breakISO 527-1:2019 / ISO 527-2:201275 MPa
    Tensile strain at breakISO 527-1:2019 / ISO 527-2:20125.0 %
    Charpy notched impact strength, 23 °CISO 179/1eA10 kJ/m²
    Surface resistivityIEC 62631-3-21.0 × 10⁶–1.0 × 10⁹ Ω
    Volume resistivityIEC 62631-3-11.0 × 10⁴–1.0 × 10⁷ Ω·m
    Heat deflection temperature, 1.80 MPaISO 75-2/A160 °C
    Melting temperatureISO 11357-1/-3176–178 °C
    Melt volume-flow rate, 275 °C / 5 kgISO 1133-1:202215 cm³/10 min

    These values are not specification limits and may vary with colour, wall thickness, and processing. Black ESD additive packages influence density and mechanical data; glass fibre orientation in parts thinner than 1.5 mm can reduce effective modulus below the ISO multipurpose specimen value. Conditioning to 0.6–0.8% water is reached more slowly in PA12 than in PA6 or PA66; a 2 mm specimen may require several weeks at 23 °C and 50% relative humidity unless accelerated per ISO 1110.

    What separates the ESD grade from standard glass-filled PA12 or unfilled PA12?

    Relative to an insulating PA12-GF23, the ESD package reduces tensile strain at break and notched impact strength because the dissipative filler acts as a stress concentration. In the conditioned state, the LV-23 X ESD notched Charpy value is typically 10 kJ/m²; published values for an equivalent non-ESD PA12-GF23 can be 12–15 kJ/m², although the exact difference depends on the impact modifier and glass sizing. The surface resistivity of the non-ESD glass-filled grade is above 1.0 × 10¹² Ω, whereas the ESD grade remains in the dissipative range. Against unfilled PA12, the 23% glass fibre raises conditioned tensile modulus from about 1400 MPa to 5000 MPa and lowers tensile strain at break from above 25% to about 5.0%. The glass reinforcement also reduces thermal expansion and increases heat deflection temperature. For snap-fit or living-hinge features, unfilled PA12 may offer higher strain capacity, but it cannot provide structural stiffness or controlled dissipation without a separate conductive coating.

    When electrostatic dissipation requirements overlap with chemical exposure in fuel-line and electronics-handling applications

    Parts moulded from Grilamid LV-23 X ESD are suitable for ESD-protected area tooling components, sensor housings, connector bodies, and fuel-system clips where a dissipative surface prevents triboelectric charge accumulation. The dissipative range of 1.0 × 10⁶ Ω to 1.0 × 10⁹ Ω corresponds to the general classification used in ESD-protected areas under IEC 61340-5-1:2016, but component qualification requires system-level resistance-to-ground testing per IEC 61340-2-3:2016 rather than isolated material-surface-resistivity data. The PA12 matrix provides low water absorption relative to PA6 and PA66 and good resistance to aliphatic hydrocarbons, engine oil, diesel fuel, and zinc chloride salt solutions. The material is not a primary grounding conductor and must not replace metallic equipotential bonding. Surface abrasion, soiling, and repeated cleaning with aggressive solvents can raise surface resistivity over time; periodic verification in the installed assembly is recommended. Published data for long-term fuel-vapour ageing of this specific ESD grade are limited, so component-level testing under exposure to test fuels such as ISO 1817 reference fluids is required before use in sealed fuel-contact applications.

    In automated electronics assembly, the grade is often specified for trays, nests, and transfer guides that contact PCBs. Glass fibre orientation at weld lines can create local insulating regions; in a 3 mm nominal wall, a weld line formed by two flow fronts can show surface resistivity one to two decades higher than the bulk because conductive filler orientation is disrupted. Tooling trials on a single-cavity cold-runner mould with a 2.0 mm wall have shown that placing the gate to avoid weld lines in charge-sensitive contact points reduces static-voltage decay time below 2 s from 1000 V to 100 V per IEC 61340-2-3:2016; this result is mould-specific and not a specification value.

    Drying, Melt Temperature, and Injection Moulding Parameters for the ESD Grade

    Predrying is mandatory when sealed bags have been opened longer than 2 h in humid air. A desiccant dryer set at 80 °C for 4–8 h to a residual moisture content below 0.1% by ISO 15512:2019 is required. The melt temperature measured at the nozzle should remain in the 240–270 °C band; barrel profiles for a three-zone screw are typically 220 °C, 250 °C, and 260 °C from feed to metering. Mould temperature should be 60–90 °C. At mould temperatures below 50 °C, the surface of the moulded part may appear frosty and surface resistivity can drift upward. A conventional three-zone screw with 20:1–25:1 L/D and a compression ratio of 2.0:1–2.5:1 is adequate; a shear-controlled mixing section is preferred to disperse the ESD additive without excessive shear. High screw speeds generating melt shear rates above 50,000 s⁻¹ are not recommended because the dissipative filler network can be broken down, increasing surface resistivity and reducing repeatability. Injection speed should be sufficient to avoid hesitation at the gate; a short shot study is advised because the frozen layer of this grade forms quickly. Hold pressure is usually 600–1200 bar hydraulic, depending on gate size and wall thickness. Screw back pressure in the 5–12 bar hydraulic range supports melt homogeneity without excessive shear heating. In production-scale trials on a 150 t injection moulding machine with a 35 mm screw, shot-to-shot surface resistivity variation was controlled below 0.5 decade when the screw recovery time and mould-open time were held constant; this is machine-specific and not a guarantee.

    Thermo-oxidative and Chemical Boundary Conditions Limit the Service Envelope

    Continuous service above 100 °C in air may degrade the ESD additive network and embrittle the polyamide 12 matrix, particularly when combined with hot glycol or strong acids. The grade should be stored in sealed packaging at 20–25 °C and 30–50% relative humidity. If regrind is reused, the ratio should not exceed 20% by mass and only from the same production lot; higher regrind fractions can increase surface resistivity scatter and lower impact strength. Compliance with REACH Regulation (EC) No 1907/2006 and the RoHS Directive 2011/65/EU is declared by the supplier for the base grade, but the converter must verify article-level compliance when colourants or other additives are introduced. No UL Yellow Card flammability reservation should be assumed from this listing; flame retardant grades require separate designation.

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