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EMS-Grivory Grilamid® LKN-3H PA12-GB30

    • Product Name: EMS-Grivory Grilamid® LKN-3H PA12-GB30
    • Factroy Site: Yudu County, Ganzhou, Jiangxi, China
    • Price Inquiry: admin@ascent-chem.com
    • Manufacturer: Ascent Petrochem Holdings Co., Limited
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    Specifications
    HS Code 911921
    Density 1.22 g/cm³
    Tensile Modulus 2600 MPa
    Tensile Strength 45 MPa
    Elongation At Break 10%
    Charpy Impact Strength Notched 5 kJ/m²
    Heat Deflection Temperature 1 8 Mpa 65 °C
    Melting Point 178 °C
    Water Absorption 24h 0.3%
    Volume Resistivity 1e14 Ohm·cm
    Dielectric Strength 25 kV/mm
    Mold Shrinkage 0.3%

    As an accredited EMS-Grivory Grilamid® LKN-3H PA12-GB30 factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing EMS-Grivory Grilamid LKN-3H PA12-GB30 is supplied as pellets in 25 kg sealed bags, ready for processing.
    Container Loading (20′ FCL) 20′ FCL: Grilamid® LKN-3H PA12-GB30 granules packed in 25kg bags on pallets, shrink-wrapped and securely loaded.
    Shipping Grilamid® LKN-3H PA12-GB30 is supplied as dry, free-flowing pellets in sealed, moisture-proof bags or drums. Ship as non-hazardous goods in clean, dry containers. Protect from humidity and direct sunlight; store below 50°C. Handle with standard industrial care, avoiding dust exposure. Ensure proper labeling and include safety data sheet.
    Storage Store in original, unopened packaging in a cool, dry, and well-ventilated area. Keep away from direct sunlight, heat sources, and moisture to prevent hydrolysis and degradation. Maintain temperatures below 30°C (86°F). Reseal any partially used containers tightly to minimize moisture absorption before processing. Shelf life is typically several years under proper conditions.
    Shelf Life Shelf life is typically 2 years when stored in original sealed packaging, kept dry, cool, and away from direct sunlight.
    Application of EMS-Grivory Grilamid® LKN-3H PA12-GB30
    Inside compressed air distribution networks, push-fit fittings, coupling bodies and release sleeves are injection moulded from Grilamid LKN-3H PA12-GB30 in multicavity tools where roundness, thread repeatability and resistance to oil-laden workshop air determine in-service performance. The compound is supplied with a fixed 30 wt% spherical glass bead content. This bead geometry reduces anisotropic shrinkage compared with glass-fibre-reinforced polyamides, which is critical when sealing faces and tapered or straight threads must remain round after ejection. Pre-drying at 80 °C for 4–6 h to a residual moisture target below 0.10 wt% is mandatory. Melt temperature is held between 230 °C and 270 °C. Mould temperature is typically 50–80 °C depending on wall thickness and tool water circuit design. Insufficient mould temperature produces a dull surface and higher internal stress at the gate. Processors using hot-runner valve-gated systems prefer low-to-moderate injection speed to avoid filler agglomeration at flow fronts. For pressure-bearing parts, regrind addition is generally limited to 15–20 wt% unless burst and leakage validation is repeated per ISO 14743. Mixing regrind from unreinforced PA12 reduces the glass bead fraction and shifts shrinkage. Dilution beyond 10 wt% without revalidation is not recommended. Finished fittings for 1/4-inch to 1/2-inch outside-diameter polyurethane or polyamide tube circuits are thread-tested against ISO 228-1 or ISO 7-1 depending on port geometry.

    What Dimensional Tolerance Limits Are Achievable in Engine Bay Sensor Housings?

    Underhood sensor housings, including manifold pressure sensor enclosures and pedal position module frames, carry mounting bosses, snap hooks and connector shrouds that must remain flat after vibration, soldering and humidity cycling. The 30 wt% glass bead loading in Grilamid LKN-3H produces a more isotropic mould shrinkage field than 30 wt% short-glass-fibre PA6 or PA66 grades. Shrinkage measured per ISO 294-4 on 2 mm plaques for glass-bead-filled PA12 commonly falls in the 0.5–1.0% range depending on wall thickness, gate position and mould temperature. Flow-direction and transverse shrinkage values often differ by less than 0.2% for this filler morphology, but article-level validation is required because local geometry can amplify variation. Published data for this specific moulded configuration is limited. The material should be pre-dried at 80 °C for 4–6 h. Melt temperature from 250 °C to 280 °C, mould temperature 60–90 °C, and hold pressure 60–100 MPa are representative processing inputs on hydraulic or electric injection moulding machines with clamp capacities from 800 kN to 2,000 kN for multicavity tools. Weld lines formed around mounting holes or connector openings are the main mechanical weak points. Although spherical filler reduces anisotropic shrinkage at the weld line, it does not restore tensile strength. A weld-line tensile specimen cut from a prototype housing should be evaluated per ISO 527-2, and the derived value should be checked against the unfilled matrix or an approved incumbent material rather than assumed. The terminal assembly is an engine bay sensor housing with brass or stainless steel threaded inserts, validated under thermal cycling per ISO 16750-4 and damp heat testing per IEC 60068-2-30.Because PA12 exhibits lower equilibrium moisture uptake than PA6 or PA66, dimensional variation in fuel vapour quick connector components exposed to humid underbonnet air is reduced. However, the glass bead filler in Grilamid LKN-3H must be assessed for low-temperature impact, not only dimensional stability. Typical parts include male ends, retaining clips and purge valve bodies designed against SAE J2044 and SAE J2260 interface dimensions. Pre-drying at 80 °C for 6 h to below 0.10 wt% residual moisture is standard before moulding. Melt temperature is kept between 240 °C and 270 °C, and mould temperature at 50–80 °C. The fixed 30 wt% glass bead fraction should not be altered by high levels of carbon black or colour masterbatch. Addition rates above 2 wt% can shift melt flow and weld integrity at gate regions. Where laser welding of two housings is used, the absorber masterbatch concentration must be validated with the specific laser wavelength and contour speed because glass beads scatter the beam and may alter melt penetration depth. Connector bodies should be subjected to fuel immersion per ISO 175 in test fuels representing CE10 or CE85 if alcohol fuel contact is expected, followed by tensile and dimensional checks per ISO 527-2 and ISO 294-4. Published data for this specific compound in fuel immersion is limited. Each fuel blend and temperature profile must be validated on finished parts. Terminal products are vapour purge connectors and fuel line male fittings for light-duty gasoline evaporative emission systems.

    Dimensional Stability of Water Meter Valve Bodies and Irrigation Manifold Components

    Water management valve bodies, manifold spools and cartridge housings are injection moulded with internal galleries, sealing faces and O-ring grooves that require low out-of-roundness after water absorption. In this compound, the 30 wt% glass bead fraction contributes to isotropic post-mould shrinkage and reduces the corner warping observed in semi-crystalline polyamides with asymmetric flow fields. Moisture uptake of PA12 is lower than that of PA6 under 23 °C/50% RH conditioning. Test data generated per ISO 62 and ISO 1110 for PA12-based grades typically fall below 2.0 wt%. However, the finished valve body must be dimensionally checked after a complete wet-conditioning cycle because wall thickness and skin-core morphology affect the dimensional change. Processing on three-plate or split-mould tools uses melt temperatures of 240–270 °C and mould temperatures of 70–90 °C to maximise crystallinity at sealing regions. Pre-drying at 80 °C for 4–8 h is required. Residual moisture above 0.15 wt% can produce gas splay on visible surfaces and inconsistent seal roundness. Regrind addition for non-pressure-bearing irrigation parts is often capped at 20 wt%. For potable-water valve bodies, any regrind use must comply with the relevant product standard and hygiene approval, not only the resin datasheet. Application-specific water-contact approval may include AS/NZS 4020, BS 6920, KTW-BWGL or ACS. These are article-level approvals and are not automatically conferred by the raw material grade. The terminal product is a water softener control valve body, irrigation manifold spool or filter cartridge housing with threaded port geometry. Because glass bead reinforcement reduces impact strength relative to unreinforced PA12, valve bodies exposed to water hammer or physical impact should be tested for burst and fatigue under the manufacturer’s selected sequence. Published data for this specific configuration is limited.
    Application contextRelevant standard or directiveTest method or clause focus
    Pneumatic push-fit fittings and coupling bodiesISO 14743, ISO 228-1Burst pressure, leakage, thread form
    Fuel vapour quick connectorsSAE J2044, SAE J2260Interface dimensions, vibration, fuel immersion
    Engine bay sensor housingsISO 16750-4, IEC 60068-2-30Thermal cycling, damp heat, dimensional stability
    Water meter valve bodiesAS/NZS 4020, BS 6920, KTW-BWGLCold water extraction, article-level hygiene approval
    Laboratory diagnostic housingsIEC 61010-1, ISO 175Electrical equipment safety, chemical immersion
    Electronic connector strips and bobbin shroudsIEC 60112, UL 94Comparative tracking index, flammability class

    When Laboratory Diagnostic Housings Require Resistance to Disinfectants and Low Warp

    In non-patient-contact in-vitro diagnostic platforms, large flat housings, sample handling decks and centrifuge shrouds are exposed to iso-propyl alcohol, ethanol and quaternary ammonium disinfectants, while snap-fit interfaces and sealing rims must remain flat over a 15–30 °C ambient operating range. Glass-bead-filled PA12 in this grade provides lower anisotropic distortion than short-glass-fibre PA grades, which is relevant when two-shot seals or adhesive gaskets are applied to long sealing ribs. The fixed 30 wt% bead loading must not be combined with high-filler regrind from other glass-fibre grades because the resulting shrinkage and viscosity are non-linear. Drying at 80 °C for 4 h, melt temperature 250 °C and mould temperature 60–80 °C are representative process settings. Residence time should be kept below 10 min to limit thermal degradation of the polyamide matrix, and screw speed should be selected to avoid excessive shear heating. Chemical resistance to disinfectants is not universal. The finished housing should be immersed in the actual cleaning agent at the maximum field concentration and contact time per ISO 175, then evaluated for stress cracking near bosses and weld lines. Electrical safety for the host instrument is assessed under IEC 61010-1, but that standard addresses the equipment rather than the polymer. Terminal products include benchtop analyser housings, centrifuge covers and sample preparation module deck plates used in clinical laboratory equipment.Precision electronic connector strips and sensor bobbin shrouds in high-cavity tools benefit from the isotropic shrinkage behaviour of the spherical glass bead filler in Grilamid LKN-3H. The material is processed with pre-drying at 80 °C for 4–6 h, melt temperature 240–270 °C, mould temperature 60–90 °C, and moderate injection speed to prevent jetting at the gate. Glass bead filled PA12 has lower melt viscosity than glass-fibre-filled PA12 at the same filler mass fraction, which assists filling of thin walls down to 0.8 mm. The lower melt strength requires adequate venting and gate sizing to prevent burn marks and short shots. Electrical properties such as comparative tracking index should be measured per IEC 60112. Unfilled PA12 is normally classified as UL 94 HB, and the glass-bead-reinforced grade does not provide flame retardancy unless specifically modified with a flame-retardant system. This limits use to low-voltage connector insulation and bobbin housings where flammability requirements do not demand UL 94 V-2 or better. Regrind incorporation is normally restricted to 15 wt% in thin-wall parts because repeated thermal history increases brittleness and reduces insulation surface quality. Terminal products are strip connector housings, sensor bobbin shrouds and relay coil forms.
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    Certification & Compliance
    More Introduction

    EMS-Grivory Grilamid® LKN-3H is an injection moulding compound based on polyamide 12 and filled with a nominal 30 wt% spherical glass-bead reinforcement; the ISO 1043-1 designation is PA12-GB30. The polyamide 12 backbone is produced from laurolactam and carries a lower amide group concentration than PA6 or PA66, which reduces equilibrium moisture uptake and contributes to a melting point near 176 °C when measured to ISO 11357-3. The manufacturer’s technical datasheet lists a dry-as-moulded density of 1.25 g/cm³ under ISO 1183 and saturated water absorption of 1.1% under ISO 62. These values place the material close to glass-fibre-reinforced PA12 in density, but the spherical filler creates a different balance of stiffness, shrinkage anisotropy, and surface quality.

    Typical dry-as-moulded mechanical values from the technical datasheet include a tensile modulus of 2600 MPa, tensile stress at yield of 55 MPa, tensile strain at yield of 5%, and tensile strain at break of 15% under ISO 527-1/-2. Notched Charpy impact strength at 23 °C is 5 kJ/m² when tested to ISO 179/1eA. Heat deflection temperature under 1.8 MPa is 135 °C, and under 0.45 MPa it is 150 °C per ISO 75-1/-2. After conditioning at 23 °C and 50% relative humidity, tensile modulus typically decreases to approximately 1800 MPa and yield stress to approximately 45 MPa, while elongation at break increases. This moisture-induced shift is smaller than that encountered in PA66 glass-bead compounds because the PA12 matrix absorbs less water.

    Mould shrinkage measured to ISO 294-4 is typically between 0.6% and 0.9%, with flow-direction and transverse-direction values remaining close. Reported application fields include automotive quick connectors, pneumatic valve housings, sensor bodies, electrical enclosures, and fluid-management components. In these parts the glass bead filler is selected for low warpage and predictable dimensional behaviour rather than maximum tensile strength. Compared with acetal homopolymer, the PA12-GB30 grade offers lower density and better resistance to alkaline road-salt exposure, although the acetal may provide higher dry stiffness in some configurations.

    What Consequences Follow from Replacing Glass Fibres with Spherical Glass Beads in PA12?

    Spherical glass beads have an aspect ratio close to unity, so they do not orient along the melt-flow direction to the same extent as chopped glass fibres. In a representative 30% glass-fibre PA12, flow-direction shrinkage can fall below 0.3% while transverse shrinkage remains near 0.7%, producing differential stress that distorts flat covers and thin-wall housings. By contrast, PA12-GB30 shrinkage typically remains between 0.6% and 0.9% in both directions under ISO 294-4. This isotropic behaviour simplifies tool compensation and reduces post-mould distortion in multi-gated parts.

    Weld-line strength is also affected by filler geometry. Glass fibres oriented parallel to a weld line create a weak plane because load transfer across the polymer matrix is interrupted; spherical beads preserve more of the unfilled polymer’s weld strength. The smoother surface of glass-bead-filled PA12 also lowers tool wear and improves demoulding consistency compared with glass-fibre-filled grades. However, the absence of high-aspect-ratio reinforcement limits tensile modulus and makes the material more notch-sensitive than a glass-fibre PA12 of equivalent filler loading.

    PropertyUnreinforced PA12PA12-GB30 LKN-3H30% GF PA12 representativeStandard
    Density1.01 g/cm³1.25 g/cm³1.25 g/cm³ISO 1183
    Tensile modulus dry1500 MPa2600 MPa6800 MPaISO 527-1/-2
    Tensile stress at yield dry45 MPa55 MPa100 MPaISO 527-1/-2
    Heat deflection temperature at 1.8 MPa50 °C135 °C160 °CISO 75-1/-2
    Mould shrinkage flow/transverse1.01.3% / 1.01.3%0.60.9% / 0.60.9%0.20.4% / 0.50.8%ISO 294-4

    The comparative values show that LKN-3H trades approximately 4200 MPa of dry tensile modulus relative to a representative 30% glass-fibre PA12, yet its low shrinkage anisotropy and reduced warpage are decisive in precision housings where dimensional acceptance limits are tighter than ±0.10 mm. Unreinforced PA12 provides lower stiffness and higher mould shrinkage, so the glass-bead variant occupies a middle position: moderate stiffness, high dimensional stability, and no pronounced fibre orientation. Published data for weld-line tensile strength in PA12-GB30 across varied gate locations and wall thicknesses is limited; mould-filling simulation and physical weld-line testing remain necessary for safety-critical components.

    When Dimensional Stability in Humid Service Environments Excludes PA6 and PA66

    PA12 contains a lower amide group concentration than PA6 and PA66, which reduces equilibrium moisture sorption. The technical datasheet lists saturation water absorption of 1.1% for LKN-3H under ISO 62; comparable glass-bead-filled PA6 and PA66 compounds can reach 79% at saturation. At 23 °C and 50% relative humidity, the PA12-GB30 moisture content is approximately 0.5%, whereas PA66-GB30 can exceed 2.0% under the same conditions. The practical consequence is smaller dimensional change and slower loss of tensile modulus when a moulded part moves from dry as-moulded storage to humid field service.

    Electrical property drift is similarly moderated. Because PA12 absorbs less water, surface resistivity and dielectric strength remain more stable in humid air than those of PA6 or PA66 glass-bead grades. The datasheet should be consulted for specific dielectric strength, comparative tracking index, and volume resistivity values under IEC 62631 or IEC 60112 test conditions. Chemical exposure in automotive fluid systems often favours PA12: the polymer is resistant to aliphatic hydrocarbons, oils, greases, diesel fuel, zinc chloride road salt, and many common automotive fluids. Continuous contact with strong mineral acids, phenols, formic acid, or strong oxidising agents is not recommended. For concentrated acids and oxygenated solvents, published compatibility data for this specific glass-bead configuration is limited, and component validation under actual service conditions is required.

    The moisture response also affects assembly tolerances. A PA66-GB30 housing may shift dimensionally after absorption of service moisture, changing press-fit interference and seal compression. LKN-3H reduces that drift because the matrix itself absorbs less water and the glass beads restrain the remaining expansion. This characteristic supports use in underhood quick connectors, air-brake valve bodies, and sensor enclosures exposed to humidity cycling. Compared with PA66-GB30, the PA12 variant accepts lower dry stiffness in exchange for better dimensional retention and lower post-mould warpage in humid environments.

    Melt Temperature, Drying Dew Point, and Screw Recovery Parameters

    Pre-drying in a desiccant dryer at 80 °C for 46 h is required before melt processing; the resin should reach a residual moisture content below 0.10% by weight. A dryer dew point of -30 °C or lower is recommended. If pellets are exposed to ambient air above 60% relative humidity for more than 1 h, re-drying is necessary to prevent splay, surface silver streaks, and hydrolytic degradation at processing temperature. Drying hoppers with insulated feed zones reduce moisture re-uptake on long production runs.

    Barrel temperature settings of 220270 °C from rear to nozzle are typical, with measured melt temperature at the nozzle maintained between 240 °C and 270 °C. Mould temperature should be held between 60 °C and 100 °C; a target of 80 °C is common for optimum crystallinity and dimensional stability. Mould temperatures below 50 °C can increase frozen-layer thickness, reduce weld-line strength, and raise shrinkage variability. On production lines using hydraulic injection moulding machines of 10002500 kN clamp force, uneven mould temperature across long flow paths is a recurrent source of batch-to-batch dimensional noise.

    Melt residence time should remain below 10 min; sustained melt temperature above 280 °C can cause thermal-oxidative yellowing and molecular weight loss. Injection speed is set medium to fast to prevent surface flow marks from the high filler loading, while excessive speed may require additional venting to avoid burn marks. Typical holding pressure is 400800 bar, back pressure is 3080 bar, and screw speed is moderate. A screw with an L/D ratio of 1822 and compression ratio of 2.02.5:1 is commonly used; a shut-off nozzle is recommended to prevent drool at higher melt temperatures.

    Tooling should provide gates of at least 0.8 mm in diameter or thickness for wall sections around 3 mm to avoid premature freeze-off. Vent depths of 0.020.05 mm in the final 20 mm of the flow path reduce burn-mark risk. Regrind addition up to 30 wt% is common, but notched Charpy impact retention must be verified; above 30 wt% the probability of glass bead agglomeration, feeding fluctuation, and surface defects increases. Injection moulding trials with this grade should establish the lowest melt temperature that still fills thin sections, because lower thermal stress preserves impact strength and colour stability.

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