| HS Code | 819711 |
| Density | 1.19 g/cm³ |
| Tensile Modulus | 17500 MPa |
| Tensile Stress At Break | 185 MPa |
| Tensile Strain At Break | 1.8 % |
| Flexural Modulus | 15500 MPa |
| Flexural Strength | 260 MPa |
| Charpy Impact Strength At 23 C Unnotched | 60 kJ/m² |
| Charpy Impact Strength At 23 C Notched | 15 kJ/m² |
| Izod Impact Strength At 23 C Notched | 12 kJ/m² |
| Heat Deflection Temperature At 1 8 Mpa | 160 °C |
| Melting Temperature | 178 °C |
| Water Absorption After 24h Immersion | 0.30 % |
As an accredited EMS-Grivory Grilamid LCL-3 H anthracite Nylon 12, 30% Long Carbon Fiber Filled, Dry factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.
| Packing | Supplied in moisture-proof, sealed 25 kg foil bags on pallets, with desiccant, ensuring dry storage and handling. |
| Container Loading (20′ FCL) | A 20-foot FCL container loading of dry Grilamid LCL-3 H nylon 12 granules, 30% long carbon fiber filled, in sealed packaging. |
| Shipping | EMS-Grivory Grilamid LCL-3 H anthracite ships as a dry, 30% long carbon fiber filled Nylon 12 in sealed moisture-barrier bags to prevent water absorption. Store in original containers in a cool, dry area; reseal immediately after use. Ensure dry handling and avoid exposure to humidity before processing. |
| Storage | Store in a cool, dry place inside the original, tightly sealed container. Protect from moisture, direct sunlight, and heat sources to prevent water absorption and property degradation. Ideal storage temperature is below 30°C (86°F). Keep away from strong oxidizers. Under proper conditions, shelf life is typically two years from date of manufacture. |
| Shelf Life | Store in a dry, sealed container away from moisture. Shelf life is typically 2 years under proper conditions. |
EMS-Grivory Grilamid LCL-3 H anthracite is specified for adjustable load-bearing orthotic hinge bosses and prosthetic socket adapters in which the design target is a dry-condition density of 1.12–1.16 g/cm³ under ISO 1183-1:2019, yielding an approximately 80% mass reduction compared with stainless steel at 7.85 g/cm³. The grade is a Nylon 12 matrix with 30 wt% long carbon fiber and is processed at 100 wt% for the structural core of polycentric knee hinge inserts and exoskeleton hip joint housings. Where snap-fit covers or adjuster knobs require lower flow-direction stiffness, a let-down ratio of 15–20 wt% into unfilled PA12 reduces long-fiber content to roughly 24–25.5 wt% and lowers tensile modulus non-linearly, with component-level validation required under ISO 527-2:2012 and ISO 178:2019 because modulus reduction does not scale linearly with dilution. Processing uses hot-runner injection moulding with a 2.5:1 compression-ratio screw and a free-flow non-return valve; barrel profiles are set with rear zone 220 °C, centre 245 °C, front 255 °C and nozzle 250 °C, while tool circulation at 90–120 °C promotes crystallisation and reduces frozen-in orientation. The resin is dried to < 0.05 wt% residual moisture in a desiccant dryer with -40 °C dew-point air for 4–6 h at 80 °C. Batch-to-batch variation in carbon-fiber sizing can shift melt viscosity by up to 12%, so cavity-pressure and injection-time monitoring are used rather than fixed screw-position control. Edge gates are located away from hinge pin bosses because weld-line regions in long-carbon-fiber PA12 reduce Charpy impact from roughly 25 kJ/m² to below 10 kJ/m² under ISO 179-1:2010. Terminal components include polycentric knee hinge inserts, prosthetic pylon adaptors, and exoskeleton hip joint housings produced under ISO 22523:2006 and documented according to the EU Medical Device Regulation 2017/745 Annex I general safety and performance requirements.
For underhood electronic modules and ADAS sensor housings, the conductive path provided by 30 wt% long carbon fiber reduces surface resistivity from unfilled PA12 values near 10^12–10^13 Ω to a dissipative range of 10^2–10^5 Ω under ASTM D257-14. This surface-resistivity reduction by itself does not guarantee radiated emission control across the 150 kHz–30 MHz conducted and 30 MHz–1 GHz radiated ranges, because partition-plane contact impedance and aperture leakage dominate above roughly 300 MHz. The material is run at 100 wt% in the enclosure base and lid; metallic spring-finger contacts or nickel-graphite elastomer gaskets are insert-moulded at the parting line rather than relying solely on resin resistivity. A ESD-only variant can be formulated by let-down at 70 wt% Grilamid LCL-3 H anthracite with 30 wt% unfilled PA12, yielding 21 wt% total carbon fiber, but shielding effectiveness and flexural modulus both decline; published data for this specific configuration is limited. Moulding is performed with a 2.0–2.4:1 compression-ratio screw, shallow feed zone, and back pressure of 0.2–0.5 MPa. Melt temperature is capped at 250 °C at the nozzle to prevent carbon-fiber sizing degradation above 260 °C, which appears as silver streaks and surface outgassing. Tool temperature is held at 80–110 °C, and the material is dried for 4 h at 80 °C with -40 °C dew-point air. Automotive electronic enclosure compliance is assessed under CISPR 25:2016 Class 3, ISO 11452-2:2019, and IEC 61340-5-1:2016; production control follows IATF 16949. Terminal formats include ADAS camera housings, steering-angle sensor covers, and underhood ECU enclosures where mass is 40–50% lower than a comparable die-cast aluminium housing.
Unmanned aerial vehicle structural arms and gimbal support yokes present a different fiber-length retention problem because wall sections are typically below 2.0 mm and the load path is unidirectional along the beam axis. Sequential valve gating is used in a 1.5–2.0 mm thick arm tool to create a continuous melt front from root to tip; this orients long carbon fiber in the main bending direction, with tensile bars cut parallel and transverse to flow showing a modulus anisotropy ratio of 1.8:1–2.4:1 under ISO 527-2:2012. The material is kept at 100 wt% in the structural arm body, with regrind limited to 5 wt% because a single granulator pass can shorten number-average fiber length from above 1.0 mm to below 0.6 mm and reduce Charpy impact by more than 20%. For snap-fit mast clamps, a mixture of 85 wt% Grilamid LCL-3 H anthracite and 15 wt% unfilled PA12 increases elongation while reducing flexural modulus; the blend ratio should be qualified with component-level ISO 178:2019 three-point bending and ISO 179-1:2010 Charpy because property changes are not linear with dilution. Processing uses a 18–22 L/D general-purpose screw with low-compression feed, screw speed of 40–60 rpm, and back pressure no higher than 0.3 MPa. Melt temperature is controlled between 230 °C and 245 °C to limit sizing degradation, and the tool is held at 85–105 °C. Material flammability is classified by UL 94 HB; the complete drone electrical/electronic system is CE-marked under 2014/53/EU, and the formulation is covered by EC 1907/2006 REACH and 2011/65/EU RoHS Annex II. Terminal components include folding quadcopter arm tubes with overmoulded pivot lugs, gimbal camera yokes, and landing-gear connector brackets.
When the design target shifts from static stiffness to sustained pedal load cycles, short-glass PA66 GF30 often loses a measurable fraction of dry tensile modulus after 24 h water immersion at 23 °C under ISO 62:2008, while the PA12 matrix of Grilamid LCL-3 H anthracite retains a higher fraction of dry stiffness at 50% RH. The 30 wt% long carbon fiber network is used at 100 wt% for the structural pedal cage and at 80 wt% with 20 wt% impact-modified PA12 in snap-over retaining features. Insert moulding of a preheated steel spindle at 120–140 °C prevents premature solidification at the metal-polymer interface; the tool runs with differential heating of 90 °C on the cosmetic face and 130 °C near the gate to reduce gate blush and frozen-in stress. Fiber attrition is controlled with a 2.0:1 compression-ratio screw, screw speed of 50–80 rpm, and back pressure not exceeding 0.3 MPa. Melt temperature is held at 230–245 °C in the rear zone and 250 °C at the nozzle, with barrel residence time below 8 min to avoid fiber shortening and surface roughness. Moulded components are tested under EN ISO 4210-2:2015 fatigue load schedules for pedals, and supplied under EC 1907/2006 REACH Annex XVII and 2011/65/EU RoHS Annex II declarations. Terminal formats are mountain-bike flat pedal cages, electric bicycle folding pedal bearing carriers, and rear derailleur inner/outer knuckle assemblies where the documented weight saving against aluminium is 55–65%.
Large-area gripper base plates and palletizer end-effector frames are moulded from Grilamid LCL-3 H anthracite when the assembly must not accumulate electrostatic charge and must survive repetitive clamping loads evaluated under ISO 10218-1:2011 industrial robot safety requirements. The material is used at 100 wt% for structural bodies and is not let down below 85 wt% because reducing total carbon fiber content below approximately 25.5 wt% shifts surface resistivity from dissipative toward insulative values. Injection-compression moulding with a 3.0–4.0 mm wall and compression stroke of 1.0 mm reduces sink marks around aluminium threaded inserts that are preheated to 160 °C before placement. Tool temperature is maintained at 100–120 °C, melt temperature at 240–255 °C, and hopper-loading drying at 80 °C for 5 h with desiccant air. Screw geometry uses a 2.0:1 metering section and free-flow non-return valve; back pressure is 0.15 MPa. Surface resistivity is verified under IEC 61340-5-1:2016 and ASTM D257-14 at 500 V test voltage, with assembled end-effector resistance to ground below 1 × 10^6 Ω in production checks. Terminal parts are vacuum-cup gripper bases, tool-changer mechanical adapter plates, and palletizer side plates where replacement of zinc-plated steel reduces mass by 45–55% and eliminates post-plating corrective straightening.
The radiolucent character of carbon-fiber-reinforced PA12 becomes relevant in radiotherapy headrest frames and table indexing adaptors, where metallic supports can generate beam scatter and degrade planning-image fidelity. The material is processed at 100 wt% single-use patient-fixture material; regrind is excluded under ISO 13485 contamination-control procedures and because lot traceability to incoming carbon-fiber tow is mandatory. Moulding is conducted on a reciprocating screw with 2.0:1 compression ratio and 30 mm diameter, with melt temperature kept at 235–250 °C and tool temperature at 100 °C. A fan gate of 1.0 mm thickness fills the base plate to maintain planar fiber orientation in the X-ray beam path; weld lines are not permitted in the indexing boss region because they degrade stiffness by more than 25% under ISO 178:2019 three-point bending. Electrical safety of the complete system is assessed under IEC 60601-1:2005/AMD1:2012. Biocompatibility for skin-contact attachments is evaluated on the finished device under ISO 10993-5:2009 and ISO 10993-10:2010, not on raw pellets. Terminal components include carbon-fiber-reinforced head support frames, stereotactic indexing plates, and proton therapy beam-line patient positioning brackets where 30 wt% carbon fiber loading yields a density of approximately 1.15 g/cm³ under ISO 1183-1:2019.
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EMS-Grivory Grilamid LCL-3 H anthracite is supplied as a dry long-carbon-fibre-reinforced polyamide 12 (Nylon 12) injection moulding compound containing 30% long carbon fibre by mass. The material designation under ISO 1043-2 is PA12-CF30; the anthracite suffix identifies a dark grey-black pellet colour. The matrix is a semicrystalline polyamide 12 with lower equilibrium moisture uptake than PA6 and PA66, while the reinforcement is introduced as continuous fibre tow and remains in the pellet as oriented fibre bundles rather than milled or short-cut fibre. This architecture affects fibre-length retention, mould shrinkage anisotropy, and failure-mode behaviour relative to short-carbon-fibre and glass-fibre PA12 grades. The “dry” supply condition indicates as-packaged moisture content below 0.10% by mass; it is not a substitute for desiccant pre-drying before melt processing.
Typical application sectors include automotive fluid-system brackets, industrial robot end-effectors, orthopaedic device housings, and lightweight machinery components. Selection of this grade is driven by the combination of low density, high specific stiffness, and reduced property drift in humid environments. The reinforcement content of 30% by mass corresponds to approximately 19% by volume when calculated from a carbon fibre density of 1.8 g/cm³ and a PA12 matrix density of 1.01 g/cm³. Published data for this specific anthracite configuration is limited for high-cycle fatigue beyond 10⁶ cycles, so component validation under end-use load spectra is required.
Mechanical data are generated on injection-moulded test specimens in the dry-as-moulded state. The values below are representative catalogue data from EMS-Grivory technical literature and are sensitive to gate geometry, mould temperature, and fibre orientation. Conditioned values at 23 °C and 50% relative humidity will show lower stiffness and higher ductility because PA12 absorbs moisture.
| Property | Test method | Typical value |
|---|---|---|
| Density | ISO 1183-1 | 1.14 g/cm³ |
| Tensile modulus | ISO 527-1/-2 | 20,000 MPa |
| Tensile stress at break | ISO 527-1/-2 | 250 MPa |
| Tensile strain at break | ISO 527-1/-2 | 2.0% |
| Charpy notched impact strength, 23 °C | ISO 179-1/1eA | 20 kJ/m² |
| Charpy unnotched impact strength, 23 °C | ISO 179-1/1eU | 55 kJ/m² |
| Heat deflection temperature, 1.80 MPa | ISO 75-1/-2 | 170 °C |
| Melting point, DSC | ISO 11357-1/-3 | 178 °C |
Thermal and mechanical values should not be treated as isotropic design allowables. Fibre orientation in the flow direction yields higher tensile modulus along the melt-flow axis and lower values perpendicular to flow. For finite-element simulation, orthotropic material data generated at multiple fibre angles are required; unidirectional coupon testing according to ISO 527-4 is not directly applicable to random-in-plane injection moulded parts. The table values therefore serve as initial screening data rather than minimum specification limits.
Moisture management during plastication is critical because residual water in PA12 hydrolyses the polymer at melt temperature and reduces molecular weight. In production-scale trials on hydraulic injection moulding machines, pre-drying in a desiccant-air dryer at 80 °C for 4–8 h to ≤0.10 wt% residual moisture is required when ambient relative humidity exceeds 60%. Hopper-air dew point should be ≤−20 °C. Melt temperature measured by axial pyrometer should be maintained from 260 °C to 280 °C; mould wall temperature is set between 80 °C and 120 °C. General-purpose screws with compression ratios above 2.5:1 or mixing sections should be avoided; a low-compression screw with an L/D ratio of 18:1 to 22:1 and a polished check ring preserves long-fibre length. These parameters reduce fibre attrition and short-shot variability on high-volume manufacturing lines.
Fibre-length retention in the moulded part is governed by screw geometry, back pressure, and gate shear. A high-compression screw with barrier sections can reduce average fibre length from 3 mm to below 1 mm, shifting the failure mode from fibre pull-out to matrix cracking. Structural tensile specimens with longer fibre pull-out paths absorb more energy before fracture than specimens dominated by brittle matrix failure. Processing parameters that maximise fibre-length retention are therefore required to achieve the notched impact values in Table 1. Cushion position should remain within 2–3 mm to avoid fibre accumulation in the check ring, which appears on production lines as cushion drift and intermittent short shots.
Back pressure should remain below 5 MPa. Injection speed is set for medium shear; holding pressure is adjusted to gate freeze without overpacking. Weld-line tensile strength can be 40–60% lower than bulk strength because fibre orientation is discontinuous at the knit line; gate positions must place knit lines away from load-bearing ribs and bosses. Total residence time above 280 °C should not exceed 10 min to limit thermo-oxidative degradation. The long carbon fibre increases apparent melt viscosity relative to unfilled PA12; therefore nozzle pressure at equivalent injection speeds is higher, and gate diameters may need to be increased by 20–30% relative to unfilled PA12 when shot volume is unchanged.
The replacement of short carbon fibre with long carbon fibre at the same 30 wt% loading changes both property translation and processing constraints. In short-carbon-fibre compounds, fibre length after plastication typically falls below 0.5 mm; in long-fibre pellets, residual fibre length in the moulded part is commonly 1–3 mm when a low-shear screw is used. With a typical carbon fibre diameter of 7 µm, residual fibre lengths of 1–3 mm correspond to aspect ratios of 140–430, above the critical load-transfer length for PA12 matrices. The longer fibre increases critical fibre aspect ratio and improves tensile modulus, notched impact, and resistance to fatigue crack propagation, but it also produces greater flow-direction shrinkage anisotropy and higher knit-line sensitivity. Glass-fibre-filled PA12 grades at 30 wt% exhibit a density near 1.25 g/cm³ and lower specific stiffness than the carbon-fibre grade at 1.14 g/cm³. PA12 absorbs approximately 1.5% water at saturation according to ISO 62, while PA66 typically absorbs 8–9% under comparable conditions; the carbon-fibre grade therefore exhibits lower property drift in humid environments than PA66 equivalents.
Because carbon fibre is electrically conductive, assemblies that place the moulded part in direct contact with aluminium or magnesium can develop galvanic coupling under persistent moisture; non-conductive bushings, coatings, or insulating washers should be specified unless an electrical path is required. Surface resistivity is anisotropic and depends on weld-line location and fibre dispersion; universal conductivity values should not be used for quality-release criteria. The anthracite colour package does not eliminate the need for UV stabilisation when parts are exposed to exterior weathering; long-term colour retention and surface chalking should be validated by accelerated weathering according to ISO 4892-2 if exterior use is intended.
Chemical resistance of PA12 to aliphatic hydrocarbons, oils, greases, and salt solutions is retained in the carbon-fibre grade, but strong acids, phenols, and oxidising media at elevated temperature are not recommended. Environmental stress-cracking resistance should be assessed by immersion testing under ISO 175 and, where service includes fuel blends, by stress-cracking tests agreed with the end user because published data for this specific carbon-filled configuration is limited.
Regulatory screening for this grade begins with the supplier’s REACH and RoHS 2011/65/EU documentation. The unfilled PA12 base polymer may meet selected food-contact and medical criteria, but the carbon fibre filler and anthracite pigment require end-use validation. Direct food-contact status under Regulation (EU) No 10/2011 is not automatically transferable from unfilled PA12 grades; medical device applications require testing to ISO 10993-5 and ISO 10993-10 unless the supplier has substance-specific letters. Component-level flammability should be assessed to UL 94; long-carbon-fibre-filled PA12 can be HB or V-2 depending on wall thickness and fibre content, and published data for this specific anthracite configuration is limited. In glow-wire applications, testing must follow IEC 60695-2-11 because conductive carbon fibre alters heat transfer and may influence ignition behaviour.
| Evaluation criterion | Reference document | Condition to verify |
|---|---|---|
| Material designation | ISO 1043-2 | PA12-CF30 |
| Restriction of hazardous substances | RoHS 2011/65/EU | Supplier declaration for each batch |
| REACH candidate list | EC 1907/2006 | SVHC content below 0.1% per article |
| Tensile property reporting | ISO 527-1/-2 | Dry and conditioned values |
| Impact property reporting | ISO 179-1/1eA | Notched and unnotched values |
| Food-contact status | Regulation (EU) No 10/2011 | Not assumed for anthracite CF30 |
| Medical device biocompatibility | ISO 10993-5 | Component-specific testing required |
| Flammability rating | UL 94 | No universal rating for all wall thicknesses |
Tooling trials for the long-fibre grade require at least 25 consecutive shots with cavity-pressure recording before dimensional adjustments. Shrinkage measured on a single plaque mould may not transfer to complex geometries because fibre orientation varies with flow pattern; a digital shrinkage map from cavity pressure and optical scanning should replace single-point shrinkage values. Hot-runner systems with dead spots, restrictive tips, or sharp bends are generally unsuitable for long-fibre pellets and should be reviewed case by case. Batch-to-batch variance in fibre length distribution, pellet moisture, and colour can be monitored by melt-flow-rate screening under ISO 1133-1 at the supplier’s recommended condition, but the long fibre can obstruct a standard melt-flow die; therefore capillary rheometry or spiral-flow moulding trials are preferred for incoming quality control.