| HS Code | 367053 |
| Density | 1.58 g/cm³ |
| Tensile Modulus | 17000 MPa |
| Tensile Stress At Break | 200 MPa |
| Tensile Strain At Break | 2.0 % |
| Charpy Notched Impact Strength 23 C | 15 kJ/m² |
| Charpy Unnotched Impact Strength 23 C | 80 kJ/m² |
| Melting Point | 178 °C |
| Heat Deflection Temperature 1 80 Mpa | 200 °C |
| Heat Deflection Temperature 0 45 Mpa | 210 °C |
| Coefficient Of Linear Thermal Expansion Parallel | 0.3 × 10⁻⁴ K⁻¹ |
| Coefficient Of Linear Thermal Expansion Normal | 0.8 × 10⁻⁴ K⁻¹ |
| Water Absorption 23 C 24 H | 0.2 % |
As an accredited EMS-Grivory Grilamid® LBV-50H FWA black 9225 PA12-GF50 factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.
| Packing | Packaging: 25 kg moisture-proof bags containing EMS-Grivory Grilamid LBV-50H FWA black 9225 PA12-GF50 pellets. |
| Container Loading (20′ FCL) | Grilamid LBV-50H granules packed in 25kg bags on pallets, shrink-wrapped, loaded into a 20-foot FCL container. |
| Shipping | Grilamid® LBV-50H FWA black 9225 is a 50% glass-fiber-reinforced PA12 granulate. Ship in sealed, moisture-proof packaging to prevent absorption; store dry below 50°C. Non-hazardous but avoid dust inhalation. Use protective gloves and eyewear. Keep away from ignition sources and incompatibles. |
| Storage | Store Grilamid® LBV-50H FWA black 9225 in its original, unopened packaging in a cool, dry, well-ventilated area. Keep away from direct sunlight, heat sources, and moisture. Maintain temperatures below 30°C and moderate humidity. Reseal partially used containers tightly to prevent water absorption, which can affect processing and final properties. |
| Shelf Life | Store dry, cool, and protected from sunlight; shelf life is typically two years from delivery when sealed in original packaging. |
Potable water distribution systems operating at continuous hydrostatic pressures up to 10 bar and transient surges above 16 bar impose simultaneous creep and hydrolysis loading on injection-moulded manifold bodies, valve housings, and union connectors. Grilamid LBV-50H FWA black 9225 is specified for these flow-control components because the 50 wt% glass fibre reinforcement, determined by ISO 3451-1, restricts hygroscopic swell of the PA12 matrix and retains dimensional stability through repeated water-temperature cycles from 5°C to 65°C. The FWA designation indicates the compound is formulated for drinking-water and food-contact evaluations; regional certification remains article-dependent and must be confirmed for the finished geometry, seal system, and water-contact surface area. The compound is injection-moulded neat at 100 wt% as the base structural material; no additional glass fibre masterbatch, mineral filler, or hydrolysis stabiliser is introduced at the moulding plant. Dry-blending with unreinforced PA12 dilutes the fibre mass fraction below the certified level and therefore invalidates mechanical design values and water-contact certification unless the blend is revalidated under the target application standard.
| Framework | Standard or code | Testing focus |
|---|---|---|
| Germany | UBA KTW-BWGL | Hygienic suitability under cold and warm water contact |
| France | ACS | Leachate and organoleptic acceptance |
| United Kingdom | WRAS, BS 6920-1 | Water-contact non-metallic materials |
| United States | NSF/ANSI/CAN 61 | Health effects of drinking-water system components |
| EU food contact | Commission Regulation (EU) No 10/2011 | Overall migration and specific migration limits |
| US food contact | 21 CFR §177.1500(b) | Nylon 12 polymer for food contact articles |
Tooling practice for manifold blocks and isolating-valve bodies favours single- or two-cavity cold-runner layouts with valve-gated sprue bushings to limit glass-fibre breakage at the gate. The material is pre-dried in a desiccant dryer with dew point below −30°C at 80–100°C until residual moisture is below 0.1%. The melt temperature is held within 250–280°C, and mould temperature is controlled between 80°C and 110°C to promote a resin-rich surface layer over the glass-fibre network. On production floors, batch-to-batch melt-viscosity drift is monitored by filling-pressure deviation; a fill-time change greater than 0.2 s at identical machine settings triggers incoming-lot verification of glass content by ashing at 600°C according to ISO 3451-1. Weld lines formed around brass-thread inserts are moved away from pressure-bearing walls by sequential valve-gate opening, and cavity-pressure switchover is set in the 40–70 MPa range. Terminal part classes include distribution manifolds, isolation-valve bodies, check-valve poppets, pressure-reducing valve cartridges, and union nut connectors.
For automotive coolant loops, the hydrolytic and thermo-oxidative environment at cold-start to 120°C coolant-exit temperature demands a material that retains hoop stress and dimensional position over accumulated mileage. Published screening for engine-cooling plastics typically references ISO 527-2 for tensile modulus, ISO 75-1/-2 for heat deflection temperature, and ISO 175 for fluid immersion. The 50 wt% glass fibre loading in Grilamid LBV-50H FWA black 9225 reduces creep under internal pressure relative to unreinforced PA12; comparative long-term performance should be generated under ISO 899-1 because the influence of coolant composition is not negligible. Chloride-enriched coolant systems above 30 ppm require immersion screening before release, and published data for this specific configuration is limited.
Formulation loading for these components is 100 wt% of the undiluted compound; the heat-stabilised H additive package is pre-dispersed in the pellet and no post-compounding additive masterbatch is added. The grade is injection-moulded on reciprocating-screw machines with L/D 20:1–22:1 and a non-return valve clearance below 0.05 mm to avoid unmelted glass-bundle carry-over. Mould temperature is held at 100–120°C, which stiffens the frozen layer and improves gate-blush resistance. Hot-runner manifold temperature is maintained within ±5°C of the melt set point; local residence time above 300°C causes PA12 matrix degradation and black specks in downstream mouldings. Gate placement at the centre of cylindrical valve-body bosses orients glass fibre in the hoop direction, which is the primary stress direction under coolant pressure cycles. Terminal part types include thermostat housings, coolant diverter-valve caps, electric water-pump impellers, water-outlet connectors, and expansion-tank nipples.
In oscillating-piston water meter metrology, the measurement insert is exposed to flow velocities up to 4 m/s and potable-water temperatures between 5°C and 60°C. The critical clearance between oscillating piston and measuring chamber is governed by metrological tolerances derived from ISO 4064-1 and OIML R49-1; any drift resulting from anisotropic hygroscopic swell or fibre-orientation-dependent thermal expansion alters the error curve over the lifetime of the meter. The low moisture uptake of PA12-GF50 measured under ISO 62—saturation below approximately 1.5% at 23°C—preserves the clearance envelope more predictably than PA6/6T gearings used in earlier meter designs. The measuring-chamber insert and piston are moulded from the unmodified compound at 100 wt%; the glass fibre mass fraction remains 50 wt% and no external reinforcing filler is added. If production requires laser marking, the black 9225 base colour is used directly without polymer-soluble dyes that could affect food-contact or water-contact certification.
High-precision injection moulding for water-meter inserts uses nickel-phosphorus plated cavity surfaces with roughness Ra below 0.2 µm and side-action cores for the piston groove. Packing pressure is maintained until gate freeze; hydraulic hold pressure is typically controlled in the 80–100 MPa band while screw rotational speed is limited to 100–150 min⁻¹ to reduce glass-fibre attrition. Dimensional audits after conditioning at 50% relative humidity and 23°C are performed by coordinate measurement with a tolerance of ±0.02 mm on the piston-to-chamber gap. Weld-line placement at the chamber window must be excluded from the metering edge because glass-fibre accumulation at the weld line produces local rigidity gradients and anomalous pressure-drop behaviour. Terminal part classes include meter chamber plates, oscillating pistons, magnet carriers, insert covers, and register drive pins.
Reverse osmosis skids concentrate multi-stage centrifugal pumps whose intermediate stage pressures range from 2 bar to 30 bar, producing axial and radial thrust loading on impeller cores and wear rings. The glass-reinforced PA12 grade is not inherently intended for pressure-contained volute shells above 50 bar; its use is limited to impellers, diffuser vanes, wear rings, and non-pressure-containing adapters unless full stress-rupture analysis to ISO 9080 supports a higher rating for a defined geometry. Compliance evaluation for reverse-osmosis systems references the Pressure Equipment Directive 2014/68/EU for pressure-critical parts, NSF/ANSI/CAN 61 for potable-water components, and ISO 306 for Vicat softening temperature as a short-term thermal integrity check.
The compound is injected neat at 100 wt%; property verification uses ISO 3451-1 for glass content and ISO 527-2 for tensile modulus. Regrind use in FWA drinking-water or food-contact components is not permitted unless the moulding site maintains a closed-loop regrind validation record and the finished article remains covered by the relevant water-contact certificate. Impeller geometry creates strongly heterogeneous fibre orientation at blade trailing edges; injection-compression moulding or a high-compression screw with consistent plastication reduces warpage at blade-root sections. Gate placement at the hub rather than the blade tip eliminates gas entrapment and shifts weld lines away from hydrodynamic stress zones. Mould temperature is held between 90°C and 120°C to control eccentricity, and residual stress is reduced by a post-mould annealing cycle in the 120–130°C range for 2–4 h in oil or nitrogen before machining the shaft bore. Terminal part classes include multi-stage RO pump impellers, wear rings, diffuser vanes, shaft guards, and pre-filter housings.
Because pneumatic push-to-connect fittings must resist hoop stress from airline pressure, thread torque, and axial pull-out forces without absorbing ambient humidity, PA12-GF50 is used where dry-state modulus under ISO 527-2 must exceed 14,000 MPa. The 50 wt% glass mass fraction provides dimensional stability at 23°C and 50% relative humidity; however, the part should be conditioned before dimensional acceptance because PA12 exhibits a measurable modulus shift between dry-as-moulded and equilibrium-moisture states. Compliance for compressed-air components is assessed under the Pressure Equipment Directive 2014/68/EU, while air quality in the finished system is defined by ISO 8573-1. For components handling inert gases, leak-tightness validation is performed by helium mass spectrometry rather than air-pressure decay alone.
Formulation addition ratio in this segment is also 100 wt% of the undiluted compound; metal gripping collets are inserted mechanically after moulding rather than co-moulded, avoiding galvanic contact and differential thermal expansion at the PA12-metal interface. Multi-cavity tools with 16–32 cavities produce family-dependent shear history; straight-flow runners and tunnel gates aligned with the longitudinal axis maximise fibre orientation along the tensile load path of the fitting barbs. Drying is identical to other PA12 applications: dew point below −30°C and 80–100°C until moisture is below 0.1%. Melt temperature in the upper interval of 270–290°C improves surface finish but shortens permissible residence time. Vent depths are held below 0.02 mm to prevent flash with high fibre packing; blocked vents produce gas-burn marks concentrated at the terminal end of the flow path. Terminal part classes include push-to-connect coupling bodies, check-valve poppets, filter/regulator bowl adapters, manifold blocks, safety relief-valve caps, and pneumatic silencer housings.
Wet-rotor circulator pump impellers for hydronic heating are exposed to start-up thermal shock from 20°C to 90°C within seconds, combined with torsional load at the shaft insert. The PA12 matrix in Grilamid LBV-50H FWA black 9225 can accommodate this gradient only when the moulding process avoids steep through-thickness fibre-orientation gradients and insert-induced weld lines. Published thermal-shock performance is not an intrinsic material constant; it is a function of gate location, fibre-orientation tensor measured by polished-section microscopy, and post-mould annealing history. Compliance evaluation for hydronic circulators references ISO 178 for flexural modulus, ISO 75-1/-2 for heat deflection temperature, and relevant drinking-water or heating-water approvals for closed-loop systems.
The impeller is injection-moulded from the undiluted compound at 100 wt%; the built-in H stabilisation is already dispersed during compounding, and no additional glass fibre or mineral filler is combined on-site. Low-shear screw geometry with L/D 20:1 and a melt cushion of 3–5 mm prevents excessive fibre fracture. Hot-runner temperature is maintained at 260–280°C within ±5°C; thermal overshoot above 300°C initiates PA12 degradation and produces brown streaking radiating from the gate. The shaft insert is preheated to 120°C before insert overmoulding; if the insert is colder, premature skin freezing creates helical flow fronts around the insert and produces micro-voids detectable only by X-ray computed tomography. Post-mould annealing at 110–120°C for 2–4 h in nitrogen or thermal oil stress-relieves the fibre-matrix interphase and dimensional distortion is then mapped against the impeller bore tolerance. Terminal part classes include circulator-pump impellers, wet-rotor pump bearing shields, magnet carriers, shaft sleeves, and hot-water distribution-manifold covers.
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EMS-Grivory Grilamid® LBV-50H FWA black 9225 is a polyamide 12 injection-molding compound classified under ISO 1043-1 as PA12-GF50. The grade combines a low-viscosity PA12 base, nominal 50% by weight glass-fiber reinforcement, heat stabilization, and a pre-compounded black color reference 9225. It is specified for pressure-bearing fluid-contact components that require high stiffness, low moisture uptake, and regulatory clearance for food-contact or potable-water service. Representative dry-as-molded values are summarized below; individual production lots should be checked against the supplier certificate of analysis because standard data are not batch guarantees.
| Parameter | Test method | Value or range |
|---|---|---|
| Density | ISO 1183-1 | 1.55–1.58 g/cm³ |
| Tensile modulus | ISO 527-1/-2 | 14 000–16 000 MPa |
| Tensile stress at break | ISO 527-1/-2 | 170–200 MPa |
| Elongation at break | ISO 527-1/-2 | 2.0–3.0 % |
| Charpy notched impact strength at 23 °C | ISO 179-1/1eA | 14–18 kJ/m² |
| Heat deflection temperature at 1.8 MPa | ISO 75-1/-2 | 165–180 °C |
| Melting peak temperature | ISO 11357-1/-3 | 175–180 °C |
| Water absorption, saturation | ISO 62 | 0.6–0.9 % |
In EMS-Grivory nomenclature, the LBV segment identifies a low-viscosity PA12 base. This raises melt volume-flow rate under ISO 1133-1 relative to standard-viscosity grades, reducing filling pressure in thin-wall sections without exceeding the recommended melt-temperature range of 250–280 °C. The 50H segment denotes nominal 50% glass-fiber loading and heat stabilization. Heat stabilization slows oxidative degradation during extended elevated-temperature service, but it does not convert the compound into a flame-retardant material. The FWA designation positions the grade for food-contact and drinking-water applications. Verification must be completed on the final molded article because pigment packages, regrind content, additives, and processing temperatures affect migration behavior.
| Framework | Verification scope |
|---|---|
| EU Regulation 10/2011 | Migration testing of plastic food-contact materials under the intended time and temperature conditions; final article composition, including pigments, must be assessed |
| FDA 21 CFR 177.1500 | Polyamide resins for food-contact use; compliance depends on food-type and end-use temperature limitations |
| NSF/ANSI 61 | Drinking-water system component certification; certification is article-specific and is not transferred solely from resin selection |
| RoHS Directive 2011/65/EU | Restricted-substance declaration; applicable lot-level documentation should be obtained from the resin supplier |
At 50% glass loading by weight, tensile modulus is 14 000–16 000 MPa compared with 1 500–2 000 MPa for unfilled PA12 under ISO 527-1/-2. Compounding of PA12-GF50 is normally carried out on a co-rotating twin-screw extruder with a 40:1 length-to-diameter ratio and side-fed continuous glass roving. Pellet fiber length is not identical to molded-part fiber length because screw rotation, back pressure, and gate geometry produce fiber attrition. Part testing under ISO 527-2 is therefore required for design data; pellet viscosity or pellet mechanical data alone are insufficient for load-bearing structural calculations. Flow-direction mold shrinkage measured under ISO 294-4 is typically below 0.2%, while transverse shrinkage may be 2–5 times higher because of anisotropic fiber orientation. This directional shrinkage must be transferred to tool dimensions for round pump housings, flanged valve bodies, and water-meter chambers.
The fiber network dominates the compound’s dimensional behavior. In a double-gated tensile plaque, weld-line tensile strength measured under ISO 527-2 can be 30–50% lower than the bulk flow-direction tensile strength because the fibers do not bridge the knit line as efficiently as the matrix transmits stress. This reduction is geometry-dependent and must be evaluated on the actual gate layout rather than derived from a generic data sheet. Where weld lines are unavoidable, sequential valve gating or melt deflectors can relocate knit lines away from constrained sections. In snap-fit design, elongation at break below 3% means strain recovery should not be relied upon for assembly; threaded inserts, welding, or retained fasteners are required if disassembly and reassembly are specified. Unfilled PA12 would provide greater ductility but loses the modulus, creep resistance, and lower shrinkage that justify the 50% glass system in pressure-containing parts.
Notched Charpy impact strength of 14–18 kJ/m² is useful for many rigid component designs but is still in the brittle range relative to unreinforced PA12. Sharp internal radii below 0.5 mm should be avoided at bosses, ribs, and gate regions. The material does not behave as a ductile polyamide under high-rate loading; a wrong snap-fit or sharp corner can initiate failure before the matrix can yield. For parts subject to repeated pressure pulses, weld lines and gate areas should be tested at the maximum service pressure and temperature, not only under standard laboratory conditions.
Moisture control is a threshold risk for PA12-GF50. Although PA12 absorbs less water than PA6 or PA66, pellets must be dried before molding. A desiccant dryer set to 80 °C with a return-air dew point of -30 °C or lower and a residence time of 4–6 h is specified to reduce residual moisture below 0.10%. Karl Fischer titration under ISO 15512:2019 is preferred over loss-on-drying because glass-filled pellets release moisture slowly and surface moisture alone can underreport the true residual level. Processing at residual moisture above 0.15% may produce silver streaks, nozzle drool, molecular weight loss, and reduced Charpy impact strength. If the molding cell operates at relative humidity above 60%, dried pellets should be conveyed in sealed lines and the feed hopper should be purged with dry air.
Mold temperature directly affects surface appearance and fiber encapsulation. At mold temperatures below 60 °C, the melt freezes before a resin-rich skin can form, producing dull surfaces and exposed glass fibers. Raising the mold temperature to 80–100 °C delays skin solidification and improves fiber coverage. Melt temperature should be profiled from 250 °C in the rear zone to 270–280 °C at the nozzle. Melt residence time should remain below 10 min to limit polymer degradation and black speck formation. The screw and barrel should be wear-resistant nitrided or bimetallic construction because of glass-fiber abrasion; a three-zone screw with at least 20:1 length-to-diameter ratio and a check ring is standard on production machines. Back pressure is limited to 0.5–1.0 MPa hydraulic on small reciprocating screws to reduce fiber attrition while maintaining shot stability. For a nominal wall thickness of 2 mm, injection pressure may range from 80–120 MPa depending on flow length, but short-shot studies are required to set the final profile. Excessive holding pressure can overpack the gate and increase orientation-induced warpage.
Compared with PA66-GF50, the PA12-based product has lower density and lower equilibrium moisture uptake because the PA12 backbone contains fewer amide groups per chain length. Under humid or hot-water exposure, a PA66-GF50 part absorbs more water and undergoes greater plasticization and thickness growth. The PA12-GF50 system retains a larger fraction of its dry tensile modulus after conditioning under ISO 1110. The trade-off is that PA66-GF50 may provide higher dry heat deflection temperature and higher dry stiffness in some formulations. Substitution therefore requires revalidation of clearance fits, press-fit retention, thermal expansion, and maximum service temperature. Mold shrinkage differences must also be transferred to tooling; PA12-GF50 typically shows lower flow-direction shrinkage but a wider flow-to-transverse shrinkage differential than PA66-GF50.
Compared with PA12-GF30 or PA12-GF40, the 50% glass-filled grade provides higher tensile modulus, higher heat deflection temperature, lower mold shrinkage, and improved creep resistance under ISO 899-2 testing. The disadvantages include lower notched impact strength, lower elongation at break, and greater anisotropy. The processor should not blend LBV-50H FWA with non-FWA PA12 regrind or with PA6/PA66 regrind because differing melting points and crystallization rates can create delamination at knit lines and can invalidate the regulatory status of the molded part. Regrind levels, if used, must be kept below a production-validated limit and verified by tensile modulus and notched Charpy impact testing; glass-fiber length attrition makes repeated recycling a performance risk.
Applications for Grilamid LBV-50H FWA black 9225 include drinking-water connector systems, pump bodies, valve bodies, water-meter housings, and food-processing equipment parts where the FWA clearance allows removal of post-mold coatings. In cold-water service, lower moisture uptake than PA66-GF50 helps maintain dimensional clearance between rotating and static elements, but continuous hot-water service requires creep testing under ISO 899-2 because absorbed water still modifies PA12 matrix behavior. Production-scale molding should target 0.05–0.10% residual moisture and a mold temperature of 80–100 °C. Gates should be located away from constrained areas to minimize weld-line loading. Final parts should be tested under the applicable end-use standard, such as ASTM D638-14 for tensile properties or ISO 527-2 for injection-molded specimens, using both dry-as-molded and conditioned samples to establish the design envelope.