| HS Code | 824113 |
| Density | 1.23 g/cm³ |
| Glass Bead Content | 30% |
| Water Absorption 24h 23 C | 0.2% |
| Water Absorption At Saturation | 0.8% |
| Tensile Modulus Conditioned | 2400 MPa |
| Tensile Stress At Break Conditioned | 45 MPa |
| Tensile Strain At Break Conditioned | 15% |
| Flexural Modulus Conditioned | 2600 MPa |
| Charpy Impact Strength Unnotched 23 C Conditioned | No Break |
| Charpy Impact Strength Notched 23 C Conditioned | 5 kJ/m² |
| Melting Point Dsc | 178 °C |
| Vicat Softening Temperature B 50 | 160 °C |
| Heat Deflection Temperature 0 45 Mpa | 140 °C |
| Heat Deflection Temperature 1 8 Mpa | 70 °C |
| Coefficient Of Linear Thermal Expansion | 80 x 10⁻⁶ /°C |
As an accredited EMS-Grivory Grilamid L XE 10987 nat Nylon 12, 30% Glass Bead Filled, Conditioned factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.
| Packing | Supplied as natural pellets in 25 kg sealed, moisture-proof bags. Conditioned Nylon 12 with 30% glass bead filling. |
| Container Loading (20′ FCL) | 20' FCL: 25kg bags on pallets, shrink-wrapped, loaded for safe transport. Approx. 14-15 MT per container. |
| Shipping | Ship as non-hazardous plastic pellets in sealed, moisture-proof bags or drums to prevent absorption. Store cool and dry, away from direct heat. Standard truck or sea freight is suitable; avoid prolonged high humidity during transit. Handle gently to prevent bag damage and ensure dry, ventilated container conditions. |
| Storage | Store in a sealed, original container in a cool, dry environment to prevent moisture absorption, which can degrade the conditioned nylon. Avoid direct sunlight, heat sources, and humidity. Ideal storage temperature is below 30°C. Use within one year; re-dry material before processing if exposure occurs. |
| Shelf Life | Shelf life is two years when stored in original, unopened packaging in a cool, dry place. |
Vehicle evaporative emission systems subject thermoplastic components to condensate compositions from fuel vapour, acidic oxidation species, and temperature excursions from −40 °C to 85 °C in underhood or fuel-tank-adjacent locations. EMS-Grivory Grilamid L XE 10987 nat, a 30 % glass bead–filled PA12 conditioned per ISO 291 at 23 °C/50 % RH, is processed into evaporative emission valve bodies, ORVR quick-connect components, and canister closure plates where annular seal retention and weld-line integrity after hydrocarbon exposure govern leak-tight performance. The spherical glass bead filler produces lower flow-direction shrinkage anisotropy than short-glass-fibre grades; post-moulding radial deviation in cylindrical valve housings is therefore reduced, which is necessary for press-fit canister solenoid seats overmoulded into the assembly. Melt processing for these parts is typically carried out at 235–255 °C with a mould temperature of 60–80 °C and a holding pressure between 60 MPa and 90 MPa; pre-drying to below 0.1 % residual moisture in a desiccant dryer with a dew point no higher than −30 °C is mandatory even when the material is supplied in a conditioned state, because the equilibrium moisture content of conditioned PA12 will generate hydrolytic degradation if driven directly into the melt phase. After moulding, assemblies are evaluated under ASTM D543 hydrocarbon exposure practices and tensile testing per ISO 527-1/2; automotive evaporative emission acceptance is assembly-level and includes sealed housing evaporative determination procedures under CARB LEV III and EPA evaporative emission regulations. Material-level permeation data for this specific grade are limited; substitution into fuel vapour contact applications therefore requires component-level permeation and weld-strength validation rather than reliance on generic PA12 permeability coefficients.
In compressed-air distribution systems, push-fit couplings and manifold blocks are expected to hold tolerance across threaded cores, O-ring grooves, and collet retention features after repeated pressure cycles from 0 bar to 10 bar at ambient temperatures between 5 °C and 60 °C. The combination of PA12 with 30 % spherical glass bead reduces post-moulding sink marks at thick boss intersections and improves roundness in cylindrical bodies with wall thicknesses of 1.8–3.2 mm, while the conditioned state retains a lower modulus but higher elongation at break than dry PA12, preventing cracking during collet barb insertion. Moulding is carried out with a melt temperature of 230–250 °C, a mould temperature of 50–80 °C, and sequential valve gating when multiple cavities are used; the gate is positioned away from the pressure boundary and into a non-critical ribbon area because glass bead–filled PA12 may produce visible knit lines at flow fronts that recombine downstream of core pins. Pneumatic performance is validated at the completed-component level according to ISO 4414:2010 for system safety and compressed air quality according to ISO 8573-1:2010; leak testing commonly applies dry air at 6 bar to 8 bar with pressure decay thresholds set by the assembly specification. Terminal parts include one-touch fittings for 6 mm to 16 mm polyamide or polyurethane tubing, adjustable flow control valves, distribution blocks with multiple outlet stations, and solenoid valve sub-bases where repeated valve shifting imposes cyclic bending on thin partition walls.
Reusable medical equipment subjects external housings, handpiece clamshells, and instrument tray handles to repeated saturated steam sterilisation at 121 °C or 134 °C and must maintain snap-fit or screw-boss alignment without deformation beyond assembly tolerance. In this application class, EMS-Grivory Grilamid L XE 10987 nat is evaluated for its combination of low water absorption relative to PA6 and PA66, conditioned ductility, and isotropic shrinkage derived from the 30 % spherical glass bead loading. The moulding protocol uses highly polished cavity surfaces, tool steel hardened to HRC 52–56 to resist glass bead abrasion, melt temperature of 240–255 °C, and mould temperature of 80 °C to promote a resin-rich surface skin that encapsulates glass beads and improves cleanability after steam exposure. Pre-drying to below 0.1 % moisture content is required before processing, although the material is supplied in a conditioned state; the conditioned label does not protect the melt from hydrolytic chain scission. Components are subjected to worst-case autoclave cycling according to ISO 17665-1:2006, with dimensional measurements before and after each sterilisation phase; fixtures are not used to constrain free recovery, and post-sterilisation warp is measured after cooling to 23 °C at 50 % relative humidity following ISO 291. Biological safety is article-specific and cannot be inferred from the resin designation alone; finished devices require evaluation according to ISO 10993-1:2018, with cytotoxicity testing under ISO 10993-5:2009 and irritation or sensitisation testing under ISO 10993-10:2010 if the device falls within the scope of a skin- or mucosa-contacting application. Published autoclave cycling data for this exact grade are limited; manufacturers must therefore establish maximum sterilisation cycles through burst testing, snap-fit retention force measurement, and screw-torque loss rather than extrapolating from glass-fibre PA12 grades.
When beverage dispensing equipment and vending-machine fluid paths are converted from machined metal to injection-moulded thermoplastics, the material must simultaneously satisfy food-contact migration limits, repeated hot-water expansion cycles, and dimensional consistency across gasket flanges. Grilamid L XE 10987 nat in the conditioned state provides lower moisture-growth differential than unfilled PA12 because the 30 % glass bead loading restricts bulk hygroscopic swelling while the PA12 matrix retains hydrolysis resistance in hot-water contact at intermittent temperatures up to 80 °C. Injection moulding of dispenser nozzles, steam valve bodies, mixing bowls, and quick-disconnect inserts uses melt temperatures from 235 °C to 250 °C and mould temperatures from 60 °C to 80 °C; the high mould temperature forms a smooth, polymer-rich surface layer that reduces exposed glass bead at the liquid-contact face, which is relevant for cleanability and microbial control in beverage lines. Compliance for food-contact use is not resin-declaration-based; the finished article must meet overall migration limits under EU Regulation (EU) No 10/2011 as amended, with migration testing conducted according to EN 1186-1, and must also fall within any applicable FDA requirement under 21 CFR 177.1580 for nylon resins where the grade is covered by a suitable food-contact notification or letter. Processors must avoid zinc stearate or external mould-release agents that could transfer to the product-contact surface, and regrind use above 25 % is not recommended unless migration testing validates the final ratio. Terminal articles include hot beverage dispenser outlet nozzles, coffee brewer steam valve bodies, concentrate mixing bowls, and quick-connect inserts used in vending machines where dimensional stability after repeated hot-water exposure governs seal compression.
| Compliance parameter | Reference | Numerical constraint |
|---|---|---|
| Overall migration limit for plastics in contact with food | EU Regulation (EU) No 10/2011 Annex I | 10 mg/dm² for article surface area |
| Migration testing protocol for aqueous, acidic, and fatty simulants | EN 1186-1 | Simulant selection per Annex III of EU 10/2011 |
| Nylon resin extractives limitation under U.S. food-contact law | 21 CFR 177.1580 | Use conditions and extractable limits stated in the regulation |
Injection-molded smart eyewear temples and spectacle frame components rarely exceed 2.0 mm nominal wall thickness, yet they must survive repeated hinge cycling, temple flexure, and occasional drop impact without visible cracking at hinge bosses. The 30 % spherical glass bead filler in Grilamid L XE 10987 nat reduces differential shrinkage between the temple arm and the hinge insert area; unlike short glass fibre, the spherical beads do not orient strongly with flow, so warpage at the hinge recess is less sensitive to gate placement. Conditioned PA12 at 23 °C/50 % RH provides higher elongation than dry PA12, which is useful for press-fit hinge pin retention and snap-in battery cover features in connected eyewear. Moulding is performed with melt temperatures of 235–255 °C and mould temperatures of 50–70 °C; wall thickness is held at 1.5–2.2 mm for temples and 1.8–2.5 mm for front rims, with a filling time established by low-velocity injection to avoid shear-induced glass bead agglomeration at the melt front. Frame-level validation follows ISO 12870:2019 for spectacle frame mechanical stability, including dimensional stability under elevated temperature and deformation resistance testing; for smart eyewear, battery compartment snap-fit retention after repeated opening is tested separately under a component-specific retention-force protocol, while tensile values from ISO 527-2 after conditioning provide only a baseline for material ductility. Published fatigue data for this exact compound are limited; component-level flexural fatigue at 2 Hz to 5 Hz and hinge-torque decay testing should therefore be used to establish endurance limits instead of substituting generic unfilled nylon 12 data.
For industrial pressure sensor housings and covers operating in heating, ventilation, or refrigeration systems, a multi-port flange face must retain flatness under bolt torque after prolonged exposure to glycol-water mixtures, mineral oils, and condensed moisture at service temperatures between −20 °C and 80 °C. Grilamid L XE 10987 nat is used for such covers when the application requires a low-warpage enclosure with a coefficient of linear thermal expansion closer to aluminium than unfilled PA12; the 30 % glass bead loading lowers mould shrinkage and thermal expansion anisotropy, reducing the risk that the flange lifts at the outer bolt circle. Processing uses a melt temperature of 235–255 °C, mould temperature of 70–80 °C, and sequential injection of thick flange sections; the packing phase is held until gate seal in the cold runner or hot tip to avoid sink opposite the bolt bosses. Exposed parts are tested after conditioning in 50 % glycol at 80 °C for 1,000 h according to ASTM D543 chemical resistance practice, followed by dimensional inspection of flatness with reference to ISO 1101 geometrical tolerancing and tensile testing per ISO 527-2; seal compression is then verified by pressure-decay testing of the assembled housing. Published data for this specific compound under long-term glycol exposure are limited, so design qualification must include flange-flatness measurements and sealing-element compression retention rather than relying on unaged properties. Terminal parts include multi-sensor manifold covers, differential pressure sensor bodies, and low-warpage electrical cover flanges for industrial refrigeration or HVAC control modules.
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EMS-Grivory Grilamid L XE 10987 nat is a polyamide 12 injection-moulding compound reinforced with 30 % spherical glass bead filler by mass. According to ISO 1043-1, the grade is described as PA12-GB30. The designation “nat” identifies the natural, unpigmented delivery form. The product declaration includes “Conditioned” because the mechanical property data referenced for design are obtained after moisture equilibrium at 23 °C and 50 % relative humidity, typically according to ISO 1110 or ASTM D618. The conditioned state is not an additive or surface treatment; it is a moisture-equilibrated material state that reflects ambient or humid service conditions more closely than the dry-as-moulded state.
Typical application fields include injection-moulded electrical connector housings, pneumatic couplings, cable conduits, fluid connectors, automotive sensor brackets, mounting clips, and enclosures where dimensional stability, low warpage, and moisture resistance are specified. The spherical glass beads raise stiffness and reduce mould shrinkage compared with unfilled polyamide 12, while maintaining a more uniform shrinkage in the flow and transverse directions than short glass fibre. The material is selected for parts with flatness requirements, thin wall sections, or tight dimensional tolerances that cannot tolerate fibre-induced anisotropy. The PA12 matrix contributes lower saturated water absorption relative to PA6 and PA66, as well as resistance to many aliphatic hydrocarbons and salt solutions.
In dry-as-moulded form, PA12 matrices are stiffer and exhibit lower elongation at break. After conditioning to 50 % relative humidity at 23 °C, absorbed water plasticises the polyamide amorphous regions and lowers tensile modulus while increasing impact ductility. Class-typical conditioned tensile modulus for 30 % glass bead filled PA12 measured according to ISO 527-1/-2 is approximately 1100–1600 MPa. Tensile strain at break is commonly above 20 % and can exceed 50 %, depending on bead-matrix adhesion, moisture content, and test speed. Charpy notched impact at 23 °C under ISO 179-1/1eA is generally in the 6–12 kJ/m² class range. Dry-as-moulded modulus and strength are higher, so the relevant data set must be selected according to the expected service moisture state.
Property values should be requested from the current EMS-Grivory technical datasheet for Grilamid L XE 10987 nat. Published data for this specific product configuration is limited to supplier-controlled release testing; independent literature on the identical bead size distribution and coupling chemistry is not generally available. Preliminary design calculations may use class-typical ranges, but final verification requires lot-specific data.
Before melt processing, residual moisture must be reduced below 0.1 % by weight to avoid hydrolytic degradation, splay, and viscosity drift. A desiccant dryer at 80 °C for 4–8 h is the standard reference point for PA12 compounds, but actual drying time varies with hopper airflow, granule bed depth, and ambient dew point. At relative humidity above 60 %, virgin material exposed to ambient air for more than a few hours may require longer drying. The natural unpigmented grade is more sensitive to discolouration from excessive residence time or elevated melt temperature than black or coloured variants.
The melt temperature measured at the nozzle is typically maintained between 230 °C and 250 °C. Mould temperature is commonly set between 40 °C and 80 °C; lower temperatures improve cycle time but reduce surface gloss and dimensional stability, while higher temperatures improve weld-line strength and lower moulded-in stress. Back pressure of 30–70 bar assists bead dispersion, but higher back pressure raises shear heating and residence time. Injection speed is set moderate to high, particularly for thin-wall sections down to 0.6 mm, because the spherical filler provides lower viscosity than an equivalent fibre-filled grade. Hold pressure is established by gate freeze and part mass; no universal value applies.
Because glass beads reduce orientation compared with fibres, gate location can be selected more freely without generating pronounced anisotropic shrinkage. Direct gates, tab gates, and pin gates are used depending on part geometry. Weld lines remain weaker than the surrounding material and should be positioned away from load-bearing regions or sealing surfaces. Venting depth typically follows PA12 practice; insufficient venting leads to burn marks and poor weld-line strength in natural grades. Hot-runner systems designed for PA12 with shear-resistant needle shut-offs are suitable; dead spots and polymer stagnation in manifolds must be avoided to prevent yellowing and black specks.
The primary difference is anisotropy. Short glass fibre strongly orients in the flow direction in thin-wall components, producing high tensile modulus and strength along the orientation axis and lower properties transversely. Shrinkage also differs by direction; a fibre-filled PA12 may show parallel shrinkage near 0.2–0.5 % and transverse shrinkage above 0.8 %, depending on fibre length and gate geometry. In contrast, a spherical bead-filled PA12 typically shows mould shrinkage of about 0.8–1.2 % in both flow and transverse directions under ISO 294-4 plaque testing. The tensile modulus of short fibre PA12 is higher than the bead-filled equivalent, but warpage, dimensional variation, and residual stress are usually greater.
Compared with unfilled PA12, the 30 % bead-filled grade has higher stiffness, lower CLTE, lower mould shrinkage, and reduced creep tendency. The coefficient of linear thermal expansion measured under ISO 11359-2 for PA12-GB30 class materials is typically lower than neat PA12 but remains higher than fibre-reinforced grades in the flow direction. Notched impact and elongation are lower than unfilled conditioned PA12 because rigid glass beads concentrate local strain at the interface. This trade-off is acceptable in housings and brackets where dimensional tolerances are more critical than maximum impact toughness.
Compared with PA6-GB30 or PA66-GB30, the PA12 base offers lower saturated water absorption and density, which reduces moisture-driven dimensional growth in humid environments. The PA12 backbone also provides better resistance to stress cracking in zinc chloride and certain glycol formulations, but the material may be softer and more flexible than PA66 at elevated temperature. Continuous service temperature for PA12 is lower than PA66; for exact heat ageing limits, current EMS-Grivory documentation should be used.
Components moulded from Grilamid L XE 10987 nat are frequently exposed to ambient humidity cycles, oils, greases, diesel, aliphatic hydrocarbons, and dilute salt solutions. PA12 has a hydrocarbon resistance profile that is suitable for under-hood and industrial fluid-handling environments. The glass bead filler does not degrade hydrocarbon resistance, but the bead-matrix interface can be attacked by hydrolysis if the component is immersed in hot water or steam. Continuous exposure to strong mineral acids, phenolic solvents, and pressurised water above 80 °C is outside the recommended operating envelope because polyamide 12 undergoes hydrolytic chain scission and loss of molecular weight under these conditions.
For electrical housings, PA12-GB30 class materials can offer high volume resistivity and good comparative tracking index when dry, but the conditioned state reduces electrical insulation performance because absorbed water increases surface and volume conductivity. Dielectric strength, comparative tracking index, and volume resistivity should be evaluated after conditioning to 50 % relative humidity if the part is used in humid electrical environments. Exact values for CTI and dielectric strength for this grade should be obtained from EMS-Grivory; published data for this specific configuration is limited.
| Property | Standard method | Specimen condition |
|---|---|---|
| Filler content | ISO 3451-4 | As received |
| Density | ISO 1183-1 | Dry |
| Tensile modulus and strain | ISO 527-1/-2 | Conditioned, 23 °C/50 % RH |
| Charpy notched impact | ISO 179-1/1eA | Conditioned, 23 °C |
| Heat deflection temperature | ISO 75-2 | Dry and conditioned |
| Water absorption | ISO 62 | 23 °C saturation |
| Mould shrinkage | ISO 294-4 | 60 mm × 60 mm × 2 mm plaque |
| Melt volume-flow rate | ISO 1133-1 | Supplier-specified conditions |
| Parameter | Reference range |
|---|---|
| Pre-drying temperature | 80 °C |
| Pre-drying time | 4–8 h |
| Maximum residual moisture | <0.1 % |
| Melt temperature | 230–250 °C |
| Mould temperature | 40–80 °C |
| Back pressure | 30–70 bar |
Compliance with REACH, RoHS, and any food-contact or medical requirements must be verified against the current EMS-Grivory material declaration for Grilamid L XE 10987 nat. Natural grade does not contain intentionally added colour pigments, but processing aids, stabilisers, and glass bead surface treatments are present. FDA 21 CFR 177.1500 may be referenced for polyamide 12 resins under specified conditions, but it does not automatically cover glass bead filled compounds in all food-contact applications. Material lot-specific certificates and batch-to-batch shrinkage verification are recommended for tight-tolerance production because bead size distribution and coupling agent addition can vary within the supplier specification.