| HS Code | 508936 |
| Density | 1.19 g/cm³ |
| Water Absorption 24h | 0.25% |
| Water Absorption Saturation | 0.70% |
| Tensile Modulus | 3600 MPa |
| Tensile Stress At Break | 65 MPa |
| Elongation At Break | 10% |
| Flexural Modulus | 3400 MPa |
| Charpy Impact Strength | 80 kJ/m² |
| Charpy Notched Impact Strength | 14 kJ/m² |
| Izod Impact Strength Notched | 10 kJ/m² |
| Melting Point | 178 °C |
| Heat Deflection Temperature At 1 8 Mpa | 110 °C |
As an accredited EMS-Grivory Grilamid L 25G nat 6011 Nylon 12, Conditioned factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.
| Packing | Available in 25 kg sealed bags, conditioned for consistent moisture content, and ready for processing. |
| Container Loading (20′ FCL) | 20′ FCL: conditioned Grilamid L 25G nat 6011 nylon 12 loaded in sealed, dry, secure containers, protected from moisture and damage. |
| Shipping | Ship in sealed, moisture-resistant containers to preserve conditioned nylon 12. Avoid prolonged exposure to humidity, heat, or direct sunlight. Standard ground freight is acceptable; no hazardous classification under normal transport. Keep upright, dry, and away from incompatible chemicals during transit. |
| Storage | Store Grilamid L 25G nat 6011 in its original, tightly sealed container in a cool, dry, well-ventilated area. Protect from direct sunlight, heat sources, and humidity, as nylon 12 absorbs moisture. Ideal storage temperature is below 25°C. Keep away from oxidizing agents and strong acids. Use within manufacturer's recommended shelf life to preserve properties. |
| Shelf Life | Shelf life is typically 2 years from production when stored unopened, in original packaging, under dry, cool conditions. |
In heavy-goods-vehicle air-brake systems, the combination of compressed-air pressure cycling from 0.8 to 1.0 MPa, road salt exposure, and bracket resonance vibration between 20 and 120 Hz imposes simultaneous requirements for dimensional stability, chloride resistance, and notched impact retention at −20°C. EMS-Grivory Grilamid L 25G nat 6011, when conditioned at 23°C and 50 % relative humidity, absorbs approximately 0.5 to 0.7 wt% water; this equilibrium moisture content lowers tensile modulus relative to the dry-as-moulded state while raising Charpy notched impact energy measured under ISO 179/1eA at 23°C. The glass-fibre mass fraction of 25 % is verified by ash content according to ISO 3451-1. Four-circuit protection valve bodies, air-suspension manifold blocks, cab tilt valve covers, and brake pressure-limiting valve housings are injection-moulded with wall thicknesses from 3 to 6 mm. Melt temperature is held between 255 and 270°C, mould temperature between 70 and 80°C, and hydraulic hold pressure between 50 and 80 MPa. The material requires pre-drying at 80°C for 4 to 6 h to a residual moisture level below 0.10 % before processing; otherwise hydrolysis at the melt stage reduces molecular weight and produces splay on valve sealing faces. A screw back pressure of 4 to 8 MPa and screw surface speed of 60 to 120 mm/s limit fibre breakage in the plasticating unit. Regrind addition is capped at 20 wt% in pressure-containing walls because repeated heat history shortens average fibre length from 250–350 µm after first compounding to below 150 µm after one recycling pass, and the resulting weld-line impact loss becomes critical at −20°C. Burst-pressure testing of production prototypes is commonly conducted at 1.5 times rated working pressure under customer-specific Knorr-Bremse or Wabco specifications; tensile and impact evidence is generated under ISO 527-2 and ISO 179/1eA, respectively. On injection lines with 80 to 120 t clamping force, cavity pressure sensors are used to switch from injection to holding phase at 80 to 95 % of maximum cavity pressure to prevent flash at valve spool bores and to stabilise the glass-fibre orientation near the sealing face.
| Parameter | Recommended range or value | Test method or equipment basis |
|---|---|---|
| Pre-drying temperature/time | 80°C for 4–6 h | ISO 15512 residual moisture < 0.10 % |
| Melt temperature | 250–270°C | Infrared pyrometer at nozzle |
| Mould temperature | 60–80°C | Water or oil tempering unit |
| Hold pressure | 50–80 MPa | Hydraulic clamp force, cavity pressure sensor |
| Back pressure | 4–8 MPa | Reciprocating screw, L/D 20:1–25:1 |
| Screw surface speed | 60–120 mm/s | General-purpose polyolefin screw with mixing tip |
| Conditioning after moulding | 23°C / 50 % RH to mass equilibrium | ISO 291 standard atmosphere |
POM is susceptible to environmental stress cracking in hot fuel and chloride-containing road-brine films; conditioned PA12-GF25 retains higher notched impact after immersion in ASTM Reference Fuel C at 60°C for 500 h, although published multi-axial impact data for this exact glass-fibre grade under hot ethanol fuels are limited. Validation therefore relies on component-level pull-off and burst tests rather than extrapolation from dry resin data. Snap-fit retainer bodies, fuel vapour line clips, and fuel sender flange caps are moulded in multi-cavity hot-runner tools with gate diameters of 1.2 to 1.8 mm and shear rate kept below 80,000 s⁻¹ to avoid glass fibre attrition at the gate. Melt temperature is 250 to 265°C; mould temperature is 60 to 80°C. Regrind in snap-fit tabs is limited to 15 wt% because weld lines formed by opposing gate fronts reduce snap-fit insertion and retention force by 20–35 % relative to a single-gate design, as measured by seat-angle pull-off tests on production-scale equipment. The glass-fibre orientation distribution is controlled by fill pattern simulation to prevent transverse orientation in the tab root, which creates a low-strength plane under SAE J2044 pull-force requirements. Permeation resistance of PA12 in fuel systems is generally assessed under SAE J2260 for low-permeation pipe assemblies; for connector bodies, hot gasolines containing 10 % ethanol are tested at 60°C under SAE J1681 for 3,000 h. Post-mould conditioning at 23°C/50 % RH raises low-temperature ductility, which is relevant for cold-start retention at −30°C according to USCAR-2 performance requirements. End components include quick-connect bodies, retainer clips, and fuel tank sender unit flanges; brass or stainless steel threaded inserts are used where service disconnection occurs more than 10 times. The critical weld-line location opposite the gate is shifted to a low-tensile-stress region using sequential valve-gate control on hot-runner systems with 2 to 4 drops per part.
Outdoor three-phase motor starter enclosures, M20 and M25 cable gland bodies, and fieldbus connector shells in coastal and food-processing environments require a balance of tracking resistance, low moisture expansion, and impact after UV exposure. Grilamid L 25G nat 6011 conditioned shows a comparative tracking index of 600 V under IEC 60112 on 3 mm plaques, which supports use in pollution degree 2 and 3 installations. The 25 wt% glass-fibre level reduces linear moisture expansion relative to unfilled PA12; at 23°C and 50 % RH the dimensional change across a 100 mm flow length is typically below 0.1 % after 1,000 h, while PA6-GF25 in the same cabinet environment can exceed 0.3 % due to higher equilibrium water absorption. For outdoor use, carbon black masterbatch is added at 2 wt% dilution through a gravimetric side feeder; the natural grade itself has limited UV retention without pigmentation. Injection moulding of thin-walled gland bodies with 1.5 mm walls uses melt temperature 240 to 260°C, mould temperature 70°C, and injection velocity 80 to 120 mm/s. The elevated mould temperature reduces surface pitting at the sealing collar where an elastomer O-ring seats. Maximum regrind level is 20 wt% for non-load-bearing shells, but for ingress-protection-critical articles it is reduced to 10 wt% to avoid microvoids at weld lines. Enclosure performance is verified under IEC 60529 for IP66/IP68 sealing with an elastomer gasket, and impact resistance after thermal ageing is tested under IEC 60068-2-30 damp heat cycling. End products include cable glands, fieldbus connector housings, and motor starter enclosures used in outdoor pump stations and food processing lines. Electrical panel assemblies additionally reference IEC 61984 for connector safety and EN 45545-2 when specified for rolling stock interior components, with smoke and toxic gas data generated by the compounder for the base grade.
Low-speed conveyor ball bearing cages, cam follower rollers in packaging machinery, and chain guide profiles traditionally machined from 6061-T6 aluminium can be converted to conditioned PA12-GF25 when operating temperatures remain below 120°C under continuous load and below 150°C for intermittent exposure. Density of the glass-filled PA12 grade is approximately 1.23 to 1.25 g/cm³, giving a mass reduction of about 55 % relative to aluminium. Moulded bearing cages with a race diameter of 20 to 50 mm use a gate located near the outer-race segment to produce circumferential glass-fibre orientation; melt temperature is 270°C, mould temperature 80°C, and packing pressure 70 MPa. Post-mould annealing at 120°C for 2 h in circulating air is applied when dimensional stability above 80°C is required; unannealed parts may show progressive creep and relaxation of moulded-in stress. The critical processing conflict is weld-line formation opposite the gate: glass fibres meeting at a 180° head-on weld line reduce Charpy notched impact under ISO 179/1eA at −20°C below 6 kJ/m², while the surrounding oriented region remains above 12 kJ/m². Regrind addition in bearing cages is therefore limited to 15 wt% and weld lines are relocated to low-tensile-stress regions using sequential valve-gate control. Lubricant compatibility is assessed under ISO 1817 in mineral oil at 80°C for 1,000 h; conditioned PA12-GF25 shows dimensional change below 0.3 % and retains more than 75 % of tensile strength. Food-grade grease contact requires separate migration testing under EU 10/2011 or FDA 21 CFR 175.300 for the specific grease formulation, not for the unmoulded resin alone. End products include ball bearing cages in stainless-steel food conveyor lines, chain guide profiles, and cam follower rollers. On a 120 t injection machine with L/D 22, hold pressure is maintained for 8 s to compensate for the high crystallinity of PA12 and to minimise sink marks on the cage inner race.
A 25 wt% glass-fibre loading in PA12 provides a balance of low density, mineral-oil compatibility, and dimensional control in hydraulic pump end plates, filter bowls, and hose barb supports used on compact construction and agricultural equipment. These components are typically moulded with wall thicknesses from 4 to 8 mm; melt temperature is 250 to 270°C, mould temperature 60 to 80°C, and hold time is 6 to 10 s per millimetre of nominal wall. Pre-drying follows the same 80°C for 4 to 6 h schedule as other applications; moisture content above 0.10 % reduces melt viscosity and promotes silver streaks on machined sealing surfaces. Regrind is limited to 20 wt% in hydraulic pump end plates because the flatness tolerance across a 100 mm sealing face must remain within 0.15 mm after 7-day oil immersion at 80°C per ISO 1817. Dimensional change in SAE 10W-30 mineral oil at 80°C is below 0.3 %; tensile strength retention after 1,000 h is typically above 80 %. Insert moulding of brass hose barbs uses insert temperature 120 to 140°C; lower insert temperatures cause premature skin freezing and sink marks around the threaded boss. The main operational boundary is hot oil ageing above 110°C, where the stabilisation package of this grade does not prevent oxidative embrittlement over extended periods. End products include hydraulic pump end plates, filter bowls, gear pump wear plates, and hose barb supports in mobile machinery. Hydraulic component makers typically require ISO 11468 viscosity number, ISO 1183 density, and ISO 178 flexural modulus as batch-release properties, along with a minimum Charpy notched impact of 8 kJ/m² at 23°C on conditioned specimens.
For pneumatic push-in fittings used in robotic end-of-arm tooling and industrial compressed-air circuits at 0.6 to 1.0 MPa, the conditioned PA12-GF25 grade is used for threaded bodies with inserted brass or stainless steel collars. Injection moulding with 10 to 20 mm flow length and wall thickness around 2 mm uses melt temperature 250 to 265°C, mould temperature 70°C, and injection velocity 100 to 160 mm/s. The 25 wt% glass-fibre content increases hoop strength around M5 and G1/8 threads; insertion torque is typically 1.5 to 2.0 N·m for brass inserts moulded into bosses with an outer diameter of at least 8 mm. Below 8 mm boss diameter, stress cracking at the insert interface occurs within 100 pressurisation cycles due to hoop stress and residual moulded-in strain. Regrind is not used in parts with internal O-ring grooves because even 10 wt% recycled material can create microvoids on the sealing surface. The material is not recommended for ISO Class 3 cleanroom use because glass-fibre reinforcement can shed particulate under sustained vibration; for such environments, unfilled PA12 is preferred despite lower stiffness. Function testing follows ISO 6150 for cylindrical quick-release couplings and ISO 4414 for pneumatic system reliability. End products include push-in fittings, flow control valve bodies, and manifold blocks used in automation and packaging machinery. On two-plate tools with tunnel gates, the use of a short first-stage injection speed below 50 mm/s avoids jetting at the gate, after which speed is ramped to 120 mm/s to fill the boss around the insert without displacing it.
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EMS-Grivory Grilamid L 25G nat 6011 is a 25 % glass-fibre-reinforced polyamide 12 compound supplied in natural-toned pellets and evaluated in the conditioned state per ISO 291 at 23 °C and 50 % relative humidity. The grade is commonly recorded under ISO 1874-1 as PA12, MHR, 14-060, GF25, identifying the base polymer viscosity class, 25 % glass reinforcement, and the natural additivated variant designated by the 6011 suffix. Conditioned values are not dry-as-moulded values; they represent near-equilibrium moisture uptake from a standard atmosphere, which reduces tensile stiffness and strength while increasing impact toughness. The material is specified when parts are expected to operate in humid air, condensation cycles, or direct contact with moisture-bearing interfaces. Published property data for this grade are generated on injection-moulded test specimens and should not be transferred directly to machined stock or additively manufactured components without validation.
Moisture absorption plasticizes the PA12 phase by disrupting intermolecular hydrogen bonding, lowering tensile stiffness and strength while increasing elongation and notched impact response. In the conditioned state, typical tensile values under ISO 527-1/-2 are approximately 5500 MPa tensile modulus, 80 MPa tensile stress at break, and 8 % elongation at break. Dry-as-moulded counterparts are approximately 7200 MPa, 110 MPa, and 5 %. Charpy notched impact under ISO 179/1eA at 23 °C moves from roughly 11 kJ/m² dry to 15 kJ/m² conditioned, while unnotched impact remains above 60 kJ/m². The glass fibre is the dominant contributor to modulus and strength retention, while the PA12 matrix continues to control low-temperature impact and puncture behaviour. For deflection-limited design, conditioned tensile modulus is the more conservative basis; for impact-limited design, dry data may understate field performance after moisture uptake.
| Property | Dry | Conditioned | Test method |
|---|---|---|---|
| Tensile modulus | 7200 MPa | 5500 MPa | ISO 527-1/-2 |
| Tensile stress at break | 110 MPa | 80 MPa | ISO 527-1/-2 |
| Elongation at break | 5 % | 8 % | ISO 527-1/-2 |
| Charpy notched impact, 23 °C | 11 kJ/m² | 15 kJ/m² | ISO 179/1eA |
| Density | 1.23 g/cm³ | ISO 1183 | |
Density under ISO 1183 is approximately 1.23 g/cm³. The glass reinforcement raises heat deflection temperature under ISO 75-2/A to roughly 155 °C, while Vicat softening temperature under ISO 306 is typically in the 160–170 °C range. Melting point by ISO 11357-3 is near 176 °C, characteristic of PA12 and lower than PA6 or PA66. The crystalline melting point constrains continuous service temperature and limits exposure to paint-bake or welding operations above the Vicat range. Thermal expansion is anisotropic because of fibre alignment; flow-direction and transverse coefficients under ISO 11359-2 are approximately 0.5 × 10-4/K and 1.0 × 10-4/K, respectively. The lower melting point permits shorter cooling cycles and reduced energy input compared with PA66-GF25, but load-bearing use above 150 °C is generally outside the continuous service window for this grade.
Drying prior to melt processing is required when incoming pellet moisture exceeds 0.10 wt%. Typical drying uses a desiccant dryer at 80 °C for 4–6 h, targeting residual moisture below 0.10 wt% before plastication. Melt processing should be conducted with a barrel profile from 220 °C to 260 °C; higher melt temperatures above 270 °C increase the risk of matrix degradation, surface streaking, and volatiles. Mould temperatures are held between 40 °C and 60 °C to balance crystallisation rate and post-mould dimensional control. The glass fibre content produces shear-thinning flow behaviour, but also makes the melt abrasive. Continuous production requires wear-resistant screw, barrel, and hot-runner tip materials. Injection moulding backpressure is typically kept in the 5–15 bar range, and screw decompression should be minimal to prevent nozzle drool and gas entrapment. Residence time at melt temperature should not exceed 10 min when production is interrupted. These parameters are machine-specific and must be qualified on the actual injection line because screw geometry, clamp force, and runner balance alter the viable processing window.
Conditioning is rarely instantaneous. A 2 mm injection-moulded plaque stored at 23 °C and 50 % RH may require several weeks to approach equilibrium; thicker sections require longer exposure. For polyamides, accelerated conditioning according to ISO 1110 using 70 °C and 62 % RH is commonly used to reach the conditioned state in days rather than weeks. The low diffusion coefficient of water in PA12 relative to PA6 means that surface moisture readings can be misleading: a dried part may pass a weight-based moisture check while the core remains below conditioned equilibrium. Production conditioning chambers should be validated with sectioned samples to confirm through-thickness moisture distribution. The dry-to-conditioned property shift is significant enough that parts qualified with dry tensile data may fail deflection-limited checks after field moisture uptake; conversely, impact-limited parts often benefit from moisture uptake.
Relative to glass-filled PA6 and PA66, Grilamid L 25G nat 6011 absorbs substantially less water. PA6-GF25 saturates at roughly 5–6 wt% under ISO 62 immersion at 23 °C, whereas PA12-GF25 saturates at approximately 1.1 wt%; equilibrium uptake at 23 °C/50 % RH is near 0.5 wt%. Lower moisture uptake reduces hygroscopic expansion and lowers the property shift from dry to conditioned service. For a wall thickness of 2 mm, the absolute linear hygroscopic expansion of PA12-GF25 is typically less than half that of PA6-GF25 when both are moved from dry to water-saturated state, although fibre orientation and glass content dominate part-level dimensional response. This behaviour supports use in snap-fit housings, electrical connector shells, and small structural brackets exposed to condensation cycles or outdoor humidity. Published data for this specific glass-fibre-reinforced configuration in continuous water/glycol exposure is limited and should be confirmed with component testing.
The separation from unreinforced PA12 is driven mainly by glass fibre content. Unfilled PA12 conditioned tensile modulus is around 1600 MPa, while the 25 % glass fibre reinforcement raises conditioned modulus to approximately 5500 MPa. Heat deflection temperature under ISO 75-2/A rises from below 60 °C for unfilled PA12 to approximately 155 °C for the reinforced grade. Elongation at break drops from above 50 % for unfilled PA12 to below 10 % conditioned. Against PBT-GF25, Grilamid L 25G nat 6011 has a lower density—typically 1.23 g/cm³ versus 1.45–1.50 g/cm³—and better resistance to hydrolysis and salt solutions, but lower dry-heat deflection temperature and lower surface hardness. Against PA6-GF25, the PA12 grade offers lower water uptake and better low-temperature impact behaviour, although PA6-GF25 may provide higher dry tensile strength at equal glass loading. The choice is application-specific: where low moisture uptake and fuel resistance dominate, PA12-GF25 is selected; where dry stiffness at lower cost is primary, PA6 or PA66 grades may be considered.
Sub-zero performance of PA12-GF25 remains one of its distinguishing features. Charpy impact at −30 °C is lower than at 23 °C but remains in the notched range of roughly 8–10 kJ/m² dry; conditioned specimens show a smaller temperature-dependent reduction because moisture plasticizes the matrix. The glass transition of dry PA12 is generally near 45–55 °C, which supports ductile response below freezing and makes the material suitable for outdoor cable clips, fluid fittings, and cold-climate housings. Glass fibres reduce the high elongation of unfilled PA12 and lower total energy absorption in puncture, but the PA12 matrix retains greater low-temperature ductility than PA66-GF25 at equal glass content.
For dimensionally critical parts, injection-moulding simulation requires fibre orientation analysis because the 25 % glass content creates anisotropic shrinkage. Typical mould shrinkage under ISO 294-4 is in the range of 0.2–0.4 % in flow and 0.5–0.8 % transverse; actual values depend on gate location, wall thickness, hold pressure, and cooling layout. Parts with abrupt thickness transitions can exhibit differential shrinkage and gate-region warpage. Post-mould annealing at 80–100 °C may reduce residual stress but can modify mould-in anisotropy and should be verified dimensionally. Pressure-volume-temperature data and fibre orientation parameters from the supplier are required for accurate flow simulation of this grade.
PA12-GF25 is resistant to aliphatic fuels, oils, greases, salt solutions, and many nonpolar solvents, but is attacked by strong mineral acids, phenols, and certain chlorinated solvents at elevated temperature. Electrical testing under IEC 62631-3-1 typically yields volume resistivity above 1012 Ω·m after conditioning; comparative tracking index under IEC 60112 is generally 600 V. Flammability is rated HB under UL 94 at the manufacturer’s listed thickness. Regulatory compliance must be confirmed with the supplier for each lot, but standard documentation generally references RoHS 2011/65/EU and REACH 1907/2006 for the natural grade. Food-contact applications require evaluation under EU 10/2011 and FDA 21 CFR 177.1500; published data for this specific glass-reinforced configuration in food-contact service is limited, and migration testing on the finished moulded part is normally required.
| Area | Standard or regulation | Typical status |
|---|---|---|
| Electrical tracking | IEC 60112 | 600 V |
| Flammability | UL 94 | HB |
| Heavy metals | RoHS 2011/65/EU | Declared per natural grade |
| SVHC screening | REACH 1907/2006 | No SVHC above 0.1 wt% |
| Food contact | EU 10/2011, FDA 21 CFR 177.1500 | Confirmation required |
Grilamid L 25G nat 6011 is used in fluid connectors, pneumatic line fittings, cable conduits, sensor housings, and structural brackets where low moisture uptake, fuel resistance, and 25 % glass-fibre stiffness are required. In parts exposed to 50–80 % RH, design stress should be based on conditioned tensile values because dry-as-moulded modulus and strength will not be retained in service. For snap-fit applications, strain recovery and relaxation should be evaluated after accelerated conditioning per ISO 1110; for cyclic loading, fatigue data under ISO 13003 or equivalent are required, but published high-cycle fatigue data for this exact configuration are limited. Post-mould dimensional tolerance must be validated with humidity-controlled storage or annealing. The material is processed as a moisture-sensitive engineering thermoplastic: incoming moisture checks, closed-loop drying, and documented conditioned-state testing are required to transfer laboratory property values to production parts.