| HS Code | 136197 |
| Density Dry | 1.01 g/cm³ |
| Melting Point | 178 °C |
| Tensile Modulus Dry | 450 MPa |
| Tensile Stress At Yield Dry | 30 MPa |
| Elongation At Break Dry | >200% |
| Charpy Impact Strength Notched 23 C Dry | 80 kJ/m² |
| Shore Hardness D Scale | 50 |
| Vicat Softening Temperature B50 | 140 °C |
| Heat Deflection Temperature 0 45 Mpa Dry | 75 °C |
| Water Absorption 24h 23 C | 1.8% |
As an accredited EMS-Grivory Grilamid L 25 W 40 X Nylon 12, Dry factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.
| Packing | Grilamid L 25 W 40 X Nylon 12 pellets packaged in moisture-proof 25 kg bags, dry, ready for processing. |
| Container Loading (20′ FCL) | Load 20′ FCL with dry Grilamid L 25 W 40 X nylon 12 pellets in sealed bags, palletized and secured for safe transit. |
| Shipping | EMS-Grivory Grilamid L 25 W 40 X Nylon 12 (Dry) ships as non-hazardous nylon 12 granules. Pack in sealed moisture-barrier bags or drums to prevent moisture pickup, on pallets for safe transport. Keep dry, avoid excessive heat and direct sunlight. Standard freight with protective handling is suitable. |
| Storage | Store Grilamid L 25 W 40 X Nylon 12 in its original, unopened container in a cool, dry area away from direct sunlight, heat, and moisture. Keep the container tightly sealed when not in use to prevent humidity absorption, which can affect processing. Under proper conditions, shelf life is typically two years from date of manufacture. |
| Shelf Life | Shelf life is indefinite when stored in original sealed packaging, kept dry, cool, and protected from moisture and UV light. |
Heavy-duty truck air brake tubing is one of the direct extrusion applications for Grilamid L 25 W 40 X. The resin is processed as a 100% virgin feed; the only standard dry-blend addition is a PA12-compatible carbon black masterbatch at 2–4 wt% when black UV-weatherable tube is required, and clean start-up regrind may be metered at 0–20 wt% only after desiccant drying to below 0.10% moisture. Drying is performed at 80 °C for 4–8 h in a desiccant dryer, and moisture above 0.15% produces vacuum sizing instability because steam pressure at the die lip collapses the melt cone on the calibration sleeve. Extrusion is carried out on a single-screw line with an L/D ratio of 24:1–30:1, a barrier mixing section, and a gear pump before the annular die. Melt temperatures are held between 220 °C and 250 °C; the closed-loop vacuum calibration tank operates at 15–25 °C to fix outer diameter before the tube enters the cooling trough. Compliance is verified according to SAE J844 and ISO 7628, with final assemblies tested under FMVSS 106 where the tube is fitted as part of an air brake system. Terminal products include straight tubing, color-coded service coils, and tractor-to-trailer coiled air bundles.
Fuel vapor return lines constitute a separate application route because the dry PA12 granulate is not used as the fluid contact layer but as the outer jacket in a coextruded barrier structure. The addition ratio is therefore a wall-thickness distribution rather than a melt blend: Grilamid L 25 W 40 X enters the outer-layer extruder as 100% virgin material, while the inner fluid-contact layer, tie resin, and EVOH barrier are fed from separate extruders and are not dry-blended into the PA12 stream. Exact outer-layer thickness is set after fuel permeation testing under SAE J1737 and SAE J2260 at 40 °C and 60 °C; published data for this specific multilayer configuration is limited, so the layer ratio must be qualified on the production line rather than assumed from monolayer values. The main process constraint is viscosity matching at the feedblock: the PA12 melt is kept at 230–245 °C, while the EVOH stream is confined to 195–210 °C to prevent gel formation at the interface. A three-extruder coextrusion line with melt pumps and a multi-layer spiral die feeds a vacuum calibration tank, after which tube ends are flared for quick-connector assemblies. Terminal products include fuel vapor return hoses, roll-over valve lines, and filler neck vent tubes designed to survive low-temperature impact at −40 °C and sour gasoline exposure cycles.
Engine-compartment wiring protection is a third downstream segment where corrugated conduit is produced by vacuum forming the PA12 melt into interlocking mold blocks. The feed is 100% virgin pellets with a PA12-based carbon black concentrate metered at 2–3 wt% for black conduit; regrind from start-up scrap is allowed up to 20 wt% only when dried to below 0.08% moisture and sieved through a 6 mm screen to remove fines. The extruder is a grooved-barrel single-screw unit with 25:1–30:1 L/D and a screen pack of 60/100/60 mesh. Melt temperature is deliberately held at the lower end of the 220–235 °C range so that the corrugated tube releases cleanly from the mold blocks without surface tearing at high block speed. After the corrugator, the tube is perforated or slit longitudinally and cut to fixed lengths. Compliance is assessed with ISO 4892-2 for xenon-arc weathering and IEC 60695-11-10 for basic flame classification when the conduit is used in unsealed engine compartments. Terminal products include corrugated harness protection tube, slit wrap, and conduit for commercial vehicle chassis and off-highway machine wiring.
Industrial pneumatic control tubing in 4 mm, 6 mm, and 8 mm outer diameters is extruded from the dry grade without reactive crosslinking. The formulation addition ratio is 100% as-supplied resin; where color identification is required, a polyamide color masterbatch is metered at 1.5–2.5 wt% and not higher, because excess inorganic pigment increases dimensional variation and reduces burst consistency after high-speed extrusion. The process uses a 30:1 L/D single-screw extruder with a mixing screw and a melt pump. Melt temperature is maintained between 225 °C and 245 °C, and melt pump suction pressure is kept below 10 MPa to avoid shear heating that would widen die swell. The calibration stage applies a vacuum of 0.03–0.05 MPa through closed sizing rings, and the line is accelerated only after the outer diameter coefficient of variation stays below 0.5% for 30 min. Industry conformance is documented under ISO 4414 for pneumatic system design and RoHS 2011/65/EU for restricted substances; tensile and elongation test methods follow ISO 527-1/-2. Terminal products are coiled control lines for packaging machinery, robotic end-effector air supply, and instrument air lines in food-processing plants.
Hydraulic hose for mobile machinery uses the material as a thin abrasion-resistant cover over textile or wire braid. The resin is not dry-blended with the liner compound; it is fed as 100% virgin pellet to a crosshead extruder with a pressure-balanced die. The braid is preheated to 80–100 °C so that the molten PA12 cover penetrates the outer braid interstices before it freezes. Adhesion is mechanical rather than chemical, so take-off tension is set to maintain 2–6% cover elongation during application. No external plasticizer is added because the EMS grade already contains the plasticizer package; adding liquid plasticizer is incompatible and should be avoided. The cover melt temperature is held at 230–250 °C. After cover extrusion, hose assemblies are tested under SAE J517 for impulse life and volumetric expansion, and cover abrasion is checked according to ISO 6945 or an OEM-specific method. Terminal products include SAE 100R7-type thermoplastic hydraulic hose, pilot-control hose, and mobile agriculture or construction machinery hose assemblies.
Optical fiber tight buffer is a small-diameter extrusion where the dry PA12 granulate is applied directly over 250 µm coated silica fiber to produce a 900 µm tight buffer. The addition ratio is 100% virgin material; colored buffer applications use a PA12-compatible color concentrate at 1–2 wt%, and the concentrate is dried with the base resin because free moisture at the die causes intermittent lump defects. Extrusion is performed on a 30:1 L/D single-screw extruder with a pressure tooling crosshead, melt temperature between 210 °C and 230 °C, and line speed in the range of 800–1,200 m/min. The key process variable is concentricity: the cladding-to-buffer wall offset must remain below 5 µm, which requires melt pump output stability better than 0.2% and a manifold design that avoids dead spots. Compliance for optical cable subassemblies follows IEC 60794-1-2 for mechanical and environmental test procedures and Telcordia GR-409 where North American indoor cable requirements apply. Terminal products include tight buffered optical fibers, breakout cable subunits, and patch-cord subassemblies.
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The grade EMS-Grivory Grilamid L 25 W 40 X is a modified polyamide 12 (PA12) supplied in a dry-as-packaged condition. The designation L places the product in the Grilamid PA12 series; W 40 identifies the stabilizer package, and X denotes the modified viscosity grade within the manufacturer’s extrusion and injection molding range. The polymer is semicrystalline, low-density, and resistant to aliphatic hydrocarbons, glycols, and many industrial process fluids. In dry condition, residual moisture is specified at ≤0.10% by weight. The material is sealed in moisture-barrier bags and requires drying only after prolonged storage in ambient relative humidity above 60%.
| Property | Representative dry value | Test method |
| Density | 1.01 g/cm³ | ISO 1183-1:2019 |
| Moisture content as supplied | ≤0.10 % | ISO 15512:2019 |
| Water absorption equilibrium at 23°C in water | 1.4 % | ISO 62:2008 |
| Tensile modulus, dry as molded | 1600 MPa | ISO 527-1:2019 / ISO 527-2:2012 |
| Tensile yield stress | 45 MPa | ISO 527-1:2019 / ISO 527-2:2012 |
| Tensile strain at break | >200 % | ISO 527-1:2019 / ISO 527-2:2012 |
| Charpy notched impact strength at 23°C | 6 kJ/m² | ISO 179-1/1eA:2020 |
| Charpy notched impact strength at −30°C | 5 kJ/m² | ISO 179-1/1eA:2020 |
| Melting point | 176 °C | ISO 11357-3:2018 |
| Vicat softening temperature B/50 | 170 °C | ISO 306:2022 |
Values are representative for dry-as-molded, unfilled PA12. Lot-specific release certificates and the current EMS-Grivory technical data sheet govern production acceptance.
Moisture uptake in PA12 is not governed solely by relative humidity; the polymer reaches equilibrium moisture near 1.4% after prolonged water contact, but surface moisture can shift within 4–6 hours under warm, humid storage. A desiccant dryer with a dew point of −30°C or lower and a bed temperature of 80°C is recommended to restore dryness. Drying time of 4–6 hours is required for material that has been exposed. Residual moisture above 0.10% hydrolyzes amide bonds during melting, causing a measurable loss of melt viscosity and formation of surface splay or silver streaks in thin-section tubing. On a 45 mm single-screw extruder with a 25:1 L/D barrier screw, undried PA12 typically produces barrel pressure fluctuation of ±5–8 bar and output variation of 3–5%. Such variation is not acceptable for pneumatic tube wall tolerances of ±0.10 mm.
Direct extrusion of monolayer tubing from this grade is performed on production lines equipped with vacuum sizing tanks and multiple-axis ultrasonic wall-thickness gauges. Melt temperature at the die should be kept between 220°C and 250°C; zone setpoints from feed to die are commonly 190°C, 210°C, 225°C, 230°C, and 235°C. Vacuum calibration water is held near 35°C, and puller speed is coordinated with die swell and shrinkage to maintain dimensional control. Injection molding of fittings from the same grade uses melt temperatures of 230–250°C, mold temperatures of 40–80°C, and hold pressures near 60 MPa. The screw should provide low compression and a mixing head to avoid excessive shear heating; melt residence time above 280°C should not exceed 5 minutes because thermal degradation shifts molecular weight distribution and reduces burst strength in the finished tube.
The property matrix in Table 2 isolates the engineering differences that determine material selection in air-brake tubing, fuel-vapor lines, and industrial pneumatic control systems. The PA12 backbone provides lower equilibrium water uptake than PA6 and PA66, which reduces dimensional change in humid service. Density of 1.01 g/cm³ permits mass reduction relative to PA6 and PA66. Tensile modulus is lower than that of PA6 and PA66, which is advantageous for flexible tube routing but requires thicker walls if equivalent hoop stiffness is specified. Low-temperature impact behavior of PA12 is superior to PA6 and PA66 and broadly similar to PA11, although PA12 has lower density and slightly lower water absorption at saturation.
| Property | Grilamid L 25 W 40 X | PA6 dry | PA66 dry | PA11 dry |
| Density, g/cm³ | 1.01 | 1.14 | 1.14 | 1.04 |
| Water absorption at saturation, % | 1.4 | 9.5 | 8.0 | 1.9 |
| Tensile modulus, dry, MPa | 1600 | 3000 | 3100 | 1500 |
| Notched Charpy at −30°C, kJ/m² | 5 | 3 | 2 | 5 |
The comparative data are typical dry-as-molded values obtained under ISO 1183-1, ISO 62, ISO 527-1/-2, and ISO 179-1/1eA. PA6 and PA66 values vary by reinforcement and nucleating package; the listed figures refer to general-purpose unfilled grades. For exact design allowables, the specific supplier datasheet of the comparative grade must be used.
For chemical contact, the operational boundary is defined by concentration, temperature, and stress state. The PA12 grade resists aliphatic hydrocarbons, diesel, zinc chloride solutions at ambient temperature, and many polyglycol-based brake fluids. Continuous contact with concentrated sulfuric acid, nitric acid, glacial acetic acid, phenol, or cresol is not recommended. Polar solvents such as strong chlorinated solvents and some ketones can swell the surface, and prolonged exposure to heated zinc chloride solution can still produce degradation. Melt contact with copper halide-based flame retardants should be avoided unless rheometric testing confirms no adverse interaction. These incompatibilities apply to all PA12 grades; the advantage of Grilamid L 25 W 40 X lies in lot-to-lot viscosity control and dry-state packaging for consistency in tube extrusion.
Below −30°C, the notched Charpy value alone does not predict component failure in pneumatic brake lines because stress concentrations at fittings, clips, and thermal expansion loops differ from an ISO laboratory prism. Tubing produced from Grilamid L 25 W 40 X is typically validated at component level according to ISO 7628 for commercial vehicle thermoplastic tubing; that standard evaluates cold impact, zinc chloride resistance, and pressure cycling. At temperatures approaching −50°C, wall thickness, fitting insertion depth, and extrusion-induced orientation become jointly controlling. Published data for this specific configuration is limited at the extreme low-temperature boundary; therefore, component-level validation on the actual extrusion line is required before service release. Semicrystalline orientation from the sizing operation raises hoop strength but can reduce axial crack resistance; the balance is machine-specific and should not be inferred solely from raw-resin datasheet values.