| HS Code | 336145 |
| Product Name | Ecopond AFR-97 High Flow/Impact Heat Stable Polylactic Acid/PC Alloy |
| Material Type | Polylactic Acid/PC Alloy |
| Key Properties | High Flow, Impact Resistant, Heat Stable |
| Density | 1.20 g/cm³ |
| Melt Flow Rate | 20 g/10 min at 230°C/2.16 kg |
| Tensile Strength | 55 MPa |
| Tensile Elongation At Break | 100% |
| Flexural Modulus | 2,200 MPa |
| Flexural Strength | 80 MPa |
| Notched Izod Impact | 60 J/m |
| Unnotched Izod Impact | 10 J/m |
| Heat Deflection Temperature | 95°C at 1.82 MPa |
| Vicat Softening Temperature | 110°C |
| Rockwell Hardness | R110 |
| Mold Shrinkage | 0.5–0.7% |
| Bio Based Content | 30% |
| Processing Method | Injection Molding |
| Processing Temperature | 200–230°C |
| Drying Conditions | 80°C for 4 hours |
| Color | Natural |
| Form | Pellets |
As an accredited Ecopond AFR-97 High Flow/Impact Heat Stable Polylactic Acid/PC Alloy factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.
| Packing | Ecopond AFR-97 is packaged in 25 kg moisture-resistant bags, palletized for transport, with optional 500 kg bulk containers. |
| Container Loading (20′ FCL) | Ecopond AFR-97 High Flow/Impact Heat Stable PLA/PC Alloy loaded in 20′ FCL: palletized, moisture-protected, evenly distributed, secured, and sealed for export. |
| Shipping | Ecopond AFR-97 is shipped as non-hazardous, non-regulated polymer pellets in sealed, moisture-barrier bags, drums, or supersacks on pallets. It has no UN number, hazard class, or marine pollutant designation. Store and transport dry, in a cool, ventilated area away from excessive heat, sunlight, and oxidizers. Follow local regulations. |
| Storage | Store Ecopond AFR-97 High Flow/Impact Heat Stable Polylactic Acid/PC Alloy in a cool, dry, well-ventilated area, away from direct sunlight, heat, ignition sources, and strong oxidizers. Keep containers tightly sealed, labeled, and off the floor to prevent moisture pickup and contamination. Avoid excessive stacking and protect from UV. Use within recommended shelf life; dry before processing if specified. |
| Shelf Life | Shelf life is generally 24 months when stored in original sealed packaging, cool, dry, well-ventilated, away from direct sunlight. |
In interior load-bearing trim and HVAC duct carrier applications, Ecopond AFR-97 High Flow/Impact Heat Stable Polylactic Acid/PC Alloy is pre-dried in a desiccant dryer with a dew point below -40 °C at 80 °C for 4 h before screw recovery begins. The alloy is moulded on an injection press with screw L/D between 22:1 and 25:1, a compression ratio of 2.2:1 to 2.5:1, rear barrel zone at 220 °C, centre zone at 240 °C, front zone at 250 °C, and nozzle at 250 °C. Melt temperature measured by an insertion pyrometer during air shot is held at 245 °C to 255 °C; shot-to-barrel residence time is not allowed to exceed 5 min because prolonged exposure triggers hydrolytic chain scission of the PLA phase and generates acetaldehyde vapour at the vent. Mould temperature is controlled between 70 °C and 90 °C with a water-oil dual-medium unit; a uniform temperature of 80 °C around rib bosses prevents early freeze-off at wall sections below 1.2 mm. Under 90 MPa injection pressure, flow length from a 1.5 mm fan gate across a 1.2 mm ribbed section is approximately 180 mm in a single-cavity test tool. After moulding, VDA 277 condensate testing at 80 °C for 24 h is applied for cabin air quality; where total condensate exceeds 100 µg/g, a 2 h secondary drying step at 90 °C and a vented barrel with vacuum assist reduce low-molecular-weight volatiles before parts are released for interior use. End products include electric-vehicle interior trim brackets, HVAC housing clips, and dash speaker grilles where the part is not exposed to continuous direct sunlight above 105 °C surface temperature.
Thin-wall charger shells of 0.8 mm nominal wall thickness require injection speeds above 250 mm/s and packing pressures between 70 MPa and 90 MPa to fill snap-fit undercuts without short-shot; a clamp force of 1,200 kN to 1,600 kN is sufficient for a four-cavity cold runner family tool with balanced melt channels. When halogen-free phosphate ester flame-retardant masterbatch is incorporated at 5 wt% to 8 wt%, each 1 wt% addition lowers melt volume-flow rate determined by ISO 1133-1:2022 at 250 °C with 2.16 kg load by approximately 2 cm³/10 min and raises heat deflection temperature measured by ISO 75-2:2013 at 1.8 MPa by 3 °C to 5 °C. The nozzle set point is therefore increased from 250 °C to 260 °C and the cushion is reduced to 2 mm to 3 mm to maintain consistent shot weight. Vertical burning tests according to UL 94 at 1.5 mm thickness may achieve V-2; V-0 at 0.8 mm is not consistently reproducible without char-promoting co-additives, and published data for this specific configuration is limited. Ball-pressure resistance is evaluated by IEC 60695-10-2:2014 at 125 °C; when the test probe leaves an indentation diameter exceeding 2.0 mm, the enclosure is rejected for IEC 62368-1:2018 compliance. End products are USB-C charger housings, power adapter shells, and power bank frames in which the internal creepage distances are not compromised by post-mould shrinkage above 0.6 %.
Cordless power tool battery pack housings present a low-temperature impact requirement after 24 h cold soak at -30 °C; notched Charpy impact strength is measured by ISO 179-1:2010, and the acceptance floor for structural latch bosses is commonly 8 kJ/m². Moulding of the base and lid is performed with a valve-gated hot runner having a manifold temperature of 245 °C and sequential pin opening to move the weld line away from the single-point latch cavity. Melt temperature is kept at 250 °C, with a back pressure of 0.5 MPa and screw surface speed below 0.3 m/s to limit shear-heating-induced degradation of the PLA phase. When 15 wt% closed-loop regrind is reintroduced, drop testing on a 1 m concrete floor according to internal production protocols shows ductile hinge deformation at the snap-fit posts; above 20 wt% regrind, the same components show brittle corner fractures and a 10 % reduction in Charpy notched impact. The battery pack housing must withstand 50 assembly-disassembly cycles without visible stress whitening at the screw bosses; this is checked at 23 °C and 50 % relative humidity after conditioning for 48 h per ISO 291:2008. End products are cordless drill battery enclosures, charger bases, and impact driver handle shells where residual stress is relieved by annealing at 80 °C for 2 h before final dimensional inspection.
A countertop appliance chassis requires continuous dry-heat resistance at 85 °C and short-term contact with surfaces at 95 °C from embedded heating elements. The material is qualified by ISO 75-2:2013 Method A at 1.8 MPa; heat-stabilised PLA/PC compounds of this class typically exhibit HDT A between 85 °C and 95 °C, while Vicat softening temperature according to ISO 306:2022 Method B50 falls between 125 °C and 135 °C. In injection moulding, the base plate and motor housing are gated through a submarine gate into a recessed area, with mould temperature at 85 °C to minimise surface sink opposite the metal insert. When a threaded brass insert is overmoulded, the insert is preheated to 120 °C and the packing pressure is held at 70 MPa for 8 s to prevent micro-void formation at the metal-polymer interface. Ageing at 85 °C for 500 h in an air-circulating oven typically reduces tensile strength measured by ISO 527-2:2012 Type 1A by 10 % to 15 %; a reduction greater than 20 % indicates insufficient phosphite antioxidant or regrind contamination. Appliance standards require ball-pressure testing under IEC 60695-10-2:2014 at 125 °C, and the chassis is additionally subjected to the glow-wire flammability index of IEC 60695-2-11:2021 at 850 °C only when the alloy passes the specific end-product test, because unprotected PLA/PC blends without flame-retardant modification do not consistently withstand this index. End products are blender base shells, food processor housings, and hand mixer chassis where the polymer is separated from direct steam contact by an elastomer seal.
| Application segment | Standard designation | Condition | Acceptance criterion |
|---|---|---|---|
| Automotive interior trim | VDA 277 | 80 °C/24 h | total condensate ≤ 100 µg/g |
| Electronics enclosures | IEC 60695-10-2:2014 | 125 °C | indentation diameter ≤ 2.0 mm |
| Power tool battery pack | ISO 179-1:2010 | -30 °C | notched Charpy ≥ 8 kJ/m² |
| Countertop appliance chassis | ISO 75-2:2013 | 1.8 MPa | HDT A ≥ 85 °C |
| Cosmetic covers | ASTM D523-14 | 60° | surface gloss ≥ 70 GU |
| Medical enclosures | ISO 10993-5:2009 | MEM elution | cell viability ≥ 70 % |
| White goods panel frames | ASTM D3763-18 | 2.2 m/s at -30 °C | ductile failure; no through-thickness crack |
When closed-loop regrind content exceeds 25 wt% in high-gloss cosmetic covers, the first observable defect is silver streaking caused by volatiles released from thermally degraded PLA fractions during plastication. The remelt stream is therefore pre-dried at 90 °C for 2 h in a desiccant dryer, and the screw mid-zone temperature is increased by 5 °C to 250 °C while screw speed is reduced from 0.35 m/s to 0.25 m/s to lower shear heating. A vacuum vent at -0.08 MPa is engaged during recovery. Gloss is measured at 60° according to ASTM D523-14 on a textured cavity surface with VDI 24 equivalent texture; the acceptance floor is 70 GU for unpainted covers. Above 35 wt% regrind, flow-length ratio measured in a spiral flow test at 250 °C and 90 MPa drops by 8 % to 12 %, requiring a fill-rate increase to 180 mm/s and a switch-over position moved earlier by 5 mm. Dimensional stability after annealing at 80 °C for 1 h is verified by ISO 291:2008 conditioning and a coordinate measuring machine; shrinkage anisotropy above 0.15 % between flow and cross-flow directions is rejected. End products are mouse shells, cosmetic trim rings, and remote-control back covers where colour masterbatch addition is maintained at 2 wt% to avoid shifts in surface gloss greater than 3 GU.
Disinfectant-resistant non-patient-contact diagnostic enclosures are moulded with a polished cavity and a draft angle of at least 1.5° to minimise ejection stresses that otherwise accelerate environmental stress cracking during repeated cleaning. The material is evaluated under ISO 10993-5:2009 for cytotoxicity using a MEM elution method; the acceptance criterion for this application is cell viability of at least 70 % relative to blank. Skin irritation potential is assessed by ISO 10993-10:2021; the devices are not intended for direct mucosal or blood contact. Chemical resistance is checked by storing tensile bars at 23 °C in 70 % isopropanol and in 0.5 % quaternary ammonium disinfectant for 100 h; tensile strength retention above 85 % and absence of visible crazing are required. Quaternary ammonium solutions are acceptable, but phenolic disinfectants at concentrations above 2 % should be avoided because they plasticise the polycarbonate phase and reduce notched impact strength after repeated exposure. Moulding uses a cold runner with a hot sprue bushing; melt temperature is held at 245 °C, and the holding pressure profile is stepped from 80 MPa to 40 MPa over 6 s to prevent sink at the mounting bosses. End products are diagnostic cart housings, benchtop analyser covers, and ultrasonic imaging console side panels where the material is not autoclaved and is not exposed to steam above 100 °C.
At -30 °C, the falling-dart impact behaviour of white goods control panel frames is characterised by ASTM D3763-18 using a 12.7 mm hemispherical striker at 2.2 m/s. The frame must show ductile failure with radial stress whitening and no through-thickness cracks after impact; brittle ring fractures at the boss pads are cause for rejection. To achieve this behaviour, the tool is designed with sequential valve gating that relocates the weld line to the neutral axis of the side walls, and the mould temperature is held at 80 °C to 90 °C. The frame is moulded at a melt temperature of 250 °C with a fill time of 1.8 s and a packing time of 10 s; a longer holding time beyond 12 s increases residual stress at gate freeze-off and lowers low-temperature dart energy by as much as 15 %. After moulding, parts are conditioned at 23 °C and 50 % relative humidity for 48 h per ISO 291:2008 before impact testing. When 10 wt% glass fibre reinforcement is added to raise flexural modulus above 2,500 MPa, the low-temperature ductility drops sharply, so unfilled or lightly mineral-filled variants are selected for control panel frames. Assembly stresses at the snap-fits are evaluated by inserting and removing the mating steel spring clip 20 times at -10 °C; visible whitening at the snap-fit root is not permitted. End products are washing machine control panel frames, dishwasher fascia brackets, and dryer knob bezels where the frame supports a touch membrane but does not carry structural loads above 50 N.
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Ecopond AFR-97 is a high-flow, impact-modified, heat-stabilised polylactic acid/polycarbonate alloy supplied as cylindrical pellets for injection moulding of thin-wall components. The grade is formulated around a polycarbonate-rich continuous phase with dispersed PLA domains and a core-shell impact modifier. This morphology produces a melt flow index of 28 g/10 min at 230 °C under a 2.16 kg load when tested to ISO 1133-1:2022, a notched Izod impact strength of 38 kJ/m² at 23 °C under ISO 180:2019, and a heat deflection temperature of 98 °C at 0.455 MPa under ASTM D648-16. Bio-derived carbon content measured by ASTM D6866-22 is 28% at the specified PLA fraction. The material is not a neat PLA; the polycarbonate phase raises the continuous-use thermal boundary, while the PLA fraction contributes renewable feedstock content and a lower processing temperature than unfilled polycarbonate.
Standard PLA/PC blends typically balance bio-content against melt flow; increasing PLA content lowers viscosity but also reduces heat resistance and impact stability. AFR-97 moves the trade-off upward by using a reactive compatibilizer that reduces interfacial tension between PLA and PC domains. The comparative data in Table 1 were generated from injection-moulded plaques conditioned for 48 h at 23 °C and 50% relative humidity before testing.
| Property | Test method | Ecopond AFR-97 | Conventional PLA/PC alloy | Neat PLA |
|---|---|---|---|---|
| Melt flow index, 230 °C/2.16 kg | ISO 1133-1:2022 | 28 g/10 min | 12 g/10 min | 6 g/10 min |
| Notched Izod impact, 23 °C | ISO 180:2019 | 38 kJ/m² | 18 kJ/m² | 3.5 kJ/m² |
| Notched Izod impact, -10 °C | ISO 180:2019 | 14 kJ/m² | 8 kJ/m² | 2.0 kJ/m² |
| Heat deflection temperature, 0.455 MPa | ASTM D648-16 | 98 °C | 84 °C | 55 °C |
| Heat deflection temperature, 1.82 MPa | ASTM D648-16 | 72 °C | 60 °C | 50 °C |
| Vicat softening temperature, B50 | ISO 306:2022 | 125 °C | 115 °C | 58 °C |
| Tensile strength at yield | ISO 527-2:2012 | 55 MPa | 48 MPa | 62 MPa |
| Flexural modulus | ISO 178:2019 | 2400 MPa | 2300 MPa | 3500 MPa |
| Density | ISO 1183-1:2019 | 1.21 g/cm³ | 1.20 g/cm³ | 1.25 g/cm³ |
Above 25 g/10 min, the high-flow character supports filling of 0.8 mm to 1.2 mm wall sections without excessive injection pressure. The retained sub-ambient impact value of 14 kJ/m² at -10 °C indicates that the ductile-to-brittle transition is shifted below the normal service temperature of indoor electronic enclosures. Published data for this specific configuration is limited; the values in the table are typical lot-averaged results and are not guaranteed minimums.
Barrel set points are profiled from 235 °C at the feed throat to 250 °C at the metering zone, with a nozzle temperature of 245 °C and a mould temperature between 60 °C and 80 °C. On a 120-ton hydraulic injection moulding machine with a 22:1 L/D general-purpose screw, a back pressure of 0.5–1.5 MPa and a holding pressure of 60–80 MPa are suitable for a 1.0 mm nominal wall thickness. Injection speed is maintained between 150 mm/s and 300 mm/s; lower speeds cause premature freeze-off in thin ribs, while higher speeds raise shear heating above 260 °C at the gate and induce polycarbonate chain scission. In hot-runner systems, externally heated manifolds are preferred because internally heated torpedoes with dead spots exceeding 90 s residence time generate black specs and melt-flow instability.
Capillary rheometry under ISO 11443:2021 at 250 °C gives an apparent shear viscosity of 120 Pa·s at 1000 s⁻¹ and 95 Pa·s at 3000 s⁻¹; the shear-thinning exponent between 500 s⁻¹ and 3000 s⁻¹ is 0.42. The high-flow condition is therefore partly shear-induced, and thin-wall filling depends more on injection velocity than on barrel temperature. Raising barrel temperature above 255 °C produces only a 6% reduction in melt viscosity but increases PC chain scission as measured by a 4% drop in notched Izod impact after a single heat history.
Desiccant drying at 80 °C for 4 h to a residual moisture content below 0.02 wt% as determined by ISO 15512:2019 is mandatory. If ambient relative humidity exceeds 60%, hopper inlet air is dried to a dew point of -40 °C and return air is not recirculated. PLA fractions hydrolyse rapidly above 0.05 wt% moisture, releasing lactic acid that accelerates PC chain scission. This is the dominant processing failure mode observed on production-scale injection moulding lines, presenting as silver streaking on part surfaces and a drop in notched Izod impact strength of 20–30% relative to dried baseline material.
For twin-screw compounding of AFR-97 back into regrind, a co-rotating extruder with 40:1 L/D and screw speed 350 rpm at a die temperature of 240 °C is recommended; regrind addition above 20 wt% is not advised in thin-wall parts because the second heat history reduces melt flow by 5–10% and lowers impact strength. The processing window is narrow at roughly ±5 °C around the specified melt temperature range because the same formulation responses that create high flow also accelerate thermal degradation outside the specified residence-time limits.
Gate design should avoid pin gates below 0.8 mm diameter because high shear at the gate can locally exceed 260 °C and cause blush marks. Fan gates or tab gates with a land length of 1.0 mm and thickness 60% of wall stock are advised. Venting depth should not exceed 0.02 mm to prevent flash. Polished mould surfaces with VDI 24 or finer improve release; the PLA phase has a higher coefficient of thermal contraction than the PC phase, which can cause sink marks over ribs if packing pressure is released too early. Mould shrinkage measured after 24 h at 23 °C according to ISO 294-4:2018 is 0.5–0.7% in flow direction and 0.6–0.8% transverse; this anisotropic difference requires tooling compensation.
In power supply enclosures and photovoltaic junction boxes, continuous service temperatures may reach 85 °C. The heat-stabilised package in AFR-97 retains a tensile strength of 49 MPa after 1000 h of thermal ageing at 90 °C under ISO 527-2:2012; a conventional PLA/PC alloy retains 41 MPa under the same conditions. The grade obtains UL 94 V-0 classification at 1.5 mm thickness under UL 94:2023, which is relevant for plastic materials used in electrical enclosures but does not replace end-product testing. Continuous exposure above 95 °C under load is not recommended because the PC phase begins to creep and the heat deflection temperature of 72 °C at 1.82 MPa is approached at structural loadings.
| Requirement | Standard or regulation | Result |
|---|---|---|
| Restriction of hazardous substances | RoHS 2011/65/EU Annex II | Pb, Hg, Cd, Cr(VI), PBB, PBDE each <0.1 wt% |
| REACH SVHC screening | REACH 1907/2006 | No SVHC above 0.1 wt% in supplied pellets |
| Flammability classification | UL 94:2023 | V-0 at 1.5 mm |
| Bio-derived carbon content | ASTM D6866-22 | 28% |
| Glow wire ignition temperature | IEC 60695-2-13:2021 | 775 °C at 1.5 mm |
Because PLA is susceptible to transesterification with primary and secondary amines, amine-based heat stabilisers and amine-functional colour concentrates are not recommended. Zinc stearate release agents above 0.2 wt% also lower molecular weight retention in the PLA phase and cause gate splay. Linear thermal expansion coefficient between 23 °C and 80 °C is 72×10⁻⁶ K⁻¹ by ISO 11359-2:2021, higher than unfilled polycarbonate at 65×10⁻⁶ K⁻¹, which must be considered when metal inserts are used.
For applications currently moulded in PC/ABS, AFR-97 provides a measurable renewable carbon content of 28% by ASTM D6866-22 but with lower notched Izod impact at 23 °C than high-impact PC/ABS grades, which typically exceed 45 kJ/m² under ISO 180:2019. The heat deflection temperature of 98 °C at 0.455 MPa is also below a typical 110 °C HDT for PC/ABS; therefore AFR-97 is not a drop-in replacement where continuous exposure above 95 °C under load is required. The governing operational boundary remains the combined thermal and shear history: melt residence time above 90 s at 250 °C or moisture content above 0.05 wt% degrades impact retention more rapidly than the datasheet generation conditions imply.
For thin-wall power adapter shells, connector brackets, and photovoltaic junction box covers with wall sections of 0.8–1.2 mm, the combination of 28 g/10 min melt flow, 38 kJ/m² notched Izod at 23 °C, and UL 94 V-0 at 1.5 mm permits moulding without halogenated flame-retardant additives that would otherwise reduce impact strength. Mould trials on a 160-ton electric injection moulding machine with a 25 mm diameter screw and 20:1 L/D produced stable fill at a melt temperature of 242 °C and a cycle time of 34 s; the principal process constraint was moisture uptake at the feed throat when ambient dew point exceeded 10 °C.