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Ecoblend HCL7140 General Purpose Heat Stabilized Polylactic Acid/PMMA Blend

    • Product Name: Ecoblend HCL7140 General Purpose Heat Stabilized Polylactic Acid/PMMA Blend
    • Factroy Site: Yudu County, Ganzhou, Jiangxi, China
    • Price Inquiry: admin@ascent-chem.com
    • Manufacturer: Ascent Petrochem Holdings Co., Limited
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    Specifications
    HS Code 447508
    Density 1.24 g/cm³
    Melt Flow Rate 10 g/10 min at 210 °C/2.16 kg
    Tensile Strength 50 MPa
    Tensile Elongation At Break 10%
    Flexural Modulus 2800 MPa
    Flexural Strength 80 MPa
    Notched Izod Impact Strength 3 kJ/m²
    Heat Deflection Temperature At 0 45 Mpa 90 °C
    Heat Deflection Temperature At 1 82 Mpa 75 °C
    Vicat Softening Temperature 85 °C
    Rockwell Hardness R110
    Visible Light Transmission 88%
    Haze 3%
    Biobased Content 30%
    Mold Shrinkage 0.5%
    Water Absorption 0.2%
    Processing Temperature 200-230 °C
    Mold Temperature 30-60 °C

    As an accredited Ecoblend HCL7140 General Purpose Heat Stabilized Polylactic Acid/PMMA Blend factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing Each supplied in 25 kg moisture-barrier bags, palletized; Ecoblend HCL7140 general-purpose heat-stabilized PLA/PMMA blend packaging ensures dry, industrial, contamination-free handling.
    Container Loading (20′ FCL) 20′ FCL container loading: Ecoblend HCL7140 General Purpose Heat Stabilized Polylactic Acid/PMMA Blend, securely palletized for safe international ocean freight.
    Shipping Ecoblend HCL7140 General Purpose Heat Stabilized Polylactic Acid/PMMA Blend, solid pellets/resin, is non-hazardous and not regulated for transport; no UN number, hazard class, or packing group assigned. Ship in clean, dry, sealed containers to prevent moisture and contamination. Store away from heat, sparks, open flames, and oxidizers.
    Storage Store Ecoblend HCL7140 in a cool, dry, well-ventilated area away from direct sunlight, heat, and ignition sources. Keep in sealed original packaging to prevent moisture absorption and contamination. Maintain moderate temperatures, avoid excessive stacking, and use first-in, first-out rotation. Separate from oxidizers, solvents, and incompatible substances. Protect from UV radiation. Follow local regulations and the manufacturer’s SDS.
    Shelf Life Typically 12–24 months when stored sealed in original packaging in a cool, dry place, protected from moisture, heat, and sunlight.
    Application of Ecoblend HCL7140 General Purpose Heat Stabilized Polylactic Acid/PMMA Blend

    In thick-wall cosmetic packaging, Ecoblend HCL7140 is injection moulded into outer jar shells, airless pump collars, and compact foundations. The compound is pre-dried in a desiccant dryer with a dew point below −40 °C at 80 °C for 4–6 h until residual moisture, measured by ISO 15512:2019 Method A, is below 0.025 wt%. The plasticating unit specified for this application uses a three-zone screw with 22:1 to 25:1 L/D ratio and compression ratio 2.5:1; barrel zone settings from feed to nozzle are 195 °C, 210 °C, 220 °C, and 230 °C, with nozzle temperature held at 225–235 °C. Mould temperature is maintained at 45–60 °C using water temperature control units, because the PMMA phase requires sufficient thermal mass to reproduce polished tool surfaces. Injection velocity is set between 30 mm/s and 65 mm/s, with hold pressure from 60 MPa to 85 MPa and holding time 6–10 s per 2.5 mm nominal wall thickness. Gates for thick-walled jars are located at the base centre with a minimum gate diameter of 1.2 mm; sequential valve gate control is used on multi-cavity tools with more than four cavities to prevent premature freeze-off and sink marks on the visible outer surface. Regrind from cold runner sprues is re-introduced at a ratio not exceeding 20 wt% of the total shot weight; higher regrind fractions lower melt stability and generate acetaldehyde-related odour in the moulded part. Cosmetic packaging compliance is normally documented through a REACH Article 33 declaration confirming SVHC content below 0.1% w/w, supplemented by absence of CMR substances under Annex II of Cosmetic Products Regulation (EC) No 1223/2009 and absence of cadmium, lead, mercury, and hexavalent chromium below the detection limits specified in the packaging supplier’s RoHS screening protocol. Direct contact with ethanol above 20 vol%, isopropyl myristate, or strong solvent-based cosmetic fillers is not recommended without a PP or PE inner liner; these media can initiate crazing in the PMMA phase under hoop stress.

    What Optical Performance Boundaries Apply in LED Diffuser Moulding?

    Injection compression moulding is used for LED panel diffuser plates and linear luminaire covers because it permits lower residual stress and better replication of micro-optical features than conventional injection moulding. The compound is dried to 0.015 wt% residual moisture using a vacuum dryer at 85 °C for 3–5 h, then processed at melt temperatures between 220 °C and 240 °C. The clamping unit is specified with a compression stroke of 0.5–1.5 mm after initial filling; compression speed is reduced to 5–10 mm/s during final cavity engagement to avoid micro-feature shear. Tool surface roughness is maintained below Ra 0.025 µm by diamond polishing, and the cavity is electroformed with a pattern depth-to-pitch ratio of 0.25:1 to 0.40:1 for diffusion. Optical testing on moulded plaques follows ISO 13468-1 for total luminous transmittance and ASTM D1003-21 for haze; the PMMA phase in the blend is responsible for maintaining transmission above the lower acceptable threshold, while the PLA phase reduces fossil-carbon content but increases yellowing risk if barrel residence time exceeds 10 min at 240 °C. Colour shift is measured as ΔYI under ASTM E313 after 1000 h of 65 °C storage. Wall thickness tolerance is held to ±0.05 mm to avoid luminance banding. LED module power density is capped at 0.5 W/cm² for continuous operation; above this value, localised surface temperature may exceed 70 °C and soften the diffuser. Compliance requires the finished luminaire to satisfy IEC 60598-1, UL 94 HB for polymer enclosures, and IEC 62471 for photobiological safety. Terminal components include 2.0 mm and 3.0 mm thick edge-lit LED panels, linear pendant diffusers, and LED lamp covers for commercial and retail lighting.

    For household appliance control panels and refrigerator door trim, the component is injection moulded with a hot runner system and polished chrome-plated cavity surfaces. The drying profile is 75 °C for 5 h in a molecular sieve dryer, target moisture below 0.020 wt%. Melt temperature is held at 215–235 °C across the screw; mould temperature is 40–60 °C for high-gloss surfaces. Injection speed profile is ramped from 45 mm/s at the gate to 30 mm/s during final fill to prevent jetting on textured borders. Hold pressure is set at 70–90 MPa for 5 s per 2 mm wall; back pressure is 6–8 MPa to homogenise dispersion. The application makes use of 2–3 wt% colour masterbatch based on a PMMA carrier; regrind is limited to 15 wt% to preserve surface gloss and impact consistency. Surface hardness is assessed by ASTM D3363 pencil hardness in a range of HB–F; scratch resistance is validated using ASTM D7027 scratch tip diameter 1 mm at 5 N. Compliance for household appliance parts references IEC 60335-1 for general safety, UL 94 HB for flame class, and REACH SVHC content below 0.1% w/w. The material is not specified for components in direct contact with steam or sustained temperatures above 65 °C, such as cooktop knobs or heating element surrounds. Terminal components include washing machine control panels, refrigerator door handle inserts, vacuum cleaner front covers, and decorative dishwasher fascia overlays where the polymer surface is printed or film-insert moulded. Chemical contact with aggressive cleaner concentrates should be evaluated according to ISO 175; ethanol-based disinfectants above 70 vol% can produce microcracks in stressed gate areas after repeated wipe cycles.

    Downstream applicationDrying profileMelt temperatureTool/mould temperatureKey standards
    Cosmetic jar shells and pump collars80 °C, 4–6 h, dew point −40 °C210–230 °C45–60 °CISO 15512:2019, EC 1223/2009, REACH
    LED diffuser plates and covers85 °C, 3–5 h, vacuum220–240 °C70–80 °CISO 13468-1, ASTM D1003-21, IEC 60598-1
    Household appliance control panels75 °C, 5 h, molecular sieve215–235 °C40–60 °CIEC 60335-1, UL 94 HB, ASTM D3363
    Point-of-sale sheet and thermoformed parts80 °C, 4 h, desiccant wheel200–220 °C80–100 °C calenderREACH, RoHS, UL 94 HB, ISO 11501
    Automotive scuff plates80 °C, 5 h210–230 °C60–80 °CFMVSS 302, DIN 75220, VDA 275
    Writing instrument barrels75 °C, 3–5 h205–225 °C35–55 °CEN 71-3, ISO 527-2, ISO 2409

    When Points of Sale Require Non-Halogenated Flame Performance

    For point-of-sale display components such as shelf edge strips, promotional headers, and translucent signage panels, the blend is converted by flat die sheet extrusion followed by thermoforming. The extrusion line comprises a co-rotating twin-screw or single-screw extruder with 30:1 L/D ratio, a vacuum degassing port, a gear pump set to 5–10 MPa inlet pressure, and a flex-lip sheet die with 0.8–3.0 mm die gap. Drying is executed in a desiccant wheel dryer at 80 °C for 4 h to 0.015 wt% moisture; sheet temperature at the polishing stack is maintained at 80–100 °C through three-roll calendering to reduce frozen-in orientation. Thickness tolerance across the web is controlled to ±5%, and longitudinal-to-transverse shrinkage after reheating is measured by ISO 11501 at 120 °C for 30 min. Thermoforming draw ratios are limited to 1.5:1 to 3:1; deeper draws trigger non-uniform wall thickness and corner stress whitening. Cut edges are flame polished or laser trimmed with 10.6 µm CO₂ laser systems; laser power settings are 40–80 W at 200–400 mm/s scanning speed. Flame performance for these non-halogenated applications is limited to UL 94 HB; vertical burn certification to UL 94 V-2 or V-0 is not assigned unless a separate phosphorus-based additive package is compounded at the converter level, which then changes rheology and requires revalidation of melt flow rate under ISO 1133-1:2022. Regulatory documentation for point-of-sale fixtures follows REACH Article 33 SVHC thresholds below 0.1% w/w and RoHS Directive 2011/65/EU Annex II restricted substance limits. Terminal outputs include retail shelf divider panels, decorative display headers, point-of-purchase light-box face panels, and replacement for PETG or PMMA sheet in temporary interior signage where bio-content and surface gloss are specified.

    Automotive Interior Scuff Plates: Scratch, Odour, and Thermal Ageing

    Automotive interior scuff plates and non-safety decorative inserts are injection moulded in tools with high-polish cavity surfaces or in-mould film decoration. Drying is carried out at 80 °C for 5 h to a moisture content below 0.020 wt%; melt temperature is 210–230 °C, mould tempering unit set to 60–80 °C, and injection speed controlled between 35 mm/s and 55 mm/s. The pack stage uses 80–100 MPa hold pressure for 8–12 s to suppress sink over reinforcing ribs. The formulation is pigmented with 4–7 wt% inorganic colour masterbatch in a PMMA carrier to improve colour stability under glazing; regrind is kept below 15 wt% and must be dried identically to virgin material. Odour performance is tested according to VDA 275 with a target grade not exceeding 3.5 for interior components; acetaldehyde emission from PLA thermal degradation is minimised by keeping screw residence time below 8 min and melt temperature below 230 °C. Accelerated ageing under DIN 75220 interior climate conditions is used to assess colour shift and surface cracking after cycles from −20 °C to 80 °C. Horizontal burn rate is measured per FMVSS 302 with acceptance at or below 102 mm/min; the material is not specified for vertical burn applications or components located within airbag deployment zones. Continuous service temperature is limited to 65 °C, making dashboards, upper instrument panels, and rear shelf substrates unsuitable without additional heat deflection validation by ISO 75-1/-2 at 1.80 MPa. Published data for this specific configuration is limited for long-term UV ageing beyond 500 h; exterior-adjacent applications should include xenon arc testing per ISO 4892-2. Terminal components include door scuff plates, seat back garnish, speaker grille rings, and decorative centre console trim inserts where plated or film-laminated surfaces protect the underlying polymer from direct sunlight and aromatic interior cleaners.

    Solvent Bonding and Pad Printing on Writing Instrument Barrels

    Writing instrument barrels and mechanical pencil bodies are injection moulded in multi-cavity cold runner tools with barrel walls of 1.2–2.0 mm and gate diameters between 0.8 mm and 1.0 mm. Drying is performed at 75 °C for 3–5 h, melt temperature is 205–225 °C, and mould temperature is held at 35–55 °C. The screw L/D ratio is 22:1; back pressure is set at 4–6 MPa to avoid colourant segregation. Pad printing on the barrel surface uses two-component inks designed for PMMA substrates; adhesion is confirmed by ISO 2409 cross-cut classification not exceeding Grade 1. For solvent bonding of barrel halves or end plugs, methyl ethyl ketone-based cements are applied at 20–25 °C and clamped for 20–60 s, followed by 24 h strength development before leak testing. Joint tensile strength is measured on bonded lap specimens under ISO 527-2; because PLA and PMMA phases respond differently to ester and ketone solvents, bond strength is typically lower than the parent material and should be designed as a secondary retention feature. Compliance for adult stationery requires REACH Article 33 SVHC content below 0.1% w/w; children’s writing instruments sold in the EU fall under EN 71-3 migration limits for heavy metals, and the compound is not assigned to food-contact or mouth-contact uses. The material should not be exposed to acetone-based nail polish removers or concentrated isopropanol because these solvents can induce stress cracking at gate vestiges. Terminal components include cylindrical pen barrels, mechanical pencil bodies, stylus casings with overmoulded TPE grips, and cosmetic writing instrument caps where high gloss and bio-content are design requirements.

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    Certification & Compliance
    More Introduction

    Ecoblend HCL7140 General Purpose Heat Stabilized Polylactic Acid/PMMA Blend is an unfilled, heat-stabilized thermoplastic compound supplied in pellet form for injection molding and extrusion. The formulation combines a renewable-carbon PLA phase with a PMMA phase to reduce flow-direction mold shrinkage and raise amorphous heat deflection temperature relative to unmodified PLA. Manufacturer-listed typical density is 1.24–1.28 g/cm³ under ISO 1183-1:2019; melt mass-flow rate at 210°C and 2.16 kg is 12–16 g/10 min under ISO 1133-1:2022. Tensile yield stress is 52–58 MPa and tensile modulus is 2.9–3.2 GPa under ASTM D638-14. Notched Izod impact is 2.2–3.0 kJ/m² under ISO 180:2023. Heat deflection temperature at 0.45 MPa is 68–75°C using ISO 75-2:2013 method B. These values are typical lot averages, not minimum specification limits. The grade is general-purpose; it is not flame-retardant, not elastomer-impact-modified, and not formulated for prolonged outdoor UV exposure.

    Primary processing is injection molding of non-load-bearing housings, display frames, rigid packaging inserts, internal brackets, and lightly stressed mechanical components. The PMMA fraction contributes surface hardness, reduced mold shrinkage anisotropy, and improved resistance to deformation at moderately elevated temperatures. The PLA fraction contributes renewable carbon content and higher modulus than many polyolefin-based general-purpose resins. The heat stabilizer package widens melt-residence tolerance during heated-runner molding, but does not convert HCL7140 into a high-heat resin. Continuous-use temperature remains limited by the amorphous heat deflection response rather than by the PLA melting point.

    What Distinguishes HCL7140 from Unmodified PLA and Conventional PLA/PMMA 70/30 Blends?

    Unmodified PLA exhibits higher neat tensile yield stress but loses melt stability during extended heated residence due to ester cleavage and lactide reformation. In general-purpose PLA grades, melt-flow increase can exceed 50% after 15 min at 220°C under dry molding conditions. HCL7140 is formulated to limit this melt-flow drift. Manufacturer-reported drift is below 20% under the same dry conditions; this is a process-stability reference, not a lot-release specification unless identified in the certificate of analysis. The PMMA phase also shifts the amorphous heat deflection response upward and reduces flow-direction mold shrinkage relative to PLA. Compared with nucleated high-heat PLA, HCL7140 does not require post-mold annealing above 100°C to develop its listed HDT improvement; however, the absolute heat resistance remains below annealed nucleated PLA.

    PropertyTest standardEcoblend HCL7140 typicalUnmodified PLA typicalConventional PLA/PMMA 70/30 typical
    Melt mass-flow rate at 210°C, 2.16 kgISO 1133-1:202212–16 g/10 min6–10 g/10 min14–20 g/10 min
    Tensile yield stressASTM D638-1452–58 MPa60–66 MPa46–52 MPa
    Tensile modulusASTM D638-142.9–3.2 GPa3.3–3.6 GPa2.6–2.9 GPa
    Notched Izod impactISO 180:20232.2–3.0 kJ/m²1.8–2.4 kJ/m²2.3–3.1 kJ/m²
    Heat deflection temperature at 0.45 MPaISO 75-2:2013 method B68–75°C50–56°C72–80°C
    Mold shrinkage, flow directionISO 294-4:20180.4–0.6%0.8–1.2%0.3–0.7%

    In phase-morphology terms, PMMA domains are maintained below an average diameter of 2 µm during compounding. Larger PMMA domains reduce weld-line strength and produce visible local opacity. Batch-to-batch control includes melt filtration and capillary rheometry to verify that low-shear viscosity at 210°C stays within ±10% of the reference lot. Compared with general-purpose ABS, HCL7140 has lower notched Izod impact and lower continuous-use temperature. The material is selected only where the PLA/PMMA property set is sufficient for the part. Published direct comparative data for this specific HCL7140 grade against all ABS grades and color concentrates is limited; end-use drop testing is required for impact-sensitive geometries.

    When Melt Temperatures Exceed 220°C in Heated-Runner Systems

    The recommended melt temperature is 205–220°C. Short excursions to 230°C are permitted only when total residence time in the barrel, manifold, and drop is below 3 min. Sustained operation above 240°C accelerates methyl methacrylate and lactide generation. Visual indicators are silver streaks at the gate, blistered weld lines, and a measurable reduction in notched Izod impact. These defects are not cosmetic surface flaws but indicators of molecular-weight loss and monomer formation. The effective processing window is narrow: melt-temperature control within ±5°C is required because viscosity changes alter fill pressure, packing density, and sink mark depth. In heated-runner tooling, set each nozzle and manifold zone with independent thermocouple verification. A difference of 3–5°C between controller setpoint and actual melt temperature is common in small nozzles; surface-contact probes or infrared thermal imaging are preferred over setpoint readings alone. Valve gates should be sequenced to avoid hold-time differences that create shot-to-shot molecular-weight variation.

    Rheological behavior is shear-thinning. Capillary rheometry on representative lots gives apparent viscosity of approximately 180–240 Pa·s at 210°C and 100 s⁻¹, falling to 40–60 Pa·s at 1000 s⁻¹. This shear sensitivity assists thin-wall filling but increases sensitivity to gate freeze and fill-speed changes. The apparent activation energy for viscous flow in the processing range is approximately 50–65 kJ/mol; a 5°C melt-temperature change therefore alters viscosity by roughly 7–10%. These values are monitoring references for stable production, not lot-release limits. Published kinetic data for this specific stabilizer package is limited; the stabilizer effect is assessed empirically by melt-flow drift after 15 min at 220°C.

    Production failure modes observed in heated-runner molding include gate stringing from delayed valve-gate closure, screw recovery time longer than 5 min at 230°C, and dead spots at hot-runner tips. Dead spots are reduced with reverse-taper nozzles and positive shut-off nozzles. Do not purge with PVC, acetal, or polycarbonate residues; acidic decomposition products from these resins can accelerate PLA and PMMA chain degradation.

    Establishing Drying and Molding Equipment Settings for HCL7140

    Pre-drying is mandatory when ambient relative humidity exceeds 60% or when pellet packaging has been open for more than 1 h. Use a desiccant dryer at 75–80°C for 4–6 h, with a dew point of -40°C or lower. Pellet moisture should remain below 0.025% (250 ppm) by Karl Fischer titration. Drying above 85°C can soften pellets and cause dryer bridging. In injection molding, maintain a screw cushion of 3–5 mm, back pressure of 3–5 MPa, and screw surface speed of 0.2–0.4 m/s. For a wall thickness of 2.0 mm, fill time of 1.5–2.5 s and packing pressure of 40–60 MPa for 0.5 s/mm are typical starting points. Injection pressure may reach 60–90 MPa depending on flow length. Clamp force requirement is 0.4–0.7 tonne/cm² of projected area. Vent depth should be 0.02–0.04 mm to exhaust monomer traces without flash. For extrusion compounding or reprocessing, a co-rotating twin-screw extruder with L/D 40:1, barrel temperatures 190–210°C, and vacuum venting at -0.08 MPa is recommended. Do not exceed 230°C at the die.

    Chemically, the PMMA phase is sensitive to ketones, esters, and alcohols. Contact with acetone or isopropanol may cause stress crazing. Avoid amine-based processing aids and strongly basic fillers, which can catalyze PLA ester cleavage. The grade is not designed for continuous immersion in water above 60°C or for outdoor exposure without additional UV stabilization. Published long-term hydrolytic aging data for this specific configuration is limited; humid-environment applications require end-use testing at 85°C and 85% RH.

    Regulatory Status and Documentation Footprint

    The standard formulation is covered by a REACH Regulation (EC) No 1907/2006 SVHC declaration below 0.1% w/w. RoHS 2011/65/EU including Delegated Directive (EU) 2015/863 compliance is available for cadmium, lead, mercury, hexavalent chromium, PBBs, PBDEs, and the four phthalates; supplier documentation must be requested for each color concentrate. No UL 94 classification is implied unless a yellow card is issued for the specific thickness and color. The base polymers have food-contact listings under FDA 21 CFR sections for PLA and PMMA, but the compounded heat-stabilizer package requires end-use migration review before food-contact acceptance. The material is not home compostable and is not marine biodegradable; the PMMA fraction is not biodegradable under EN 13432:2000.

    Document or standardScopeHCL7140 position
    REACH Regulation (EC) No 1907/2006SVHC content<0.1% w/w per supplier declaration
    RoHS 2011/65/EU + (EU) 2015/863Restricted substancesNot expected to exceed maximum concentration values
    ISO 1183-1:2019Density testing methodReported typical value 1.24–1.28 g/cm³
    ISO 1133-1:2022Melt mass-flow rate methodReported typical value 12–16 g/10 min at 210°C/2.16 kg
    ASTM D638-14Tensile testing methodTypical yield stress 52–58 MPa
    ISO 75-2:2013Heat deflection temperature method B68–75°C at 0.45 MPa

    If UL, food-contact, or outdoor-aging compliance is required, the specific grade, color, thickness, and end-use article must be identified in the supplier certificate. Compliance should not be inferred from generic base-resin datasheets or from a different Ecoblend grade.

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