| HS Code | 937311 |
| Polymer Type | High-density polyethylene (HDPE) |
| Density | 0.954 g/cm³ |
| Melt Flow Rate | 0.2 g/10 min at 190 °C / 2.16 kg |
| Tensile Strength At Yield | 26 MPa |
| Tensile Strength At Break | 30 MPa |
| Elongation At Break | >600% |
| Tensile Modulus | 1000 MPa |
| Flexural Modulus | 1200 MPa |
| Notched Impact Strength | 20 kJ/m² at 23 °C |
| Shore D Hardness | 62 |
| Vicat Softening Temperature | 76 °C |
| Heat Deflection Temperature | 65 °C at 0.45 MPa |
| Brittleness Temperature | -70 °C |
| Environmental Stress Cracking Resistance | >1000 h |
| Water Absorption | <0.01% |
| Volume Resistivity | >1×10^15 Ω·cm |
| Dielectric Constant | 2.3 at 1 MHz |
| Thermal Conductivity | 0.35 W/(m·K) |
| Coefficient Of Linear Thermal Expansion | 1.2×10^-4 /°C |
| Melting Point | 130 °C |
| Oxygen Index | 17% |
| Flammability Rating | HB (UL 94) |
As an accredited DSM HDPE SB71 factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.
| Packing | DSM HDPE SB71 is packaged in 25 kg moisture-resistant bags, supplied on 1,000 kg pallets for safe transport and storage. |
| Container Loading (20′ FCL) | DSM HDPE SB71 in 25 kg bags, palletized and shrink-wrapped, loaded into a 20′ FCL container for dry ocean transport. |
| Shipping | Shipping description: DSM HDPE SB71, high-density polyethylene pellets, non-hazardous, not classified as dangerous goods under DOT, IMDG, IATA, or ADR. Proper shipping name: Polyethylene, high density. UN number: none. Pack in sealed bags/octabins; protect from moisture, heat, and contamination. Follow local transport regulations. |
| Storage | Store DSM HDPE SB71 in a cool, dry, well-ventilated area, preferably indoors, in tightly closed original containers or bags. Protect from direct sunlight, heat, moisture, and contamination. Keep away from ignition sources and strong oxidizing agents. Use first-in, first-out stock rotation and avoid physical damage to packaging. Do not store near food, water sources, or incompatible materials. Maintain clean, dry conditions. |
| Shelf Life | DSM HDPE SB71 shelf life is typically 24 months when stored unopened in original packaging, dry, cool, and away from direct sunlight. |
On single-station accumulator-head extrusion blow moulding lines, DSM HDPE SB71 is processed at a melt temperature of 190 °C–205 °C. The upper boundary is constrained by parison sag, measured on production machines as a rapid increase in drop-length change once the melt exceeds 205 °C, while the lower boundary is set by incomplete plastification of the high-molecular-weight fraction in the metering zone of a grooved-barrel extruder. Extruder configurations use 90 mm–120 mm cylinder diameters and 24:1–30:1 L/D ratios, with barrier screws delivering a melt pressure of 20–35 MPa at the die head. Batch-to-batch variance in melt mass-flow rate, controlled under ISO 1133-1:2022 at 190 °C/2.16 kg, is revalidated by the processor before setting parison profiles because a shift of 0.05 g/10 min can alter the narrow sag window. The accumulator shot capacity is sized between 2.5 L and 5.0 L for 20 L jerrycans, allowing a complete parison to drop in 2.5–4.5 s. When ambient relative humidity exceeds 60%, regrind surfaces rather than virgin pellets become the main source of splay; regrind hoppers are conditioned at 60–70 °C for 2–3 h before use.
The formulation for UN-certified service uses 100 parts by weight of virgin SB71, 2.0–4.0 wt% of UV-stabilised colour masterbatch, and 0.15–0.30 wt% of a phenolic/phosphite antioxidant masterbatch. Closed-loop regrind from pinch-off and top scrap is limited to 25 wt%; above this level, batch-to-batch environmental stress-cracking resistance values measured under ASTM D1693-15 may become non-linear. Wall-thickness programming on the parison head uses 20–100 point profiles to compensate for draw-down, targeting a minimum wall thickness of 1.8 mm at container corners and 2.5–3.5 mm in the body. Blow pressure is maintained at 0.6–1.0 MPa, mould cooling water is held at 10–25 °C, and cycle times observed on production machines fall between 85 s and 180 s for 20–25 L containers. SB71 is not directed to thin-wall injection moulding; the same molecular characteristics that stabilise parison hang time produce flow-length limitations in narrow gates.
Compliance for finished packaging is demonstrated under 49 CFR §178.509 for UN 3H1 and 3H2 design types, including drop tests at -18 °C per 49 CFR §178.603, stack tests, and leakproofness tests. The material designation is controlled via ISO 17855-2:2020, density by ISO 1183-1:2019, melt mass-flow rate by ISO 1133-1:2022, and environmental stress-cracking resistance by ISO 16770:2019. Outputs include 20 L, 25 L, and 30 L jerrycans, as well as 120 L and 220 L tight-head and open-head drums for liquid industrial chemicals, lubricants, and detergents.
Sheet extrusion of SB71 for reusable dunnage runs on single-screw extruders with 30:1–34:1 L/D ratios and barrier screws, feeding a coat-hanger flat die of 1,600 mm–2,500 mm width. The melt temperature is elevated to 200–230 °C to reduce die swell and stabilise edge bead; the three-roll polishing stack is maintained at 70–95 °C to control crystallinity and sheet flatness. The formulation is 100 parts by weight of SB71, 1.0–2.0 wt% of antistatic masterbatch, and 10–20 wt% clean edge-trim regrind; slip/anti-block masterbatch is added at 0.05–0.10 wt% only when thermoformed parts are nested for transport. Sheet thickness is held between 1.5 mm and 8.0 mm, with a transverse gauge variation of ±0.10 mm on a 2.0 m die using automatic die-bolt control.
Thermoforming of cut sheet is conducted at a surface temperature of 150–175 °C with plug-assisted forming to distribute wall thickness in deep-draw parts. Melt-phase orientation is controlled by forming speed; excessive draw ratios above 4:1 produce thinning below 0.8 mm in pallet top decks. Compliance for general-purpose industrial sheet references ISO 17855-2:2020 and ASTM D4976-12a; where food-contact logistics trays are produced, FDA 21 CFR 177.1520(c) and EU Regulation (EU) No 10/2011 Annex I Table 1 govern specific migration limits. Finished outputs are pallet top caps, separator sheets, dunnage trays, and interlayer sheets used in automotive glass and heavy-goods packing.
Agrochemical packaging lines filling ester-based emulsifiable concentrates expose HDPE bottle walls to polar solvents that accelerate environmental stress cracking; acceptance therefore rests on ISO 16770:2019 full notch creep tests conducted at 80 °C in 2.0 wt% nonylphenol ethoxylate solution rather than on short-term tensile values. The formulation for 1–20 L monolayer containers uses 100 parts by weight of DSM HDPE SB71, 1.0–2.5 wt% carbon black masterbatch, and 0.10–0.20 wt% fluoropolymer processing aid; post-consumer recyclate is excluded, and closed-loop regrind is capped at 10–15 wt% because weld-line and pinch-off zones show faster solvent penetration on recycled fraction. Co-extrusion blow moulding on six-layer dies with a polyamide or EVOH barrier core positions SB71 as the structural outer and inner layers, with melt temperatures at 185–200 °C, die gap 1.0–2.0 mm, and mould cooling at 8–18 °C. Finished outputs are 1 L, 5 L, 10 L, and 20 L agrochemical bottles and jerrycans rated as UN 3H1/3H2 under 49 CFR §178.509 and labelled in accordance with the Globally Harmonized System.
Where SB71 is used to blow-mould conductive drums and jerrycans for flammable liquid handling, the surface resistivity requirement is specified under ASTM D257-14 as 104–106 Ω/square for dissipative packaging, with additional ESD control verification under IEC 61340-5-1. The compound recipe is 100 parts by weight of SB71, 6.0–12.0 wt% of conductive carbon black masterbatch, and 0.10–0.20 wt% of lubricant; regrind is limited to 10 wt% because repetitive extrusion cycles break the carbon black network and produce resistivity values outside the target range.
Processing on accumulator-head machines uses a low-compression screw to prevent excessive shear that would degrade the conductive carbon black structure; melt temperature is maintained between 190 °C and 210 °C, the die gap is set at 1.5–2.5 mm, and the parison drop speed is reduced to avoid melt fracture. Mould cooling water at 10–20 °C and blow pressure of 0.6–1.0 MPa are standard. Finished products include 25 L, 60 L, and 220 L conductive drums and IBC inner bottles, marked according to ISO 11469:2016 and targeted to solvent decanting areas where static discharge control is mandatory.
For food-contact bottles, SB71 is processed on continuous rotary-wheel machines with 6–12 mould stations or shuttle machines, with melt temperature held at 180–200 °C to minimise taste and odour carryover. The recipe uses 100 parts by weight of SB71, 2.0–3.0 wt% of TiO2 white masterbatch, and 0.05–0.10 wt% of slip additive; only in-house regrind is used, limited to 20 wt%, and any post-consumer recyclate is excluded unless a food-contact suitability letter supports the specific source. Blow pressure is 0.5–0.8 MPa, mould cooling is set at 8–15 °C, and a 1 L bottle cycles in 8–12 s on wheel machines. The finished packaging must comply with FDA 21 CFR 177.1520(c) and EU Regulation (EU) No 10/2011 Annex I Table 1, with overall migration below 10 mg/dm². Outputs are 200 mL–5 L HDPE bottles for milk, juices, personal care liquids, and pharmaceutical syrups.
Automotive washer-fluid and coolant reservoirs blow-moulded from SB71 are produced on 3D suction-blow machines that manipulate a downward-extruded parison around a moving lower mould, enabling the serpentine geometries dictated by under-hood packaging. The compound uses 100 parts by weight of SB71, 2.0–3.0 wt% black masterbatch selected for heat ageing at 125 °C, and 0.2–0.5 wt% hindered amine light stabiliser masterbatch; regrind from pinch-off and trim is limited to 20 wt% and must be dried to below 300 ppm moisture to prevent surface pitting at the weld line. Melt temperature is controlled between 190 °C and 205 °C, with the lower boundary set by melt strength at the 3D parison and the upper boundary by thermal sag during the open-mould transfer; blow pressure is 0.5–0.9 MPa, mould temperature is 15–25 °C, and pinch-off trim is completed in-mould with hydraulic pinch bars. Conformity rests on ISO 16770:2019 FNCT, ISO 527-2 tensile tests at 23 °C, OEM-specific odour/fogging limits under VDA 270:2018, and process control documentation under IATF 16949:2016. Final outputs are 2–10 L washer-fluid reservoirs, coolant expansion tanks, and auxiliary fluid bottles.
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DSM HDPE SB71, referenced in legacy producer documentation as Stamylan HD SB71, is an unfilled high-density polyethylene resin positioned for extrusion blow moulding of rigid containers. The numerical suffix is derived from the nominal melt-mass-flow rate under a 5.0 kg piston load at 190 °C, and the grade is used in monolayer and multilayer bottles, canisters, and hollow technical parts up to approximately 5 L. It is not a pipe pressure-rating resin and does not carry an ISO 12162 MRS classification. The polymer is supplied as pellets and requires no predrying under normal storage conditions; however, surface moisture from cold storage should be removed before extrusion because water at the die can generate surface defects.
Table 1 consolidates typical lot-average values published for the grade. These values are not specification limits and should be read alongside the producer’s certificate of analysis for the specific lot. The melt-flow ratio between the 5.0 kg and 2.16 kg values is approximately 10.1, indicating a broad molecular weight distribution. That breadth is functionally important in blow moulding because it promotes shear thinning in the die while retaining sufficient melt strength to limit parison sag.
| Property | Test method | Typical value |
|---|---|---|
| Density | ISO 1183-1 | 0.956 g/cm³ |
| Melt-mass-flow rate, 190 °C, 2.16 kg | ISO 1133-1 | 0.70 g/10 min |
| Melt-mass-flow rate, 190 °C, 5.0 kg | ISO 1133-1 | 7.1 g/10 min |
| High-load melt flow rate, 190 °C, 21.6 kg | ISO 1133-1 | 22 g/10 min |
| Tensile stress at yield, 50 mm/min | ISO 527-2/1B | 27 MPa |
| Tensile modulus, 1 mm/min | ISO 527-2/1A | 1050 MPa |
| Flexural modulus, 2 mm/min | ISO 178 | 1150 MPa |
| Notched Charpy impact strength, 23 °C | ISO 179-1/1eA | 5 kJ/m² |
| Notched Charpy impact strength, −30 °C | ISO 179-1/1eA | 3 kJ/m² |
| Vicat softening temperature, 50 N | ISO 306/A50 | 127 °C |
| Shore D hardness, 15 s | ISO 868 | 63 |
| Melting temperature, DSC second heat | ISO 11357-3 | 134 °C |
| Environmental stress-cracking resistance, 100% Igepal CO-630, 50 °C, F50 | ASTM D1693-21 Method B | >100 h |
Detailed capillary rheometry data for DSM HDPE SB71 in the 1 s⁻¹ to 100 s⁻¹ shear-rate window are not widely published. Die design and parison programming should therefore be validated on the target lot rather than interpolated from generic high-density polyethylene curves. In particular, the grade’s die-swell response should be measured on the intended tooling because die geometry and land-length ratio alter the extrudate diameter more than a single rheological index can capture.
When SB71 is substituted for a fractional-MFR HDPE blow moulding grade with a 2.16 kg melt-flow rate below 0.40 g/10 min, the immediate difference is lower head pressure and faster parison extrusion at the same screw speed. On a 65 mm single-screw extruder with a 24:1 L/D barrier screw and a 2.5 L accumulator head, the lower viscosity reduces shear heating and allows higher output, but the usable screw-speed range is constrained by parison sag. Above approximately 40 rpm, pre-blow and drop-time settings must be shortened to maintain wall-thickness consistency. Operators typically compensate by lowering the melt temperature toward 190 °C, which increases melt strength but also raises the risk of unfused pellets if the barrel profile is not adjusted in the feed zone.
Barrel temperature settings for the grade should begin at 190 °C in the feed zone, 200 °C in the compression zone, and 205 °C in the metering zone, with head and die zones held at 200–205 °C. The measured melt temperature at the die exit should remain between 195 °C and 205 °C. Sustained operation above 210 °C narrows the residence-time margin before oxidative gel formation; if a line stoppage exceeds 5 min, the accumulator and head should be emptied or purged. Blow mould temperatures between 15 °C and 30 °C balance cooling time and part release. Cooling time is commonly estimated at 1.2 s per millimetre of nominal wall thickness at a mould temperature of 25 °C, but this must be calibrated on the target tool because pinch-off geometry and flash thickness affect heat removal.
Pigment masterbatches should be metered at 2–4 wt% through a gravimetric throat feeder. A grooved-feed extruder with a barrier screw or dispersive mixing element is preferred because shear at the die can be insufficient to distribute colour uniformly. If streaks appear at screw speeds above 40 rpm, the mixer gap should be checked rather than increasing the temperature, which lowers melt strength and increases parison sag.
Environmental stress-cracking resistance is the dominant performance limit for containers holding detergents, surfactant-based cleaners, agrochemicals, oil-based formulations, and alcohol-water mixtures. DSM HDPE SB71 is specified on the basis of ASTM D1693-21 Method B F50 in 100% Igepal CO-630 at 50 °C; the typical value exceeds 100 h. This ranking does not translate linearly to field failure because moulded-in residual stress, wall-thickness distribution, and pinch-off weld quality control crack initiation. A container moulded with frozen-in stress above approximately 8 MPa can fail below the hoop stress suggested by laboratory ESCR results. Finished-component validation should therefore include drop impact and hydraulic burst testing under ASTM D2463-23 and ASTM D2911-23 rather than resin-level ESCR alone.
Stackability is governed by top-load resistance and creep. The flexural modulus of the grade, tested under ISO 178, is approximately 1150 MPa; this provides stiffness for container sidewalls and labels, but top-load strength is also controlled by container geometry, thread design, and cooling uniformity. Long-term static loads above 60 °C should be validated by creep testing because HDPE loses stiffness as the Vicat softening temperature of 127 °C is approached. The grade is not recommended for continuous service above 80 °C under load without a part-specific creep assessment.
High-flow injection moulding HDPE grades with a 2.16 kg MFR of 7–25 g/10 min are designed for fast mould filling and thin walls, but they cannot sustain a parison during blow moulding. Their low melt strength causes uncontrolled drawdown, so wall-thickness distribution becomes unstable. Conversely, fractional-MFR blow moulding grades with a 2.16 kg MFR below 0.40 g/10 min provide higher melt strength and better ESCR, but they require higher head pressure and reduce output. SB71 occupies the intermediate space where small and medium containers can be moulded without sacrificing ESCR to an injection-level MFR.
| Attribute | DSM HDPE SB71 | Fractional-MFR blow moulding HDPE | High-flow injection HDPE |
|---|---|---|---|
| Melt-mass-flow rate, 190 °C, 2.16 kg | 0.70 g/10 min | 0.20–0.40 g/10 min | 7–25 g/10 min |
| Density | 0.956 g/cm³ | 0.950–0.955 g/cm³ | 0.960–0.965 g/cm³ |
| Melt strength and parison stability | Moderate | High | Low |
| ESCR, ASTM D1693-21 Method B F50 | >100 h | >200 h | 10–40 h |
| Typical use | Bottles, jerrycans up to 5 L | Large drums, intermediate bulk containers | Caps, closures, thin-wall articles |
When polypropylene impact copolymers are considered as alternatives, DSM HDPE SB71 typically exhibits lower heat deflection temperature but better resistance to stress cracking in the presence of detergent and oil formulations. Polypropylene impact copolymers may require different tooling due to higher volumetric shrinkage and different hinge behaviour.
DSM HDPE SB71 is typically supplied with a food-contact statement referencing FDA 21 CFR 177.1520(c) for use as a component of articles intended for food contact, subject to end-use conditions. For the European Union, the base resin may be evaluated under Commission Regulation (EU) No 10/2011, Annex I; the finished article manufacturer remains responsible for overall migration and specific migration testing under Article 19. Electrical and electronics waste regulations such as RoHS 2011/65/EU and registration under REACH 1907/2006 are confirmed by the producer only for the substance as sold; downstream additives, printing inks, and adhesives may change the regulatory status of the finished container.
The grade is incompatible with strong oxidizing acids at elevated temperature and with halogenated solvents that plasticize high-density polyethylene and reduce environmental stress-cracking resistance. It should not be processed with free-halogen flame-retardant additives that generate acidic degradation products during extrusion. Regrind levels up to 20 wt% are generally acceptable for blow moulding, but higher proportions shift the melt-flow rate and reduce notched impact. If regrind is used above 20 wt%, the melt-flow stability and ISO 179-1 notched Charpy impact should be re-verified on the finished article.