Dsm Hdpe Sb51

DSM HDPE SB51

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    Specifications
    HS Code 673210
    Product DSM HDPE SB51
    Density 0.951 g/cm³
    Melt Flow Rate 190 C 2 16 Kg 0.4 g/10 min
    Tensile Strength At Yield 26 MPa
    Tensile Modulus 1100 MPa
    Elongation At Break >600%
    Notched Izod Impact Strength 23 C 20 kJ/m²
    Shore D Hardness 62
    Vicat Softening Temperature 125 °C
    Melting Temperature 133 °C
    Water Absorption <0.01%
    Coefficient Of Linear Thermal Expansion 1.5E-4 /°C
    Volume Resistivity >1E15 ohm·cm
    Dielectric Constant 1 Mhz 2.3
    Thermal Conductivity 0.4 W/m·K
    Specific Heat Capacity 1.9 kJ/kg·K

    As an accredited DSM HDPE SB51 factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing DSM HDPE SB51 is packaged in 25 kg bags, 40 bags per pallet (1,000 kg), shrink-wrapped for secure transport.
    Container Loading (20′ FCL) 20′ FCL container loading for DSM HDPE SB51: palletized 25 kg bags, stretch-wrapped, labeled, secured, approx. 18–20 MT net.
    Shipping For transport, DSM HDPE SB51 is a non-hazardous high-density polyethylene resin. Ship in sealed, labeled bags or bulk containers; keep dry, away from heat, ignition, and contamination. Not DOT/IMDG/IATA regulated. No special hazard labels required. Store cool and ventilated; avoid moisture, sunlight, and damage. Follow SDS and local rules.
    Storage Store DSM HDPE SB51 indoors in a cool, dry, well-ventilated area, away from direct sunlight, heat, flames, and ignition sources. Keep original containers sealed to prevent moisture, dust, and contamination. Avoid prolonged UV exposure and contact with strong oxidizers. Maintain ambient temperatures, stack securely to prevent deformation, and follow local regulations and supplier guidance.
    Shelf Life Typically, DSM HDPE SB51 has a 24-month shelf life when stored sealed in original packaging, dry, cool, away from sunlight.
    Application of DSM HDPE SB51

    In 60 L UN-rated jerrican production, the accumulator-head extrusion blow moulding line processes HDPE SB51 under a parison temperature window that is rarely widened beyond 190–220 °C at the die bushing. The grade’s high-molecular-mass architecture, with a producer-listed melt flow rate of 0.30 g/10 min at 190 °C/5 kg and density of 0.953 g/cm³, provides the melt strength required to hold a 1,200–1,800 g parison without measurable sag on a 90 mm grooved-barrel extruder with 30D L/D. Die gap programming remains critical: wall-thickness setpoints for sidewalls, top skirt, and chime are entered as 0.8–2.0 mm, 1.5–2.5 mm, and 1.8–2.8 mm respectively, because post-mould shrinkage at the chime can exceed 1.5 % when mould temperature is below 12 °C. Compliance for dangerous goods packaging is verified against UN Model Regulations 6.1.5.2 and ADR 6.1.3.1, with design-type approval requiring a hydraulic pressure test at 250 kPa for jerricans and a 1.2 m drop test at -18 °C for high-density polyethylene packagings. The formulation is kept deliberately lean: 100 parts by weight HDPE SB51, 2.0–4.0 wt% carbon black masterbatch for outdoor UV resistance, and 0.05–0.15 wt% external lubricant where mould release becomes limiting; antioxidant loadings are already compounded into the grade, so post-additions above 0.10 wt% are avoided because they can shift the slow-crack-growth resistance measured under ASTM D1693-15 Condition B. Finished parts leaving the line are trimmed, deflashed, and leak-tested to 30–50 kPa air pressure while clamped in a water bath, then palletised as 5–60 L UN 1H2 jerricans and 120–220 L open-head drums for solvents, lubricants, and intermediate chemicals.

    What Limits Wall-Thickness Uniformity in 1,000 L IBC Blow Moulding?

    In 1,000 L and 1,250 L intermediate bulk container shell production, parison programming with at least 100 control points is required because the vertical wall length exceeds 1,200 mm and the part mass can approach 20–24 kg. HDPE SB51 is processed on a single- or dual-head accumulator machine with a clamp tonnage of 1,500–2,500 kN; melt temperature at the die is held at 200–225 °C, while mould cooling water enters at 8–12 °C to keep cycle time between 10 and 20 min. The grade’s melt flow ratio between 21.6 kg and 5 kg loads—typically near 31:1 for high-molecular-mass HDPE—governs parison swell and drawdown concurrently, and any deviation in die gap exceeding ±0.1 mm produces local thinning at the top chime and bottom discharge sump. Blow pressure is set at 6–9 bar, with a pre-blow delay of 0.3–1.0 s to avoid weld-line weakness at the pinch-off.

    Regulated transport service is assessed under the UN Model Regulations Chapter 6.5 and ADR 6.5.2.1 for rigid plastics IBC types 31H1/31H2; stack-load testing applies a load equivalent to 1.8 times the maximum permissible gross mass for 28 days at 40 °C. The formulation uses 100 parts by weight HDPE SB51 and 2.0–5.0 wt% UV-stabilised black masterbatch, achieving a final carbon black content near 1.0 wt% in the wall. Addition of regrind must be limited to 10–20 wt% from internally generated top-trim only, because higher regrind fractions reduce the slow crack growth resistance measured by ISO 16770:2019. Terminal components include 1,000 L and 1,250 L bottle-type IBC shells with integrally moulded top valve bosses, bottom discharge stubs, and galvanised steel frames, used for water-based resins, food-grade syrups, and non-hazardous high-density liquids.

    Multilayer Barrier Structures for Solvent-Borne Agrochemicals

    Agrochemical packaging for xylene-containing emulsifiable concentrates and high-ionic-strength aqueous formulations cannot rely on monolayer HDPE SB51 because permeation of active solvents exceeds acceptable limits. Six-layer continuous coextrusion blow moulding inserts an EVOH barrier core between adhesion layers and HDPE SB51 outer skins; the layer distribution is controlled within 40/2/3/3/2/50 in percentage of total wall thickness from inner to outer surface. Melt streams are fed from separate extruders at 200–230 °C for HDPE SB51 and 190–215 °C for the EVOH tie-resin system; melt temperature differences greater than 15 °C at the die produce interfacial instability visible as wavy inner-wall lines. The total wall thickness is 1.2–2.5 mm, with the barrier layer not less than 3 vol% of the wall. Container design qualification follows the UN Model Regulations 6.1.5.2 and the FAO Manual on the Development and Use of FAO Specifications for Plant Protection Products, including a 28-day product storage test at 40 °C and a 1.2 m drop test after conditioning at -18 °C. The formulation by total wall mass is 70–80 wt% HDPE SB51, 10–15 wt% clean in-house regrind, 3–5 wt% EVOH, 2–3 wt% maleic-anhydride-modified tie resin, and 0.5–1.0 wt% processing aid. Terminal parts are 1–20 L coextruded bottles and jerricans for organophosphate, pyrethroid, and sulfonylurea crop-protection concentrates where product-specific permeation loss must meet fill-volume retention criteria established in the buyer’s formulation stability protocol.

    Comparative formulation and compliance matrix for HDPE SB51 downstream segments
    Downstream segmentHDPE SB51 loadingProcessing routeCompliance anchorTerminal article
    UN dangerous goods packaging100 parts by weight; 2–4 wt% carbon black masterbatchAccumulator-head extrusion blow mouldingUN 6.1.5.2, ADR 6.1.3.15–60 L jerricans, 120–220 L open-head drums
    Intermediate bulk containers100 parts by weight; 2–5 wt% UV-stabilised black masterbatch; 10–20 wt% regrindLarge-part accumulator blow mouldingUN Chapter 6.5, ADR 6.5.2.1, ISO 16770:20191,000–1,250 L IBC shells
    Solvent-borne agrochemical packaging70–80 wt% HDPE SB51 in coextruded wallSix-layer continuous coextrusion blow mouldingUN 6.1.5.2, FAO Manual1–20 L barrier bottles and jerricans
    Automotive fluid reservoirs100 parts by weight; 1–2 wt% carbon black masterbatch; 0.1–0.3 wt% heat stabiliser3D suction blow mouldingIATF 16949:2016, REACH 1907/2006, RoHS 2011/65/EU2–6 L washer reservoirs, 1–3 L surge bottles, 10–20 L DEF reservoirs

    Because under-hood fluid reservoirs combine 85–95 °C continuous air exposure, ethylene glycol coolant, and vibration-induced stress cracking, suction blow moulding with 3D parison manipulation is used instead of conventional pinched-bottom moulding. The HDPE SB51 grade is extruded at 210–230 °C through a 50–70 mm variable-die head and transferred into a tilting mould to create a shell with 2.5–4.0 mm wall thickness and no bottom pinch weld. This design removes the weld line that otherwise becomes a crack-initiation site in hot coolant environments. Blow pressure is maintained at 6–10 bar, mould clamping force is typically 800–1,200 kN, and cycle time is 45–75 s depending on reservoir volume. Material compliance is declared under REACH Regulation (EC) No 1907/2006 and RoHS Directive 2011/65/EU, while production control is expected to follow IATF 16949:2016 within the OEM supply chain. The formulation uses 100 parts by weight HDPE SB51, 1.0–2.0 wt% carbon black masterbatch for UV resistance, and 0.1–0.3 wt% long-term heat stabiliser where reservoir wall temperatures exceed 90 °C in continuous engine load. Published data for this specific reservoir configuration is limited; the lower wall thickness boundary is therefore product-specific and must be confirmed through pressure-cycle testing rather than extrapolated from resin datasheet values. Terminal parts include 2–6 L windscreen washer reservoirs, 1–3 L coolant surge bottles, and 10–20 L diesel exhaust fluid reservoirs where stress-crack resistance is verified according to ISO 16770:2019.

    When Hot-Plate Welding Governs Joint Service Life in Blow-Moulded Tank Shells

    Large closed-top water and rainwater storage tanks of 500–3,000 L are blow-moulded from HDPE SB51 as a single shell, but subsequent fitting of inlet and outlet spigots by hot-plate welding determines the practical service limit. The moulded shell is produced on a large-part accumulator machine with a 120–150 mm die head and mould closing force above 2,500 kN; parison mass ranges between 25 and 70 kg. After demoulding, the shell is conditioned for 24 h at 20–25 °C before welding. Hot-plate welding is executed to DVS 2207-1 with a PTFE-coated aluminium plate at 200–220 °C; bead-up pressure is 0.15–0.25 MPa and joining pressure is 0.10–0.20 MPa for a wall thickness of 5–8 mm. Burst testing of the welded assembly follows EN 12573-1:2000 for stationary welded thermoplastic tanks, and the weld factor is not assumed above 0.8 without destructive bend testing of sample coupons. The formulation is 100 parts by weight HDPE SB51 with 2.0–3.0 wt% carbon black masterbatch for outdoor UV exposure; no filler is used, because calcium carbonate addition above 2 wt% lowers weld strength at the fitting bosses. Terminal components include 500–3,000 L above-ground rainwater tanks, 1,000 L cylindrical water transport containers, and agricultural dosing tanks with ultrasonically inspected welded spigots.

    Migration Limits, Not Density Alone, Govern Returnable Water Bottle Clearance

    Returnable 18.9 L water cooler bottles moulded from HDPE SB51 require a separate organoleptic and migration assessment because high-molecular-mass HDPE can release low-molecular-weight fractions under repeated hot-wash cycles. The resin is processed on extrusion blow moulding machines at 200–220 °C with mould cooling water at 7–10 °C; wall thickness is set at 1.2–1.8 mm to balance top-load strength and drop impact. The cleaning cycle uses 1–2 % sodium hydroxide solution at 60 °C for 15 min, which imposes a stress-cracking environment that must be survived for at least 200 cycles without leakage. Compliance is evaluated under 21 CFR 177.1520(c) for olefin polymers in food contact and EU Regulation (EU) No 10/2011 Annex I Table 1 with an overall migration limit of 10 mg/dm² for aqueous simulants. The formulation is 100 parts by weight HDPE SB51, with no post-added colourants or slips unless a food-contact-approved white masterbatch at 1.0–2.0 wt% is required; recycled content is excluded from the food-contact layer. Terminal products are 18.9 L returnable and single-trip water bottles, 10 L mineral-water canisters, and 15 L bulk water dispenser inserts for institutional catering.

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    Certification & Compliance
    More Introduction

    DSM HDPE SB51 is a high-density polyethylene grade positioned for continuous extrusion blow moulding of rigid packaging, industrial containers, and technical hollow parts. The SB51 designation identifies a specific melt-flow range and density target within the DSM HDPE portfolio; it is not a cross-linked or bimodal pipe resin. The supplied resin has a density of 0.951 g/cm³ when measured under ISO 1183-1:2019. High-load melt index at 190 °C and 21.6 kg is 5.1 g/10 min, and the conventional melt index at 190 °C with 2.16 kg is typically below 0.5 g/10 min according to ISO 1133-1:2022. These values place SB51 in the high-molecular-weight HDPE class, in which melt strength and parison hang time are prioritized over cycle-time reduction. Compared with injection-moulding HDPE grades, the high molecular weight reduces mould-fill fluidity but increases tensile elongation and environmental stress cracking resistance.

    What Processing Window Prevents Melt Fracture in the Accumulator Head?

    On a reciprocating-screw blow moulding machine with a 90 mm barrier screw and 25:1 L/D, a rising temperature profile from 170 °C in the feed zone to 210 °C at the adapter is recommended. The melt temperature at the die exit should be held between 180 °C and 220 °C; below 180 °C, high shear stress at the die land can initiate melt fracture, while above 220 °C oxidative degradation increases the risk of odour and colour shift in unpigmented parts. Back pressure should be maintained between 80 bar and 150 bar to homogenise the high-viscosity melt without excessive shear heating. Shear heating must be monitored at the die adapter; a measured stock temperature above 230 °C indicates that screw speed and back-pressure require reduction. Pre-drying of SB51 is not required for clean, dry granules stored below 60 % RH. If sacks are exposed to relative humidity above 60 % RH for more than 24 h, drying at 80 °C for 2 h in a desiccant dryer reduces surface moisture and prevents bubble defects in thin flash zones.

    Tensile yield stress measured after conditioning at 23 °C and 50 % RH is 25 MPa, and tensile elongation at break exceeds 600 % when tested under ISO 527-2/1B/50. The tensile modulus of 1100 MPa is typical for a medium-density high-density polyethylene grade and is lower than that of highly crystalline HDPE pipe resins with density above 0.958 g/cm³. The notched Charpy impact value of 12 kJ/m² at 23 °C and 6 kJ/m² at -30 °C under ISO 179-1/1eA indicates sufficient cold-impact toughness for transport containers. Environmental stress cracking resistance measured according to ASTM D1693-B in 10 % Igepal CO-630 solution exceeds 600 h; this is substantially higher than the 10–50 h range observed for many high-flow HDPE injection grades. The property balance is enabled by a broad molecular weight distribution that permits both shear thinning during extrusion and chain entanglement during parison inflation.

    Property Standard designation Typical value
    Density ISO 1183-1:2019 0.951 g/cm³
    High-load melt index ISO 1133-1:2022, 190 °C/21.6 kg 5.1 g/10 min
    Melt index ISO 1133-1:2022, 190 °C/2.16 kg 0.5 g/10 min
    Tensile stress at yield ISO 527-2/1B/50 25 MPa
    Tensile elongation at break ISO 527-2/1B/50 >600 %
    Tensile modulus ISO 527-2/1B/1 1100 MPa
    Charpy notched impact, 23 °C ISO 179-1/1eA 12 kJ/m²
    Charpy notched impact, -30 °C ISO 179-1/1eA 6 kJ/m²
    Vicat softening point ISO 306/A50 126 °C
    Shore D hardness ISO 868 63
    Environmental stress cracking resistance ASTM D1693-B, 10 % Igepal CO-630 >600 h

    Table values are representative data for grade-selection purposes. The supplier technical data sheet for the specific production lot should be referenced for certificate of analysis limits.

    Large-part continuous blow moulding requires a low-sag, high-strength parison.

    Parison sag is governed by zero-shear viscosity and the extensional viscosity growth rate at typical deformation rates. SB51 exhibits a complex viscosity at 190 °C and 0.1 rad/s of approximately 1.2 × 104 Pa·s, falling to 1.1 × 103 Pa·s at 100 rad/s, giving a shear-thinning ratio near 11:1. This rheological response permits high head pressure during die flow while maintaining parison length during tool transfer. On a twin-station blow moulding machine with 300 kN clamp force per side, mould cycle times for 10 L containers are typically 55–75 s when running at 190 °C melt temperature. Adding 20–30 wt% in-house regrind is technically acceptable for non-food containers, provided the flake is free from paper labels and moisture; for food-contact containers, the regrind fraction should be validated against end-use compliance requirements and should not exceed 30 wt% without supplementary migration testing. Blow ratio should not exceed 4:1 for non-round cross-sections; weld-line thickness at the pinch-off should remain above 0.3 mm to avoid stress concentrations.

    Parameter DSM HDPE SB51 General HDPE injection-moulding grade General LDPE extrusion grade
    Density 0.951 g/cm³ 0.958–0.965 g/cm³ 0.918–0.930 g/cm³
    Melt flow condition 190 °C/21.6 kg 190 °C/2.16 kg 190 °C/2.16 kg
    Melt index 5.1 g/10 min 8–20 g/10 min 0.2–2.0 g/10 min
    Tensile yield stress 25 MPa 28–31 MPa 9–14 MPa
    Charpy notched impact at -30 °C 6 kJ/m² 3–5 kJ/m² no break
    Environmental stress cracking resistance under ASTM D1693-B >600 h 10–50 h >1000 h

    The comparative data show why SB51 is selected for blow moulded containers requiring a balance of stiffness, cold impact, and detergent resistance. Unlike a general HDPE injection moulding grade, SB51 is not suitable for thin-wall injection moulded caps or closures because the low melt index results in premature freeze-off in sections below 1 mm wall thickness.

    Chemical resistance and permeation behaviour in HDPE SB51 containers.

    HDPE SB51 resists aqueous acids, alkalis, and many polar organic solvents at ambient temperature. Immersion in 37 % hydrochloric acid at 60 °C for 30 days produces mass changes below 0.5 % and tensile yield retention above 85 % in general high-density polyethylene grades; published data for this specific SB51 configuration is limited, so production validation is required for aggressive oxidiser packages. Nonpolar hydrocarbons such as toluene and xylene cause swelling after prolonged contact, reducing tensile yield and increasing permeation. Oxygen permeation is lower in high-density polyethylene than in LDPE because the higher crystallinity of 0.951 g/cm³ reduces the amorphous volume fraction available for diffusive transport. For aggressive solvents under continuous pressure, an HDPE grade with higher density or a fluoropolymer liner should be specified. Stress cracking resistance is most relevant in the presence of surfactants and detergents; SB51 is therefore suitable for detergent bottles and industrial cleaning-product containers, but esters, terpenes, and halogenated solvents should be excluded from the formulation unless compatibility is confirmed by internal testing.

    Compliance with food contact regulations is not a property of the polymer alone; it is a property of the finished article after compounding, processing, and any post-treatment. However, the base resin is generally assessed against FDA 21 CFR 177.1520(c) for olefin polymers and EU Regulation No 10/2011 for plastic materials intended to come into contact with food. Overall migration from the finished article must not exceed 10 mg/dm² under EU 10/2011 for many food types. The manufacturer should verify whether the SB51 batch carries a food-contact statement in the technical datasheet; published data for this specific configuration is limited if the supply chain does not include the required documentation.

    If the Mould Contains Polyamide or Acetal Contact Surfaces, an Incompatibility Audit Is Required Before Production

    Polyamide and acetal contact surfaces in tooling can retain moisture or acidic residues that are incompatible with the high-viscosity HDPE melt. Mould surfaces should be cleaned with a non-silicone, pH-neutral cleaner between production campaigns; silicone mould-release agents should be avoided, as silicone contamination on the parison surface reduces adhesion and can produce visual defects or weld-line weakness. SB51 should not be processed in equipment that has previously compounded PVC, because residual chlorinated species can degrade the polyethylene at high temperature and corrode tool surfaces. If a running change from LDPE to SB51 is required, a purge sequence using a low-density polyethylene with a melt index of 2 g/10 min at 190 °C should be run for 20–30 min or until the die head temperature returns to the SB51 profile. Amine-based antistatic masterbatches should be evaluated separately; at loadings above 1 wt%, such additives can alter the surface energy of the blow-moulded part and affect label adhesion and ink transfer. Published data for this specific combination is limited; a production trial is required.

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