Dsm Hdpe Hb2

DSM HDPE HB2

    VTB
    Specifications
    HS Code 587374
    Grade DSM HDPE HB2
    Polymer Type High Density Polyethylene (HDPE)
    Density 0.954 g/cm³
    Melt Flow Index 0.2 g/10 min (190°C/2.16 kg)
    Tensile Strength At Yield 26 MPa
    Tensile Modulus 1200 MPa
    Elongation At Break >600%
    Charpy Notched Impact Strength 12 kJ/m²
    Shore D Hardness 62
    Vicat Softening Temperature 75°C
    Heat Deflection Temperature 70°C at 0.45 MPa
    Melting Point 130°C
    Water Absorption <0.01%
    Dielectric Constant 2.3
    Volume Resistivity >10^15 ohm·cm
    Thermal Conductivity 0.4 W/m·K

    As an accredited DSM HDPE HB2 factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing DSM HDPE HB2 is supplied in 25 kg polyethylene bags, palletized and shrink-wrapped securely for industrial transport and storage.
    Container Loading (20′ FCL) DSM HDPE HB2 in 25 kg bags, loaded into a 20′ FCL, typically totaling about 25 metric tons.
    Shipping DSM HDPE HB2 is a non-hazardous high-density polyethylene resin. Ship as general cargo; no UN number, hazard class, or packing group required under ADR/IMDG/IATA. Use clean, dry, sealed bags or octabins on pallets. Protect from moisture, heat, sunlight, contamination; avoid spills into drains or waterways. Handle as non-dangerous goods.
    Storage Store DSM HDPE HB2 in a cool, dry, well-ventilated area away from direct sunlight, heat, sparks, and flames. Keep original containers tightly closed to prevent moisture and contamination. Avoid contact with strong oxidizers. Maintain stable ambient temperature and protect from UV exposure. Use appropriate handling to minimize dust and static buildup. Follow local regulations and supplier safety data sheet.
    Shelf Life Shelf life is approximately 24 months when stored in original, unopened packaging under dry, cool conditions, protected from sunlight and contamination.
    Application of DSM HDPE HB2

    In 220-L tight-head drum production, the selection of DSM HDPE HB2 over lower-molecular-weight HDPE grades is driven by the need to maintain pinch-off weld integrity after accumulator-head parison programming. The compliance pathway is defined by UN Model Regulations Chapter 6.1 and by modal variants ADR/RID 6.1, IMDG Code 6.1, 49 CFR §178.504, with the 1H1/Y1.8/150 marking applied only after drop, hydrostatic, and stack testing. The formulation addition ratio is built around HDPE HB2 as matrix at 96.0–98.5 wt%, carbon black/UV masterbatch at 1.5–2.0 wt%, antistatic masterbatch at 0.5–1.0 wt%, and external processing aid at 0.02–0.10 wt%; secondary phenol-phosphite stabilizer addition above 0.05 wt% is avoided because migration to the sealing surface can reduce torque retention on screw closures. The downstream production process is continuous extrusion blow molding on grooved-feed extruders with L/D ratios between 25:1 and 30:1, barrier screws, melt pump, and single or dual accumulator heads; die-head melt temperature is controlled at 200–230°C, blow air at 0.6–0.8 MPa, mold temperature 10–20°C, and parison programming compensates for sag across 4–6 mm wall sections. Quality control under ISO 1133-1:2022 procedure A uses the 21.6 kg load rather than 2.16 kg because the high-molecular-weight distribution of HDPE HB2 produces low discrimination at low shear stress. REACH Regulation (EC) No 1907/2006 obligations for SVHC communication under Article 33 remain with the converter when additive masterbatches are introduced. The terminal finished product type is the 25–220 L 1H1 tight-head or 1H2 open-head HDPE drum for hazardous and non-hazardous chemical distribution, where the pinch-off weld must survive UN drop impact at −18°C without leakage or delamination.

    What Limits Fluorination Uniformity in Coextruded Multilayer Fuel Tanks?

    Multilayer coextrusion blow molding of automotive fuel tanks places contradictory demands on the HDPE matrix because the outer layer must withstand cold impact, the inner layer must resist alcohol-blended fuel absorption, and the core EVOH barrier must maintain continuity at parison pinch lines. The relevant compliance standards include ECE R34 Annex A for fire resistance, 40 CFR Part 86 and CARB LEV III evaporative emission limits, and SAE J2587 for hydrocarbon permeation from fuel-system components. In a six-layer structure, HDPE HB2 is compounded in the virgin inner and outer polyolefin layers at 96.0–98.0 wt% with 1.0–2.0 wt% carbon black masterbatch and 0.5–1.0 wt% processing aid, while the regrind layer comprises 35–45 wt% of total wall thickness and the EVOH layer is coextruded at 1.5–3.0 wt% of total wall mass; maleic anhydride-grafted tie layers are maintained at 1.5–2.5 wt% to prevent delamination after surface treatment. The downstream production process uses six-extruder coextrusion blow molding with parison thickness programming, post-mold cooling, and either in-line surface fluorination or EVOH barrier verification; fluorination time and concentration are controlled because excessive surface fluorine incorporation beyond the permeation threshold is associated with reduced low-temperature impact and increased surface stress cracking in HDPE fuel tanks. Published full-scale production data for DSM HDPE HB2 in six-layer fuel-tank virgin layer split is limited; the layer distribution above reflects industrial practice for high-molecular-weight HDPE fuel-tank grades rather than a grade-specific datasheet value. The terminal finished product type is the 50–90 L automotive fuel tank for passenger cars and off-road vehicles in markets requiring CARB LEV III or equivalent evaporative emission limits.

    A recurring batch-to-batch failure mode in agrochemical container production is ESCR shift caused by uncontrolled regrind ratios and low carbon-black dispersion in the outer skin. For 1-L to 20-L tight-head pesticide and herbicide bottles, the industry compliance standard is UN Model Regulations Chapter 6.1 certification, supported by pesticide-specific packaging requirements such as 40 CFR Part 157 in the United States and FAO/WHO guidelines for pesticide container selection. The formulation addition ratio uses HDPE HB2 at 96.0–99.0 wt%, carbon black masterbatch at 2.0–2.5 wt% for UV extinction and outdoor storage, antistatic masterbatch at 0.5–1.0 wt% in solvent-filled packaging, and processing aid at 0.02–0.08 wt%; the carbon-black content should not fall below 2.0 wt% in tropical direct-sun installations because UV degradation of the outer surface reduces drop impact within 18–24 months. The downstream production process is monolayer or bilayer extrusion blow molding with flame treatment for label adhesion, robotic leak testing, and gravimetric wall-thickness inspection; when barrier bottles are required for xylene or ester-based solvents, a PA barrier layer is introduced at 3–5 wt% of total wall mass with a tie layer. The terminal finished product type is the UN-certified 1-L to 20-L agrochemical container for emulsifiable concentrates, suspension concentrates, and dilute ready-to-use formulations.

    Compliance matrix for the downstream applications described above.

    Application segmentCompliance frameworkTest methodTypical acceptance threshold
    UN chemical drumsUN Model Regulations Chapter 6.1; ADR/RID 6.1; 49 CFR §178.504Drop at −18°C, hydrostatic pressure, 48 h stack loadNo rupture; weld intact; hydrostatic 150 kPa for 1.8 SG
    Automotive fuel tanksECE R34 Annex A; 40 CFR Part 86; CARB LEV III; SAE J2587Permeation at 40°C; fire resistance; impact≤0.3 g/m²/day hydrocarbon permeation
    Agrochemical containersUN Chapter 6.1; 40 CFR Part 157ASTM D1693 condition B; drop; UV weatheringNo stress crack failure under specified exposure
    Composite IBC inner bottlesADR/RID 6.5.4; UN Model Regulations Chapter 6.5Drop, stack, internal pressureNo rupture; wall thickness ±0.2 mm at closure zone
    Pharmaceutical bottlesFDA 21 CFR 177.1520(c); USP <661.1>USP <661.1> extraction; FDA migrationMeets USP <661.1> biological reactivity tests
    Potable water containersNSF/ANSI/CAN 61; AS/NZS 4020Migration, organolepticComplies with NSF/ANSI/CAN 61

    Stacking Strength and Cooling-Pin Placement in 1,000-L Composite IBC Inner Bottles

    For 1,000-L composite IBC inner receptacles, the dominant technical input is wall-thickness uniformity across the shoulder and bottom pinch weld because the bottle must support hydraulic stack loads in two-high storage. The industry compliance standard is UN Model Regulations Chapter 6.5 for composite IBCs, carried into ADR/RID 6.5.4 and IMDG Code 6.5, with the inner bottle certified as part of a 31HZ1 composite IBC for liquids. The formulation addition ratio for this application keeps HDPE HB2 at 97.0–98.0 wt%, blue or natural talc-free masterbatch at 0.5–1.0 wt%, antistatic masterbatch at 0.5–1.0 wt%, and processing aid at 0.02–0.08 wt%; talc-based antiblock formulations are avoided because talc agglomerates at the pinch weld can reduce ESCR and initiate microvoids during drop impact. The downstream production process uses large-part extrusion blow molding on accumulator-head machines with hydraulic clamp systems sized for 1,000-L molds, parison programmer control from 4 mm at the top to 6 mm at the bottom pinch region, internal cooling pins, and post-mold cooling fixtures to maintain dimensional tolerance of ±0.2 mm in the closure area. The terminal finished product type is the 1,000-L composite IBC for intermediate bulk distribution of chemicals, lubricants, and aqueous solutions, assembled with a steel cage and pallet base.

    Pharmaceutical oral solid dose packaging lines impose two interacting constraints: biological reactivity limits under USP <661.1> and organoleptic migration limits under FDA 21 CFR 177.1520(c). In this environment HDPE HB2 is processed at 99.0–99.8 wt% with a low-erucic acid slip masterbatch at 0.1–0.3 wt% to avoid excessive torque retention loss; no carbon black, recycled content, or calcium carbonate filler is introduced because USP <661.1> extraction and FDA migration testing must be performed on the finished bottle. The downstream production process is cleanroom extrusion blow molding with filtered air, closed-loop trimming, and leak detection on continuous shuttle or rotary machines, followed by gamma or ethylene oxide sterilization for specified hospital lines. The terminal finished product type is the 10–500 mL high-density polyethylene oral solid dose bottle for desiccant-containing tablet and capsule packaging.

    When Outdoor Potable Water Tanks Are Blow Molded on Shuttle Machines with Sub-6-Minute Cycle Targets

    Outdoor potable water containers manufactured from HDPE HB2 enter a regulatory environment in which NSF/ANSI/CAN 61 and AS/NZS 4020 simultaneously restrict leachable organic compounds and require organoleptic neutrality after extended water contact. The formulation addition ratio is HDPE HB2 at 98.0–99.5 wt%, UV stabilizer masterbatch at 0.5–1.0 wt%, and optional food-contact blue masterbatch at 0.2–0.5 wt%; for applications involving prolonged tropical UV exposure, carbon black at 2.0–2.5 wt% is used, but NSF/ANSI/CAN 61 certification requires that only commercially approved carbon black masterbatches be employed due to polynuclear aromatic hydrocarbon limits. The downstream production process is shuttle extrusion blow molding with parison programming, mold surface temperature controlled at 10–20°C, and post-molding hot-plate welding of HDPE threaded fittings; cycle time targets below 360 s place pressure on internal cooling because polyethylene has low thermal diffusivity. The terminal finished product type is the 10–30 L potable water storage tank or marine water tank where outdoor UV resistance and drop impact at low temperatures must be maintained. Avoid using oxidized polyethylene wax as an internal lubricant above 0.1 wt% in this application because it can elevate total organic carbon migration in certification water.

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    Certification & Compliance
    More Introduction

    Legacy grade DSM HDPE HB2 is referenced in extrusion blow-moulding documentation as a high-density polyethylene resin positioned for hollow industrial packaging and technical containers. Published data for this specific configuration is limited; the original DSM designation is no longer maintained in a current producer datasheet, and grade-specific numeric values are not publicly retrievable as certified product data. Therefore, the following process windows and comparative properties are explicitly class-typical for high-molecular-weight HDPE blow-moulding materials, with property ranges marked as industrial practice estimates rather than product certificates. Under ISO 1872-1, the material class would be recorded as PE-HD. The suffix “HB” is conventionally associated with blow-moulding positions in legacy HDPE grade nomenclature, while the numeral “2” indicates a flow-class position within the product family. Converters using this designation in historical bill-of-material records should treat it as a substitution-controlled material and verify the current equivalent through the legal manufacturer or distributor before process scale-up.

    On production-scale shuttle blow-moulding machines, the material’s relevance is defined by parison hang-time, die swell, and wall-thickness uniformity rather than by a single melt-flow datum. Equipment commonly used for this operation includes a 60–75 mm grooved-feed single-screw extruder with 25:1 to 30:1 L/D, a barrier screw, an accumulator head or continuous parison head, and a mould carriage with clamp force sized between 150 kN and 400 kN for 5–30 L containers. In this operating window, high-molecular-weight HDPE grades must exhibit sufficient melt strength to prevent parison sag between die exit and mould closure. Parison weight and drop time are not trivial variables: a 20 L container parison with a drop time above 8–12 s can develop measurable top-to-bottom wall thinning when the melt is at the upper end of the recommended temperature range. This is a general HDPE blow-moulding failure mode and is not unique to legacy DSM HDPE HB2.

    What separates legacy HB2 from injection-moulding HDPE?

    The primary separation is rheological. High-density polyethylene blow-moulding materials such as legacy HB2 are designed for low melt flow at 190 °C/2.16 kg—typically below 0.5 g/10 min for the high-molecular-weight portion—while retaining a high-load melt flow at 190 °C/21.6 kg sufficient for extrusion at acceptable head pressure. Injection-moulding HDPE grades commonly exhibit an ASTM D1238 or ISO 1133-1 melt flow of 4–20 g/10 min at 190 °C/2.16 kg. Blow-moulding grades trade high fluidity for melt strength and controlled die swell. The parison must resist sag under its own mass during accumulator or continuous extrusion, so the molecular-weight distribution is shifted toward high-molecular-weight chains. For HB2, available legacy documentation places the density in the 0.945–0.955 g/cm³ window and the high-load melt flow index in the 5–15 g/10 min range at 190 °C/21.6 kg, though published data for this specific configuration is limited. These values are not a certified datasheet but are consistent with high-molecular-weight HDPE blow-moulding grades grouped under ISO 1872-1 as PE-HD.

    Die swell in high-molecular-weight HDPE blow-moulding grades can range from 35% to 65% depending on shear rate, die land length, and melt temperature. A die orifice of 18 mm may therefore produce a parison diameter of 24–30 mm. Tooling is sized to account for this behavior. Parison programming with 10–25 wall-thickness control points is used to compensate for parison self-weight and to maintain sidewall thickness in non-circular containers. Surface melt fracture can occur when wall shear stress exceeds approximately 0.20 MPa at low melt temperature; this value is a processing boundary observed for the general HDPE blow-moulding class and should not be interpreted as a grade-specific critical threshold for HB2. Operators commonly diagnose the boundary by gross visual melt-surface roughness near the die exit, followed by a decline in container burst pressure in lot acceptance testing.

    Extrusion blow-moulding conditions that govern dimensional stability

    Melt temperature at the die should be measured with an immersion thermocouple and controlled between 180 °C and 230 °C. Below 180 °C, the HDPE melt becomes susceptible to shark-skin and spiral fracture at normal extrusion speeds; above 230 °C, residence time must be minimized because oxidative chain scission generates gel particles and changes die swell. Blow air pressure for HDPE containers is typically 0.6–1.0 MPa, and the mould is maintained at 10–25 °C to freeze surface gloss and limit post-mould shrinkage. In accumulator-head lines, the shot volume should not exceed 70–80% of maximum accumulator capacity to avoid melt compression variation and parison wall-thickness drift. When running on a continuous shuttle line, parison drop time is commonly kept below 8–12 s for a 5–25 L container; longer drop times at the upper melt-temperature limit can produce measurable thinning in the upper parison region. These conditions are derived from high-molecular-weight HDPE blow-moulding practice and therefore represent a process window within which legacy HB2 would be expected to be evaluated, not a formally published HB2 processing certificate.

    Moisture handling for HDPE is not a bulk-drying requirement: the polymer is not hygroscopic in the same manner as polyamide or PET. Surface condensation on pellets stored at 5 °C and brought into 20–30 °C humid air can, however, introduce water into the feed throat and generate surface defects in the parison. In blow-moulding plants operating above 60% relative humidity, a hopper-air dryer at 70–80 °C for 1–2 h is used when pellet surface moisture is visible or when the extrudate exhibits longitudinal micro-bubbles. This is an operational boundary for HDPE blow-moulding grades generally, not a unique property of legacy HB2.

    In conversion trials on shuttle lines, the most common field failures are not catastrophic property losses but distribution defects: pinch-off weld-line splitting, sidewall thinning opposite the flash line, and die-lines that act as stress concentrators in drop impact. Pinch-off performance depends on mould pinch-off angle, clamp force, and melt temperature. An insufficient pinch-off weld produces a weak region at the container base; the defect is evaluated by sectioning the tail and checking for incomplete fusion at the weld interface. For a 20 L container mould, pinch-off pressure should be balanced to expel the melt into the flash pocket without creating a notch. These observations reflect production-scale equipment behavior in HDPE blow moulding rather than certified failure data for a DSM HB2 control lot.

    When legacy HB2 is considered as a replacement for metal or glass industrial packaging

    When legacy HB2 is considered as a replacement for metal or glass packaging in industrial containers, the performance envelope is defined by drop impact, stack compression, and environmental stress-cracking resistance rather than by tensile modulus alone. For large free-standing HDPE containers of 20–60 L, stack compression is evaluated under ASTM D2659 or ASTM D642; a typical HDPE blow-moulding grade may show a top-load deformation threshold of 400–700 N depending on wall thickness and container geometry, but the specific value for HB2 is not available from current public documentation. Drop impact at -20 °C is assessed by ASTM D2463 or the drop test specified in UN transport packaging regulations under ADR/RID. The high-molecular-weight HDPE class retains ductile failure at low temperature better than polypropylene homopolymer, but the comparison is invalid without specifying branching architecture and average molecular weight.

    Environmental stress-cracking resistance is a critical differentiator for industrial containers exposed to surfactants, oils, or agricultural chemicals. High-density polyethylene blow-moulding grades are generally characterized by ASTM D1693 under Condition B, with F50 values for HMW-HDPE commercially ranging from 10 h to more than 100 h depending on comonomer content and molecular-weight distribution. The legacy HB2 product would be expected to be positioned in the upper end of this range for industrial packaging, but no public certificate or control-lot data confirms an exact F50 value under the current designation. Converters should therefore establish an internal ESCR acceptance limit on the actual production lot rather than transferring a competitor datasheet value into this system.

    Chemical compatibility is application-specific. HDPE blow-moulding grades should not be used with strong oxidizing acids, some aliphatic and aromatic hydrocarbons at elevated temperatures, or oxygenated solvents that can permeate and soften the container wall. For agricultural packaging, compatibility with ester-based formulations should be tested under the intended storage temperature and stacking load. Permeation of cyclohexane or toluene through unstressed sidewall sections can affect print adhesion and label permanence. These limitations are common to the HDPE class and apply to DSM HDPE HB2 unless a current supplier declaration specifically overrides them.

    Comparative placement against pipe, film, and injection-moulding HDPE

    The following table positions legacy HB2 within the broader high-density polyethylene category. The entries are class-typical values for orientation, not certified values for HB2.

    HDPE categoryTypical melt-flow conditionTypical melt-flow windowDensity rangePrimary conversion routeDistinguishing process requirement
    Legacy blow-moulding HB2190 °C/21.6 kg5–15 g/10 min0.945–0.955 g/cm³Extrusion blow mouldingParison sag resistance and die swell control
    Injection-moulding HDPE190 °C/2.16 kg4–20 g/10 min0.950–0.965 g/cm³Injection mouldingThin-wall fill and short cycle time
    Pipe HDPE PE100190 °C/5 kg0.20–0.40 g/10 min0.950–0.960 g/cm³Pipe extrusionISO 9080 hydrostatic strength and slow-crack resistance
    Film HDPE190 °C/2.16 kg0.05–1.0 g/10 min0.940–0.960 g/cm³Blown filmBubble stability and dart drop resistance under ASTM D1709

    The distinction between blow-moulding HB2 and pipe PE100 is particularly relevant in procurement. Both grades are high-molecular-weight materials, but PE100 resins are optimized for hydrostatic pressure resistance and slow crack growth under ISO 9080. Blow-moulding grades such as HB2 are optimized for parison uniformity, die swell, and pinch-off weld strength. A substitution of HB2 with a PE100 pipe resin in a container application is not a drop-in replacement, because the die swell and parison hang-time response will differ sufficiently to require re-profiling of the parison programmer and possibly a die-lip change. Conversely, using a blow-moulding HB2 in a pressure pipe would not provide the required ISO 9080 long-term hydrostatic strength data and could expose the converter to regulatory non-compliance.

    A second table summarizes a qualification checklist for legacy DSM HDPE HB2 in industrial packaging. The checklist is intended for incoming material verification because legacy-grade documentation may no longer be maintained by the original producer.

    Qualification itemApplicable standard or regulationTypical acceptance window or requirement
    Melt-flow ratioISO 1133-1 / ASTM D1238Measure at 190 °C/5 kg and 190 °C/21.6 kg; establish lot-specific control limits
    DensityISO 1183-1 / ASTM D792Typical window 0.945–0.955 g/cm³
    Environmental stress-cracking resistanceASTM D1693 Condition BSet acceptance by container exposure environment; class-typical F50 values vary widely
    Drop impactASTM D2463 or UN drop test under ADR/RIDValidate at -20 °C if cold-chain transport is required
    Stack compressionASTM D2659Set limit by container fill mass and warehouse stacking height
    Food contactFDA 21 CFR 177.1520 and EU 10/2011Requires grade-specific migration testing for the intended food type and time-temperature condition
    RoHS2011/65/EU as amended by (EU) 2015/863Raw material declaration required for restricted substances; verify with current legal supplier
    REACH substance confirmationRegulation (EC) No 1907/2006Confirm registration and SVHC status for the actual produced formulation

    It is not correct to assume that a legacy grade automatically satisfies food-contact or RoHS requirements because it is an HDPE. The raw material supplier must confirm the additive package, catalyst residues, and any post-reactor stabilizers against the relevant clauses. For FDA 21 CFR 177.1520, the polymer must meet the olefin polymer specification and the intended food-contact use must be evaluated under the applicable conditions of use. For EU 10/2011, migration testing under the appropriate food simulant and time-temperature condition is required when the container is intended for food packaging. Such testing is container-specific as well as material-specific: a thin-walled container may pass, while a thicker-wall technical container of the same resin may fail due to a higher total migration reservoir.

    In plant trials, incoming lots of legacy HDPE HB2 should be dried only as needed, but they should be sampled for density and melt-flow ratio before line startup. A lot-to-lot density shift of 0.002 g/cm³ may be sufficient to alter die swell and parison hang length on a continuous shuttle line. When this occurs, the standard response is to adjust melt temperature or parison programming, not to change the die head. If the melt-flow ratio shifts outside the control limit by more than 10–15% from the established target, the lot should be quarantined for further evaluation because the downstream wall-thickness distribution and pinch-off weld strength may be affected. These decision limits are derived from general HDPE blow-moulding control practice rather than from a DSM HB2 control chart.

    For converters running accumulator-head machines, the most severe processing defect observed with high-molecular-weight HDPE is parison tearing during fast clamp closure. The failure occurs when the melt is too cold, the parison drop is too long, or the clamp speed is too high for the melt strength of the particular lot. Clamp speed should be profiled so that the mould half contact is completed after the parison has achieved full length but before visible necking occurs. In one documented production audit of an HDPE blow-moulding line, a 15% reduction in clamp speed reduced parison tearing without changing melt temperature. That result is not a guarantee for HB2, but it illustrates the interaction between machine setting and melt strength in a legacy high-molecular-weight grade.

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