| HS Code | 533550 |
| Materialtype | High Density Polyethylene (HDPE) |
| Environmentalstresscrackresistance Hours | >1000 |
| Waterabsorption Percent | <0.01 |
| Color | Natural |
| Form | Pellets |
As an accredited Dow HDPE DMDB-6240 NT 7 factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.
| Packing | Dow HDPE DMDB-6240 NT 7 is supplied in 25 kg polyethylene bags, 55 bags per pallet (1,375 kg). |
| Container Loading (20′ FCL) | 20′ FCL loading for Dow HDPE DMDB-6240 NT 7: 25 kg bags, palletized, stretch-wrapped, evenly distributed, secured for ocean transport. |
| Shipping | Dow HDPE DMDB-6240 NT 7 ships as a non-hazardous, solid high-density polyethylene resin. It is typically packaged in 25 kg bags, bulk boxes, or bulk trucks/railcars. Store in a dry, cool area away from ignition sources. Not regulated for transport under DOT, IMDG, or IATA. |
| Storage | Store Dow HDPE DMDB-6240 NT 7 in a cool, dry, well-ventilated area away from direct sunlight, heat, sparks, and flames. Keep material in original, sealed bags or containers on pallets, off the ground. Protect from moisture, dust, oils, and other contaminants. Avoid excessive stacking and prolonged UV exposure. Follow local regulations and the manufacturer’s SDS. Use first-in, first-out stock rotation. |
| Shelf Life | Typically 2 years if stored unopened in original packaging under cool, dry, well-ventilated conditions, away from direct sunlight and moisture. |
In agricultural chemical packaging, the specifying parameter for high-density polyethylene monolayer containers is not the melt index alone but the combined response of environmental stress crack resistance and pinch-off integrity after contact with xylene-containing emulsifiable concentrates. Dow HDPE DMDB-6240 NT 7 has a published typical melt flow rate of 0.7 g/10 min at 190 °C/2.16 kg per ISO 1133-1:2022 and a density of 0.954 g/cm³ per ISO 1183-1:2019. Continuous shuttle blow moulding lines process the resin at a melt temperature of 185–205 °C, with die head temperatures held at 190–200 °C and mould cooling water set to 10–18 °C. The parison die gap on a 65 mm grooved-feed extruder with L/D 25:1 is adjusted to 1.8–2.8 mm to compensate for die swell of 20–35% and to maintain an average lower-sidewall thickness of 1.0–1.2 mm. Batch formulation for agricultural chemical containers typically consists of 85–90 wt% virgin resin and 10–15 wt% certified in-house regrind from flash and tailing removal, with carbon black masterbatch dosage of 2.0–2.5 wt% where a UV-opaque shell is required by 40 CFR Part 165 for portable pesticide containers. Pre-drying is not required below 0.02% surface moisture, but storage at ambient RH above 60% may require a 2 h hopper drying cycle at 70 °C to suppress melt-phase hydrolysis at the die lip. The terminal containers, commonly 5 L, 10 L and 20 L tight-head designs, must satisfy UN 3H1 performance tests under Packing Group II, including a drop height of 1.2 m at −18 °C, a leakproofness test at 20 kPa, and an internal hydraulic pressure test at 100 kPa for 30 min. The notch resistance of the grade under ASTM D1693 condition B in 100% Igepal CO-630 at 50 °C is therefore applied to prevent sidewall fissures that propagate from label-panel sink marks and handle pinch-off welds when wetted by dilute emulsifiable concentrate formulations.
UN-certified jerrycan production in DMDB-6240 NT 7 requires accumulator-head parison programming to move material from the top chime area into the bottom pinch-off. On a 75 mm barrier screw with L/D 28:1, a shot volume of 1,200–1,800 cm³ is delivered through a diverging die gap of 1.2–3.8 mm across a 30 to 40 point programming profile. The mould clamp force is set to 250–400 kN for a 30 L tool. Process instability occurs when the die gap is widened above 3.8 mm or when the drop time exceeds 3.5 s, because the parison stretches under its own melt strength and creates thin corners at the base weld. The permissible regrind fraction for UN-rated jerrycan production is capped at 20 wt% because higher levels increase melt flow ratio variability under ISO 1133-1:2022 and reduce ESCR margins under ASTM D1693 condition B. Batch-to-batch variation in die swell requires adjustment of parison weight by ±3% to keep nominal 1,650 g jerrycan weight within the calibration band of the leakproofness fixture.
| UN Packing Group | Drop Height | Leakproofness | Internal Hydraulic Pressure |
|---|---|---|---|
| I | 1.8 m at −18 °C | 20 kPa | 100 kPa for 30 min |
| II | 1.2 m at −18 °C | 20 kPa | 100 kPa for 30 min |
| III | 0.8 m at −18 °C | 20 kPa | 100 kPa for 30 min |
The terminal article is a tight-head 30 L jerrycan with a 51 mm neck finish, induction-sealed aluminium foil and polypropylene cap. The pinch-off weld is the limiting structural zone in cold-condition drop testing: if the weld flash is trimmed too aggressively or the tail is recycled above 20 wt%, the weld can split at the base chime because frozen-in orientation is highest in that region. Blow pressure is maintained at 0.8 MPa, and the cooling cycle includes a 5–8 s post-blow hold at 0.4 MPa internal air to stabilise the base weld against residual shrinkage after demoulding.
Long-neck 1 L sodium hypochlorite containers require a different moulding strategy because high die swell and short parison drop on wheel machines create nonuniform wall distribution near the handle. DMDB-6240 NT 7 is processed on 8–12 cavity vertical wheel blow moulders with a 60 mm screw, L/D 24:1, melt temperature 190–200 °C, and water-cooled aluminium moulds at 8–15 °C. Blow pressure is held at 0.7 MPa, and pre-blow timing is set to 0.3–0.6 s before full inflation. Tooling uses a diverging die gap of 1.5–2.2 mm and a 45° land entry angle to stabilise parison diameter. Formulation for bleach-grade bottle production includes 1.5–2.0 wt% TiO₂ white masterbatch for opacity and 0.05–0.10 wt% hindered amine light stabiliser concentrate, with 10 wt% clean regrind derived from rejected preforms and start-up purgings. Amine-free process aids are specified for this formulation because residual low-molecular-weight amines can accelerate yellowing after repeated bleach contact.
The finished 1 L bottle at 28–32 g is subjected to a 24 h drop test on a concrete floor from 1.5 m after filling with 5% sodium hypochlorite solution; closure integrity is verified under ISO 8317:2015 for child-resistant packages where specified. The neck finish is calibrated for a 38 mm tamper-evident closure, and the moulded thread must retain ≥95% of its engagement after two closure application cycles. Because wheel machines have short cooling residency relative to shuttle lines, the mould is run with a post-mould cooling station that holds bottles at 10 °C for 3–5 s to reduce handle distortion during downstream trimming.
A separate processing pathway is applied to 10 L and 20 L diesel exhaust fluid (DEF) containers because the filling and storage environment is regulated by ISO 22241-3:2019 and the resin wall must limit aldehyde and silicate migration into the fluid. In this application, DMDB-6240 NT 7 is extruded on a single-station accumulator machine with a 70 mm grooved-feed screw, L/D 26:1, at a melt temperature of 190–205 °C. The die temperature is kept at 185–195 °C to prevent premature parison sag; the mould core is cooled to 12–16 °C. Blow air pressure is 0.8 MPa, and the pre-blow sequence is delayed 0.5–1.0 s for uniform pre-form inflation. The compounding recipe uses 88–92 wt% virgin DMDB-6240 NT 7, 8–12 wt% closed-loop regrind, and carbon black masterbatch at 2.0 wt% where ultraviolet stabilization of bulk-stored DEF is specified. Titanium dioxide and carbonate fillers are excluded because particulate abrasion can influence closure seal integrity after repeated fill cycles.
Terminal containers are tight-head 10 L and 20 L formats with 51 mm or 60 mm necks, induction-sealed foil and polypropylene closures. The moulded parts are inspected for wall thickness using ultrasonic gauging at 6 points per sidewall; the failure threshold is a minimum wall of 0.8 mm, below which the stacking test at 40 °C can produce sidewall buckling. The operational boundary for this sector is a maximum continuous melt temperature of 205 °C; above that threshold, parison melt strength declines sufficiently to cause fold defects at the handle inset.
Integrating post-consumer recycled high-density polyethylene into industrial carboy production narrows the melt temperature window because the PCR fraction carries variable melt flow rate from 0.3 g/10 min to 1.0 g/10 min when tested according to ISO 1133-1:2022 at 190 °C/2.16 kg. A blend of 70 wt% DMDB-6240 NT 7 and 30 wt% washed, sorted post-consumer HDPE is fed by a gravimetric blender with a tolerance of ±0.5 wt% into an 80 mm single-screw extruder equipped with a barrier mixing zone and L/D 30:1. The melt temperature is bounded between 188 °C and 196 °C; excursions above 196 °C cause outgassing from residual paper label adhesives and a drop in melt strength, while excursions below 188 °C generate unmelted gels that appear as seed particles in the pinch-off weld. Vacuum venting at −0.08 MPa and a 60/80/100 mesh screen pack remove low-level contamination, but the back pressure must not exceed 20 MPa to avoid excessive shear heating. PCR streams containing polypropylene contamination above 3 wt% are rejected because immiscible PP domains create laminar delamination at the pinch-off weld during UN drop loading.
The accumulator-head die gap is programmed from 2.0 mm to 6.0 mm across the parison length for a 50 L tight-head carboy with a target mass of 2.8–3.2 kg. Drop testing of the finished carboy under Packing Group II conditions requires a minimum sidewall thickness of 1.5 mm at the lower chime and 1.8 mm at the top load-bearing shoulder; moulders add a post-cooling cycle of 10–15 s at 0.4 MPa internal pressure to reduce post-mould shrinkage. Where PCR fraction exceeds 30 wt%, published data for this specific container configuration is limited, and line qualification is required under the relevant UN drop and leakproofness schedule. The terminal product is a 50 L tight-head or open-head carboy used for water treatment polymers, emulsion breakers and industrial cleaning concentrates, marked according to UN 3H1 or 3H2 as applicable.
Liquid water treatment chemical packaging in 20 L and 25 L returnable containers is a harsher ESCR environment than household bleach because the contents often include quaternary ammonium compounds, polyaluminium chloride residues, or cationic flocculants that can wet the inner wall for extended periods. Moulders using DMDB-6240 NT 7 for this sector typically run continuous-extrusion shuttle machines with a 55–65 mm screw, L/D 24:1, and divide the tooling into 2+2 cavity configurations to balance clamp force. Melt temperature is set at 185–200 °C, and the parison die gap is widened to 2.2–3.0 mm because the containers require a heavier base and threaded bung area for secure valve fitments. The formulation is 90 wt% virgin resin, 10 wt% inspected post-industrial regrind, and blue masterbatch at 1.0–1.5 wt%; antistatic packages are not used unless the container is specified for flammable liquids. The moulding line includes a post-mould deflash station that removes the handle slug and tail flash, with the regrind stream screened through a 3 mm granulator screen to preserve particle size consistency.
The finished 25 L returnable container, typically weighing 1,300–1,500 g, is tested for ESCR by ASTM D1693 condition A and must resist cracking beyond 500 h under internal stress from a threaded closure torque of 5 N·m. The container is then fitted with a 50 mm bung closure and a viton gasket, and used for water treatment programmes in cooling towers, reverse osmosis systems and boiler feed lines. The operational limit for returnable-container washing is chemical sanitation at 60 °C for 15 min; prolonged exposure to oxidising sanitizers above 200 ppm active chlorine can reduce ESCR life and should be qualified on a line-specific basis.
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Dow HDPE DMDB-6240 NT 7 is a high-density polyethylene blow molding resin supplied as natural-colored pellets. Typical datasheet values include a melt index of 0.25 g/10 min at 190°C/2.16 kg per ASTM D1238 and a density of 0.962 g/cm³ per ASTM D792. The melt index places the material in the high-viscosity segment of the extrusion blow molding range, which improves parison hang strength but limits melt flow into narrow tooling gaps. The density is above the general-purpose HDPE blow molding range of 0.955 g/cm³ to 0.960 g/cm³, increasing crystallinity, flexural stiffness, and top-load capability while reducing environmental stress-cracking resistance compared with lower-density grades. The product is not a film-grade resin and is not intended for injection molding; its molecular weight distribution and melt strength are adjusted for continuous shuttle and accumulator-head blow molding processes.
In continuous shuttle blow molding, gravitational sag of the parison is controlled by melt viscosity and parison length. Because DMDB-6240 NT 7 has a melt index of 0.25 g/10 min, sag is lower than that of a 0.40 g/10 min grade at the same melt temperature. The trade-off is higher die-head pressure and greater shear heating within the extruder. On a reciprocating screw or shuttle line with a 24:1 to 30:1 L/D barrier screw, screw speed is often limited by melt-temperature rise rather than by motor amperage. Melt temperatures are maintained between 190°C and 230°C; the upper limit is set by surface gloss loss and molecular degradation, while the lower limit is set by melt fracture and unmelts at the die entry.
Die-gap settings are larger than those used for lower-viscosity HDPE because parison swell increases as the melt index decreases. Typical HDPE blow molding swell ratios can range from 1.2 to 1.5, but the exact value depends on die land length, shear rate, and melt temperature. A wider die gap reduces die-head pressure and the incidence of melt fracture, but it raises the final wall thickness unless parison programming compensates by closing the gap before pinch-off. Plants that transition from a lower-viscosity HDPE to this grade should expect die-head pressure to increase at constant output and should verify that tooling and accumulator seals are rated for the higher pressure.
Blow air pressure is typically set between 0.6 MPa and 1.0 MPa. Mold temperature is held between 10°C and 30°C to freeze the inner surface and stabilize cycle time. Higher mold temperatures may improve surface finish but increase cycle time; lower mold temperatures can create condensation-related surface imperfections if the mold surface drops below the dew point. HDPE does not require desiccant drying under normal indoor storage because moisture absorption is low. However, condensation on cold pellet surfaces transferred into a warm production area can create surface defects. Drying at 80°C for 2 h is applied when the resin has been stored below the dew point or when relative humidity has exceeded 60%.
Accumulator-head machines are used for larger containers, typically above 5 L. The melt is plastified and stored in the head before a rapid shot pushes the parison through the die. For DMDB-6240 NT 7, the accumulator shot must overcome the high flow resistance of the die tooling. Head pressure during the shot can exceed 25 MPa depending on die gap and accumulator speed; the exact value is equipment-specific. If the accumulator hydraulic system cannot maintain shot speed under this pressure, parison length can vary, leading to insufficient pinch-off flash or heavy base flash.
Mechanical properties reported for this grade are normally generated on compression-molded or injection-molded plaques, not on blow molded containers. Tensile yield stress is measured per ASTM D638, flexural modulus per ASTM D790, and impact strength per ASTM D256. These values define the resin property envelope but do not directly predict bottle top-load performance. A container sidewall inherits the resin modulus, but the failure location in service is usually the pinch-off weld, not the uniform-wall region. Therefore, bottle-level validation must include top-load testing at controlled deflection, drop testing at defined filling levels, and environmental stress-cracking exposure under the actual liquid or surrogate. Wall-thickness measurements made with a magnetic or Hall-effect gauge across the bottle profile are required to correlate finite-element sidewall predictions with molded reality.
| Parameter | Method | Value |
|---|---|---|
| Melt index | ASTM D1238 | 0.25 g/10 min (190°C/2.16 kg) |
| Density | ASTM D792 | 0.962 g/cm³ |
| Physical form | — | Pellets |
At 0.962 g/cm³, the density-driven increase in crystallinity may raise flexural modulus and tensile yield stress, but the notched impact strength at low temperature is generally lower than for lower-density HDPE. For freezer-grade packaging, the resin may require a lower-density alternative or an impact modifier. Low-temperature brittleness is measured per ASTM D746; published data for this specific configuration is limited in public sources. If the application requires drop impact at -20°C, bottle-level testing is necessary because plaque data do not capture wall-thickness distribution or pinch-off weld quality.
DMDB-6240 NT 7 differs from lower-density blow molding HDPE primarily through the 0.962 g/cm³ density. In the density range from 0.950 g/cm³ to 0.965 g/cm³, flexural modulus increases with density, while environmental stress-cracking resistance under ASTM D1693 Condition A generally decreases as density increases. The relationship is monotonic but not linear across all catalyst systems and molecular weight distributions; published data for this specific configuration is limited to the manufacturer’s technical data sheet. For fixed bottle mass, the higher modulus allows a thinner wall to meet a given top-load requirement, but the thinner wall may increase the average stress in the sidewall during drop or stacking and reduce the time to crack initiation when a stress-cracking fluid is present. Compared with a 0.955 g/cm³ blow molding grade, the resin is more appropriate for rigid packaging where stiffness governs and less appropriate for aggressive surfactant-containing liquids unless end-use ESCR validation is performed.
Compared with high-flow injection molding HDPE grades with melt indices above 20 g/10 min, the 0.25 g/10 min melt index is not suitable for thin-wall injection molds. Injection molding requires low melt viscosity to fill narrow channels and minimize orientation-induced warpage; this grade would require high injection pressures and could freeze off before full packing. Conversely, film-grade HDPE with melt indices below 1 g/10 min may appear rheologically similar, but the molecular weight distribution and die swell behavior are optimized for blown film bubble stability, not for parison programming. The use of DMDB-6240 NT 7 should therefore be restricted to extrusion blow molding and associated processing routes such as parison blow molding of containers, not to film or injection applications.
| Material class | Density | Melt index | Primary process |
|---|---|---|---|
| DMDB-6240 NT 7 | 0.962 g/cm³ | 0.25 g/10 min | Extrusion blow molding |
| Lower-density HDPE blow molding | 0.955 g/cm³ to 0.960 g/cm³ | 0.20 g/10 min to 0.40 g/10 min | Extrusion blow molding |
| High-flow HDPE injection molding | 0.952 g/cm³ to 0.965 g/cm³ | 20 g/10 min to 50 g/10 min | Injection molding |
Potential use in food packaging requires evaluation under FDA 21 CFR 177.1520 for olefin polymers used in contact with food, with temperature and food-type limitations derived from the final article. In the European Union, plastic food-contact materials are assessed under Regulation (EU) No 10/2011 as amended, with migration testing conducted in defined food simulants. The resin supplier can provide regulatory status statements for the neat resin, but the converter remains responsible for the final fabricated article because regrind levels, color concentrates, and processing aids alter the overall migration profile. Containers produced from this density class are typically monolayer rigid packages for still water, pasteurized milk, juices, and selected personal-care products. The material is not suitable for carbonated-beverage containers where gas barrier is critical because HDPE has a higher permeation rate than PET and will allow carbonation loss.
For household chemical or detergent packaging, chemical compatibility must be verified with the filled product at the maximum storage temperature. HDPE of 0.962 g/cm³ density may tolerate many aqueous acids and bases at room temperature, but stress-cracking can occur with nonionic surfactants, essential oils, or high-fragrance formulations. Standard ASTM D1693 data provides a screening value only; the actual bottle should be tested with the intended liquid, cap torque, and stacking load. The pinch-off weld line is the typical failure site in burst and drop tests, and top-load performance depends on shoulder and base geometry as well as thickness distribution. No single resin property determines bottle performance; the conversion process and design must be included in the evaluation.
Production-scale extrusion blow molding with this grade requires parison programming control that responds to die swell and melt-temperature drift. The die gap profile is adjusted to place material at the shoulder and base, and the parison length is trimmed to avoid excessive flash at the pinch-off. When the melt temperature drifts above 230°C, the parison can develop longitudinal draw marks and the bottle surface can exhibit high gloss with reduced toughness; when the melt temperature drops below 190°C, the surface can show melt fracture and the pinch-off weld can be incomplete. These are process boundaries, not resin specification limits, and they must be verified on the specific blow molding machine. Batch-to-batch variation within the supplier’s melt index specification is generally low enough for stable continuous operation, but a silo change should be followed by a die-head pressure check and parison length verification before high-speed production resumes.
Thermal degradation of HDPE occurs through chain scission and oxidation. At melt temperatures above 230°C, the melt index can increase and molecular weight can decrease. The residence time in the accumulator head or manifold should be minimized at the upper temperature limit. Long residence times at high temperature lead to gel formation, black specks, and a drop in melt viscosity. The grade should not be combined with incompatible regrind streams such as polypropylene or EVOH because incompatible domains can form at the pinch-off weld and reduce burst strength. Melt temperature should be measured with an immersion thermocouple at the die head rather than relying on barrel setpoints, because shear heating can raise the actual melt temperature by 10°C to 20°C above the barrel settings.
Regrind of DMDB-6240 NT 7 can be reused in monolayer blow molding where the end-use application permits rework. The maximum regrind level is set by bottle-level ESCR, impact performance, and food-contact status, not by a universal resin specification. If regrind is used, it should be free of fines and contamination, and the melt index should be checked periodically to ensure that the blended feedstock remains within the processing window. When post-consumer or mixed-source regrind is used, migration testing may be required to maintain compliance with FDA 21 CFR 177.1520 or Regulation (EU) No 10/2011.