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Dow ELITE mLLDPE 5220G

    • Product Name: Dow ELITE mLLDPE 5220G
    • Factroy Site: Yudu County, Ganzhou, Jiangxi, China
    • Price Inquiry: sales8@ascent-chem.com
    • Manufacturer: Ascent Petrochem Holdings Co., Limited
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    Specifications
    HS Code 652904
    Polymer Type Metallocene Linear Low Density Polyethylene (mLLDPE)
    Comonomer Octene
    Density 0.920 g/cm³
    Melt Index 190 C 2 16 Kg 1.0 g/10 min
    Melt Flow Ratio I10 I2 25
    Melting Point 122 °C
    Vicat Softening Point 100 °C
    Tensile Strength At Break Md 40 MPa
    Tensile Strength At Break Td 35 MPa
    Elongation At Break Md 500%
    Elongation At Break Td 600%
    1 Secant Modulus Md 200 MPa
    1 Secant Modulus Td 220 MPa
    Dart Impact Strength 210 g
    Elmendorf Tear Strength Md 170 g
    Elmendorf Tear Strength Td 400 g
    Haze 8%
    Gloss 45 60

    As an accredited Dow ELITE mLLDPE 5220G factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing Dow ELITE mLLDPE 5220G is packaged in 25 kg polyethylene bags, typically shipped as 1,000 kg pallets.
    Container Loading (20′ FCL) Dow ELITE mLLDPE 5220G loaded in 25 kg bags into a 20′ FCL container, palletized and secured for safe ocean transport.
    Shipping Dow ELITE mLLDPE 5220G is a non-hazardous polyethylene resin supplied as pellets in moisture-proof bags or octabins. Ship in clean, dry, covered transport at ambient temperature, avoiding direct sunlight, heat, and moisture. Not classified as dangerous goods; follow standard polymer handling and local shipping regulations.
    Storage Store Dow ELITE mLLDPE 5220G resin in a cool, dry, well-ventilated area away from direct sunlight, heat, ignition sources, moisture, and oxidizers. Keep original containers/packages closed and labeled; prevent dust generation and environmental release. Avoid prolonged high temperatures. Use first-in/first-out stock rotation, inspect packaging, and maintain good housekeeping to prevent spills and slipping hazards.
    Shelf Life Dow ELITE mLLDPE 5220G typically has a shelf life of 24 months from date of manufacture under recommended storage conditions.
    Application of Dow ELITE mLLDPE 5220G

    In three-layer cast pallet stretch film, ELITE 5220G is introduced into the two outer skin layers at 10–25 wt% of total throughput, while the core layer carries a higher-density LLDPE or a lower-MI metallocene LLDPE for load retention. The resin has a nominal density of 0.915 g/cm³ by ASTM D792 and a melt index of 3.5 g/10 min at 190°C/2.16 kg by ASTM D1238. On 30:1 L/D single-screw cast film extruders with barrier screws, melt temperature is maintained at 240–255°C; exceeding 260°C accelerates gel formation in the narrow-MWD resin. Die gap is set at 0.6–0.8 mm, air gap at 8–12 mm, and chill roll temperature at 18–24°C. Vacuum box pressure is trimmed to −0.2 to −0.5 kPa to eliminate air entrapment and thickness bands. Because the shear viscosity profile of metallocene LLDPE is more Newtonian than that of Ziegler-Natta LLDPE, die pressure at equivalent screw speed can drop; this requires tighter melt pump control if a gear pump is installed upstream of the die.

    Puncture resistance measured by ASTM D5748 and Elmendorf tear measured by ASTM D1922 are the critical release criteria for pallet wrap. Cling force is controlled by 1–3 wt% polyisobutylene in the skin layer and measured by ASTM D5458 at 23°C/50% RH; antiblock is added to the opposite skin at 1000–3000 ppm. Storage of finished rolls above 40°C accelerates PIB migration and can produce cling force drift; published data for 5220G-specific storage stability are limited. Cold storage below 10°C retards migration and is specified for long-term inventory. The low gel count of 5220G is verified by camera-based gel analysis per ASTM D7310, but die lip deposit formation remains a production bottleneck when PIB levels exceed 3 wt% and run time exceeds 8 hours. Line operators purge with a higher-viscosity LLDPE after visual inspection detects edge die drool.

    On high-speed wrappers, pre-stretch is commonly set between 200% and 300%. Above 300%, films containing high PIB levels can show localized yielding and transverse gauge bands if gauge variation exceeds ±2 µm across a 500 mm web. The usable pre-stretch range is determined by the difference between yield stress and ultimate tensile stress measured by ASTM D882; a narrow difference limits elastic recovery and promotes permanent deformation. Capacitance thickness gauges are positioned after the chill roll to control gauge to ±1.5 µm in high-speed cast lines. Film runs with 5220G in skin layers are evaluated by ASTM D1709 Method A; published comparative data for this specific grade are limited.

    Why Does Stretch Hood Film Demand Controlled Puncture Propagation Energy Instead of High Dart Impact Alone?

    Stretch hood film used in pallet unitization is oriented in both machine and transverse directions and must resist tear propagation when the hood is pulled over sharp pallet corners. ELITE 5220G is evaluated as a skin-layer modifier in three-layer blown film lines with die diameter 250–350 mm, blow-up ratio 2.8–3.2, and frost line height 600–900 mm. Published loading data for 5220G in commercial stretch hood structures are limited; converters commonly blend 15–25 wt% with a higher-density LLDPE to maintain stiffness while improving Elmendorf tear in MD per ASTM D1922. Puncture propagation resistance is tested by ASTM D5748, and tensile properties are measured by ISO 527-3:2018 with elongation at break control limits above 600%. The narrow molecular weight distribution of 5220G reduces melt pressure in the die; however, bubble stability is lower than that of broad-MWD LLDPE, so output on blown lines is often limited by bubble respiration rather than extruder capacity.

    Cold-climate load retention is assessed by drop-puncture testing at −10°C using ASTM D5748 with a 19 mm probe; film thickness is generally held between 80 and 140 µm. If the hood is applied at high speed on automatic machines, the film must not split at the gusset folds. A practical control is to track TD tear energy and puncture resistance; published minimum values for 5220G-containing hood films are limited. Processors set frost line height to stabilize bubble symmetry, because asymmetric cooling produces TD gauge error and local stress points at pallet corners. Film gauge is monitored by contact or capacitance sensors and maintained at ±5 µm across the web width.

    For silage wrap film, ELITE 5220G is converted into 25–30 µm cast or blown film with high puncture resistance and UV stabilization. The resin is blended with 10–20 wt% LDPE to improve bubble stability on blown lines where frost line height is constrained; on cast lines, the LDPE fraction also modifies cling and unwind behavior. UV protection is achieved with hindered amine light stabilizer packages at 0.4–0.8 wt% and titanium dioxide or carbon black to block photosynthetically active radiation. Oxygen transmission rate is measured by ASTM D3985 at 23°C/0% RH; for a 25 µm film, the target is typically below 8000 cm³/m²·day·atm to limit aerobic spoilage, but published data for 5220G in this exact gauge are limited. The European standard EN 13206 specifies tensile, puncture, and UV requirements for agricultural covering films; converters evaluate 5220G formulations against the specific grade class in that standard. Storage of finished rolls above 35°C or exposure to direct sunlight on the silage clamp can reduce cling and puncture resistance before application.

    The silage film must retain stretch after outdoor exposure. Accelerated weathering tests are conducted according to EN 13206 or ISO 527-3 after 2000 hours of UV exposure; property retention below 70% of original elongation triggers reformulation. High-cling formulations for bale wrapping use slip additives such as erucamide at 500–1500 ppm, but excessive slip can reduce adhesion to the bale and cause unwinding failure in automatic wrappers. Film width is controlled to 250 mm, 500 mm, or 750 mm depending on bale diameter. Published data for 5220G in multi-season silage wraps remain limited; converter trials evaluate tensile retention and puncture resistance under actual silage clamp conditions.

    When Sealant Web Hot-Tack Determines Vertical Form-Fill-Seal Throughput

    Lamination sealant webs for dry food packaging use ELITE 5220G as a cast sealant layer because the sealing initiation temperature, measured by ASTM F1921 at 0.5 s dwell and 2.0 bar pressure, is reported in industrial data to be in the 90–105°C range; published values for 5220G specifically are limited. Seal strength measured by ASTM F88/F88M-21 at 135°C seal temperature and 0.5 s dwell typically exceeds 15 N/25 mm for a 40 µm web, but this depends on lamination adhesive and substrate. Food contact compliance is established under FDA 21 CFR 177.1520 for olefin polymers and EU Regulation No 10/2011 with specific migration limits for non-volatile substances. Converters run the sealant web on cast lines with 0.5–0.7 mm die gap and maintain melt temperature below 245°C to limit off-odor formation in the sealant layer. The hot-tack window narrows if adhesive migration into the sealant layer occurs; roll storage is specified at maximum 35°C and below 60% RH before slitting. Pre-drying after open silo storage is required when ambient RH exceeds 60% for more than 12 hours to prevent hydrolysis-induced specks.

    Low-Gel Lamination Film and Peelable Interface Stability

    In furniture and textile lamination, industrial film requires controlled interfacial adhesion and low gel content to avoid visible surface defects. ELITE 5220G is used as the sealant or bulk layer in coextruded films where peel adhesion to EVA or EMA tie layers is tested by ASTM D3330/D3330M Method A on stainless steel at 180° peel angle. The resin’s low gel count, quantified by ASTM D7310 or film quality cameras, supports lamination of heat-sensitive substrates at line speeds up to 150 m/min. The melt index of 3.5 g/10 min permits lower melt temperatures in the outer die zones, reducing thermal stress on substrates. REACH and RoHS compliance is documented under Regulation (EC) No 1907/2006 and Directive 2011/65/EU. Compatibility with tie resins containing maleic anhydride-grafted polyolefins is typical; amine-based additives should be avoided because they can interact with residual catalyst components and generate visible discoloration in high-temperature cast film. Pre-drying is required when ambient RH exceeds 60% and the resin has been stored in open silos for more than 12 hours, because surface moisture can generate hydrolysis-induced specks in cast films.

    Cast film lines running lamination grade 5220G must control interfacial stress in the die to prevent optical defects. Die temperatures are set in a narrow band of 240–250°C across the die width; differences greater than ±5°C produce thickness variation and transverse stress marks. The air gap is set at 10–14 mm for lamination film to reduce neck-in and improve film flatness. Adhesion to EVA tie layers is sensitive to chill roll temperature; if the chill roll is below 18°C, the sealant layer may develop surface haze and reduced peel strength. The film is wound at contact pressure below 0.4 N/mm² to prevent blocking of the tacky sealant surface. These processing limits are derived from equipment manufacturer technical bulletins for metallocene LLDPE cast film; published data for 5220G in specific lamination structures are limited.

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    Certification & Compliance
    More Introduction

    Dow ELITE mLLDPE 5220G is a single-site catalyzed ethylene-octene copolymer supplied as free-flowing pellets for blown film extrusion. The nominal density is 0.916 g/cm³ when measured according to ASTM D792, and the melt index is 2.0 g/10 min at 190 °C under a 2.16 kg load as specified in ASTM D1238. The resin is manufactured using INSITE™ catalyst technology, which produces a narrow molecular weight distribution and a more uniform octene comonomer distribution than conventional Ziegler-Natta linear low-density polyethylene. Typical end uses include monolayer and coextruded packaging films, frozen food and ice bags, high-toughness liners, lamination films, and structures where downgauging or optical performance is specified. The material is generally processed on blown film lines without routine desiccant drying, but surface moisture control after outdoor storage is recommended. The product is typically supplied without slip and antiblock additives; surface coefficient of friction and blocking resistance are adjusted on the film line with masterbatch additions at 2-5 wt%.

    What Distinguishes mLLDPE 5220G from Conventional C8-LLDPE Resins?

    Molecularly, 5220G differs from heterogeneously branched C8-LLDPE in the distribution of short-chain branching. Conventional Ziegler-Natta C8-LLDPE contains a broad interchain comonomer distribution; the higher-molecular-weight chains are often less branched, forming crystallites that elevate haze and restrict sealability. In 5220G, the comonomer is incorporated more uniformly, which lowers the melting peak relative to a Ziegler-Natta C8-LLDPE of equal density and shifts the seal-initiation temperature downward. The narrow molecular weight distribution also reduces shear-thinning response. On a blown film extruder with a 24:1 L/D barrier screw and an 80 mm annular die, the head pressure at fixed screw speed may exceed that of a broad-MWD Ziegler-Natta C8-LLDPE of equivalent melt index by 10-30%, depending on melt temperature and die gap. The lower melt strength compared with LDPE requires attention to bubble stability. In practice, 10-30 wt% of a high-pressure LDPE is often blended to improve bubble stability and gauge uniformity. The blend ratio is adjusted on the film line to balance the desired dart impact and tear resistance against stable neck geometry.

    Within the ELITE family, 5220G is positioned as a higher-flow complement to lower-melt-index products such as 5400G at a nominal 1.0 g/10 min. The higher melt index of 5220G favors thin-gauge film and higher throughput, while it may sacrifice some dart impact and melt strength relative to the lower-flow product. Compared with C4-LLDPE, the octene comonomer architecture provides higher tear and puncture resistance at equivalent density. Compared with high-pressure LDPE, 5220G offers lower haze and higher tensile strength, but it does not reproduce the high melt strength and bubble stability of LDPE in deep-draw or large-bubble processes.

    Blown Film Extrusion Parameters and Equipment Requirements

    Processing is typically carried out on single-screw extruders with L/D from 24:1 to 30:1, compression ratios of 2.5:1 to 3.5:1, and barrier screws with a low-shear mixing section. Die gaps between 1.8 mm and 2.5 mm are common for monolayer film, while blow-up ratios of 2.0:1 to 2.8:1 and melt temperatures of 190 °C to 220 °C are typical. Barrel settings should not exceed 230 °C for extended periods because thermo-oxidative degradation can produce gel defects and reduce film toughness. If pellets are stored in humid conditions with surface moisture above 0.1%, a hopper dryer at 60-70 °C for 2 h reduces visible moisture. Internal bubble cooling reduces frost-line height and improves output by 15-25% when compared with single-stack air cooling, provided the IBC exhaust temperature does not exceed 45 °C.

    Rheologically, 5220G displays a flatter shear-viscosity curve than high-pressure LDPE. On a capillary rheometer according to ISO 11443, the flow curve is closer to an ideal linear polymer. Since increasing screw speed does not lower melt viscosity as rapidly as with LDPE, specific energy input and melt temperature require monitoring. In coextruded structures, this flatter viscosity profile can stabilize layer thickness when paired with a more shear-thinning skin resin.

    Coextrusion lines running 5220G in a skin layer with an adjacent LDPE or tie layer require independent melt-temperature control on each extruder. On a 3-layer die fed by 50 mm, 60 mm, and 50 mm extruders, a 20 wt% addition of 5220G to the middle C8-LLDPE layer has been used to maintain dart impact when the total structure is reduced from 50 µm to 40 µm. The film is tested according to ASTM D1709 Method A. Published data for this specific configuration is limited, and the property response depends on die gap, frost-line height, and the amount of LDPE in the skin layer.

    When Downgauging Mono- or Coextruded Structures with 5220G

    Downgauging trials on blown film equipment evaluate tensile, tear, and dart impact properties. ASTM D1709 Method A is used for dart impact; a 25 µm film made from 5220G typically demonstrates dart impact values in the 300-600 g range, while a comparable C4-LLDPE may require a thicker gauge to reach the same impact. Elmendorf tear measured according to ASTM D1922 is orientation-dependent; changing the BUR from 2.0:1 to 3.0:1 can shift the MD/TD tear balance by 10-40%. Tensile properties are measured according to ASTM D882 at 500 mm/min. The MD and TD tensile stress values in blown film usually differ by 10-30% due to anisotropic orientation; adjusting BUR and take-off ratio can rebalance the orientation. Puncture resistance according to ASTM F1306 improves as the octene content increases, but the numerical gain is governed by film gauge and sealant layer thickness. In practice, replacing a C4-LLDPE layer with 5220G can permit a gauge reduction of 10-20% while retaining dart impact and tear resistance. Published data for this specific configuration is limited.

    Seal initiation and hot-tack stability are evaluated on vertical form-fill-seal equipment using a dwell time of 0.5 s and a sealing pressure of 0.4 MPa. Hot-tack force is measured according to ASTM F1921 at 150 mm/s peel speed. The uniform comonomer distribution of 5220G produces a seal-initiation temperature between 95 °C and 105 °C in monolayer film, which is lower than typical LDPE-rich structures and supports higher packaging speeds on VFFS machines. Haze is measured according to ASTM D1003 and gloss at 45° according to ASTM D2457; a 25 µm film typically exhibits haze below 8% and gloss above 60, though these values are affected by cooling conditions and die gap. Coefficient of friction is tested according to ASTM D1894 and is controlled by masterbatch addition rather than the base resin.

    Property Ranges Reported After Conditioning at 23 °C and 50% RH

    Representative values for 25 µm blown film are summarized below. These values are not batch specifications and are dependent on die gap, BUR, and frost-line conditions.

    PropertyTest methodTypical rangeProcessing condition
    Resin densityASTM D7920.916 g/cm³Base pellet
    Melt indexASTM D12382.0 g/10 min190 °C, 2.16 kg
    Dart impactASTM D1709 Method A300-600 g25 µm, BUR 2.5:1
    HazeASTM D10035-8%25 µm, BUR 2.5:1
    Gloss at 45°ASTM D245760-8025 µm, BUR 2.5:1
    Seal initiation temperatureASTM F192195-105 °C25 µm monolayer

    How U.S. and EU Food-Contact Status Is Established for This Resin

    The regulatory status is determined under the applicable food-contact frameworks. The following table lists the principal compliance positions.

    RegulationCitationCondition
    U.S. FDA21 CFR 177.1520(c) 3.2aOlefin polymers for food-contact articles, subject to end-use limitations
    European UnionRegulation (EU) No 10/2011Plastic materials and articles intended for food contact
    REACHRegulation (EC) No 1907/2006, Article 2(9)Polymer exemption; monomer and additive registration required
    RoHSDirective 2011/65/EUNo inherently restricted substance class in PE; final article evaluation required

    Continuous outdoor service is not recommended without stabilization. For agricultural or construction films, a hindered amine light stabilizer masterbatch at 3-5 wt% or carbon black at 2-3 wt% is typically required. Strong oxidizing agents and chlorinated solvents at elevated temperature can degrade molecular weight. Pellets should be stored in dry conditions below 30 °C and 50% relative humidity to maintain flow consistency.

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