| HS Code | 720039 |
| Product Name | deTerra XP758-V0 Extrusion Flame Retardant Biodegradable Polylactic Acid |
| Brand | deTerra |
| Grade | XP758-V0 |
| Manufacturer | Mitsubishi Chemical Corporation |
| Material Base | Polylactic Acid (PLA) |
| Processing Method | Extrusion |
| Flame Retardant | Yes |
| Biodegradable | Yes |
| Compostable | Yes (EN 13432 compliant) |
| Density | 1.35 g/cm³ |
| Melt Flow Rate | 8 g/10 min at 190°C/2.16 kg |
| Melting Temperature | 170-180°C |
| Tensile Strength | 50 MPa |
| Tensile Modulus | 3500 MPa |
| Elongation At Break | 3% |
| Flexural Modulus | 4000 MPa |
| Flexural Strength | 80 MPa |
| Notched Charpy Impact | 3 kJ/m² |
| Heat Deflection Temperature | 55°C at 0.45 MPa |
| Vicat Softening Temperature | 60°C |
| Flammability Rating | UL 94 V-0 |
| Glow Wire Flammability Index | 960°C |
| Biobased Content | >50% |
| Moisture Absorption | 0.2% |
| Mold Shrinkage | 1.2-1.4% |
| Drying Temperature | 80°C |
| Drying Time | 4 hours |
| Recommended Melt Temperature | 170-190°C |
| Form | Pellets |
| Color | Natural |
As an accredited deTerra XP758-V0 Extrusion Flame Retardant Biodegradable Polylactic Acid factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.
| Packing | deTerra XP758-V0 is packaged in 25 kg foil-lined, moisture-barrier paper sacks, palletized and shrink-wrapped for safe transport. |
| Container Loading (20′ FCL) | Container Loading (20′ FCL): deTerra XP758-V0 Extrusion Flame Retardant Biodegradable Polylactic Acid, palletized in 25 kg bags, shrink-wrapped, and secured. |
| Shipping | deTerra XP758-V0 ships as a solid polymer compound in sealed 25 kg moisture-barrier bags, palletized and stretch-wrapped. Transport classification per current SDS; typically not DOT/IMDG/IATA regulated. Label with product name, lot, and net weight. Keep dry, avoid heat, contamination, excessive stacking. Use standard freight. Provide SDS and emergency contact information. |
| Storage | Store in a cool, dry, well-ventilated warehouse away from direct sunlight, heat, sparks, and open flames. Keep original containers tightly sealed to prevent moisture uptake. Protect from humidity, water, and strong oxidizers. Use pallets, avoid excessive stacking, and follow FIFO. Recommended storage below 30°C, with adequate ventilation and dust control. Store separately from incompatible materials; maintain clean, labeled containers and spill containment. |
| Shelf Life | Store sealed in a cool, dry place away from moisture and heat; shelf life is approximately 12 months from manufacture. |
deTerra XP758-V0 Extrusion Flame Retardant Biodegradable Polylactic Acid is fed directly into single-screw profile lines for slotted cable trunking, DIN-rail wiring duct, and control panel cable channels. The material must be dried in a desiccant dryer at 80°C for 4 h to a residual moisture level below 250 ppm; exposure to ambient air above 60% RH for more than 30 min is sufficient to reintroduce surface moisture and initiate hydrolysis in the melt. Extruder configuration uses an L/D ratio between 24:1 and 30:1, a compression ratio between 2.5:1 and 3.0:1, and a barrel temperature profile from 160°C in the feed zone to 190°C in the metering zone, with die temperature held at 195°C. Melt flow rate is checked under ISO 1133-1:2022 at 190°C and 2.16 kg; material with MFR below 2 g/10 min generates shear heating in thin walls, while material above 8 g/10 min tends to sag in open profiles. A screen pack of 60/80/120 mesh is installed to trap char particles generated by the flame retardant system, and the pressure drop across the pack is monitored because blockage raises melt temperature and accelerates depolymerization. Profile wall thickness is maintained at 1.5 mm or greater; the UL 94 V0 classification is valid only at the thickness recorded in the supplier's UL yellow card and must be revalidated if the finished article is thinner. Colour masterbatch using a PLA carrier is limited to 2 wt%; PE-carrier or EVA-carrier masterbatch is incompatible because it depresses anti-drip behaviour. Regrind from in-process start-up scrap is limited to 10 wt% without re-certification. Regulatory documentation for exported control panel components routinely requires RoHS 2011/65/EU Annex II and REACH SVHC confirmation. If the trunking is installed in rail vehicles, the completed assembly must be evaluated under EN 45545-2 for the assigned hazard level and the relevant R-group; the base PLA compound cannot be presumed to satisfy smoke density and gas toxicity limits without full article testing.
During conversion of the compound into 2.0 mm flat sheet for point-of-sale terminal backplates, converter-box side panels, and internal electronics barriers, the primary process conflict is post-extrusion cooling and edge stress rather than melt pumping. The sheet die is fed from a single-screw extruder at a melt temperature of 190–200°C, and the web is conditioned on a three-roll polishing stack with bottom roll at 30°C, middle roll at 45°C, and top roll at 60°C to control curl. Plate-out from the phosphorus-based flame retardant system collects on the polishing roll surface and is removed with a non-abrasive PLA purging grade; PE purging compounds should not be used because residual contamination can compromise UL 94 V0 results. Sheet is routed or die-cut after conditioning at 23±2°C and 50±5% RH for 24 h; cutting below 15°C produces local stress whitening and a higher probability of crack propagation at mounting holes. Electrical safety evaluation of the finished enclosure under IEC 62368-1 requires material flammability assessment as part of the final assembly; UL 94 V0 on the raw sheet is necessary but not sufficient. Long-term thermal exposure for PLA compounds remains bounded by the heat deflection temperature of the base resin, which for unfilled PLA is typically near 55–60°C under 0.45 MPa load per ISO 75-2; internal components that operate above 55°C continuously should not be specified without additional heat ageing data. The industrial compostability claim is documentable only under EN 13432 for the final compounded article, not for the base polymer alone, because flame retardant additives may inhibit disintegration in industrial composting.
Extruded door harness wire retainers, A-pillar wiring clips, and under-dash HVAC air deflectors produced from this compound are specified where the interior flammability requirement is a horizontal burn rate not exceeding 100 mm/min under ISO 3795 or FMVSS 302. The critical processing difference is reduced hot melt strength caused by the flame retardant filler, which becomes visible as sagging in open U-channel profiles when die temperature exceeds 200°C. A vacuum sizing tank is operated at 0.6–0.8 bar vacuum with water temperature at 20–25°C; colder water below 18°C freezes the skin before crystallisation is complete and produces embrittled zones at sharp corners. Impact modification is added at 5–10 wt% only when rear clip insertion causes cracking, and the modifier masterbatch must be PLA-based; hindered amine light stabilisers are not recommended because amine-phosphorus acid-base interactions can reduce the char-forming chemistry responsible for V0. Service temperature is the main boundary: unannealed PLA compounds retain adequate modulus only up to roughly 55°C, while dark interior surfaces in solar soak can exceed 85°C. Under-dash parts are therefore confined to shaded lower-interior positions and must not be mounted on the upper instrument panel unless the compound is annealed at 80°C for 4 h and the tooling allowance is adjusted for 0.3–0.5% linear shrinkage. For mass transit interior applications, ISO 3795 does not provide smoke density or gas toxicity data; additional testing under ISO 5659-2 and EN 45545-2 is required before any rail or bus interior use.
In lithium-ion cell separator racks and workshop transport trays, the fire propagation path is not the only risk variable; dripping and afterglow are equally critical because burning droplets from a tray can ignite adjacent cells or paper packaging. The compound is processed into 3.0–4.0 mm solid or twin-wall sheet and thermoformed into racks with cell pockets. Extrusion uses a single screw with L/D of 30:1 at screw speeds between 30–50 rpm; melt temperature above 200°C with residence time beyond 5 min produces depolymerisation, brown streaking, and a loss of UL 94 skin integrity. The UL 94 V0 test under IEC 60695-11-10 is performed on specimens cut from the formed tray, not from the original sheet, because thermoforming can orient and thin the walls. Anti-drip behaviour depends on char formation; the char layer is friable and should not be removed by surface cleaning before testing because the UL 94 protocol evaluates the specimen as produced. Thermoforming requires sheet surface temperature between 90–110°C; below 85°C the sheet tears at deep draw corners, and above 120°C micro-bubbles form at the FR-rich surface. Compliance for battery logistics must distinguish between packaging and internal dunnage: UN 38.3 covers transport of lithium cells, but the tray material is not a UN package if used as internal handling dunnage; nevertheless the operator should hold a supplier UL 94 test report and, if available, an ASTM D1929 self-ignition temperature value. Published thermal-runaway response data for this specific compound is limited; end users should conduct their own full-thickness vertical burn tests on formed parts rather than extrapolating from flat sheet data. Regrind from thermoforming skeletons is limited to 10 wt% and must be dried with virgin material; regrind that has been exposed to carbonate-based battery electrolyte should not be reintroduced because solvent swelling degrades both mechanical strength and flame retardancy.
| Downstream operation | Melt or surface temperature | Moisture limit | Maximum regrind loading | Critical boundary |
|---|---|---|---|---|
| Profile extrusion | 190–195°C at die | <250 ppm | 10 wt% | Residence time below 5 min at ≤ 200°C |
| Flat sheet extrusion | 190–200°C at die | <250 ppm | 10 wt% | Chill roll plate-out; roll temperatures 30–60°C |
| Thermoforming | 90–110°C sheet surface | <300 ppm | 5 wt% | Tearing below 85°C; bubble formation above 120°C |
| CNC routing and die-cutting | Ambient 23±2°C | <300 ppm | Not applicable | Stress whitening if below 15°C |
For temporary exhibition stand panels, retail display slabs, and modular signage, the specification frequently combines a fire requirement for public assembly spaces with an end-of-life requirement for industrial composting. This compound is extruded into 2.0–3.0 mm sheet and CNC-cut into display components. Fire behaviour of the final panel is tested under UL 94 V0 at the extruded thickness; if the project requires surface spread of flame certification, ASTM E84 or EN 13501-1 testing on the complete sandwich or coated panel is mandatory because a UL 94 V0 rating does not automatically translate into a Class A or B interior finish classification. Compostability documentation must reference EN 13432 or ASTM D6400 for the compounded sheet, not for the base PLA resin; the flame retardant additive and any coloured masterbatch are part of the final material composition and can slow disintegration in an industrial composting cycle. The ratio of in-process regrind is held at 5–10 wt% because higher loadings increase surface pitting and reduce fire-test reproducibility. Extrusion is performed with a flat die and embossed roll to create a matte surface; the melt temperature at the die is 195–205°C, and the roll gap is set to produce sheet thickness tolerance within ±0.10 mm. Mechanical fastening is preferred over solvent bonding because cyanoacrylate adhesives and aggressive solvent cements can craze PLA at drilled holes, and crazed regions can fail the post-ageing UL 94 vertical burn test. The panel is limited to indoor service below 40°C continuous; direct sunlight or high-intensity stage lighting can soften the sheet and reduce structural stability long before flame retardant performance is affected.
Linear LED strip housings, diffuser holder profiles, and track lighting side covers are extruded from the compound where lamp insulation and flame protection requirements apply under IEC 60598-1. The dominant production issue is plate-out of the phosphorus-based flame retardant system at the die lip, which appears as longitudinal streaks and black specks when the die temperature is held at 190–195°C for more than 60 min. Die lip buildup is removed at intervals of 30–60 min, and a commercial PLA purging compound is run through the extruder at the end of the shift to reduce char accumulation in the screw root and adapter. A breaker plate with an 80/120 mesh screen pack is installed to filter unmelted additive particles; the pressure drop across the screen should be recorded because an increase above 100 bar indicates screen blockage and can drive melt temperature into the depolymerisation range. The compound is processed at 100% or with 1–2 wt% PLA-carrier colour masterbatch; external lubricants and waxes are avoided because they migrate to the surface and alter the UL 94 burn rate. Finished profile wall thickness is specified at 1.5 mm for V0-critical sections; diffuser wings below 1.0 mm may not reproduce V0 and must be tested at the thinnest cross-section. Glow wire testing under IEC 60598-1 or IEC 60335-1 may be required for live-part separation; PLA compounds without halogenated additives may not achieve a 750°C glow wire ignition temperature, so the supplier's glow wire report must be reviewed before design freeze. Cleaning agent compatibility is limited: ester-containing cleaners, glycol ethers, and acrylic adhesive removers can swell the profile and create surface defects that alter the flame propagation path. Extruded liners are cut to length and installed into aluminium channels where they separate wiring from the metal profile; the UL 94 classification applies only to the plastic article in its final thickness and mounting orientation.
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deTerra XP758-V0 is an extrusion-grade polylactic acid compound formulated with a halogen-free phosphorus–nitrogen intumescent flame retardant system. The material is supplied as cylindrical pellets and is intended for profile, sheet, and conduit extrusion where UL 94 V-0 vertical burn performance is required at 1.5 mm and 3.0 mm. Representative physical properties include a melt flow rate of 5.5 g/10 min at 190 °C/2.16 kg per ISO 1133-1:2022, a density of 1.23 g/cm³ per ISO 1183-1:2019, tensile yield stress of 47 MPa per ISO 527-2:2012, and Charpy notched impact of 3.8 kJ/m² per ISO 179-1:2023. The compound differs from unmodified PLA extrusion grades by higher melt viscosity, lower elongation at break, and the presence of an intumescent char-forming component.
Drying before processing is mandatory because PLA hydrolyzes rapidly at melt temperature when moisture exceeds 250 ppm. Pellets should be dried in a desiccant dryer at 80 °C for at least 4 h with an air dew point of -40 °C or lower. Hopper dryers using ambient air at RH > 60% do not reliably reach this moisture level. The recommended melt temperature at the die is 185 °C to 195 °C; temperatures above 205 °C for prolonged residence time cause decomposition of the phosphorus-based synergist, discoloration, and die plate-out. Avoid amine-based additives because amine functionality neutralizes the acidic phosphorus species and reduces flame retardant efficiency.
Hydrolytic degradation of PLA follows pseudo-first-order kinetics with respect to moisture content at melt temperature. For a melt temperature of 190 °C, the molecular weight reduction rate increases by approximately 2.5× when moisture rises from 150 ppm to 350 ppm. Equipment should therefore include closed-loop desiccant drying with dedicated hopper capacity matched to material consumption. A residence time of 4 h at 80 °C is the minimum; material stored in humid environments may require up to 6 h. The hopper throat should be blanketed with dry air at -40 °C dew point to prevent re-absorption before the feed zone.
Vertical burn classification is evaluated according to UL 94 with bar thicknesses of 1.5 mm and 3.0 mm after conditioning at 23 °C/50% RH for 48 h. The product achieves V-0 with no burning drips and afterflame times below the standard threshold. Limiting oxygen index measured per ISO 4589-2:2017 is reported as 29%. Heavy-metal restrictions are assessed using IEC 62321 digestion and detection protocols under Directive 2011/65/EU. Industrial compostability claims require ≥90% absolute mineralization after 180 days in aerobic composting at 58 °C under EN 13432; testing according to ISO 14855-1:2012 is used for biodegradation.
| Standard / method | Condition or scope | Result / classification |
|---|---|---|
| UL 94 | Vertical burn, 1.5 mm and 3.0 mm | V-0 |
| ISO 4589-2:2017 | Limiting oxygen index | 29% |
| ISO 527-2:2012 | Tensile yield stress, 5 mm/min | 47 MPa |
| ISO 179-1:2023 | Charpy notched impact, 23 °C | 3.8 kJ/m² |
| ISO 1133-1:2022 | Melt flow rate, 190 °C/2.16 kg | 5.5 g/10 min |
| EN 13432 | Industrial composting, 58 °C | ≥90% in 180 days |
The intumescent flame retardant fraction increases low-shear viscosity and imparts a more pronounced yield stress than unfilled PLA. Melt rheology at 190 °C shows shear-thinning behavior with a power-law index of approximately 0.55 between 100 s⁻¹ and 1000 s⁻¹. During profile extrusion through a 2.5 mm strand die, die pressure is typically 15% to 30% higher than unfilled PLA at the same throughput. This shift requires rebalancing of breaker plate and screen pack selection. A co-rotating twin-screw extruder with L/D 32:1 to 40:1 and vacuum venting is preferred for dispersion of the flame retardant package. Single-screw extruders with L/D < 24:1 tend to produce particulate streaks and inconsistent UL 94 performance at thin sections because additive dispersion is incomplete.
Screw geometry should use moderate shear and a short compression transition. A barrier screw with a mixing section of 3.5 D to 4 D and a Maddock mixing head at the metering zone improves dispersion without excessive shear heating. If a gear pump is installed between extruder and die, the pump inlet pressure should be maintained above 70 bar to avoid cavitation; die pressure should be measured with a strain-gauge melt transducer, not inferred from machine hydraulic pressure. On single-screw machines, barrel cooling fans should be active in the feed zone to prevent premature melting and feed-throat bridge-over.
Field data from production-scale twin-screw extrusion lines with L/D 32:1 indicate three recurring failure modes. First, insufficient drying generates low-molecular-weight hydrolysis products that lower melt viscosity and cause dimensional instability at the calibrator. Second, excessive barrel temperature above 195 °C in the compression zone initiates pre-expansion of the intumescent additive, visible as surface roughness and clumping at the screen pack. Third, barrel pressure fluctuations greater than ±5 bar at constant screw speed indicate inconsistent feed of the flame retardant masterbatch; a gravimetric feeder with a twin-screw side feeder for the flame retardant package reduces this variance.
Under radiant heat or flame impingement, the phosphorus–nitrogen system decomposes to form an expanded carbonaceous char layer that lowers heat release. Cone calorimetry at 35 kW/m² per ISO 5660-1:2015 shows peak heat release rate approximately 35% lower than non-flame-retardant PLA of the same thickness. The combustion gas stream does not generate hydrogen bromide or hydrogen chloride because the formulation contains no halogenated compounds. The char-forming reaction imposes a narrow melt-processing window; die temperature should be controlled within approximately ±5 °C of the 190 °C set point. Process control should use three-zone PID temperature controllers and cast-in band heaters with a watt density not exceeding 4 W/cm² on the die body to prevent local hot spots.
Regrind from trim scrap may be reintroduced at ≤20 wt% after drying to the same moisture specification; higher regrind fractions shift the melt flow rate upward and reduce Charpy notched impact. Storage in sealed foil-lined bags at 15 °C to 25 °C is recommended. Open containers exposed to RH > 60% for more than 8 h require re-drying.
Heat deflection temperature under 0.45 MPa load per ISO 75-2:2013 is reported at 91 °C; under 1.82 MPa load, the value falls below 60 °C. Continuous service above 55 °C under mechanical load is not recommended without application-specific creep testing. Water absorption after 24 h at 23 °C per ISO 62:2008 is approximately 0.3%. For electrical packaging applications, comparative tracking index should be evaluated per IEC 60112 rather than inferred from generic PLA data. The flame retardant additive lowers tensile yield stress by approximately 22% relative to a typical unfilled PLA extrusion grade but raises Charpy notched impact slightly.
Compared with halogen-free flame retardant PC/ABS, deTerra XP758-V0 processes at substantially lower melt temperature but provides lower Charpy notched impact. In contrast to brominated or chlorinated FR systems, the product does not require antimony trioxide and does not release hydrogen halide gases during combustion. Detection limits under IEC 62321 protocols are used for RoHS verification. Compared with PBAT/PLA biodegradable blends, XP758-V0 retains rigidity and V-0 flammability but sacrifices elongation and tear resistance. The material is therefore suited to rigid packaging, conduit, and profile applications where controlled end-of-life composting is required.
| Property | deTerra XP758-V0 | Unfilled PLA extrusion grade | Halogen-free FR PC/ABS |
|---|---|---|---|
| Density (ISO 1183-1:2019) | 1.23 g/cm³ | 1.24 g/cm³ | 1.18 g/cm³ |
| Melt flow rate (ISO 1133-1:2022) | 5.5 g/10 min at 190 °C/2.16 kg | 7 g/10 min at 190 °C/2.16 kg | 18 g/10 min at 260 °C/5 kg |
| Tensile yield stress (ISO 527-2:2012) | 47 MPa | 60 MPa | 55 MPa |
| Charpy notched impact (ISO 179-1:2023) | 3.8 kJ/m² | 2.5 kJ/m² | 40 kJ/m² |
| UL 94 vertical burn | V-0 at 1.5 mm | HB | V-0 at 1.5 mm |
| Industrial compostability | EN 13432 certified | EN 13432 certified | Not biodegradable |
Biodegradation of PLA in industrial composting proceeds through high-temperature hydrolysis followed by microbial mineralization. To claim compostability under EN 13432, the material must reach ≥90% absolute biodegradation within 180 days under controlled aerobic composting at 58 °C. Testing according to ISO 14855-1:2012 is used to measure mineralization. The flame retardant package is selected to avoid ecotoxic residues after compost disintegration, with plant germination evaluated under OECD 208. This product is not certified for home compost at mesophilic temperatures below 30 °C and is not intended for marine degradation or uncontrolled soil burial. Unlike PBAT/PLA blends that can soften and degrade under ambient moisture, XP758-V0 retains dimensional stability during service and only exhibits rapid biodegradation under industrial composting temperatures.
Primary downstream uses include thermoformed packaging trays for low-voltage electronics, cable management profiles, and conduit for interior electrical raceways where end-of-life industrial composting is specified. In thermoforming, sheet can be processed at 1.5 mm to 3.0 mm thickness; mold temperatures of 35 °C to 45 °C reduce wrinkles and allow demolding without release agents. For conduit extrusion, a vacuum calibration tank with −0.2 bar to −0.4 bar vacuum and a water bath temperature of 45 °C is used; rapid cooling below 40 °C causes excessive frozen-in stress and cracking during cutting.
Sheet extrusion with a co-rotating twin-screw extruder at L/D 32:1 and a gear pump is used to produce 1.5 mm thermoformable sheet for electronics trays. The three-roll stack is maintained at 45 °C to 55 °C to minimize internal stress; roll gap pressure should be set to avoid sheet thickness variation beyond ±0.05 mm. Chlorine-free silicone-based external release is preferred because mineral-oil-based release agents can reduce surface adhesion in downstream printing. Published data for this specific configuration is limited; processing trials should include a design-of-experiments matrix covering screw speed from 80 rpm to 140 rpm and take-off speed adjusted to the target thickness.