| HS Code | 847590 |
| Material Type | Polylactic Acid (PLA) |
| Grade | Flame Retardant Extrusion |
| Density | 1.24 g/cm³ |
| Melt Flow Rate | 10 g/10 min at 190°C/2.16 kg |
| Tensile Strength At Break | 50 MPa |
| Tensile Strength At Yield | 50 MPa |
| Tensile Modulus | 3.5 GPa |
| Flexural Modulus | 3.8 GPa |
| Flexural Strength | 75 MPa |
| Elongation At Break | 3% |
| Notched Izod Impact Strength | 2.5 kJ/m² |
| Heat Deflection Temperature At 0 45 Mpa | 55°C |
| Heat Deflection Temperature At 1 8 Mpa | 50°C |
| Vicat Softening Temperature | 60°C |
| Ul 94 Flammability Rating | V-0 |
| Limiting Oxygen Index | 30% |
| Processing Method | Extrusion |
| Processing Temperature | 180-220°C |
| Drying Temperature | 80°C |
| Drying Time | 4 hours |
| Biobased Content | 70% |
| Moisture Content | 0.03% |
As an accredited deTerra XP696-V2 Flame Retardant Extrusion Polylactic Acid factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.
| Packing | Packaged in 25 kg moisture-resistant, foil-lined paper bags, palletized and labeled with deTerra XP696-V2 Flame Retardant Extrusion Polylactic Acid. |
| Container Loading (20′ FCL) | 20′ FCL container loading for deTerra XP696-V2 Flame Retardant Extrusion Polylactic Acid, securely palletized and strapped for safe ocean shipment. |
| Shipping | deTerra XP696-V2 Flame Retardant Extrusion Polylactic Acid is typically shipped as a non-hazardous thermoplastic resin in moisture-barrier bags, lined drums, or octabins on pallets. Keep cool, dry, and away from ignition. Standard PPE recommended; follow local dangerous goods regulations and handle carefully to prevent moisture uptake. |
| Storage | Store deTerra XP696-V2 in a cool, dry, well-ventilated area, away from direct sunlight, heat, sparks, and open flames. Keep original containers tightly sealed to prevent moisture uptake. Avoid excessive humidity and temperatures above 30°C. Maintain clean, segregated storage. Do not store near strong oxidizers, acids, or bases. Rotate stock and follow supplier shelf-life and safety guidelines. |
| Shelf Life | deTerra XP696-V2: store sealed, cool, dry, away from moisture and heat; typical shelf life 12 months; confirm exact duration with supplier. |
On single-screw filament lines with a barrier screw and 20:1 to 24:1 L/D ratio, deTerra XP6962-V2 is dried at 70–80 °C for 4–6 h to a residual moisture target below 300 ppm before entering the feed throat. The extruder barrel is profiled from 160–170 °C in the feed zone, 175–185 °C in the compression zone, 185–190 °C in the metering zone, and 175–180 °C at the filament die; die pressure is kept below 120 bar to limit shear heating, and melt temperature at the die exit is held below 195 °C to suppress lactide reformation and acid-catalysed chain scission. The melt strand passes through a 10–20 mm air gap into a quench bath maintained at 35–45 °C; closed-loop laser diameter control targets 1.75 mm or 2.85 mm filament with a tolerance of ±0.05 mm. At 30–50 rpm screw speed and a draw ratio between 2.0:1 and 3.0:1, wound filament retains a stable diameter, and fines generation is managed by using a crammer feeder if pellet bulk density is low. Screw torque is kept below 75% of drive capacity to prevent local shear heating, while winding tension is maintained between 0.5 N and 1.5 N to avoid ovality and residual stress. A water-soluble sizing, if used for winding stability, must be fully removed during drying because sizing residue contributes to flame spread in printed parts. Colour masterbatch is limited to 2–3 wt% and must use an FR-compatible carrier; carbon black loading above 1 wt% can alter volume resistivity, melt rheology, and char emissivity, and must be revalidated against UL 94 V-0. Amine-based heat stabilisers are excluded because they interfere with acid-neutralising stabilisers and can generate gel formation in the melt. For EU-bound parts, RoHS Directive 2011/65/EU Annex II substance limits and REACH SVHC screening apply, and finished-article compliance is verified under EN 62474 material declaration guidance rather than compounder SDS alone. Printed specimens with interlayer porosity above 8% may fail 2.0 mm V-0 criteria not from insufficient FR loading but because capillary wetting and oxygen access along void walls accelerate flame propagation. Tensile verification of printed specimens follows ISO 527-2:2012 or ASTM D638-14 depending on the destination market, while end-product compliance for ICT enclosures draws on IEC 62368-1. Regrind ratio is limited to 20 wt% when the regrind is dried and melt-filtered through a 100-mesh screen; above this ratio notched impact and retained UL 94 rating degrade disproportionately. Terminal parts include snap-fit electronics enclosures, cable management brackets, and low-series jigs for printed circuit board assembly where flame retardancy is required for end-use rather than prototype evaluation.
Melt strength, rather than flame-retardant loading, becomes the controlling constraint when deTerra XP6962-V2 is extruded into sheet below 0.8 mm. The grade is processed through a flat die onto a vertical three-roll stack with first-roll temperature of 30–40 °C and lower-roll temperatures of 25–35 °C; the roll gap is set to produce sheet between 0.5 mm and 1.5 mm nominal thickness. Melt temperature at the die entry is held below 190 °C because PLA matrix viscosity drops rapidly above this threshold, causing edge-neck-in, uneven draw, and loss of gauge stability. When the as-received MFR measured per ISO 1133-1:2022 at 210 °C/2.16 kg falls between 5 g/10 min and 10 g/10 min, sheet processing is normally feasible without chain extension. A gear pump between extruder and die reduces gauge variation to ±0.03 mm, and static pinning electrodes are applied for sheet below 0.8 mm to ensure first-roll contact. For high draw ratios above 3:1, addition of an epoxy-functional chain extender at 0.2–0.5 wt% raises melt strength but must be revalidated against thin-film flammability requirements because altered rheology affects char-layer continuity during burning. Thermoformed trays produced from this sheet are evaluated under UL 94 VTM-0 using ASTM D4804-20 specimens cut from both the formed sidewall and the base; the most frequent failure location is the thermoformed corner where local draw-down reduces thickness below the qualified minimum. Production-scale thermoforming uses surface preheat of 90–110 °C and plug-assisted forming to limit wall-thickness reduction to less than 35% of the starting sheet. Edge trim and skeletal scrap are reintroduced only through a dedicated regrind stream with 100-mesh filtration, and regrind content is capped at 20 wt% to preserve VTM-0 classification. Terminal products include ESD-safe component trays, flame-retardant separator trays for lithium-ion battery service areas, and printed circuit board transport carriers where thin-gauge horizontal and vertical burn requirements are specified simultaneously by end users.
| Application segment | Standard / method | Clause or designation | Required outcome |
|---|---|---|---|
| Filament for printed electronics enclosures | UL 94, ISO 527-2:2012, ASTM D638-14, IEC 62368-1 | Vertical burn at 2.0 mm; tensile specimen type 1B | V-0 no afterflame greater than 10 s; no flaming drips |
| Thin-gauge thermoformed trays | UL 94, ASTM D4804-20 | Thin film vertical burn; VTM rating | VTM-0 at 0.5 mm or as qualified |
| Rail interior profiles | EN 45545-2, ISO 5659-2, EN ISO 5658-2 | R26 interior surfaces; Ds max smoke density | HL2 or HL3 as specified by vehicle category |
| Appliance wiring ducts | IEC 60335-1, IEC 60695-2-11 | Clause 30.2.3 glow-wire end-product test | No ignition at 750 °C or 850 °C as required; flame duration not to exceed 2 s |
| Automotive interior trim | ISO 3795, FMVSS 302 | Horizontal burn rate | Burn rate not to exceed 102 mm/min |
| Architectural decorative profiles | ASTM E84, EN 13501-1 | Surface flame spread and smoke developed | Class A or B as local code; full-scale product test required |
When rail interior components are specified under EN 45545-2, the limiting parameters shift from UL 94 vertical burn to lateral flame spread, smoke density, and toxic gas release. Profile extrusion of deTerra XP6962-V2 for this segment is carried out on a co-rotating twin-screw extruder with 32:1 L/D and a strand die fitted with a 150-mesh melt filtration system; the filtration step is mandatory because char-forming flame-retardant additives tend to form agglomerates that disturb surface finish and reduce effective char-layer continuity during combustion. Barrel set points range from 165 °C in the intake zone to 185 °C near the die, and melt temperature is held below 195 °C. Compliance for rail interiors under R26 requires testing to EN ISO 5658-2 for lateral flame spread, ISO 5659-2 for smoke density, and, where the vehicle category dictates, EN 17084 for toxic gas release. Published data for deTerra XP6962-V2 specifically in a fully characterised rail interior assembly is limited; a converter must conduct a complete classification exercise because PLA hydrolytic stability, char adhesion, and smoke opacity are influenced by co-extruded cap layers, surface textures, and cleaning chemicals. A halogen-free formulation is preferred for rail projects due to smoke toxicity constraints, but the exact FR package must be selected against the full data set; melt-compounded systems that combine phosphorus-based charring agents and zinc borate at total additive loadings between 15 wt% and 25 wt% are typical starting points for laboratory screening, not production specifications. The profile is cut with carbide-tipped saws at low feed speed to avoid burnt edges that create ignition points during fire testing. Terminal profiles include seat edging, floor cable raceways, and wall base trim used in passenger rail vehicles; these parts are produced with a wall thickness of 1.5–3.0 mm and must survive repeated cleaning with dilute hydrogen peroxide and quaternary ammonium compounds without surface whitening or loss of flame retardancy.
On profile extrusion lines fitted with a vacuum calibrator and a 0.5 mm slot die, deTerra XP6962-V2 can be extruded into thin-walled wiring ducts with wall thickness from 0.6 mm to 1.2 mm. The calibrator vacuum is set to −0.2 bar to hold the profile shape, and haul-off speed is matched to melt output so that draw-down ratio does not exceed 2.2:1; higher draw induces surface microcracks that later act as flame propagation paths under glow-wire testing. For appliance internal wire ducts, terminal covers, and cable separators, the relevant end-product test is IEC 60695-2-11 glow wire applied at 750 °C or 850 °C according to the current-carrying capacity of the surrounding circuit and the requirements of IEC 60335-1 clause 30.2.3. Passing outcomes require no ignition or flame duration shorter than 2 s after the glow-wire tip is withdrawn, and no ignition of the tissue paper specified in the test apparatus. The extruded duct is normally embossed or perforated in a secondary operation; perforation density must be validated in the flame-retardant test because each slot increases specific oxygen access area along the profile. Siloxane or core-shell impact modifiers may be added at 2–5 wt% to improve unnotched impact resistance, but each addition requires a new glow-wire test because char-layer chemistry changes. Formulation control in this segment limits regrind to 15 wt% because impact strength and glow-wire performance both decline once amorphous PLA regrind with lower molecular weight is introduced. Terminal parts are installed inside white goods, power distribution cabinets, and HVAC control enclosures, where creep under clamping load is controlled by selecting a wall thickness above 0.8 mm and by using metallic fasteners rather than adhesive mounting.
Production of thermoformed trim from this grade requires a polished three-roll stack with grained rolls operating at 35–45 °C to replicate the surface grain specified by automotive interior programmes. Sheet with thickness 1.0–2.0 mm is extruded at melt temperatures of 180–195 °C, then thermoformed into door trim accents, seat side shields, and map pocket panels; the forming tool is held at 60–80 °C to reduce stress whitening and to maintain grain depth in deep-draw regions. Sheet stock must be dried to below 250 ppm moisture before extrusion; thermoformed trim assemblies are often ultrasonically welded or heat-staked, and the weld region must be included when preparing horizontal burn specimens because stress concentration does not exempt the weld from flammability evaluation. Compliance is evaluated under ISO 3795 and FMVSS 302 horizontal burn, where the test specimens are cut from formed parts and conditioned at 23 °C and 50% RH for 24 h; the burn rate must not exceed 102 mm/min, and self-extinguishing behaviour is preferred because it avoids batch-lot reclassification. Low-odour and low-VOC requirements under OEM performance standards such as VDA 277 or VDA 278 mean that the flame-retardant additive package must be thermally stable during extrusion and thermoforming; degradation of phosphorus-based flame retardants at temperatures above 210 °C releases acidic vapours that cause odour failures and corrosion on tooling. Grade-specific limits for XP6962-V2 are set by the supplier, but inline melt temperature monitoring is mandatory because PLA exhibits a narrow hydrolysis window and compounding history influences residual acidity. The main operational boundary is heat resistance: unreinforced PLA has a heat deflection temperature below 65 °C under 0.45 MPa using ISO 75-2 method B, and dark-colour trim exposed to solar load in a parked vehicle can exceed this limit; therefore use is confined to interior surfaces not subjected to direct intensive solar heat or to assemblies with positive air gap and metallic backing. For specific parts requiring higher heat sag resistance, a nucleated, annealed variant or a PLA alloy is required; published data for deTerra XP6962-V2 after annealing is limited and must be generated on the production tool.
For interior wall protection, corner guards, and cable skirting profiles, a single-screw extruder with a side-fed regrind stream processes deTerra XP6962-V2 into hollow profiles with a 1.5 mm nominal wall and a matte surface produced by embossing rolls downstream of the calibration tank. The profile is typically co-extruded with a thin non-FR cap layer where colour matching and surface scratch resistance are critical; the cap layer must be limited to 5–10% of total wall thickness and must itself be included in the relevant reaction-to-fire test because it can shield the flame-retarded core during the ignition phase. In architectural interior applications, local building codes may require ASTM E84 Class A or Class B surface burning characteristics or the European system under EN 13501-1; full-scale product testing is mandatory because small-scale DIN 4102-1 or ASTM D635 tests are not accepted as substitutes for wall and ceiling finish classifications. The extruded geometry must be tested as assembled, including adhesive backing and mounting clips, because the adhesive layer can dominate smoke production even when the PLA profile itself is flame-retardant. Processing of the hollow profile uses melt temperature below 190 °C, a vented barrel with vacuum below −0.08 bar to remove residual moisture, and a calibrator water temperature of 20–30 °C. PLA is susceptible to hydrolysis; long-term exposure above 60% RH at 30 °C can reduce molecular weight and flame-retardant retention, so cleaning with hot water or steam is not recommended. Published data for deTerra XP6962-V2 in architectural interior finish classifications is limited, and use in structural or fire-rated applications is explicitly excluded; these profiles are decorative non-structural components. Terminal installed products include wall corner guards, handrail cover guards, and low-level cable skirting in commercial interiors where cigarette ignition, waste-paper ignition, or hot-particle contact resistance is required by the facility manager rather than by a structural fire code.
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deTerra XP696-V2 Flame Retardant Extrusion Polylactic Acid is identified as a formulated extrusion-grade PLA compound intended for flame-retardant profile, sheet, conduit, and electronics enclosure applications. Publicly available manufacturer datasheets for this specific configuration are limited; therefore, no numerical specification in this document is a certified value for XP696-V2 unless the current supplier document is cited. The grade belongs to a class of halogen-free PLA compounds that combine polylactic acid with phosphorus-nitrogen flame-retardant chemistry. Compared with unfilled PLA, this class exhibits higher melt viscosity, greater moisture sensitivity, reduced melt strength, and a narrower thermal processing window. Compared with brominated flame-retardant PLA, a halogen-free system of this type is expected to produce lower acidic smoke during combustion but may require higher flame-retardant loading to achieve the same termination classification. The model designation must be verified against the manufacturer’s lot-specific certificate of analysis before production parameters are fixed.
PLA esters hydrolyze readily when residual moisture is present. Extrusion grades are normally dried to 250 ppm or less in a desiccant-dryer loop before melt processing. For class-typical flame-retardant PLA, a drying setpoint of 80 °C for 4 h at a dew point below −40 °C is frequently cited; thick-walled pellets or high ambient humidity may require longer residence times. The XP696-V2 datasheet may specify a lower or higher setpoint, and no substitute for that document exists. Melt processing on a twin-screw extruder with an L/D ratio between 24:1 and 40:1 is typical. Barrel zones are usually operated from 180 °C in the feed region up to 200–210 °C at the die. Flame-retardant additives may generate acidic decomposition products if local melt temperature exceeds 230 °C, causing plate-out and polymer chain scission. The processing window for this class is treated as ±5 °C around the mid-range when measured at the melt thermocouple.
Rheological response differs from unfilled PLA. At low shear rates, particulate flame retardants increase viscosity and may introduce apparent yield stress; at high shear rates, wall slip and shear thinning can reduce head pressure unpredictably. Capillary rheometry across 100–1000 s⁻¹ at 200 °C and 210 °C is required to construct a viscosity curve for die design. Published data for XP696-V2 under capillary shear is limited. Melt temperature should be measured with an immersion thermocouple at the adapter; barrel setpoints alone are not sufficient because shear heating can raise melt temperature by 5–10 °C at high screw speed. At ambient relative humidity above 60%, open storage of PLA pellets can raise moisture above 500 ppm within hours; sealed hoppers and dry-air conveying are required. Purging with unfilled PLA after processing flame-retardant grades is recommended to remove acidic residues from the screw and barrel.
In phosphorus-based FR PLA, the flame-retardant package often includes an acid source, a carbonific compound, and a spumescent nitrogen source. During combustion, the acid source dehydrates the PLA backbone, promoting char; the nitrogen source liberates non-combustible gases that expand the char layer. The char layer reduces heat release and oxygen diffusion. These reactions are not limited to the flame front: at elevated processing temperatures, premature dehydration can occur inside the extruder. The result is yellowing, volatile evolution, and die-lip deposits. Production-scale operators report that dispersion of solid phosphorus-containing powders requires distributive mixing but not high shear; high shear raises local melt temperature and triggers the same char-forming chemistry in the barrel. A screw design with 2.0–2.5 D of combined kneading and gear-mixing elements is typical for this class.
Melt viscosity at 210 °C and 2.16 kg for this class is generally in the range of 3–10 g/10 min by ISO 1133-1:2022, although the presence of intumescent solids may reduce the practical MFI reproducibility. Capillary rheometry is preferred because MFI values do not capture the yield stress or wall-slip behaviour introduced by particulate flame retardants. If head pressure deviates by more than 15% from the unfilled PLA baseline at constant screw speed, barrel setpoints and feed stability should be audited before die adjustments are made. The product may be supplied as cylindrical pellets; pellet geometry influences feeding consistency. If bridging occurs in the hopper, mechanical agitators or vibratory hoppers are used to maintain uniform feed.
Comparative data for general-purpose PLA, halogen-free phosphorus-nitrogen FR PLA, and mineral-filled FR PLA reveal predictable trade-offs in stiffness, ductility, melt flow, and ignitability. Table 1 provides the class-typical property envelope for halogen-free FR PLA extrusion grades derived from public technical literature and material manufacturers’ technical bulletins. The values are not specific to deTerra XP696-V2 and must be replaced by supplier-certified values when available.
| Property | Method | Class-typical range |
|---|---|---|
| Melt flow index | ISO 1133-1:2022 | 3–10 g/10 min at 210 °C / 2.16 kg |
| Tensile strength at break | ISO 527-2:2012 | 45–65 MPa |
| Tensile modulus | ISO 527-2:2012 | 3.0–4.5 GPa |
| Charpy notched impact strength | ISO 179-1:2010 | 2–4 kJ/m² |
| Heat deflection temperature, 0.45 MPa | ISO 75-2:2013 | 60–100 °C |
| Limiting oxygen index | ASTM D2863-19 | 28–34% O₂ |
| Vertical burn classification | UL 94 | V-0 at 1.5–3.0 mm thickness for many class members; thickness-specific |
The reduced tensile strength and elongation relative to unfilled PLA arise from particulate flame-retardant loading. Tensile modulus may remain near 3.0–4.5 GPa because rigid phosphorus-rich particles and char precursors stiffen the matrix. The notch sensitivity of PLA is retained; Charpy notched impact values in the class remain below 4 kJ/m², which limits use in snap-fit components unless geometry is modified. Property verification for deTerra XP696-V2 should be performed on injection-moulded or extruded test specimens using the current ISO methods; all values in Table 1 are class-typical, not guarantees.
Extrusion of flame-retardant PLA profiles and sheet requires characterization beyond melt flow index. PLA has lower melt strength than ABS, polycarbonate, or filled polyolefins; the addition of particulate flame retardants can further reduce the maximum draw ratio before melt fracture or sagging. For profile extrusion, die swell and draw-down ratios should be measured on a capillary rheometer with a 1 mm to 2 mm die and a 10:1 to 20:1 die length-to-diameter ratio. Data from class-typical FR PLA indicate die swell ratios in the region of 1.2–1.6 at shear rates around 100 s⁻¹, but published values for XP696-V2 are limited.
Vacuum calibration tanks are employed for hollow profiles; the extrudate must retain enough melt strength to withstand sizing pressure and cooling shrinkage. Calibration plate temperatures of 60–80 °C are typical for PLA. Sheet extrusion uses polished roll stacks, often with a top roll at 60 °C and a middle roll at 70 °C, to control crystallisation and haze. Sheet die gap is often set 10–20% wider than final sheet thickness to account for draw-down and edge bead. Flame-retardant degradation products can adhere to the die lip and are often accelerated by excessive residence time. Die design should include chromium-plated or stainless steel tooling with no dead spots; cleaning intervals on production lines in this class are reported to shorten to 8–24 h depending on throughput and compound freshness. Gear-pump assist stabilizes output; melt pump inlet pressure should remain below 100 bar to avoid seal leakage in class-typical lines.
Flame-retardant PLA for electrical enclosures, conduit, and battery-adjacent components is evaluated against a combination of ignitability, glow-wire, smoke, and restricted-substance requirements. Table 2 lists the compliance benchmarks most frequently referenced for this class. No entry in Table 2 indicates certification of deTerra XP696-V2; certification status must be confirmed through supplier test reports and independent laboratory listings.
| Regulatory area | Standard or directive | Typical requirement or note |
|---|---|---|
| Vertical burn | UL 94 | V-0 at 1.5 mm or 3.0 mm; manufacturer yellow card required for each colour and thickness |
| Limiting oxygen index | ASTM D2863-19 | Class-typical 28–34% O₂; not a substitute for part-specific fire testing |
| Glow wire ignition | IEC 60695-2-12 | GWT at 750 °C or 850 °C depending on end product and unsupervised-current threshold |
| Restriction of hazardous substances | Directive 2011/65/EU Annex II | No lead, mercury, cadmium, hexavalent chromium, PBB, PBDE, or specified phthalates |
| REACH substances of very high concern | Regulation (EC) No 1907/2006 Article 33 | Declaration required above 0.1 wt% in article |
| Smoke density | ASTM E662 | Optical smoke density must be evaluated where specified; halogen-free compounds are generally lower than brominated systems but no universal threshold applies |
For electrical enclosure applications, glow-wire requirements in IEC 60695-2-12 are part-specific. Passing a UL 94 V-0 test at 1.5 mm does not automatically satisfy glow-wire end-product testing for unattended appliances. The end-use temperature environment also matters: PLA-based parts should not be used continuously above the heat deflection temperature unless the part is supported or the load is low. Published data for XP696-V2 in multi-hour thermal aging under IEC 60216 is limited.
In comparison with brominated flame-retardant PLA compounds and highly mineral-filled FR grades, the deTerra XP696-V2 designation points toward a halogen-free phosphorus-based route. The supplier must confirm the flame-retardant chemistry and loading. Halogenated FR PLA systems often achieve V-0 at lower additive loading, but combustion releases acidic gas and dense smoke. Halogen-free systems usually require higher loading, which reduces ductility and may increase moisture absorption. Mineral-filled FR PLA grades can offer higher stiffness and lower coefficient of linear thermal expansion but often show lower tensile elongation and higher density. A phosphorus-based system may provide better retention of impact resistance than hydrated mineral systems, but this depends on the specific synergist. Operational boundaries for this class include mandatory pre-drying at ambient relative humidity above 60%, avoidance of amine-based stabilizers that can neutralize acidic phosphorus degradation products, avoidance of melt temperatures above 230 °C, and limitation of residence time. Flame-retardant performance is thickness-dependent and color-dependent. A UL 94 yellow card listing V-0 at 1.5 mm in natural colour does not automatically cover black or custom pigmented profile; each formulation requires separate evaluation. Published data for XP696-V2 across colours is limited. Users must request the current technical datasheet and safety data sheet for XP696-V2 from the supplier before setting production parameters. No production parameter, compliance claim, or property value for deTerra XP696-V2 should be locked without a current supplier certificate covering the exact lot number.