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Compostable 3002 Blown Film Compostable PLA Blend

    • Product Name: Compostable 3002 Blown Film Compostable PLA Blend
    • Factroy Site: Yudu County, Ganzhou, Jiangxi, China
    • Price Inquiry: admin@ascent-chem.com
    • Manufacturer: Ascent Petrochem Holdings Co., Limited
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    Specifications
    HS Code 930217
    Productname Compostable 3002 Blown Film Compostable PLA Blend
    Manufacturer NatureWorks LLC
    Grade 3002
    Polymertype Polylactic acid (PLA) blend
    Biobasedcontent Renewable resource-based
    Compostability Industrial compostable
    Compostabilitystandards EN 13432, ASTM D6400
    Certifications BPI, DIN CERTCO, OK Compost
    Processingmethod Blown film extrusion
    Meltflowrate 3 g/10 min at 210°C/2.16 kg
    Density 1.24 g/cm³
    Meltingpoint 145-155°C
    Glasstransitiontemperature 55-60°C
    Tensilestrength 50 MPa
    Elongationatbreak 3-5%
    Flexuralmodulus 3500 MPa
    Vicatsofteningpoint 55°C
    Heatdeflectiontemperature 55°C
    Filmthicknessrange 20-50 µm
    Shelflife 12 months
    Storageconditions Cool, dry place

    As an accredited Compostable 3002 Blown Film Compostable PLA Blend factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing Product is supplied in 25 kg moisture-resistant compostable kraft paper bags, palletized and stretch-wrapped for industrial transport.
    Container Loading (20′ FCL) Compostable 3002 Blown Film Compostable PLA Blend loaded in 20′ FCL, palletized, stretch-wrapped, secured for export ocean freight; non-hazardous.
    Shipping Shipped as nonhazardous solid resin in 25 kg moisture-barrier bags or bulk lined containers, palletized and stretch-wrapped. Protect from moisture, heat, and UV. Store below 40°C in a dry, ventilated area. Standard freight, sea, or air transport acceptable; no special hazardous labels required.
    Storage Store in a cool, dry, well-ventilated area away from direct sunlight, heat, ignition sources, and moisture. Keep sealed in original packaging until use to prevent hydrolysis and degradation. Avoid incompatible chemicals and excessive stacking. Maintain stable temperature and humidity; follow FIFO rotation and manufacturer/SDS recommendations. Inspect containers for damage or moisture ingress, and use within shelf life. Do not store outdoors.
    Shelf Life Typically 12 months when stored unopened in a cool, dry, ventilated area away from heat, sunlight, and moisture.
    Application of Compostable 3002 Blown Film Compostable PLA Blend

    For municipal and commercial organic waste collection programs, the compound is processed almost exclusively on mono-layer high-output blown film lines equipped with automatic gauge control and internal bubble cooling; typical film thickness falls between 12 µm and 18 µm, which places the material at the lower bound of the blown film gauge envelope and makes bubble stability dependent on tightly controlled melt temperature rather than output rate alone. Formulation addition ratio in this segment keeps the base resin at 95–98 wt%; a carbon-black-free green or grey masterbatch is added at 2–4 wt%, and a slip/antiblock package is introduced at 0.5–1.0 wt% to permit film separation on automatic bag-making machines. Processors that dilute the grade with more than 10–15 wt% of PBAT-rich reclaim observe a measurable drop in dart impact and an increase in seal elongation, which then requires re-validation under EN 13432:2000/AC:2005 because the final formulation rather than the base resin must carry the certification. Extrusion conditions on a single-screw line with L/D 30:1 and a barrier screw maintain a melt temperature of 165–175 °C at the die inlet; die gap is set to 1.8–2.2 mm, blow-up ratio between 3.5:1 and 4.5:1, and frost line height held at 2–3 die diameters. Pellet moisture must be reduced below 250 ppm in a desiccant dryer at 60–70 °C for 4–6 h before extrusion; residual moisture above this threshold causes hydrolysis, bubble holes, and die-lip oligomer deposition. Bag conversion uses bottom-seal machines with heated jaw temperatures of 135–155 °C, dwell times of 0.3–0.6 s, and jaw pressure between 2.5 N/mm² and 4.0 N/mm²; seal strength is checked by ASTM F88/F88M-21 on a 15 mm strip. Terminal products include 8–20 L kitchen caddy liners and 10–45 L municipal organics bags. Certification for this application is governed by EN 13432:2000/AC:2005, which requires at least 90% biodegradation by weight relative to a reference within 180 days under ISO 14855-1:2012, disintegration such that at least 90% of material passes through a 2 mm sieve after 12 weeks under ISO 16929:2021, and ecotoxicity testing under OECD 208 with germination rate and plant biomass at least 90% of the blank. The equivalent North American specification ASTM D6400-23 applies the same 90%/180-day carbon conversion threshold under ASTM D5338-15. Heavy metal limits follow the packaging directive 94/62/EC threshold scaled to 50% for compostable materials.

    Standard referenceTest methodThresholdRequirement
    EN 13432:2000/AC:2005, clause 4.2ISO 14855-1:2012≥90% within 180 daysAerobic biodegradation relative to control
    EN 13432:2000/AC:2005, clause 4.3ISO 16929:2021≥90% < 2 mm after 12 weeksDisintegration in industrial composting
    EN 13432:2000/AC:2005, clause 4.4OECD 208≥90% relative to blankEcotoxicity by plant germination and biomass
    ASTM D6400-23ASTM D5338-15≥90% within 180 daysMineralization under aerobic composting

    At What Service-Life Threshold Does Soil-Incorporation Performance Fail in Mulch Film?

    Agricultural mulch film produced from Compostable 3002 enters a different regulatory category than compostable packaging: soil-biodegradable mulch is covered by EN 17033:2018, which requires ≥90% absolute or relative soil biodegradation within 24 months under ISO 17556:2019, combined with OECD 208 plant emergence and OECD 207 earthworm acute toxicity data. The critical formulation conflict in this segment is that UV stabilizers and carbon black both extend field service life but may reduce the soil biodegradation rate; therefore the addition of hindered amine light stabilizers is capped at ≤0.25 wt% and the total organic filler content is limited to ≤5 wt% unless new certification is obtained. The base resin is loaded at 96–98 wt%; a carbon black masterbatch at 2–4 wt% is added for black film, while a white or reflective grade substitutes 4–6 wt% titanium dioxide concentrate. Processors targeting both a 60–90 day service life and complete soil incorporation should keep non-biodegradable additives other than carbon black and titanium dioxide below 1 wt% because residual fragments larger than 2 mm after 18 months will fail the physical disintegration element. Film production for this end use runs monolayer on gusseted blown film towers with layflat widths between 1.0 m and 1.8 m, die gap 1.5–2.0 mm, blow-up ratio 2.5–3.5:1, and melt temperature 160–170 °C. The most sensitive process variable is transverse-direction gauge distribution; because mulch films are installed under tension by mechanical laying equipment, thickness variation above ±2 µm on a 15 µm film causes tearing at the edge embossment during tractor installation. Automatic gauge control using segmented air rings is therefore mandatory above 80 kg/h output; at lower output, manual bubble geometry adjustment is insufficient on lines without internal bubble stabilization. Terminal products include 12–25 µm mulch rolls for processing tomato, strawberry, cucumber, and sweet corn fields, with edge folds of 10–15 cm for soil anchoring. Published data for this specific compound in cold, wet, low-microbial-activity soils is limited; certification under EN 17033:2018 represents a standardised laboratory and field test sequence rather than a guarantee of identical degradation across every agricultural soil. In particular, degradation slows significantly at soil temperatures below 10 °C, and the film must be incorporated into the top 20 cm of biologically active soil to reach the required mineralisation window.

    On high-speed vest-carrier conversion lines, the film grade must be treated as a sealability-critical substrate rather than a direct LDPE replacement because the heat-seal initiation temperature is lower and the processing window narrower. Formulation addition ratio in retail bag applications keeps the compound at 98.0–99.5 wt%; colour concentrate is added at 1.0–2.0 wt%, and a slip/antiblock masterbatch is held at 0.5–1.0 wt% to maintain machineability without pushing the total organic carbon load above certification limits. Compliance for printed carrier bags follows EN 13432:2000/AC:2005 for the finished bag, including all inks and adhesives; under EU waste law, bags supplied for fresh produce and retail checkout must also comply with packaging minimisation requirements in 94/62/EC. If the bag is labelled as home compostable, industrial compostability under EN 13432 alone does not cover backyard conditions, and the claim must be validated under a separate home-composting protocol such as TÜV AUSTRIA OK compost HOME. Blown film is produced at 15–25 µm thickness with a die gap of 1.6–2.0 mm and blow-up ratio 3.0–4.0:1. Immediate corona treatment to 38–42 mN/m is required before flexographic printing; water-based or solvent-less inks are selected on the basis of EN 13432 biodegradability data. The conversion line uses bottom-seal bag machines with seal temperatures 120–140 °C and dwell 0.4–0.8 s; operators report blocking on the hot jaw when the film is wound at tension above 0.3 N/mm. Terminal products include 10–25 L vest carrier bags and boutique retail bags with reinforced punched handles.

    Seal Initiation Temperature and Food-Contact Compliance in Dry-Food Flowrap

    Dry-food flowrap applications impose a dual requirement: the film must be suitable for direct contact with low-moisture foods under the applicable national framework and must also demonstrate a narrow heat-seal window on horizontal form-fill-seal machinery. In the European Union, the lactic acid monomer in polylactic acid is listed in Annex I of Commission Regulation (EU) No 10/2011 as FCM substance 185; overall migration is assessed against a limit of 10 mg/dm² under test condition OM2 or OM3, as specified for dry foods. In the United States, the applicable authorisation is a Food Contact Notification rather than a single 21 CFR citation, and converters must confirm that the specific masterbatch and processing aids do not alter the notified formulation. The formulation addition ratio for this segment uses 96–98 wt% base resin, 1–3 wt% silica-based antiblock, and 0.5–1.5 wt% erucamide slip; erucamide loadings above 1.5 wt% are not recommended because plate-out on the corona treater electrodes increases the risk of back-side treatment irregularity and reduces seal strength on high-speed flowrap equipment. Blown film for dry-food packaging is run at 20–30 µm thickness, die gap 1.5–2.0 mm, blow-up ratio 3.0–3.5:1, and melt temperature 160–170 °C. After bubble collapse, the web is corona-treated to 40–44 mN/m and slit into reels for horizontal flow-wrapping; the heat-seal applied by the packaging machine is typically set between 120–145 °C with dwell 0.4–0.8 s and jaw pressure 3.0–4.5 N/mm². Seal strength is measured according to ASTM F88/F88M-21; films with seal initiation below 110 °C are preferred for high-speed lines, while seal initiation above 135 °C causes jaw contamination and missed seals on intermittent motion machines. Terminal product types include bakery bags, dry pasta pillow packs, cereal bar flowwrap, and individually wrapped dry confectionery. This grade is not suitable for moist or fatty foods requiring strong water-vapour and oxygen barriers; PLA-based films have lower moisture barrier than PE or PET, so applications are confined to low-water-activity products.

    Warehouse Storage Humidity Alters Seal Strength After Composting Certification

    Compostable e-commerce mailer stock produced from Compostable 3002 accumulates static surface charge faster than LDPE reference film when ambient humidity drops below 30% RH; converters therefore add an antistatic masterbatch at 1.0–2.0 wt% and a grey or black masterbatch at 1.0–2.0 wt%, keeping the base resin at 96–98 wt%. Certification follows EN 13432:2000/AC:2005 or ASTM D6400-23 for the finished mailer including adhesive strip and label stock; if the outer bag carries a self-seal strip, the adhesive must be compostable or present below 0.5 wt% of total package weight to avoid exceeding the organic content allowance under the relevant certification scheme. Blown film for mailers is extruded at 30–50 µm thickness, with die gap 2.0–2.4 mm, blow-up ratio 2.5–3.5:1, and melt temperature 165–175 °C. The layflat tubing is converted on mailer machines that apply a self-seal flap and perforated tear strip; longitudinal re-winding tension must remain below 0.4 N/mm because the film's low modulus creates telescoping and blocking during warehouse storage above 60% RH. Seal strength on the flap is assessed by ASTM F88/F88M-21; a minimum peel value of 4 N/15 mm is commonly specified, and storage beyond 6 months under uncontrolled humidity can reduce peel force below this threshold due to slip-agent migration. Terminal products include 250 mm × 350 mm, 300 mm × 400 mm, and 400 mm × 500 mm compostable mailers for non-food e-commerce shipments. Published data for this specific configuration is limited; each converter must run its own seal peel and blocking test under target storage conditions.

    When the Grade Is Downgauged to 20 µm for Personal-Care Overwrap with a Matte Finish

    When the same resin is reduced to 20 µm for personal-care overwrap, the critical control points shift from tear resistance to surface aesthetics and fibrous-film machineability. The formulation addition ratio changes accordingly: base resin is loaded at 95–98 wt%, a calcium carbonate matting masterbatch at 2.0–3.0 wt% to reduce gloss below 20 GU at 60° incidence, and a slip package at 0.5–1.0 wt% to prevent blocking on roll stock. Compliance is anchored to EN 13432:2000/AC:2005 for compostability of the finished overwrap; where the wrapped article is a cosmetic or personal-care product, the packaging itself does not require compliance with EC No 1223/2009, but any compostability claim must still align with EN ISO 14021:2016 self-declared environmental claims to avoid misleading communication. Blown film is produced on high-clarity dies with die gap 1.4–2.0 mm, blow-up ratio 2.8–3.5:1, and melt temperature 160–170 °C; the matting agent raises viscosity slightly and narrows the bubble window, so line speed is typically reduced by 10–15% relative to clear film. Corona treatment is set to 38–42 mN/m before flexographic printing. Terminal products include compostable overwrap for organic cotton pads, bamboo dry wipes, and dry personal-care accessory sets. The film is not suitable for wet-wipe packaging because moisture contact initiates PLA hydrolysis and lowers tear strength during storage.

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    Certification & Compliance
    More Introduction

    Compostable 3002 Blown Film Compostable PLA Blend is a polylactide-rich pellet compound for single-layer and coextruded blown film lines where aerobic industrial composting under EN 13432:2000 or ASTM D6400-23 is the specified end-of-life route. The grade is specified for film thickness 10–80 µm; the most repeatable gauge control is recorded in the 18–45 µm band on lines fitted with 0.8–1.2 mm die gaps and dual-lip air rings. A melt-flow index measured according to ISO 1133-1:2022 at 190 °C and 2.16 kg is typically 3–7 g/10 min; density determined by ISO 1183-1:2019 is 1.24–1.28 g/cm³. The material differs from unmodified PLA extrusion grades because a biodegradable copolyester minor phase and a reactive chain-extension package are included to increase melt strength and reduce film brittleness below 10 °C. Compostability certification must be verified for the final film construction, including inks, adhesives, and lamination layers, because approval applies at a defined total organic carbon loading and film thickness. The pellets are cylindrical with nominal diameter 3.0 mm ± 0.2 mm, bulk density 0.78–0.82 g/cm³, and are supplied in moisture-barrier bags with a storage limit of 12 months at 15–30 °C and below 70 % RH.

    Predrying in a desiccant dryer with a -40 °C dew-point air supply at 70–80 °C for 4–6 h is required before extrusion. The maximum permissible pellet moisture is <250 ppm as measured by ISO 15512:2019. At moisture above 400 ppm, melt-phase hydrolysis reduces zero-shear viscosity and produces pinholes in film below 20 µm. Hoppers should be heated or blanketed with dried air when ambient relative humidity exceeds 60 %. The blend is intended for aerobic industrial composting; published data for anaerobic digestion of this specific configuration is limited, and operators should not claim anaerobic digestibility without project-specific validation under ISO 15985:2014.

    What Limits Stable Bubble Formation in High-Stalk Extrusion of Compostable 3002?

    High-stalk processing is the limiting configuration because the melt undergoes extensional thinning between die exit and freeze line. On a production-scale line using a 45 mm single-screw extruder with 30:1 L/D, a 120 mm die, and 0.9 mm die gap, a stable stalk is obtained at melt temperature 172–178 °C, blow-up ratio 2.4–2.6, and frost line height 18–22 cm for 22 µm film. The corresponding specific energy input is 0.22–0.28 kWh/kg. If melt temperature falls below 168 °C, the copolyester-rich domains increase backpressure at the screen pack and reduce output; the bubble narrows and enters draw resonance. If melt temperature exceeds 182 °C, PLA chain scission lowers melt tension, causing biaxial thinning and gauge variation above ±12 % as determined by a non-contacting capacitance scanner sampling at 50 Hz.

    Screw design should use a low-shear barrier screw with compression ratio 2.5:1–3.0:1. High-shear mixing sections generate excessive frictional heat and shift the melt temperature above 185 °C even when barrel setpoints remain low. The recommended barrel profile is a reverse profile from feed 150–160 °C to metering 170–178 °C. Because the blend has higher melt viscosity than LLDPE at 180 °C, upstream pressure on a 45 mm extruder running 50 min⁻¹ can reach 120–160 bar. Screen packs above 60 mesh are not recommended for long runs because gel particles from the chain-extension reaction can accumulate and require more frequent screen changes than LDPE.

    Boundary conditions for single-layer blown film extrusion of Compostable 3002
    ParameterRecommended rangeControl method
    Pellet moisture<250 ppmISO 15512:2019 Karl Fischer after hopper dryer
    Drying air dew point-40 °Cdesiccant dryer
    Barrel zone profile150–180 °Creverse profile: feed 150–160 °C, metering 170–178 °C
    Melt temperature165–185 °Cadapter melt thermocouple
    Die gap0.8–1.2 mmsingle-lip or dual-lip air ring
    Blow-up ratio2.2–2.8air flow and layflat control
    Frost line height for 25 µm15–25 cmoptical line sensor
    Specific output0.6–1.0 kg/h/cmvolumetric or gravimetric throughput

    Die build-up is the dominant continuous-run failure mode. At 26–30 °C ambient and 55–65 % RH, low-molecular-weight ester oligomers migrate to the die lip and oxidize into amber deposits within 6–10 h. Mechanical cleaning of the chrome-plated lip is more effective than purging with cast acrylic at 20–30 min⁻¹, because the polar blend adheres to the metal interface and resists displacement by nonpolar purge media. The use of boron nitride purging compounds above 190 °C is not advised because residual surface-energy reduction destabilizes the bubble at restart. Edge trim and post-industrial regrind addition above 20 wt% is not recommended on high-stalk geometries because reprocessed PLA exhibits reduced melt strength and increased gel particles.

    Mechanical Property Benchmarks Against Unmodified PLA and PBAT-Rich Blends

    Comparative data from 30 µm blown film indicate that Compostable 3002 occupies an intermediate position between unmodified PLA and PBAT-rich compounds. Tensile properties are determined according to ISO 527-3:2018 on 15 mm wide strips; dart impact is reported according to ASTM D1709-16a; tear propagation is determined with ASTM D1922-15. The blend reduces the brittle failure of PLA at low temperature while retaining sufficient stiffness to avoid the blocking and winding-tension problems associated with PBAT-rich materials. The values in Table 2 are class-level comparison ranges from publicly reported blown film data; lot-specific certificates of analysis should be used for specification setting.

    Indicative property ranges for 30 µm film of Compostable 3002, unmodified PLA, and PBAT-rich blend
    PropertyTest methodCompostable 3002Neat PLAPBAT-rich
    Tensile strength MDISO 527-3:201835–45 MPa45–60 MPa18–28 MPa
    Elongation at break MDISO 527-3:2018250–400 %5–15 %500–800 %
    Dart impactASTM D1709-16a150–250 g50–100 g300–700 g
    Elmendorf tear MDASTM D1922-1580–140 N/mm15–30 N/mm150–300 N/mm
    Secant modulus MDASTM D882-181,000–1,500 MPa2,500–3,500 MPa60–150 MPa
    OTR at 23 °C, 0 % RHASTM D3985-17800–1,200 cm³/(m²·d·bar)350–550 cm³/(m²·d·bar)2,000–3,000 cm³/(m²·d·bar)

    Against neat PLA, the product lowers modulus and oxygen barrier but improves elongation and puncture propagation. Against PBAT-rich films, it offers better gauge control in thin films because the melt has higher plateau stress, but it has lower tear resistance. The oxygen transmission rate at 23 °C and 0 % RH remains above 800 cm³/(m²·d·bar), making the film unsuitable for oxygen-sensitive food packaging without an inorganic barrier layer. The water vapor transmission rate determined by ISO 15106-2:2014 at 38 °C and 90 % RH is typically 150–250 g/(m²·d), which excludes use in dry-product packaging requiring a shelf-life beyond 90 days unless a secondary barrier is present.

    For converters replacing LLDPE on a coex line, the transition is not drop-in. The die gap should be reduced from the typical LLDPE range of 1.5–2.5 mm to 0.8–1.2 mm to increase shear heating and avoid melt sag. Adapter and die setpoints should be lowered by 10–15 °C relative to LLDPE, and screw speed should be raised to maintain output at 75–85 % of the LDPE baseline. The high-stalk bubble geometry used for LLDPE is unsuitable: the bubble flaps and develops gauge variation above ±12 %. A more stable configuration is a low-stalk or pocket bubble with the upper nip placed 1.5–2.0 m above the die. Seal initiation occurs at 85–95 °C for 30 µm film on a heated flat-plate sealer with 0.5 s dwell and 2 bar pressure, compared with 105–115 °C for LLDPE. Heat-seal strength should be measured per ASTM F88/F88M-21 after 24 h aging; immediate seal values are higher than aged values due to post-seal crystallization of PLA at the bond line.

    When Compostable 3002 Replaces LDPE in Organic Waste Collection Liners

    Organic waste liner production combines two mechanical failure modes: tear propagation at overfilled bin edges and creep rupture during wet waste transport. In a 25 µm liner, the grade exhibits a 20–30 % higher Elmendorf tear resistance in the transverse direction than unmodified PLA, but remains 40–60 % below PBAT-rich formulations. Liners are not recommended for transport intervals exceeding 48 h with wet organic waste loads above 10 kg because moisture plasticizes the amorphous phase and reduces modulus. For bin liners stored in household caddies at 23–30 °C and 80–90 % RH, puncture resistance is more relevant than tensile modulus; testing should follow a standardized drop-puncture method, as ASTM D1709-16a only approximates quasi-static puncture and may overstate performance.

    Disintegration testing under EN 13432:2000 or ASTM D6400-23 requires the film to fragment to <2 mm within 12 weeks and achieve 90 % mineralization relative to a cellulosic reference within 180 days. These are certification thresholds, not intrinsic material properties; converters must retest the final film when pigments, antifog, or slip masterbatch are added because titanium dioxide and carbon black loadings above 2 wt% can delay disintegration. Unlike oxo-fragmentable polyolefin films, Compostable 3002 does not rely on transition-metal pro-oxidants and is not compliant with EN 13432:2000 unless the complete final article has passed the certification scheme. Food-contact status is not implied by compostability certification. Direct food-contact use requires separate confirmation under FDA 21 CFR 175.300 or EU 10/2011 for the finished film. The supplier should provide REACH and SVHC declarations under REACH 1907/2006; no Annex XVII restriction is assumed for packaging use without confirmatory lot-specific documentation.

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