Cnooc Shell Cspc Huizhou Hdpe B53 35h

CNOOC & Shell (CSPC Huizhou) HDPE B53-35H

    • Product Name: CNOOC & Shell (CSPC Huizhou) HDPE B53-35H
    • Factroy Site: Yinchuan, Ningxia, China
    • Price Inquiry: sales8@ascent-chem.com
    • Manufacturer: Ascent Petrochem Holdings Co., Limited
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    Specifications
    HS Code 380006
    Density 0.953 g/cm³
    Melt Flow Rate 190 C 2 16 Kg 0.35 g/10 min
    Melt Flow Ratio 100
    Tensile Strength At Yield 26 MPa
    Tensile Strength At Break 30 MPa
    Elongation At Break >600%
    Flexural Modulus 1100 MPa
    Notched Izod Impact Strength 23 C 20 kJ/m²
    Charpy Notched Impact Strength 23 C 15 kJ/m²
    Vicat Softening Temperature 125 °C
    Heat Deflection Temperature 0 45 Mpa 70 °C
    Shore D Hardness 65
    Environmental Stress Crack Resistance F50 >1000 h
    Water Absorption <0.01%
    Melting Point 130 °C
    Brittleness Temperature <-70 °C
    Volume Resistivity >10^16 Ω·cm
    Dielectric Constant 1 Mhz 2.3
    Dissipation Factor 1 Mhz 0.0002
    Thermal Conductivity 0.4 W/m·K
    Coefficient Of Linear Thermal Expansion 1.2×10^-4 /°C
    Specific Heat 1.9 kJ/kg·K
    Oxygen Index 17%
    Flammability UL94 HB
    Crystallinity 70–80%

    As an accredited CNOOC & Shell (CSPC Huizhou) HDPE B53-35H factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing CNOOC/Shell CSPC Huizhou HDPE B53-35H is packed in 25 kg polyethylene bags, with 40 bags per 1,000 kg pallet.
    Container Loading (20′ FCL) Container Loading (20′ FCL) for CNOOC & Shell (CSPC Huizhou) HDPE B53-35H: palletized 25 kg bags, securely stowed and waterproofed.
    Shipping CNOOC & Shell (CSPC Huizhou) HDPE B53-35H is a non-hazardous high-density polyethylene resin, usually supplied as pellets in 25 kg bags, jumbo bags, or bulk. It ships by truck, rail, or container without dangerous-goods classification. Keep dry, ventilated, away from heat, moisture, and UV. Store under cover.
    Storage Store CNOOC & Shell (CSPC Huizhou) HDPE B53-35H in a cool, dry, well-ventilated warehouse, away from direct sunlight, heat, and ignition sources. Keep original bags or containers sealed, palletized, and off the floor to prevent moisture, dust, and contamination. Avoid strong oxidizers. Protect from physical damage and observe safe stacking limits, local regulations, and SDS guidance.
    Shelf Life Shelf life is typically 12 months from production when stored unopened in a cool, dry, well-ventilated area away from sunlight.
    Application of CNOOC & Shell (CSPC Huizhou) HDPE B53-35H

    Industrial chemical jerry cans in the 20–30 L UN-certified class are manufactured from CNOOC & Shell (CSPC Huizhou) HDPE B53-35H on accumulator-head extrusion blow-moulding lines equipped with 80–110 mm grooved-barrel extruders at 24:1–30:1 L/D. The resin is characterised by a nominal density of 0.953 g/cm³ under ISO 1183-1:2019 and a high-load melt mass-flow rate of 35 g/10 min at 190 °C and 21.6 kg under ISO 1133-1:2022. Melt temperature is maintained between 180 °C and 210 °C, while the die gap is set from 1.5 mm to 2.5 mm. Parison length is held within ±5 mm because larger deviations generate wall thinning below 0.8 mm above the bottom pinch-off zone. For UN 3H1/Y approval, the filled container is conditioned at -18 °C for 24 h and drop-tested under UN Model Regulations 6.1.5.3, then subjected to an internal hydraulic pressure of 100 kPa for 30 min. Outdoor-grade packs use 2.0–2.5 wt% carbon black masterbatch dry-blended at the throat; this raises die-head pressure by 6–12%, which must be offset by reducing accumulator fill rate or the parison develops an uneven circumference. Top-load resistance is verified by a 200 kg dead load applied for 24 h at 40 °C using a calibrated compression platen in accordance with ISO 12048:1994. The terminal product is a 20.0–25.0 L jerry can with calibrated screw cap, 0.8–1.2 mm nominal wall, and product-contact layer free of post-consumer recycled resin unless solute-specific permeation data support incorporation.

    Compliance matrix for HDPE B53-35H downstream applications
    Application segmentStandard or test methodCritical requirement or measured parameter
    Industrial jerry can for solvents and corrosivesUN Model Regulations 6.1.5.3, ISO 12048:1994Drop at -18 °C; hydrostatic 100 kPa for 30 min; top load 200 kg at 40 °C for 24 h
    Diesel exhaust fluid / AUS 32 packISO 22241-3:2019, ASTM D2463-15Urea immersion 32.5 wt% at 40 °C for 120 h; drop at -40 °C after 24 h
    Portable fuel canEPA 40 CFR 59.203, ASTM F2874-19Permeation limit 0.4 g/gal/day; fluorination 0.1–1.0 vol% F₂/N₂ at 25–40 °C
    Crop-protection container40 CFR Part 156, ISO 12048:1994Stack load 250 kg at 40 °C for 28 days; child-resistant closure
    Automotive lubricant bottle94/62/EC Article 11, ASTM D543-21Heavy metals sum < 100 ppm; engine oil compatibility for 7 days at 23 °C

    What limits wall-thickness reduction in AUS 32 container blow moulding?

    For diesel exhaust fluid (AUS 32) packs in the 5–20 L range, HDPE B53-35H is processed on shuttle or rotary-wheel blow-moulding machines with dry-air blow circuits rated at 1.0–1.4 m³/min and oil-free blow pressure of 0.55–0.75 MPa. The governing constraint is parison sag at long hang times. At a parison length of 500 mm, wall thinning of 0.15–0.30 mm occurs when the programmed die gap falls below 1.8 mm; therefore, 10–20 L containers are produced with a minimum die gap of 1.8 mm and a 1.2–1.5 mm final minimum wall. Melt temperature is 185–205 °C, while mould coolant is maintained at 12–18 °C. A lower mould temperature reduces pinch-line fusion and creates weld-line leaks under ASTM D2463-15 drop testing, while a higher temperature lengthens cycle time and causes surface sink marks behind the handle. Compliance with ISO 22241-3:2019 for AUS 32 handling and storage excludes copper- and zinc-containing additives, amine-based antistatic agents, and siloxane-based external mould release agents. Finished containers are immersed in 32.5 wt% urea solution at 40 °C for 120 h; the liquid is then screened for aldehyde oxidation products and metal extractables. The only formulation addition in the contact layer is 0.8–1.5 wt% titanium dioxide white masterbatch; slip agents and antistatic concentrates are excluded unless extractables are validated. Drop impact is tested under ASTM D2463-15 after conditioning at -40 °C for 24 h. Terminal products are 10-L tamper-evident DEF bottles and 20-L closed-loop refill drums with an integrally moulded vent seat. The high-load MFR of 35 g/10 min permits 20-L parison extrusion but demands active parison programming to avoid thin spots near the weld line.

    For portable fuel containers in the 5–20 L monolayer format, HDPE B53-35H is used as the substrate for post-mould fluorination rather than as a standalone barrier layer. The U.S. EPA 40 CFR 59.203 permeation limit for portable fuel containers is 0.4 g/gal/day; untreated monolayer HDPE of 2.0 mm wall thickness can exceed this limit under certification conditions, so surface fluorination is applied. The moulded can is transferred to a sealed stainless-steel fluorination chamber and exposed to 0.1–1.0 vol% fluorine in nitrogen at 25–40 °C for 5–20 min. The surface reaction replaces hydrogen atoms near the polymer surface with fluorine, reducing hydrocarbon diffusion by 85–95% in laboratory permeation testing. The acceptable process window is narrow. Fluorine concentrations above 1.2 vol% or residual oxygen above 0.2 vol% produce brown discoloration and handle-hinge embrittlement; fluorine levels below 0.05 vol% leave permeation above the regulatory limit in the closure boss region. Wall-thickness distribution is therefore fixed at 2.0–2.5 mm on broad panels and 2.5–3.0 mm along the pinch line. Drop testing is conducted under ASTM D5276-19 at -18 °C with the can filled to 90% of brimful capacity. Flame mitigation devices are verified to ASTM F2874-19. Terminal products are CARB-compliant petrol and diesel utility cans with spill-proof spouts. Published data for this specific resin in fluorinated monolayer fuel cans is limited; the operating ranges cited derive from fluorination equipment manufacturer practice and EPA certification test protocols rather than a single B53-35H certification file.

    When a crop-protection pack must hold stack load under tropical warehouse heat

    Agricultural chemical containers in the 1–10 L range are produced from HDPE B53-35H on single-station shuttle blow-moulding machines with 60–80 mm extruders at 18–22 rpm and 185–205 °C melt temperature. The contact layer is formulated as virgin material only; post-consumer recycled resin is not used in the product-contact layer. For phenoxy herbicides, glyphosate formulations, and organophosphate solutions, in-line formulation consists of 3.0–3.5 wt% hindered-amine light stabilizer masterbatch, 2.0–2.5 wt% carbon black or titanium dioxide masterbatch, and 0.2–0.5 wt% processing antioxidant. The container/closure system is qualified under 40 CFR Part 156 pesticide container criteria and under ISO 12048:1994 for stack compression after filled storage at 40 °C for 24 h. A stack load of 250 kg is applied for 28 days at 40 °C; permanent deformation above 5% of original height disqualifies the pack for warehouse stacking. The closure is a tamper-evident polypropylene cap with a wax-free EPDM liner; liner compatibility is verified by a 14-day storage test at 40 °C and 85% relative humidity, with dimensional change assessed against the cap torque retention limit. Terminal products are 1-L, 5-L and 10-L UN 3H1/Y containers with 1.2–1.6 mm wall thickness and child-resistant closures where required by the crop-protection registration. The process is less thermally demanding than fuel-pack fluorination, but the critical fault is parison pinch-line contamination at the handle insert; mould release residue on the insert reduces weld strength and causes drop failure under UN Model Regulations 6.1.5.3.

    Three-layer coextrusion blow moulding of 1–5 L automotive lubricant bottles uses HDPE B53-35H as the inner and outer skins around a post-consumer recycled HDPE core. Layer distribution is set at 20/60/20 to 25/50/25 and is maintained by three extruders feeding a single multilayer die; the machine configuration is a 6-station rotary wheel with in-mould labelling. Melt temperature is 190–205 °C, and the die gap is controlled between 1.2 mm and 1.8 mm. Compatibility with 5W-30 engine oil is evaluated under ASTM D543-21 for 7 days at 23 °C; dimensional change and weight change are measured, and any exceedance of the agreed packaging specification triggers reduction of the recycled core fraction. Heavy metals in the final bottle are kept below a sum of 100 ppm for lead, cadmium, mercury and hexavalent chromium under Directive 94/62/EC, Article 11. The terminal bottle is a 1-L or 4-L motor oil pack with a 38-mm calibrated neck finish, a 0.7–0.9 mm minimum wall, and residual flash allowance below 0.5 mm. Incoming post-consumer HDPE is screened by ISO 1133-1:2022; a core resin with high-load MFR above 55 g/10 min causes parison curvature at the die and is rejected before batch blending. The segment has lower processing risk than fluorinated fuel containers, but viscosity mismatch between the B53-35H skins and the recycled core remains the main source of batch-to-batch wall-thickness variation.

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    Certification & Compliance
    More Introduction

    CNOOC & Shell (CSPC Huizhou) HDPE B53-35H is a high-density polyethylene extrusion blow-moulding resin produced at the CSPC petrochemical complex in Huizhou, Guangdong Province, China. The product is supplied as pelletised, stabilised resin and is identified by producer nomenclature for blow-moulding use. Published nominal specifications list density as 0.953 g/cm³ at 23°C and melt flow rate as 0.35 g/10 min at 190°C under 2.16 kg load, with density determined by ISO 1183-1:2019 or ASTM D1505 and melt flow rate by ISO 1133-1:2022 or ASTM D1238. These values place the grade in the medium-high molecular weight HDPE blow moulding class, intended for continuous shuttle, accumulator-head, and reciprocating-screw extrusion blow moulding of rigid hollow parts. It is not classified as a film, pipe, or injection-moulding grade. The primary processing selection criterion is parison melt strength rather than rapid screw recovery.

    When B53-35H Replaces Lower-Density HDPE in Rigid Packaging Applications

    Substitution of a lower-density HDPE resin (0.946–0.950 g/cm³) with B53-35H changes the thermal and mechanical balance of the formed article. The higher density of 0.953 g/cm³ increases crystallinity and therefore raises tensile yield stress as measured by ISO 527-2:2012 and flexural modulus as measured by ISO 178:2019. This shift improves top-load capacity and stack resistance in packaging but may reduce low-temperature dart impact or drop-impact performance at equivalent wall thickness. Cold-drop acceptance is evaluated by ASTM D2463-15 or by internal converter drop tests. The higher density may also increase the crystalline melting peak by several degrees Celsius relative to lower density grades; the actual differential is to be confirmed by differential scanning calorimetry per ISO 11357-3:2018. Published data for this specific substitution scenario is limited, so conversion trials should compare wall-thickness distribution, pinch-off weld integrity, and environmental stress crack resistance side by side rather than relying on density and melt flow rate alone.

    Specific measurement of top-load strength on finished containers is commonly performed according to ASTM D2659-16 or ISO 12048:1994. Because B53-35H has a higher density than 0.949 g/cm³ HDPE, the same part geometry typically shows higher column crush resistance, but processing conditions must be adjusted to avoid excessive orientation-induced stress. Environmental stress crack resistance remains a separate variable and is evaluated with ASTM D1693, condition B, 10% Igepal CO-630, or with notched constant tensile load tests under ISO 16770:2004. Higher density can reduce ESCR if molecular weight and comonomer type are held constant; therefore, B53-35H should not be specified for large industrial containers exposed to aggressive surfactants without written ESCR data from the supplier.

    In continuous extrusion blow moulding of small-to-medium industrial containers, B53-35H is processed on shuttle machines with single-screw extruders of L/D 24:1–30:1, barrier screws, and grooved or smooth feed sections. Low melt flow resin of 0.35 g/10 min develops higher shear viscosity than 0.60 g/10 min HDPE; therefore, head pressure and screw torque at equal screw speed are correspondingly higher. Melt temperature is typically maintained between 180°C and 210°C, with die head temperature at or near 200°C to homogenise parison temperature. Sustained melt temperatures above 230°C invite oxidative degradation, while barrel zones below 170°C can produce unmelts and surface roughness. These limits are class-typical for HDPE and should be confirmed by supplier technical data because grade-specific additive stabilisation and antioxidant packages influence high-temperature tolerance. Blow-air pressure is commonly set between 4 bar and 7 bar; mould cooling water is commonly supplied at 8–15°C. Accumulator-head machines with parison lengths above 300 mm benefit from the resin’s melt strength, but published data for this specific configuration is limited.

    Drying is not normally required for HDPE if the pellet bag is sealed and condensation is absent. When hopper condensation or surface moisture is present, a dehumidified air dryer at 60–80°C for 1–2 h is used to prevent surface splay and microvoids. Pellets should not be air-canned with compressed air containing oil or water aerosol. Magnetic grates and fine-mesh screens of 60/80/60 or similar pack configuration are used to protect the head tooling from contaminants. Processors should avoid mixing B53-35H with PET, PVC, or acetal residues in regrind systems; even low-level contamination can produce phase incompatibility and melt-pressure fluctuations.

    ParameterNominal valueTest standard
    Density0.953 g/cm³ISO 1183-1:2019 / ASTM D1505
    Melt flow rate0.35 g/10 minISO 1133-1:2022 / ASTM D1238
    Moisture handlingNot normally requiring forced drying unless surface condensation is presentSupplier bulk handling guidance

    What Are the Practical Differences Between B53-35H and Higher Melt Index Blow Moulding Resins?

    Compared with a higher melt flow blow moulding resin of similar density (0.60 g/10 min or 0.80 g/10 min), B53-35H exhibits higher elongational viscosity and greater parison sag resistance. On a continuous shuttle machine, a lower MFR of 0.35 g/10 min generally requires higher screw torque and develops higher die-head pressure at the same screw speed. The practical difference is longer open-mould transfer time before visible parison necking, permitting larger container diameters and more consistent wall-thickness control in multi-cavity tools. The processing penalty is lower throughput at fixed extruder speed, which may extend cycle time if the extruder is undersized. Higher MFR grades are preferred where short cycle time and thin-wall rapid inflation dominate, while B53-35H is selected where melt strength and part weight consistency are the dominant acceptance criteria.

    Melt pressure must be monitored against the extruder manufacturer’s maximum continuous head-pressure rating. For 65 mm or 75 mm single-screw extruders used in HDPE blow moulding, maximum rated head pressure commonly falls between 350 bar and 450 bar. If die pressure approaches this limit, processor responses include raising barrel temperature in the metering zone, reducing screw speed, changing screen pack configuration, or selecting a higher-MFR resin. The actual pressure response for B53-35H on a given machine cannot be calculated solely from MFR; slip effects, die geometry, temperature uniformity, and lot-to-lot molecular weight distribution affect measured values. Published data for this specific configuration is limited, and start-up trials should record pressure, torque, melt temperature, and parison length before setting production limits.

    Another difference lies in molecular weight distribution effects on die swell. Low-MFR HDPE grades often show higher die swell and heavier preform wall, but die swell is not specified by MFR alone. Converters may need to adjust die pin and bushing dimensions when switching from a 0.60 g/10 min resin to B53-35H. A larger die gap or modified divergence angle may be required to maintain target parison outer diameter. These tooling adjustments are typically validated by short-shot studies and wall-thickness distribution measurements using ultrasonic gauging or optical sectioning, not solely by melt flow data.

    Storage, Handling, and Regulatory Verification Requirements

    Store B53-35H in original sealed packages, on pallets away from direct sunlight and rain, at temperatures below 50°C. Although HDPE is not hygroscopic, surface condensation on pellets can reduce melt quality and cause surface defects; therefore, cold pellets should be brought to processing-floor temperature before hopper loading. If condensation is evident, warm-air or dehumidified-air drying at 60–80°C for 1–2 h is sufficient to remove surface moisture. Processors should not use high-shear dryers or vacuum dryers routinely used for PET; they are unnecessary and may generate fines.

    At the hopper and feed throat, avoid contamination with ferrous particles from worn granulator blades and with foreign polymer powders. Regrind from post-industrial scrap may be incorporated into B53-35H up to levels validated by the converter, but closed-loop containers exposed to aggressive contents must be assessed for molecular weight degradation. Regrind fraction above 30% is not supported by published data for this specific grade and should be evaluated for melt flow shift, colour, and odour before use. Do not add unapproved nucleating agents, clarifiers, or low-molecular-weight hydrocarbon oils without supplier validation because these additives alter crystallisation behaviour and may reduce environmental stress crack resistance.

    Regulatory compliance is end-use dependent and is not established by the nominal density or melt flow rate. For direct food-contact packaging, obtain written supplier certification citing FDA 21 CFR 177.1520 or the applicable European Union food-contact regulation (EU) No 10/2011, including overall migration and specific migration limits for each additive. For drinking water containers, compliance must be proven against the applicable national potable water certification; no claim of potability is made by this document. For European market placement, confirm REACH registration and Safety Data Sheet status. For electronic packaging or restricted substance programmes, request supplier declaration under RoHS Directive 2011/65/EU. Do not assume that a generic HDPE resin automatically meets all end-use food-contact or drinking-water regulations.

    Compliance areaApplication conditionRequired verification
    Food contactDirect food contact packagingSupplier letter citing FDA 21 CFR 177.1520 or (EU) No 10/2011
    Drinking water contactIf used for potable water containersCertification to applicable national potable water standards; do not infer from HDPE resin density or MFR
    RoHS / REACHEU market placementSafety Data Sheet and supplier declaration
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