| HS Code | 410166 |
| Productname | CiaoPlas™ PLA212LST Natural Color Easy Process Biodegradable Polylactic Acid |
| Brand | CiaoPlas™ |
| Grade | PLA212LST |
| Materialfamily | Polylactic Acid (PLA) |
| Color | Natural |
| Form | Pellets |
| Odor | Low characteristic |
| Density | 1.24-1.25 g/cm³ |
| Meltflowrate | 10-20 g/10 min (190 °C/2.16 kg) |
| Meltingtemperature | 150-170 °C |
| Glasstransitiontemperature | 55-60 °C |
| Tensilestrength | 50-70 MPa |
| Tensilemodulus | 3000-4000 MPa |
| Elongationatbreak | 2-10% |
| Flexuralstrength | 70-90 MPa |
| Flexuralmodulus | 3000-4000 MPa |
| Hardness | 80-85 Rockwell R |
| Heatdeflectiontemperature | 50-60 °C (0.45 MPa) |
| Vicatsofteningtemperature | 55-65 °C |
| Moisturecontent | <0.5% |
| Biodegradability | Biodegradable |
| Compostability | Industrial compostable |
| Renewablecontent | Biobased |
| Processingmethod | Injection molding, extrusion |
| Dryingtemperature | 80 °C |
| Dryingtime | 4 hours |
| Melttemperature | 190-220 °C |
| Moldtemperature | 20-40 °C |
As an accredited CiaoPlas™ PLA212LST Natural Color Easy Process Biodegradable Polylactic Acid factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.
| Packing | Packaged in 25 kg moisture-barrier foil bags, palletized, for CiaoPlas™ PLA212LST Natural Color Easy Process Biodegradable Polylactic Acid. |
| Container Loading (20′ FCL) | 20′ FCL container loading: CiaoPlas™ PLA212LST Natural Color Easy Process Biodegradable Polylactic Acid, palletized and secured for shipment. |
| Shipping | CiaoPlas™ PLA212LST is shipped as non-hazardous, biodegradable, natural-color polylactic acid resin in moisture-barrier bags or drums. It requires cool, dry conditions, away from heat, sunlight, and moisture. No special dangerous goods classification; standard freight, air, or sea transport is suitable, with sealed packaging to prevent hydrolysis and contamination. |
| Storage | Store CiaoPlas™ PLA212LST in a cool, dry, well-ventilated area away from direct sunlight, heat, moisture, and ignition sources. Keep containers sealed to prevent dust and moisture absorption. Maintain stable temperature and humidity; avoid prolonged exposure above recommended limits. Segregate from strong oxidizers, acids, and bases. Follow local regulations and manufacturer's instructions. Use appropriate housekeeping to control dust. |
| Shelf Life | Typical shelf life is 12–24 months when stored sealed in original packaging, cool, dry, protected from moisture, heat, and sunlight. |
On roll-fed thermoforming lines producing deli cups, produce trays, and clear bakery clamshells, CiaoPlas™ PLA212LST is first dried in a desiccant dryer with a dew point below -40°C at 80°C for 4 h until residual moisture by Karl Fischer titration under ISO 15512:2019 remains below 250 ppm. Dried resin is conveyed to a single-screw extruder with a 30:1 L/D barrier screw and a screen pack configured at 20/40/60 mesh, maintaining melt temperature at 195°C to 210°C at the flex-lip die. Sheet thickness is controlled between 0.30 mm and 0.50 mm; polishing roll temperatures are held at 40°C to 60°C to reduce surface haze without inducing premature cold crystallization. During plug-assist thermoforming, sheet surface temperature must stay within 90°C to 105°C. Excursions above 110°C create wall thinning at plug contact points, while temperatures below 85°C trigger stress whitening at corner transitions. Mould temperature is maintained at 25°C to 35°C. Because PLA212LST has a narrow thermoforming window, sheet temperature variation across the web should not exceed ±5°C. Final articles are tested for compostability under EN 13432:2000 or ASTM D6400-23, and food contact compliance is verified under Regulation (EU) No 10/2011, including migration testing according to Annex V. Limitations include low heat resistance above approximately 55°C to 60°C; hot-fill applications are excluded unless secondary annealing is added after forming.
| Operation | Equipment/condition | Set point | Measured or controlled variable |
|---|---|---|---|
| Drying | Desiccant dryer, dew point below -40°C | 80°C for 4 h | Residual moisture below 250 ppm by ISO 15512:2019 |
| Sheet extrusion | Single-screw extruder 30:1 L/D, barrier screw | Melt 195°C to 210°C | Die pressure, sheet gauge 0.30 mm to 0.50 mm |
| Thermoforming | Roll-fed plug-assist | Sheet surface 90°C to 105°C; mould 25°C to 35°C | Corner thickness, stress whitening |
| Monofilament extrusion | Single-screw extruder 24:1 L/D, gear pump | Melt 200°C to 215°C | Diameter 1.75 mm ± 0.05 mm; 2.85 mm ± 0.10 mm |
| Injection moulding | Reciprocating screw, 20:1 L/D to 24:1 L/D | Melt 200°C to 215°C; injection pressure 80 MPa to 120 MPa | Part weight, gate freeze time |
| Extrusion coating | Coextrusion feedblock, slot die | Melt 205°C to 220°C | Coating weight 15 g/m² to 30 g/m²; adhesion by ASTM F904 |
| Blown film | Blown film line 30:1 L/D, die gap 1.4 mm | Melt 155°C to 170°C | Film thickness 10 μm to 25 μm; BUR 2.5:1 to 3.0:1 |
Before extrusion into fused filament fabrication feedstock, PLA212LST requires the same sub-250 ppm moisture ceiling applied in sheet extrusion. Monofilament lines typically use a single-screw extruder with a 24:1 L/D screw, melt pump, and laser diameter gauge. Melt temperature is set between 200°C and 215°C; higher temperatures reduce melt viscosity but increase lactide regeneration and molecular weight loss. Filament is quenched in a water trough held at 50°C to 60°C, and puller tension is trimmed to maintain diameter at 1.75 mm ± 0.05 mm or 2.85 mm ± 0.10 mm. Ovality is controlled below 0.05 mm because downstream feeding consistency in Bowden and direct-drive extruders deteriorates when out-of-roundness exceeds that threshold. Printed articles produced from PLA212LST filament are evaluated for tensile properties according to ISO 527-2:2012 or ASTM D638-14. The operational boundary is moisture: in ambient relative humidity above 60%, filament spools must be stored in sealed containers with desiccant, and the resin must be dried immediately before extrusion. Printer build plates are commonly kept between 50°C and 60°C to promote first-layer adhesion without reaching the heat deflection limit of the material.
For disposable cutlery and thin-wall portion cups moulded in multi-cavity tools, PLA212LST is processed on reciprocating-screw injection moulding machines with screw L/D ratios from 20:1 to 24:1 and check rings sized for low-viscosity polymer melts. The barrel temperature profile is set from 180°C at the feed throat to 215°C at the nozzle; actual melt temperature is confirmed at 200°C to 215°C. Injection pressure typically ranges from 80 MPa to 120 MPa, and hold pressure is set at 60% to 80% of peak injection pressure until gate freeze. Tooling uses direct edge gates with land lengths below 0.8 mm for 1.2 mm wall thickness; cold runner diameters are not less than 6 mm to avoid premature solidification. Mould temperature is held at 25°C to 30°C. Ejection is initiated after the part surface cools below 50°C to prevent fork tine deformation. Wall thickness above 3 mm increases sink marks and cycle time without proportional stiffness gain. Final cutlery requires compostability documentation under EN 13432:2000 and ASTM D6400-23, and food contact verification under Regulation (EU) No 10/2011 or the relevant FDA food contact notification for the finished article. PLA212LST is not suitable for hot-fill or high-load reusable cutlery unless a secondary annealing step or polymer modification is used.
| Article category | Framework | Standard/method | Verification point |
|---|---|---|---|
| Food-contact thermoformed articles | EU | Regulation (EU) No 10/2011, Annex II, Annex V | Overall migration and specific migration limit by food simulant |
| Compostable packaging and food service | US/EU/ISO | ASTM D6400-23; EN 13432:2000; ISO 17088:2021 | Disintegration, biodegradation, heavy metals, ecotoxicity |
| Paperboard food-contact laminate | US FDA | 21 CFR 176.170 | Extractives in food simulants under conditions of use |
| Agricultural mulch film | EU | EN 17033:2018 | Biodegradation in soil, ecotoxicity, absence of non-biodegradable particles |
| Filament and printed articles | EU | RoHS Directive 2011/65/EU | Restricted substance screening |
In extrusion coating of paperboard for beverage cups and take-out cartons, PLA212LST is processed through a slot die at melt temperatures of 205°C to 220°C and applied at coating weights between 15 g/m² and 30 g/m². Adhesion to paperboard is the controlling variable because polylactic acid does not wet oxidized cellulose as readily as low-density polyethylene. Corona treatment of the paperboard surface to 38 mN/m to 42 mN/m before coating improves anchorage, and some lines use a starch-based primer or a coextruded tie layer. Line speed is constrained by melt draw resonance; at speeds above 120 m/min, edge tearing and coating weight variation increase unless the melt is modified or a coextrusion feedblock is used. Chill roll temperature is maintained at 20°C to 30°C to solidify the coating without excessive crystallinity that would reduce heat-seal performance. Final laminates are tested for adhesion by ASTM F904, and food contact status is verified under 21 CFR 176.170 for paperboard components and Regulation (EU) No 10/2011 for the coating. The moisture barrier contribution is moderate; PLA212LST coating reduces water vapour transmission relative to uncoated board but does not replace high-barrier coatings for oxygen-sensitive products.
Agricultural mulch film operations running PLA212LST as a blend component with poly(butylene adipate-co-terephthalate) typically dose the PLA fraction at 15 wt% to 35 wt%. Higher loadings raise modulus but reduce dart impact and machine-direction tear resistance under field conditions. The blend is dried at 70°C for 4 h because PBAT and PLA have different moisture uptake behaviours. A blown film line with a 30:1 L/D double-flighted screw, die gap of 1.4 mm, and blow-up ratio between 2.5:1 and 3.0:1 is used. Melt temperature is held at 155°C to 170°C to avoid thermal degradation of PBAT while achieving sufficient dispersion of PLA212LST. Film thickness is controlled from 10 μm to 25 μm. For processing widths above 1.5 m, bubble stability requires uniform air-ring pressure and trimmed frost line height; PLA content above 35 wt% narrows the bubble stability window and increases splitting tendency at the nip. Final mulch film is tested under EN 17033:2018 for biodegradation in soil and ecotoxicity. Mechanical properties are measured according to ISO 527-3:2018. The film is not intended for permanent soil cover because degradation begins after the designed service period and is influenced by soil temperature and microbial activity.
In spunbond nonwoven processes, PLA212LST is dried to below 250 ppm moisture and extruded through spinnerets with hole diameters of 0.30 mm to 0.50 mm at melt temperatures from 210°C to 235°C. Filament attenuation uses high-velocity air at 3 bar to 5 bar; the narrow melt strength window of PLA requires closer spinneret-to-collector distance control than polypropylene. Calender bonding is performed at 80°C to 120°C with nip pressure adjusted to produce a bond area of 12% to 20%. Higher bond area reduces drape and increases stiffness beyond acceptable hygiene topsheet limits. Fabric basis weight is verified according to ISO 9073-1, and tensile strength is measured by ISO 9073-3. The final nonwoven is applied in wipes and hygiene top sheets where compostability claims are supported by ASTM D6400-23 or EN 13432:2000 only if all components of the finished article, including adhesives and additives, meet the same standard. Thermal shrinkage above 60°C restricts use in high-temperature sterilization or ironing processes.
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CiaoPlas™ PLA212LST Natural Color Easy Process Biodegradable Polylactic Acid is a thermoplastic polyester resin supplied in natural-color pelletized form for injection moulding and extrusion. The model designation PLA212LST identifies a high-flow lactide-based polyester within the manufacturer’s PLA212 series; the suffix LST may denote lubricated, stabilised, and easy-processing characteristics, but the exact suffix definition remains manufacturer-specific and should be verified on the certificate of analysis. Natural color indicates the absence of pre-compounded inorganic pigment, not the absence of process stabilisers or residual monomer. The resin belongs to the industrially compostable polylactic acid class when the finished article meets EN 13432 or ASTM D6400. Because PLA212LST is an aliphatic polyester, it exhibits a glass transition temperature in the range of 55–60°C and a melting endotherm between 145–170°C, as determined by differential scanning calorimetry according to ISO 11357-3:2018. The easy-process character reduces melt viscosity relative to general-purpose PLA grades of similar molecular weight, permitting lower injection pressure and shorter fill time. Published data for this specific grade are limited; lot-to-lot variation in melt flow rate, tensile properties, and moisture content should be checked against the supplier’s batch certificate.
High-flow PLA grades are typically characterised by a melt flow rate of 15–30 g/10 min when measured at 210°C with a 2.16 kg load under ISO 1133-1:2022. The viscosity of PLA212LST is therefore lower than that of standard extrusion PLA grades with melt flow rates below 10 g/10 min. On a 30 mm single-screw extruder with an L/D ratio of 30, this difference may reduce screw torque by 10–20% relative to standard PLA, depending on screw design, back pressure, and barrel temperature profile. The lower viscosity also permits filling of thin-wall sections down to 0.5 mm with reduced injection pressure and shorter cycle times. However, the same rheological feature narrows the safe processing window because low melt viscosity increases the risk of nozzle drool, gate stringing, and uncontrolled flash. At melt temperatures above 210°C, polylactic acid degrades by random chain scission, intramolecular transesterification, and thermo-oxidative cleavage. Melt residence time in the barrel should be kept below 8 min. A barrel profile of 160–200°C for the feed, compression, and metering zones is appropriate for the easy-processing grade, with the nozzle set 10–20°C lower than the front zone. Shot volume should be controlled so that the melt cushion remains 3–6 mm to avoid melt stagnation at the screw tip.
Pre-drying is mandatory when pellet moisture exceeds 0.025% by weight. PLA hydrolyzes rapidly in the melt, and the cleavage of ester bonds reduces molecular weight, raises melt flow rate, and lowers impact strength. Pellets exposed to relative humidity above 60% can exceed the moisture limit within 24 h at 23°C. A desiccant dryer with a dew point of -30°C or lower should be used at 80°C for 4 h as a starting condition. The drying hopper should be insulated and sealed, and return air should be filtered to prevent dust accumulation. On production-scale injection moulding machines, a loss-in-weight feeder with a nitrogen-purged hopper reduces moisture reabsorption. Screw speed should be held to 50–150 min¹ in injection moulding and back pressure to 0.3–0.7 MPa. On a 25 mm twin-screw compounding extruder, screw speeds of 150–250 min¹ avoid excessive shear heating, but the actual limit depends on the residence time distribution and barrel temperature profile. These parameters are derived from published high-flow PLA processing data and should be verified for PLA212LST on the specific production line.
Mould temperatures below 25°C shorten cycle time by accelerating solidification of the amorphous skin, but they also suppress crystallinity and increase residual orientation. For unfilled PLA212LST in articles with wall thicknesses of 1.0–1.2 mm, cycle times of 15–25 s are commonly observed with water-cooled moulds at 15–25°C. Fast skin vitrification reduces sink marks in thin ribs but increases the risk of warpage and anisotropic shrinkage. Mould shrinkage for unfilled PLA is typically 0.3–0.5% parallel to flow and 0.2–0.4% perpendicular to flow after conditioning at 23°C and 50% relative humidity for 48 h. In natural-color PLA, the absence of pigment particles removes a potential nucleating surface, which may produce lower and more anisotropic shrinkage than in pigmented grades. Mould temperature above 30°C increases crystallinity and heat deflection temperature but lengthens cycle time and may cause part distortion during ejection if the tool design lacks adequate draft angles. For dimensionally stable parts, the tool should include draft angles of 0.5–1.0° and ejector pins with enlarged surface area to reduce stress whitening. Processors should verify final dimensions only after post-mould conditioning because crystallisation can continue over several hours at ambient temperature.
Unfilled PLA grades of the high-flow class exhibit tensile yield stress in the range of 45–65 MPa, tensile modulus of 3.0–3.8 GPa, and elongation at break between 3% and 10% when tested according to ISO 527-2:2012. Flexural modulus is generally 3.0–3.5 GPa under ISO 178:2019, and notched Izod impact strength at 23°C is reported between 2.0 kJ/m² and 4.0 kJ/m² under ISO 180:2023. Heat deflection temperature at 0.45 MPa is commonly 50–60°C for amorphous mouldings, while annealed or nucleated grades may reach 60–70°C under ISO 75-2:2013. These ranges are compiled from publicly available PLA literature and do not replace the PLA212LST batch certificate. Biodegradation is a finished-article claim, not a resin property. Industrial compostability under EN 13432 requires 90% biodegradation within 180 days and 90% disintegration within 12 weeks at 58°C in a controlled composting environment. ASTM D6400 sets corresponding requirements for compostable plastics in the United States. Home composting at lower temperatures is not automatically satisfied by PLA212LST and should not be claimed without a specific certification.
| Property | Test method | Reported range |
|---|---|---|
| Density at 23°C | ISO 1183-1:2019 | 1.24–1.26 g/cm³ |
| Melt flow rate at 210°C/2.16 kg | ISO 1133-1:2022 | 15–30 g/10 min |
| Tensile yield stress | ISO 527-2:2012 | 45–65 MPa |
| Tensile modulus | ISO 527-2:2012 | 3.0–3.8 GPa |
| Elongation at break | ISO 527-2:2012 | 3–10% |
| Flexural modulus | ISO 178:2019 | 3.0–3.5 GPa |
| Notched Izod impact at 23°C | ISO 180:2023 | 2.0–4.0 kJ/m² |
| Heat deflection temperature at 0.45 MPa | ISO 75-2:2013 | 50–60°C |
| Recommended moisture content after drying | ISO 15512:2019 | ≤0.025% |
Use of PLA212LST is concentrated in injection-moulded compostable serviceware, rigid food packaging, thin-wall containers, caps and closures, and other short-cycle articles with wall thicknesses down to 0.5 mm. The natural color grade is selected when colouring is performed by masterbatch addition, because the absence of pre-compounded pigments reduces plate-out on mould surfaces and may improve colour consistency across lots. Compared with standard PLA grades, PLA212LST fills thin-wall parts at lower injection pressure and may allow shorter holding pressure time due to its lower melt viscosity. The same characteristic reduces melt strength, which makes the material less suitable for blown film or deep-draw thermoforming than branched or high-viscosity PLA grades. Compared with mineral-filled PLA compounds, PLA212LST has lower stiffness and lower heat deflection temperature but provides higher clarity in translucent parts. Compared with PBAT/PBS biodegradable polyesters, PLA212LST is stiffer, more brittle, and more sensitive to notches; blending may improve toughness, but the phase morphology must be confirmed by scanning electron microscopy and the modulus drop should be measured under ISO 527-2:2012.
| Regulation or standard | Scope | Typical required evidence |
|---|---|---|
| EN 13432 | Industrial compostable packaging | Biodegradation ≥90% in 180 days; disintegration ≥90% in 12 weeks; ecotoxicity pass |
| ASTM D6400 | Compostable plastics in the United States | Heavy metal limits, biodegradation, disintegration |
| REACH Regulation (EC) No 1907/2006 | European chemical safety | Safety data sheet, SVHC confirmation |
| RoHS Directive 2011/65/EU | Electrical and electronic articles | Pb, Hg, Cd, Cr VI, PBB, PBDE below legal limits |
| EU Regulation (EC) No 10/2011 | Plastic food contact materials | Overall migration and specific migration limits |
PLA212LST is not recommended for continuous service above 50–55°C unless the moulded part is annealed or contains an effective nucleating agent. At temperatures above the glass transition, amorphous regions soften, and the part loses snap-fit retention and creep resistance. Steam sterilisation at 121°C causes severe distortion and should be avoided. The resin is incompatible with strong aqueous bases, which hydrolyze the polyester backbone, and with amine-containing additives that accelerate transesterification. Chlorinated solvents and ketones dissolve or swell PLA; alcohol-based cleaning agents may cause environmental stress cracking in stressed parts. When using masterbatch, the carrier resin should be PLA-compatible and should be dried with the base pellets. Regrind levels above 20% by weight may lower melt viscosity and impact strength; multiple heat histories increase carboxylic acid end-group concentration and accelerate hydrolysis. For purging after shutdown, a high-viscosity PLA or purging compound should be used to avoid carbonised residues. Because PLA212LST is industrially compostable, storage should be in a dry environment below 50°C and away from direct sunlight to prevent premature hydrolysis and yellowing.