| HS Code | 423193 |
| Polymer Type | Acrylonitrile Butadiene Styrene (ABS) |
| Grade | PA-765A |
| Flame Retardancy | UL94 V-0 at 1.5 mm |
| Processing Method | Injection molding |
| Form | Pellets |
| Density | 1.18 g/cm3 |
| Melt Flow Rate | 5 g/10 min (200°C/5 kg) |
| Tensile Strength | 42 MPa |
| Flexural Strength | 68 MPa |
| Flexural Modulus | 2300 MPa |
| Notched Izod Impact Strength | 10 kJ/m2 |
| Heat Deflection Temperature | 78°C at 1.82 MPa |
| Vicat Softening Temperature | 95°C |
| Mold Shrinkage | 0.4-0.7% |
| Rockwell Hardness | 100 R |
As an accredited CHIMEI Zhenjiang ABS PA-765A factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.
| Packing | CHIMEI Zhenjiang ABS PA-765A is supplied in 25 kg moisture-barrier paper bags, stacked on pallets for safe storage and transport. |
| Container Loading (20′ FCL) | 20′ FCL container loaded with CHIMEI Zhenjiang ABS PA-765A in 25 kg bags, palletized, stretch-wrapped, and secured for ocean transport. |
| Shipping | CHIMEI Zhenjiang ABS PA-765A is supplied as thermoplastic resin pellets, typically packed in 25 kg bags or 1,000 kg jumbo bags on pallets. Ship in dry, covered containers at ambient temperature; avoid moisture, direct sunlight, and heat. Generally non-hazardous for transport; follow local regulations and the SDS. |
| Storage | Store CHIMEI Zhenjiang ABS PA-765A in a cool, dry, well-ventilated warehouse, away from direct sunlight, heat sources, flames, and moisture. Keep original packaging sealed and palletized; avoid stacking damage, dust, and static buildup. Separate from oxidizing agents and incompatible chemicals. Maintain stable temperature and humidity, observe shelf life, and use first-in, first-out stock rotation. |
| Shelf Life | Shelf Life: Approximately 12 months when stored dry, below 30°C, in original sealed packaging, away from sunlight. |
In fixed-installation and portable electrical accessory housings, PA-765A is specified where UL 94 V-0 flammability, dimensional stability, and resistance to repeated mechanical insertion are non-negotiable. Because socket and plug bodies are commonly overmolded around brass or phosphor-bronze pin carriers, the melt must form strong weld lines around inserts and fill wall sections from 2.0 mm to 4.5 mm without gas entrapment. Compliance is anchored to IEC 60884-1, UL 498, and national derivatives such as BS 1363 and DIN VDE 0620-1; accessible insulating parts are also evaluated under UL 94 at 1.5 mm, and glow-wire testing under IEC 60695-2-11 at 750°C or 850°C applies to parts retaining live contacts. Raw material documentation is screened against REACH SVHC and RoHS Directive 2011/65/EU as amended by (EU) 2015/863. The formulation is charged at 100 wt% virgin PA-765A; clean in-house sprues and runners may be added up to 10 wt% only after three consecutive production lots pass the same V-0 and glow-wire criteria. Drying is carried out in a desiccant dryer at 80°C for 2–3 h until moisture content is below 0.02% by Karl Fischer analysis. Molding is performed on 100–250 tonne hydraulic injection machines with a screw L/D of 20:1 to 22:1 and compression ratio of 2.0:1 to 2.5:1; melt temperature is held from 200°C to 230°C, mold temperature from 40°C to 70°C, and shot size is controlled at 30–70% of barrel capacity so that residence time does not exceed 5 min. Insert pins are preheated to 100–120°C to reduce premature cooling and internal stress around the metal-plastic boundary. Venting is cut at 0.02–0.05 mm depth to prevent burn marks at knit lines. Terminal parts include wall socket front plates, plug bodies, portable socket-outlet shells, shaver socket housings, and cord reel drums.
Multi-cavity charger and adapter production demands wall thicknesses from 0.8 mm to 1.5 mm, which reduces molten plastic inventory and tightens the processing window for flame-retardant ABS. The primary compliance framework is IEC 62368-1:2018 with its 2020 amendment for AV/ICT equipment; enclosure plastics must meet UL 94 V-0 at the minimum wall thickness, and the material is supplied against RoHS Directive 2011/65/EU as amended by (EU) 2015/863. The material preparation uses 85–90 wt% virgin PA-765A, 10–15 wt% clean in-house regrind re-dried at 80°C for 3 h, and 2–3 wt% color masterbatch whose carrier melt flow rate under ISO 1133-1:2022 at 220°C/10 kg is within 10% of the base resin. Thin-wall injection molding is performed in 16–32 cavity tools with hot runner valve gates; melt temperature is maintained between 210°C and 240°C, mold temperature between 60°C and 80°C, injection speed from 100 mm/s to 150 mm/s, and holding pressure from 70 MPa to 90 MPa to counteract in-mold shrinkage of 0.4–0.6%. Hot runner temperatures are kept 5–10°C above melt set point but below 240°C to avoid decomposition; sequential valve-gate opening moves weld lines to low-stress regions, and gas channels are not recommended because the flame-retardant system releases trace volatiles during hold. Cavity plates and tool inserts are chrome-plated or nickel-plated to resist acid gas corrosion. Dimensions are held to ±0.1 mm for ultrasonic welding or snap-fit assembly. Terminal products include USB-C charger housings, travel adapter shells, desktop power supply covers, and clip-on plug adapters.
Across monitor, set-top box, and audio-visual peripheral enclosures, the specification focus shifts toward surface appearance, rib stiffness, and long-term color stability while retaining the same UL 94 V-0 margin. Compliance for these products is anchored to IEC 62368-1, UL 94 V-0 at 1.5 mm, RoHS Directive 2011/65/EU, and California Proposition 65 screening for brominated flame-retardant degradation products in service. The recommended formulation is 95–100 wt% virgin PA-765A with 0–5 wt% same-grade regrind produced from identical color lots; if custom color is required, 1–2 wt% masterbatch is added, and external release agents are excluded because they interfere with in-mold texturing and post-mold painting. The downstream production process is large-part injection molding on 350–850 tonne machines using sequential valve-gate systems with 3–6 drops, a screw L/D of 20:1, and shot weight at 40–60% of rated capacity to retain melt homogeneity. Melt temperature is set between 210°C and 235°C, mold temperature from 45°C to 65°C, fill speed at a moderate value to avoid jetting, and packing pressure from 60 MPa to 80 MPa for 5–15 s depending on gate seal. Texture depth is controlled at 0.02–0.04 mm so that effective wall thickness at flame front spread does not fall below 1.5 mm. Drying at 80°C for 3–4 h to below 0.02% moisture is mandatory before hot-runner trials. Terminal product forms include monitor rear bezels, set-top box base covers, router housings, A/V receiver front panels, and projector lamp covers.
In power supply and power distribution unit enclosures, the pressure to reuse regrind collides with the narrow thermal stability window of brominated flame-retardant ABS, so the regrind limit is set by flammability testing rather than economics alone. The applicable standards are IEC 62368-1 for ICT equipment, UL 1778 for uninterruptible power systems, and UL 94 V-0 at 1.5 mm; where the housing forms part of a medical power supply, IEC 60601-1 may also apply. The qualified formulation for exposed UL-listed covers is 90–100 wt% virgin PA-765A with 0–10 wt% in-house regrind that has passed a three-lot heat-history verification; internal non-listed brackets may use up to 20 wt% regrind, but no post-consumer or unknown-source material is permitted. Production uses injection molding of sections between 2.0 mm and 3.5 mm, with melt temperature 205–230°C, mold temperature 50–70°C, and pack/hold pressure from 80 MPa to 100 MPa to suppress sink marks around bosses and metal inserts. Screw speed is kept at 60–100 rpm and back pressure at 0.3–0.7 MPa to avoid shear heating of the flame-retardant package. Cavity pressure transducers confirm gate freeze before hold release, because premature hold release creates voids that can behave as ignition paths during glow-wire testing. Drying is executed at 80°C for 3 h in a desiccant dryer with a dew point of ≤ -30°C and a final moisture level below 0.02%. Terminal products include modular PDU shells, UPS front panels, server power supply covers, and power management module housings.
Office automation and business machine chassis present a different processing hierarchy: long flow lengths, multiple snap-fit features, and high cosmetic surface demand must be balanced against flame-retardant resin melt stability over cycles exceeding 30 s. The compliance baseline is IEC 62368-1, UL 94 V-0 at 1.5 mm, and ISO 11469 for polymer marking; many OEM specifications also require halogen content reporting under IEC 61249-2-21 when the end equipment is exported to European markets. Incoming lot acceptance includes tensile yield strength verification under ISO 527-2 and Izod impact under ISO 180:2023. The formulation is 100 wt% virgin PA-765A for painted or plated outer covers; internal paper path components and non-critical brackets can carry up to 15 wt% same-grade regrind if the V-0 marking is not applied to those parts. Production uses 500–1300 tonne injection molding machines with multi-cavity hot runner systems; melt temperature is 200–230°C, mold temperature 40–65°C, and screw L/D of 20:1 to 22:1. Long flow lengths require filling analysis to position weld lines away from snap-fit hooks; gate locations are verified by short-shot studies and cavity pressure sensors. Cavity pressure during packing is maintained at 35–45 MPa, and texture depth is controlled at 0.02–0.04 mm to allow paint adhesion without thinning the flame front. Drying at 80°C for 3–4 h is standard, with moisture below 0.02% and desiccant bed regeneration at 120°C. Terminal products include printer front covers, copier side panels, scanner lids, multifunction peripheral control panel housings, and paper tray handles.
Household appliance control boxes are not tested only under UL 94; they are subjected to glow-wire end-product tests under IEC 60695-2-11 according to IEC 60335-1, and the acceptance value depends on whether the part is an unattended appliance or a manually attended device. The compliance chain includes IEC 60335-1:2020, IEC 60695-2-11 at 750°C or 850°C, UL 94 V-0 at 1.5 mm, and RoHS Directive 2011/65/EU. The material is charged at 100 wt% virgin PA-765A; regrind addition is limited to 5 wt% and only for parts not in contact with live terminals, because regrind particles lower melt homogeneity and can create local ignition sites. The production process requires a low-shear screw with L/D of 20:1 to 24:1, melt temperature 190–215°C, mold temperature 40–60°C, back pressure 0.3–0.5 MPa, and screw rotation speed below 80 rpm to minimize frictional heat and flame-retardant decomposition. Barrel residence time must not exceed 4 min; if a machine interruption occurs, the barrel is purged with a heat-stable carrier resin before restart. Drying at 80°C for 2–4 h to moisture below 0.02% is mandatory. Injection speed is set to a moderate profile to avoid jetting, and gate geometry is selected for smooth melt-front advancement because turbulent fill can entrain gas and increase surface defects. The relevant production equipment is typically a 120–250 tonne hydraulic or servo-hydraulic machine with a shut-off nozzle and insulated hot sprue bushing. Published data for 850°C glow-wire performance at thicknesses below 2.0 mm for this exact compound configuration is limited; therefore, end-product qualification must include the as-molded minimum wall zone. Terminal products include air conditioner control boxes, washing machine power module covers, refrigerator relay housings, boiler ignition control panels, and small-pump control enclosures.
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CHIMEI Zhenjiang ABS PA-765A is a flame-retardant acrylonitrile-butadiene-styrene injection moulding grade intended for electrical and electronic enclosure applications requiring defined flammability behaviour. The grade is identified within the CHIMEI PA-765 series as a brominated flame-retardant ABS with reported UL 94 V-0 classification at 2.5 mm nominal wall thickness and, for selected colours and plate thicknesses, UL 94 5VA at 3.0 mm. The compound is not halogen-free and is therefore incompatible with product declarations made under IEC 61249-2-21 halogen-free criteria, although compliance with Directive 2011/65/EU Annex II restricted-substance limits must be verified through the supplied material declaration. Specific gravity is approximately 1.17–1.19 g/cm³ by ISO 1183-1:2019, reflecting the flame-retardant loading; this density shift must be considered for moulded part weight and shot capacity. Melt viscosity is controlled for injection moulding, but the material has a narrow thermal processing window above 230 °C because the halogenated additive system can generate acidic degradation products when overheated or allowed to stagnate in the barrel.
Manufacturer-published typical data, not specification limits, place PA-765A in the general flame-retardant ABS range. Tensile yield strength is commonly reported at 40–45 MPa per ISO 527-2, flexural modulus at 2,200–2,400 MPa per ISO 178, and notched Izod impact strength at 18–22 kJ/m² at 23 °C per ISO 180/A. Melt volume-flow rate at 220 °C/10 kg is typically around 28–35 cm³/10 min per ISO 1133-1:2022, although the exact value depends on lot, colour, and regrind history. Heat deflection temperature under 1.8 MPa is reported at 78–85 °C per ISO 75-2/Ae, and Vicat softening temperature by ISO 306 is in the 92–98 °C range. Surface resistivity is typically above 1×10¹⁵ Ω by IEC 60093. These values are lower in impact and heat resistance than those of unfilled general-purpose ABS, although the flame-retardant grade provides a defined vertical burn rating that general-purpose ABS does not.
| Property | Test standard | PA-765A | General-purpose ABS | Unfilled PC/ABS |
|---|---|---|---|---|
| Density | ISO 1183-1:2019 | 1.17–1.19 g/cm³ | 1.04–1.07 g/cm³ | 1.12–1.15 g/cm³ |
| Tensile yield strength | ISO 527-2 | 40–45 MPa | 44–52 MPa | 55–60 MPa |
| Flexural modulus | ISO 178 | 2,200–2,400 MPa | 2,400–2,700 MPa | 2,100–2,400 MPa |
| Notched Izod impact, 23 °C | ISO 180/A | 18–22 kJ/m² | 22–30 kJ/m² | 40–55 kJ/m² |
| Heat deflection temperature, 1.8 MPa | ISO 75-2/Ae | 78–85 °C | 88–95 °C | 115–125 °C |
| Flame rating at 2.5 mm | UL 94 | V-0 | HB | V-0 in selected grades |
Values are representative ranges from published datasheets, not lot-specific specification limits. Current manufacturer documentation must be consulted before tool design or product certification.
After predrying in a desiccant dryer to ≤0.02 % moisture, the compound is processed at barrel set points of 190–230 °C from feed throat to nozzle, with a measured melt temperature of 210–235 °C. A general-purpose three-zone screw with L/D 20:1–24:1 and compression ratio 2.0:1–2.5:1 is adequate; the use of a non-return valve and hardened screw tip is standard. Mould temperature should be controlled at 40–80 °C. Hydraulic holding pressure is typically 30–60 MPa, and back pressure is set at 0.5–1.5 MPa to homogenize the flame-retardant dispersion without excessive shear heating. Injection velocity is profiled to prevent jetting and to fill the cavity before gate freeze-off. For wall sections below 2.0 mm, melt temperature may be increased to 230–240 °C, but total barrel residence time should remain below 4–6 min to prevent yellowing and acidic gas generation.
On production-scale toggle-clamp machines, clamp force is typically selected at 3–5 kN/cm² of projected mould area. Hot-runner systems must be fully balanced and free of dead spots; stagnant flame-retardant melt in manifold corners or valve-gate channels will form black specks and carbonized deposits. When purging between materials, general-purpose ABS or HIPS is preferred; direct purging with acetal or PVC is not recommended because halogenated degradation products can corrode processing equipment and cause plate-out on mould surfaces. Regrind from sprues and runners may be added at 15–25 % by weight, but repeated regrind cycles degrade impact strength and flame rating, and end-product certification must be repeated if the regrind fraction exceeds the original qualification window.
When an existing enclosure tool is converted from general-purpose ABS to PA-765A, the flame-retardant grade raises the part density by approximately 0.10–0.14 g/cm³, which increases shot weight and may require longer screw recovery or a larger barrel capacity if the original shot was near maximum. Mould shrinkage is generally within 0.4–0.7 %, but the relationship between flow-direction and transverse shrinkage differs from general-purpose ABS because of the particulate flame-retardant phase; dimensional validation with the production tool is necessary. Gate freeze-off time, packing intensity, and cooling time must be re-optimized rather than copied from the previous ABS grade. Melt temperature should not exceed 240 °C at the nozzle, because the brominated flame retardant can produce surface splay and inconsistent colour at higher thermal stress. The substitution from PA-765 to PA-765A may involve different lubrication or stabilizer balance; published data for direct property equivalence between suffix variants is limited, and qualification lots must be compared on the same injection machine.
Compared with unfilled PC/ABS, PA-765A has lower heat deflection temperature and lower notched impact; it is not a drop-in replacement where structural toughness or high-temperature creep resistance is specified. However PA-765A can be moulded at lower barrel temperatures than many PC/ABS grades, reducing energy input and thermal degradation risk in thin-wall tools. Where both UL 94 V-0 and high impact are required, PC/ABS should be evaluated; where flame retardancy, electrical insulation, and cost-constrained enclosure production are primary, PA-765A is a candidate. The comparative tracking index of halogenated ABS is generally lower than that of PC/ABS, so design clearances for creepage and tracking in live parts must follow end-product testing to IEC 60112 and IEC 60664-1. Compared with halogen-free flame-retardant ABS variants, PA-765A generally provides a wider processing window and higher stiffness but cannot meet halogen-free criteria under IEC 61249-2-21.
Application classes typically selected for PA-765A include monitor rear covers, television back covers, power adapter housings, power strip enclosures, uninterruptible power supply fronts, appliance control panels, and circuit-breaker bodies. For appliance parts under IEC 60335-1, end-product glow-wire testing to IEC 60695-2-11 is required at the actual wall thickness and colour; PA-765A is not a universal exemption from external ignition tests. In medical device or skin-contact use, biocompatibility testing to ISO 10993-1 is required because the grade is not marketed as medical-grade ABS. Outdoor exposure should be limited or protected by painting, plating, or UV-stabilized capstock because the brominated flame-retardant system can chalk and shift colour under prolonged UV irradiation.
Acceptance is normally controlled by a combination of material-level and end-product standards. The material-level UL 94 V-0 classification appears on a UL Yellow Card for specific thickness and colour; the card should be checked for minimum allowed thickness and the permitted colour range. Restricted-substance compliance is documented through the supplier’s RoHS declaration under Directive 2011/65/EU Annex II and through REACH SVHC statements under EC 1907/2006 Article 33. Halogen-free declarations under IEC 61249-2-21 are not satisfied by this product. In end-product testing, IEC 60335-1 and IEC 60695 glow-wire requirements depend on the appliance category and the current-carrying nature of the part; a moulded part can pass or fail based on wall thickness, colour concentrate, and weld-line position, so material certification does not replace product certification.
| Requirement | Applicable standard or regulation | Material status |
|---|---|---|
| Flame retardancy at 2.5 mm | UL 94 | V-0 reported; product-specific colour and wall thickness must be verified |
| Restricted substances | Directive 2011/65/EU Annex II | Supplier declaration required; brominated system may require XRF verification |
| SVHC disclosure | EC 1907/2006 Article 33 | Supplier declaration required for SVHC above 0.1 wt% |
| Glow-wire ignition | IEC 60335-1 / IEC 60695-2-11 | Product-specific test required at actual wall thickness |
| Halogen-free designation | IEC 61249-2-21 | Not applicable; product is not halogen-free |
| Comparative tracking index | IEC 60112 | Must be verified; not automatically equivalent to PC/ABS |
Storage and drying boundaries are stricter than for general-purpose ABS. At relative humidity above 60 %, open containers may absorb atmospheric moisture and reduce impact strength through hydrolysis of the rubber phase; preconditioning in a desiccant dryer at 80 °C for 2–4 h is standard. Avoid amine-based release agents, sulphur-containing antioxidant packages, and strong alkaline detergents; these chemistries can react with the halogenated flame-retardant system and create plate-out or surface bloom. The material should not be processed on machines with copper alloy thermocouple wells or brass filter elements that can corrode under acidic degradation gases. If an operator notices acrid odour or surface bubbles during production, the melt temperature and residence time must be reduced and the barrel purged immediately.