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Chimei POLYLAC SAN D-178HF

    • Product Name: Chimei POLYLAC SAN D-178HF
    • Factroy Site: Yudu County, Ganzhou, Jiangxi, China
    • Price Inquiry: sales8@ascent-chem.com
    • Manufacturer: Ascent Petrochem Holdings Co., Limited
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    Specifications
    HS Code 497541
    Polymer Type Styrene Acrylonitrile (SAN)
    Specific Gravity 1.08
    Melt Flow Rate 4.5 g/10min (200°C, 5kg)
    Tensile Strength 700 kg/cm²
    Elongation At Break 3.0%
    Flexural Strength 1,000 kg/cm²
    Flexural Modulus 34,000 kg/cm²
    Izod Impact Strength Notched 2.0 kg-cm/cm
    Rockwell Hardness M80
    Vicat Softening Point 105°C
    Heat Deflection Temperature 95°C (1.82 MPa)
    Light Transmission 90%
    Haze 1.0%
    Mold Shrinkage 0.4-0.7%
    Dielectric Constant 3.0 (60 Hz)
    Volume Resistivity >10^15 ohm-cm

    As an accredited Chimei POLYLAC SAN D-178HF factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing Chimei POLYLAC SAN D-178HF is packaged in 25 kg moisture-proof paper bags, palletized for industrial handling and storage.
    Container Loading (20′ FCL) Chimei POLYLAC SAN D-178HF: 20′ FCL typically loads ~17 MT in 25 kg bags, palletized, subject to carrier/road weight limits.
    Shipping Chimei POLYLAC SAN D-178HF is shipped as solid styrene-acrylonitrile copolymer pellets in moisture-barrier bags or bulk containers. It is generally not classified as dangerous goods. Store in a cool, dry, ventilated area away from heat, sunlight, and ignition sources; avoid dust and static during handling.
    Storage Store in a cool, dry, well-ventilated area away from direct sunlight, heat, sparks, and open flames. Keep original containers tightly closed to prevent moisture pickup and contamination. Avoid prolonged UV exposure and extreme temperatures. Maintain good housekeeping to prevent dust accumulation, and follow local regulations for combustible thermoplastic storage.
    Shelf Life For Chimei POLYLAC SAN D-178HF, shelf life is typically two years from manufacture when kept unopened in cool, dry conditions.
    Application of Chimei POLYLAC SAN D-178HF

    In high-volume cosmetic packaging lines, transparent jars, overcaps, airless dispenser shells, and compact mirror frames are produced from Chimei POLYLAC SAN D-178HF using hot-runner injection moulds with valve-gated drops to minimize gate vestige and weld-line visibility. Barrel temperature profiles are typically set with rear zones at 180–200 °C, middle zones at 200–220 °C, front zones at 210–230 °C, and nozzle at 200–220 °C; mould temperature is held between 40 °C and 60 °C to balance surface gloss and cycle time. The high-flow segment of the grade permits filling of vertical jar sidewalls at thicknesses down to 0.8 mm, but injection velocity must be maintained between 80 mm/s and 150 mm/s to avoid jetting at the gate and flow marks on polished cavity surfaces. Back pressure is limited to 5–10 bar hydraulic because excessive screw work accelerates thermal degradation of the acrylonitrile segment and shifts colour toward yellow. Screw geometries with L/D 20:1 to 24:1 and compression ratio 2.0:1 to 2.5:1 provide sufficient melting homogeneity without excessive shear heating; recovery speed is set so that screw rotation completes before cooling time expires. Drying in desiccant hopper dryers at 80 °C for 2–4 h is required when ambient relative humidity exceeds 50%, as residual moisture above 0.10% produces splay on transparent surfaces and weakens knit lines at cap hinge points. The high-flow designation is confirmed by melt volume-flow rate under ISO 1133-1:2022 using the temperature and load stated on the lot certificate.

    Compatibility with cosmetic formulation components governs dimensional stability and crack resistance more directly than food-contact regulation. POLYLAC SAN D-178HF resists aliphatic mineral oils, non-ionic emulsifiers, and low-moisture creams; it is incompatible with ketones, aromatic hydrocarbons, chlorinated solvents, and ethanol concentrations above approximately 10 wt%, which induce environmental stress cracking at gate and weld-line locations. Compatibility testing for new fragrance or solvent blends follows ISO 22088-3 for bent-strip stress cracking under controlled strain. Mechanical acceptance criteria for snap-fit overcaps use tensile elongation at break under ISO 527-2/1A/50 and notched Charpy impact under ISO 179-1/1eA; values should be obtained from the certificate of analysis because colour masterbatch and regrind content shift low-temperature impact response. Regrind levels are limited to 20% by weight in transparent packaging to maintain haze below 2.0% when measured under ASTM D1003-21.

    What Limits Polylac SAN D-178HF in Detergent and Water Reservoir Applications?

    Because clear reservoirs in steam irons, coffee machines, and floor-cleaning appliances operate under intermittent hot water and wetting-agent exposure, POLYLAC SAN D-178HF offers low water absorption and stable optical clarity but requires defined boundary conditions. Water absorption at saturation for SAN is typically in the range 0.20–0.30% under ISO 62, which limits swelling and dimensional drift in humid service; however, continuous immersion in water above 60 °C can hydrolyse nitrile groups over prolonged intervals, and published multi-year ageing data for this specific high-flow grade is limited. Reservoir bodies with wall thicknesses of 2.0–3.0 mm are moulded with melt temperatures of 210–230 °C and mould temperatures of 40–60 °C; injection velocity is reduced to 30–60 mm/s to prevent turbulent filling around float bosses and sight-glass ribs. Holding pressure of 60–80 MPa hydraulic and holding time of 2–3 s/mm are applied to control sink at threaded ports and snap-fit undercuts. Weld lines in multi-point gated reservoirs are inspected under polarized light because residual stress at knit lines is the primary initiation site for detergent-induced environmental stress cracking.

    Non-ionic and anionic surfactant solutions below 5 wt% are generally compatible; cationic quaternary ammonium formulations with pH above 9 and prolonged contact at 50 °C or higher may craze stressed gate regions. Compatibility validation for each detergent formulation uses ISO 22088-2 constant-strain exposure, and dimensional stability after water contact is assessed by ISO 294-4 on moulded plaques. Steam iron reservoir applications additionally require burst pressure testing according to IEC 60335-2-3, with weld-line strength being the limiting factor rather than base resin tensile strength. Typical parts include water tanks, sight-glass housings, detergent drawers, and steam iron reservoirs.

    In Vitro Diagnostic Housing Moulding and Optical Birefringence Control

    For benchtop diagnostic readers and laboratory instrument covers, POLYLAC SAN D-178HF is selected for high luminous transmittance and low haze, with optical performance measured under ASTM D1003-21. Transparent covers of 2.0 mm wall thickness typically retain light transmittance above 88% and haze below 2.0%, but fast injection speeds and high packing pressures generate residual birefringence that distorts LED excitation signals in the 450–650 nm wavelength band. To reduce this effect, mould temperature is raised to 60–80 °C where feasible, and post-mould annealing at 70–80 °C for 1–2 h relaxes orientation stresses before optical inspection. Gate placement on non-optical edges and minimum corner radii of 0.5 mm reduce stress concentration at mounting bosses, which are isolated from optical windows. Surface disinfection with 70% isopropanol is acceptable for short contact times, but continuous solvent exposure at stressed bosses produces microcrazing; compatibility testing for disinfectant wipes is conducted under ISO 22088-3 bent-strip conditions.

    Electrical safety of diagnostic housings is assessed under IEC 61010-1:2010/A1:2019, and flammability classification under IEC 60695-11-10 is typically HB for non-flame-retarded SAN; design engineers should not assign this grade to enclosures requiring V-2 or higher without specific UL Yellow Card confirmation. RoHS compliance for electrical and electronic equipment is governed by 2011/65/EU and its delegated directives; lead, cadmium, mercury, and hexavalent chromium thresholds are verified by XRF screening of moulded parts. Moulded covers, cuvette adapters, and display windows are representative components; patient-contact and implantable applications are outside the intended scope.

    Pre-drying in desiccant hopper dryers at 80 °C for 4–6 h is mandatory for transparent food-contact containers and small kitchen appliance parts moulded from POLYLAC SAN D-178HF when ambient relative humidity exceeds 60%. Desiccant air must reach a dew point below -30 °C, and inlet moisture content must fall below 0.10% before processing; pellet moisture above this threshold generates splay in clear bowls, canisters, and juicer jars. Melt temperatures in the 200–230 °C range and mould temperatures of 40–60 °C are typical, with screw back pressure limited to 5–10 bar hydraulic to avoid shear-induced yellowing in transparent parts. Food-contact status for SAN copolymers is evaluated under 21 CFR 177.1040 in the U.S. and Regulation (EU) No 10/2011 in the European Union; finished articles are migration-tested according to EN 1186-1 and EN 13130-1 using the food simulant assigned to the actual contact category. The grade is suited to cold-fill and ambient service such as dry goods storage, refrigerator shelves, and salad bowls; continuous service above 70 °C or hot-fill operations with fatty foods are not recommended because heat deflection behaviour under ISO 75-2/A and environmental stress cracking under ISO 22088 become limiting. Fatty food simulants such as olive oil may extract low-molecular-weight fractions over time; specific migration results depend on wall thickness, contact time, and regrind content, so lot-specific compliance documentation must be retained. Production lines for food-contact parts typically restrict regrind to material generated from the same grade without colourants or contamination.

    When Micronized Polymer Beads Are Added for LED Diffusers

    Light-diffusing polymer beads such as crosslinked PMMA microspheres or silicone particles are metered into POLYLAC SAN D-178HF at 0.5–2.0 wt% when producing diffuser covers and edge-lit panel lenses for architectural LED luminaires. Masterbatch prepared on a co-rotating twin-screw extruder with L/D 40:1 and gentle screw elements prevents premature bead deformation; the final injection moulding stage uses melt temperatures no higher than 240 °C to avoid thermal degradation of both the SAN matrix and the diffusing particles. Injection-compression moulding with a compression gap of 0.2–0.5 mm and final packing pressure 40–70 MPa hydraulic reduces gate stress and birefringence, preserving optical uniformity. Luminous transmittance and haze are measured under ASTM D1003-21 on flat plaques and must be tuned to luminaire design; higher additive loadings increase haze but reduce total forward light output. The base resin contributes heat resistance with a typical HDT A value near 85–90 °C under ISO 75-2/A, which is adequate for remote phosphor LED systems if the diffuser is spaced from the heat sink and local board temperature does not exceed 80 °C. Thermal ageing of diffuser parts under ISO 4892-2 accelerated weathering is used to assess yellowing after UV exposure; SAN is not inherently UV-stable for outdoor use and requires UV absorber or capstock protection if exterior luminaires are specified. Surface defects from bead agglomeration are controlled by back pressure below 8 bar hydraulic and screw speed below 100 rpm; agglomerates above 30 µm produce visible defects and optical hot spots. Finished parts include LED diffuser plates, edge-lit panel lenses, and interior luminaire covers.

    Transparent Stationery Components Require Ink Compatibility Screening

    For transparent stationery components such as pen barrels, mechanical pencil bodies, ruler strips, and desk accessory covers, ink compatibility screening precedes volume production, and POLYLAC SAN D-178HF is processed in multi-cavity cold-runner tools with melt temperatures of 210–230 °C. Mould temperatures between 35 °C and 50 °C are sufficient for gloss, while wall thicknesses of 1.0–1.5 mm fill readily due to the high-flow nature of the grade. Scratch resistance is moderate relative to PMMA; pencil hardness under ISO 15184 and Taber abrasion under ASTM D4060 should be specified if the stationery item is exposed to repeated surface contact. Ink formulations containing ketones, aromatic hydrocarbons, or glycol ethers at total solvent contents above 10 wt% can cause environmental stress cracking in gate regions and at printed markings; a change of ink supplier or solvent package must be qualified by ISO 22088-2 constant-strain immersion using the actual barrel geometry. Low-viscosity alcohol-based marking inks below 10 wt% alcohol are generally acceptable, but long-term contact with high-concentration ethanol-based inks may produce microcrazing around sharp lettering or snap-fit features. Dimensional stability of moulded barrel bodies is measured after 48 h conditioning at 23 °C and 50% relative humidity under ISO 294-4; shrinkage anisotropy between flow and cross-flow directions can cause ovality if gates are positioned asymmetrically. Multi-cavity runners should be balanced to within 2% of cavity fill time to reduce batch-to-batch dimensional variation. Hot-tip thermal control and cold runner sizing are critical because degraded material from dead spots can appear as brown specks in transparent barrels.

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    Certification & Compliance
    More Introduction

    Chimei POLYLAC SAN D-178HF is a high-flow styrene-acrylonitrile copolymer pellet grade supplied for injection moulding of transparent rigid components. The material combines styrene for melt processability with acrylonitrile content in the commercial SAN range, yielding a nominal melt mass-flow rate of 23 g/10 min at 200°C/5.00 kg when measured to ISO 1133-1:2022. Typical datasheet properties include tensile stress at yield of 68 MPa under ISO 527-2/1A/50, flexural modulus of 3400 MPa under ISO 178:2019, and Vicat softening temperature of 104°C under ISO 306:2022. Published data for highly pigmented or rubber-modified variants using D-178HF as the base resin is limited.

    What separates D-178HF from lower-flow SAN, clear ABS, and PMMA in transparent injection moulding?

    The following table lists typical commercial datasheet values, not specification limits. Lower-flow SAN grades retain slightly higher heat resistance and tensile strength, while clear ABS grades provide rubber-phase toughening at the expense of clarity and modulus.

    PropertyTest methodPOLYLAC SAN D-178HFLower-flow SANClear ABS
    DensityISO 1183-1:20191.06 g/cm³1.06 g/cm³1.05–1.08 g/cm³
    Melt mass-flow rate, 200°C/5.00 kgISO 1133-1:202223 g/10 min5–12 g/10 min10–20 g/10 min
    Tensile stress at yieldISO 527-2/1A/5068 MPa72–75 MPa45–50 MPa
    Flexural modulusISO 178:20193400 MPa3600–3800 MPa2200–2500 MPa
    Notched Charpy impact, 23°CISO 179-1/1eA2.0 kJ/m²2.5–3.0 kJ/m²15–25 kJ/m²
    Vicat softening temperature VST/B50ISO 306:2022104°C106°C94–97°C
    Light transmittance, 3 mmASTM D1003-2190%90%88–90%
    Haze, 3 mmASTM D1003-210.6%0.5–0.7%1.5–3.0%
    Mould shrinkage, parallelISO 294-4:20180.3–0.7%0.3–0.6%0.4–0.8%

    Pre-drying of D-178HF in a desiccant dryer at 75–80°C for 3–4 h is required when ambient relative humidity exceeds 60%, targeting residual moisture below 0.05%. Melt-temperature settings between 200°C and 250°C are used on general-purpose reciprocating screws with L/D 20:1 to 22:1 and compression ratio 2.5:1. Mould temperatures of 30–70°C are acceptable; the lower portion assists flow length, while the upper portion improves surface polish and reduces flow-line visibility on highly polished cavities. Shot size should remain within 40–70% of barrel capacity, with decompression limited to 3–5 mm to prevent air entrapment. At 250°C melt temperature, total residence time beyond 5 min increases the probability of yellowing and acrid odour from acrylonitrile degradation; purging with polystyrene or low-viscosity SAN is employed after line stoppages. High-shear dispersion is not required because D-178HF is delivered as a stabilized pellet; aggressive screw speeds above 0.5 m/s peripheral velocity can raise melt temperature unpredictably in thin-wall moulding.

    Mould design for D-178HF requires vents at the end of fill with depth 0.02–0.05 mm to prevent burn marks and short shots in thin sections. Direct gates or edge gates above 0.8 mm diameter are preferred; submarine gates below 0.6 mm can generate excessive shear heating and local yellowing. Cold-runner diameters of 6–8 mm for multi-cavity layouts maintain pressure transmission without excessive runner regrind. Hot-runner systems are acceptable if the manifold is maintained at 200–220°C and the nozzle tip temperature does not exceed 250°C. Needle-valve nozzles with poor thermal uniformity can produce cold slugs and visible gate blush in transparent parts; sequential valve-gate settings should avoid overlapping pressure spikes that induce stress birefringence around the gate.

    Transparent SAN parts display stress birefringence when moulded-in stress exceeds the resin threshold. Polarized-light inspection is used in production to sort parts with visible gate stress or non-uniform retardation. To reduce residual stress, mould temperature is held above 50°C, injection speed is reduced in the final 10% of stroke, and packing pressure is kept below 60 MPa for 2–4 s. Overpacking increases sink-free appearance but raises residual stress near gates; a stepped packing profile with hold pressure at 60–70% of peak injection pressure is used in production.

    Optical clarity, chemical resistance, and thin-wall fill behaviour in cosmetic and appliance mouldings

    The acrylonitrile segment provides resistance to aliphatic hydrocarbons, dilute acids, and cosmetic formulations containing ester solvents. In contrast to polycarbonate, D-178HF does not require high-temperature drying at 120°C; however, exposure to acetone, methyl ethyl ketone, or concentrated aromatic solvents causes stress cracking. When tested under constant strain with a 0.5% imposed flexural strain using ISO 22088-3, parts exposed to isopropanol show higher retention of tensile yield stress than clear ABS. A limitation is UV stability: unprotected outdoor exposure for more than 6 months can produce yellowing, so UV-stabilized masterbatches or coextruded acrylic cap layers are necessary for exterior glazing. The optical properties at 3 mm thickness are generally 90% total transmittance and 0.6% haze under ASTM D1003-21, with refractive index near 1.56; these values are compatible with rear-illuminated display applications but not optical lenses requiring Abbe-number control.

    In cosmetic packaging, D-178HF is used for transparent caps, lipstick sleeves, and thick-walled jar bodies where wall thickness varies from 1.5 mm to 6.0 mm. The high-flow melt permits filling of thin-walled flat areas without excessive orientation; parts ejected at 30–70°C mould temperature exhibit low in-mould stress. In vending-machine display windows and appliance lenses, the material is processed in polished P20 or stainless-steel moulds to maintain light transmission above 88% and haze below 1.0% at 3 mm. A common production failure mode is splay from wet resin; pre-drying must be verified with a moisture analyser rather than timed drying alone. Another failure mode is jetting at gates when high injection velocity is used; gate diameters below 0.8 mm should be avoided unless a tab gate or flow-leader geometry is present.

    When D-178HF is tumble-blended with colour masterbatches, the carrier resin should be SAN or polystyrene to avoid haze and delamination. Dosing accuracy of ±0.1% on a gravimetric blender is required for transparent tinted parts because the human eye detects colour differences below 0.5 ΔE. Migration of small-molecule processing aids can occur at elevated service temperatures; slip and antiblock additives loaded above 0.2% may increase haze at 3 mm thickness. Antistatic additives can reduce surface resistivity to 1010–1012 Ω/sq under IEC 62631-3-2, but their compatibility with D-178HF must be verified because some amine-based antistats cause yellowing at melt temperatures above 230°C.

    When D-178HF is selected over PMMA for transparent lenses and display windows

    When D-178HF is substituted for PMMA, density decreases from 1.19 g/cm³ to 1.06 g/cm³, reducing shot weight by roughly 11% for identical cavity geometry. Mould shrinkage increases; D-178HF exhibits 0.3–0.7% parallel shrinkage under ISO 294-4:2018, while PMMA typically falls near 0.2–0.6%. Scratch resistance and surface hardness are lower than PMMA; steatite pencil-hardness values for SAN remain near 2H compared with 4H–6H for crosslinked or high-molecular-weight PMMA, so display lenses may require hard-coat post-treatment. Impact resistance is also lower than clear ABS; notched Charpy impact at 2.0 kJ/m² means snap-fit features require radiused roots and low moulded-in stress. The differentiating factor is chemical resistance to alcohol-based cleaning agents and cosmetic oils, which stress-crack PMMA more readily than SAN. In medical and food-contact housings, D-178HF is not a sterilizable engineering resin; autoclave exposure above 100°C can induce dimensional distortion, so hydrogen peroxide gas plasma or gamma treatment must be validated for the specific part geometry.

    Regulatory screening is performed against RoHS Directive 2011/65/EU as amended by (EU) 2015/863, with lead, mercury, cadmium, hexavalent chromium, PBB, PBDE, DEHP, BBP, DBP, and DIBP below the indicated maximum concentration values. Food-contact suitability of D-178HF is assessed under applicable acrylonitrile copolymer provisions of 21 CFR 177.1010 only when the finished article is tested for overall migration and compositional limits; additives, colourants, and processing aids can alter the regulatory status. REACH SVHC screening follows the 0.1% w/w candidate-list threshold under Regulation (EC) No 1907/2006. Because D-178HF is a bulk thermoplastic, compliance must be confirmed on the homogeneous material as placed on the market, not on the granule-only data sheet.

    For transparent medical device housings, D-178HF is specified where clarity and chemical resistance to disinfectants are required but load-bearing impact is moderate. Injection moulding is conducted in cleanrooms with oil-free hydraulic machines or electric machines; moulded-in stress is minimized by maintaining mould temperature above 50°C and using post-mould annealing at 60°C for 2 h. Dimensional stability after annealing is acceptable for non-critical features, but part designers must compensate for post-anneal shrinkage of up to 0.3% in the flow direction. The resin grade is not suitable for steam-sterilized devices exceeding 100°C or for applications requiring repeated autoclaving. Plasticizers and phthalate-containing elastomers should not be compounded into D-178HF without migration testing, because low-molecular-weight additives can alter optical haze and chemical resistance.

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