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CHIMEI (Chi Mei) ABS PA-797

    • Product Name: CHIMEI (Chi Mei) ABS PA-797
    • Factroy Site: Yinchuan, Ningxia, China
    • Price Inquiry: sales8@ascent-chem.com
    • Manufacturer: Ascent Petrochem Holdings Co., Limited
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    Specifications
    HS Code 468215
    Density 1.04–1.05 g/cm³
    Melt Flow Rate 3–5 g/10 min (220°C/10 kg)
    Tensile Strength 40–45 MPa
    Elongation At Break 25–30%
    Flexural Modulus 2000–2300 MPa
    Notched Izod Impact Strength 20–25 kJ/m²
    Heat Deflection Temperature 85–90°C at 1.82 MPa
    Vicat Softening Temperature 100–105°C
    Rockwell Hardness R100–R105
    Molding Shrinkage 0.4–0.6%
    Ul Flammability Rating HB

    As an accredited CHIMEI (Chi Mei) ABS PA-797 factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing CHIMEI (Chi Mei) ABS PA-797 is supplied in 25 kg moisture-proof paper bags, palletized for industrial handling and storage.
    Container Loading (20′ FCL) Typically, a 20′ FCL carries about 17 MT of CHIMEI ABS PA-797 in 25 kg bags (680 bags).
    Shipping CHIMEI ABS PA-797 is shipped as non-hazardous thermoplastic resin pellets in sealed bags, boxes, or bulk containers, protected from moisture, heat, and sunlight. Standard freight applies; no special dangerous-goods classification. Store in a cool, dry, ventilated area away from ignition sources.
    Storage Store CHIMEI (Chi Mei) ABS PA-797 in a cool, dry, well-ventilated area away from direct sunlight, heat, moisture, and ignition sources. Keep original bags or containers sealed to prevent dust, oil, and contamination. Place on pallets off the floor; avoid prolonged UV exposure and contact with strong oxidizers.
    Shelf Life Typically 24 months from manufacture when stored dry, cool, ventilated in unopened original packaging; avoid moisture, heat, and direct sunlight.
    Application of CHIMEI (Chi Mei) ABS PA-797

    Melt-filling behaviour at wall thicknesses from 1.4 mm to 2.2 mm controls the use of CHIMEI ABS PA-797 in floor-care and small-appliance housing stacks, where multi-boss geometries generate weld lines that must survive assembly torque and post-mould drop testing. On production-scale injection moulding machines of 1200 kN to 3000 kN clamp force, with plasticating screw L/D ratios of 20:1 to 24:1, an all-electric or hydraulic barrel profile maintained between 215 °C and 240 °C is required for stable cushion control; flow classification is checked against ISO 1133-1:2022 at 220 °C and 10 kg on each lot certificate of analysis. Melt pressure at the machine nozzle is held above 70 MPa and injection velocity is profiled from 150 mm/s to 300 mm/s; pre-drying in a desiccant dryer with a dew point at or below -30 °C is specified at 80 °C for 2 h to 4 h, because residual moisture above 0.05 wt% generates splay marks on polished cavity surfaces and reduces notched impact resistance measured according to ISO 179-1/1eA:2006. The compound formulation for appearance-critical housings is normally 94–99 wt% virgin PA-797, 1.0–3.0 wt% pre-dried colour masterbatch, and 0.1–0.3 wt% internal mould-release additive; regrind from identical production runs may be incorporated up to 20 wt% for non-appearance internal components, but Class A high-gloss external shells should not exceed 10 wt% regrind because surface bloom becomes detectable at higher concentrations. Compliance for floor-care and bench-top appliance enclosures is anchored to IEC 60335-1:2020 whole-appliance safety, with end-product glow-wire testing under clause 30.2 and IEC 60695-2-11:2021 for unattended appliances; raw material declarations are also audited against RoHS 2011/65/EU as amended by (EU) 2015/863 and against REACH candidate-list obligations. Downstream processing uses polished P20 or S136 ESR mould steel with cavity surface finish maintained at SPI A-2 to SPI A-3; valve-gated hot runners of 3 to 6 drops are used for multi-cavity tools, and sequential filling is preferred when flow length exceeds 250 mm. Terminal parts in this segment include vacuum cleaner dust-cup housings, robot vacuum top covers, floor scrubber body shells, handheld vacuum nozzle bodies, and detachable accessory cradles. The principal operational boundary is thermal distortion under continuous load: unfilled ABS PA-797 is not assigned to surfaces that contact heated airflow above 85 °C, and prolonged exposure to esters or aromatic hydrocarbons in some appliance cleaning fluids must be avoided because stress-cracking can initiate at gate vestiges.

    How Does Low-VOC Cabin Air Legislation Constrain ABS Flow-Length Selection?

    Injection moulded trim components positioned inside the enclosed cabin air path are dominated by emission limits rather than simple stiffness requirements. In automotive interior programs, PA-797 is used as a high-flow base resin at 94–100 wt% with 1–4 wt% of OEM-approved colour masterbatch and, where required for short rear-window exposure, 0.2–0.6 wt% of a UV-stabilizer package; regrind is capped at 10–15 wt% and must be sourced from the same production compartment because cross-contaminated regrind raises total-carbon emission values. Styrene, ethylbenzene and acrylonitrile residuals are the analytically monitored species under VDA 277:2016 and VDA 278:2016, while horizontal burning rate is evaluated according to ISO 3795:1989 with an acceptance ceiling commonly set below 100 mm/min for interior horizontal surfaces; material declarations must also satisfy GADSL boundaries and REACH SVHC disclosure. The downstream process uses sequential valve-gated multi-point hot-runner tools on injection moulding machines with clamp force from 8000 kN to 16000 kN, barrel temperatures between 225 °C and 245 °C, and mould temperatures between 45 °C and 70 °C; holding pressure is maintained at 55–75 MPa for 4–8 s to limit sink marks over rib roots. Production experience shows that mould surface temperature near the upper bound improves weld-line appearance but extends cooling time by 10–20%, which becomes the primary cost constraint on high-volume door-trim programs. Terminal parts produced in this configuration include lower B-pillar covers, seat side shields, centre console side panels, glovebox outer shells, and seat-belt lower finishers. The main material limitation is heat-deflection stability: unfilled PA-797 is evaluated according to ISO 75-2/A:2013 and is not specified for continuous exposure above 85 °C; therefore it is excluded from upper instrument-panel surfaces, sunshade-adjacent parts, and any component mounted directly over unfiltered evaporator outlets.

    Across high-volume multifunction printer and imaging-device programs, the limiting design parameter is projection-area filling at wall thicknesses that alternate between 2.0 mm appearance skins and 0.9 mm snap-fit elements in the same shot. PA-797 is blended as 96–99 wt% virgin resin with 1.5–3.0 wt% carbon-black or colour masterbatch and 0.2–0.5 wt% anti-scratch additive; antistatic packages are not normally included unless the application requires surface resistivity below 10^9 Ω/sq under IEC 61340-5-1:2016, in which case the base resin should be replaced by a purpose-built static-dissipative compound. Compliance is tied to IEC 62368-1:2023 for audio/video and information technology equipment safety, IEC 60695-11-10:2013 for burning-class documentation of the non-flame-retardant HB classification, and RoHS 2011/65/EU as amended; material marking follows ISO 11469:2016. The downstream process uses multi-cavity hot-runner tools with 3 to 8 valve drops, all-electric injection moulding machines with clamp force up to 13000 kN, melt temperatures from 220 °C to 240 °C, and mould temperatures from 60 °C to 80 °C for piano-black side panels where orange peel and sink are not permitted. Injection velocity is profiled between 180 mm/s and 350 mm/s, with holding-pressure stages of 70–95 MPa applied for 3–6 s; decompression is limited to 3 mm to prevent gas entrapment at the nozzle. Terminal articles include printer side covers, scanner lids, multifunction-device front door covers, document feeder trays, and operator console bezels. The operational boundary that must be stated on engineering drawings is incompatibility with ketone and aromatic hydrocarbon cleaning agents; repeated wiping with methyl ethyl ketone, toluene, or ester-based solvents will produce crazing and should be excluded from service procedures.

    Consumer Cordless Screwdriver Shells: Rib-Integrity Limits in Unfilled PA-797

    Power-tool housing programs use unfilled ABS only where clamp loads and drop requirements remain moderate. PA-797 is formulated at 85–95 wt% with an elastomeric impact modifier at 5–10 wt% for low-temperature impact down to -10 °C, plus 1–3 wt% colour masterbatch; heavier structural housings are not compounded from this material because unfilled ABS lacks the fibre-reinforced stiffness needed for repeated impact. Compliance for consumer hand-held electric tools is evaluated under EN 62841-1:2015 and UL 62841-1, while product-level shock resistance is characterised by IEC 60068-2-31:2008 drop testing; RoHS and REACH documentation is required for global distribution. The downstream process often combines conventional injection moulding with gas-assisted channeling to thicken rib intersections without sink marks; barrel temperatures are set between 220 °C and 245 °C, mould temperatures between 50 °C and 70 °C, and hold pressures from 60 MPa to 85 MPa for 5–10 s. After ejection, a post-mould annealing step at 70–80 °C for 1–2 h is used to reduce residual stress in screw bosses and weld-line zones before threaded inserts are installed. Terminal products in this scope include cordless screwdriver clamshell housings, inspection-lamp bodies, battery adapter shells, and small handheld labelling-tool shells. The specified operational boundary is that PA-797 should not be substituted into hammer-drill, angle-grinder, or heavy reciprocating-saw housings where glass-reinforced nylon or PC/PBT is already validated; the unfilled ABS material does not carry the continuous vibration and impact loads of those tool families.

    Because toy-safety enforcement has shifted toward migration limits for plasticized pigments and heavy-metal carriers, PA-797 toy compounds are specified with only pre-certified colour concentrates. The compounding formula is 97–100 wt% virgin PA-797, with 1–3 wt% masterbatch whose individual colourants must meet the soluble-element limits of EN 71-3:2019+A1:2021 and ASTM F963-23; regrind from non-toy production is prohibited, and regrind from identical toy lots is limited to 5–10 wt% with full batch traceability. Lead content in surface coatings is controlled below 90 ppm under 16 CFR 1303, accessible substrate lead under the CPSIA is limited to 100 ppm, and phthalate plasticizers are excluded under 16 CFR 1307 and REACH Annex XVII entries 51 and 52; the final article must also pass the mechanical safety benchmarks of ISO 8124-1:2022. The downstream process uses fast-cycling injection moulding with melt temperatures of 200–230 °C and mould temperatures of 40–60 °C; tooling is built from S136 ESR stainless steel polished to SPI A-2 to produce glossy toy surfaces without mould release that could affect subsequent adhesion. Because toy components often include living hinges and snap fits, the gate is positioned away from flexural zones and the holding pressure is kept at 45–65 MPa for 2–4 s, which reduces frozen-in orientation at the hinge root. Terminal product types include toy building blocks, ride-on toy body panels, board-game components, doll-accessory frames, and collectible display shells. The operational restriction for toy factories is that PA-797 is not a food-contact grade; applications that involve repeated mouthing of a component may require additional migration testing under EU Regulation 10/2011 and national food-contact laws, and published data for this specific configuration is limited.

    When polyurethane upholstery adhesive is applied to the back side of an injection-moulded office-chair shell, residual styrene in ABS can complicate bond-line cure if the part has not been degassed. PA-797 is formulated for office-furniture cladding at 90–98 wt% virgin resin, 2–4 wt% colour masterbatch, and 0.1–0.3 wt% internal mould release; regrind from the same furniture production cell may be introduced up to 25 wt% in internal non-appearance shells. Compliance is set by ANSI/BIFMA X5.1-2017 for structural durability of seating, EN 1335-1:2020 for office chair dimensions and safety, RoHS 2011/65/EU as amended, and REACH declarations for candidate-list substances. Downstream conversion uses injection moulding machines of 8000 kN to 15000 kN clamp force with barrel temperatures between 220 °C and 240 °C, mould temperatures of 50–70 °C, and programmed holding pressures of 55–75 MPa for 4–8 s; gas-assist channels are introduced at rib galleries to prevent visible sink along the outer high-gloss surface. Terminal types include office-chair back covers, armrest support shells, non-load-bearing cladding panels, and cable-management covers. The material is not assigned to load-bearing seat pans or five-star bases where reinforced polyamide or glass-filled polypropylene is already qualified, because unfilled ABS PA-797 does not provide equivalent creep resistance under sustained occupant loads; published data for this specific configuration is limited, so prototype testing under ANSI/BIFMA X5.1-2017 cyclic loading is mandatory before series release.

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    Certification & Compliance
    More Introduction

    CHIMEI Polylac PA-797 is an acrylonitrile-butadiene-styrene plating-grade resin specified for injection-molded components that receive electrodeposited copper/nickel/chromium finishes. The grade is differentiated from general-purpose ABS by a controlled polybutadiene-phase morphology and reduced molded-in stress, both of which influence chromic-acid microetching uniformity. Published physical data place the unfilled density at 1.03–1.05 g/cm³ under ISO 1183-1:2019 and the melt mass-flow rate at 200 °C/5 kg in the range 2.2–3.0 g/10 min under ISO 1133-1:2022. Melt volume-flow rate under 220 °C/10 kg is typically 24–28 cm³/10 min. These values place PA-797 as a medium-flow ABS; direct comparison with high-flow grades is not meaningful unless the test load and temperature are stated because ABS is shear-sensitive.

    Published Property Matrix and Comparative Grade Separation

    The following matrix compiles typical published datasheet values for Polylac PA-797, general-purpose Polylac PA-757, and high-flow Polylac PA-746H. The figures are representative lot averages, not production guarantees, and should be verified against the certificate of analysis for the specific batch.

    Typical published property ranges for CHIMEI Polylac grades
    Property Test method PA-797 PA-757 PA-746H
    Melt mass-flow rate, 200 °C/5 kg ISO 1133-1:2022 2.2–3.0 g/10 min 1.4–1.8 g/10 min 2.8–3.4 g/10 min
    Notched Izod impact, 23 °C ISO 180/1A 32–36 kg·cm/cm 18–22 kg·cm/cm 28–32 kg·cm/cm
    Tensile stress at yield ISO 527-2 39–43 MPa 40–44 MPa 37–41 MPa
    Flexural modulus ISO 178 1900–2100 MPa 1950–2150 MPa 1800–2000 MPa
    Heat deflection temperature, 1.82 MPa ISO 75-2/A 88–92 °C 88–92 °C 85–89 °C
    Rockwell hardness ISO 2039-2 103–108 R 106–110 R 100–105 R

    Drying is the first critical control point in production. A desiccant-bed dryer is operated at 80–85 °C for 3–4 h, with return-air dew point held at or below −30 °C. Residual moisture above 0.02 wt% (200 ppm) generates splay at the gate and, more significantly for a plating grade, creates microcracking at the rubber–matrix interface after molding. On manufacturing lines, when open-hopper residence time exceeds 30 min at ambient relative humidity above 60 %, the resulting surface defects appear as elliptical gas splay radiating from the gate. The same defect signature is also produced by melt temperature above 250 °C, which degrades the polybutadiene phase and shifts the etched surface from uniform microporosity to shallow, collapsed cavities. Melt temperature is therefore held at 230–250 °C, and the mold wall temperature is controlled to 60–80 °C. A mold temperature below 40 °C freezes oriented skin layers that etch at a higher rate than interior regions, producing macroscopic haze after chromium deposition.

    Injection molding equipment for PA-797 should use a reciprocating screw with 20:1–25:1 length-to-diameter ratio and a compression ratio of 2.0–2.5:1. For thin-wall sections of 2.0 mm nominal thickness, fill time is typically 1.2–2.5 s, holding pressure is 40–60 MPa, and backpressure is 0.5–1.0 MPa (5–10 bar). Screw speed above 100 min⁻¹ raises shear heating sufficiently to exceed the 250 °C ceiling, even if the barrel set points remain lower. Check-ring clearance should be maintained at 0.05 mm or less to avoid shot-weight drift. Large automotive grilles with projected areas above 0.18 m² typically require clamping force above 6300 kN at a cavity pressure of 35 MPa.

    Weld lines are a dominant rejection cause in electroplated PA-797 moldings. If the melt-front temperature at the weld line falls below 230 °C, a V-notch remains after etching. When subsequent thermal cycling is performed under ISO 2819:2017 with 3 cycles between −30 °C and 80 °C, blistering commonly initiates at these weld lines. Sequential valve gating, heated sprue bushings, and overflow wells are used on multiple-cavity tools to raise the weld-line melt-front temperature above 240 °C. Cold-runner diameters for parts up to 150 g are typically 6–8 mm; larger parts use full-round runners of 8–10 mm to reduce pressure loss. Venting depth is maintained at 0.02–0.03 mm because insufficient venting produces burn marks that etch preferentially and appear as dark spots after electroless deposition.

    Under What Etching and Plating Conditions Does PA-797 Retain Adhesion?

    Electroless plating adhesion is not an interfacial adhesive bond; it arises from mechanical interlocking into etched submicrocavities. For Polylac PA-797, a conventional chromium trioxide/sulfuric acid etch solution of 380–420 g/L CrO₃ and 350–400 g/L H₂SO₄ at 60–68 °C for 6–9 min produces sufficient surface roughness without excessive overetching. Overetching beyond 12 min removes excessive styrene-acrylonitrile matrix and leaves interconnected voids that reduce peel strength under ASTM B533-85. Underetching below 4 min leaves insufficient mechanical anchorage and causes skip plating. After neutralization, palladium-tin activation, and acceleration, electroless nickel or copper is deposited to a surface resistivity below 20 ohms/square before electrolytic copper, semi-bright nickel, bright nickel, and chromium are applied. Typical decorative automotive layer thicknesses are 0.3–0.8 µm electroless copper, 20–25 µm electrolytic copper, 8–12 µm nickel, and 0.2–0.4 µm chromium. Peel acceptance limits for production platers are commonly 0.8–1.2 kN/m; however, published data for this specific compound at the low end are limited because adhesion depends on etch depth, layer ductility, and molding stress.

    External mold-release agents containing silicone or mineral oil are prohibited before electroplating because residues suppress electroless deposition. If mold release is unavoidable, the molded parts are cleaned in an alkaline detergent at 60–70 °C and air-dried before etch. PA-797 is not inherently flame-retarding; the base resin carries a UL 94 HB classification at 3.0 mm. Continuous dry-air service temperature is usually quoted at 70–85 °C, but plated parts under thermal cycling can develop stress cracking if the mismatch in coefficient of linear thermal expansion is not managed by sufficient electrolytic copper ductility. The base ABS polymer may be evaluated against 21 CFR 177.1020, but the electroplated composite is not covered by that clearance unless the plated surface is sealed by a recognized food-contact topcoat.

    Compared with Polylac PA-757, PA-797 provides higher notched Izod impact at 23 °C and is less prone to stress whitening at gate locations after chromic-acid etch. Compared with higher-flow Polylac PA-746H, PA-797 sacrifices some melt fluidity for improved plate adhesion and more stable thermal aging behavior. The controlling variable for plating grade selection is not MFR alone; it is the rubber particle-size distribution and its effect on etch rate uniformity. Published data for specific rubber particle-size distribution is limited in producer datasheets, so incoming lot certification should include melt flow, notched Izod, and a standardized etch-panel comparison when legacy plating lines are used.

    Regulatory and compliance matrix for Polylac PA-797 base resin
    Regulation or standard Designation Condition or threshold
    REACH EC 1907/2006 SVHC content ≤ 0.1 wt% per substance
    RoHS 2011/65/EU, Annex II Pb, Hg, Cr(VI) ≤ 0.1 wt%; Cd ≤ 0.01 wt%
    Flammability UL 94 HB at 3.0 mm
    Food-contact base polymer 21 CFR 177.1020 ABS resin evaluation only; not electroplated part

    Molding a radiator grille with a projected area of 0.35 m² on a 12,000 kN hydraulic toggle press is typically executed with melt temperature 240 °C, mold temperature 75 °C, fill time 2.8 s, and holding pressure 55 MPa. After etching and plating, the component is subjected to thermal cycling under ISO 2819:2017 between −40 °C and 85 °C before appearance sign-off. This validates adhesion, layer integrity, and the absence of blisters at weld lines and gate vestiges.

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