| HS Code | 738407 |
| Density | 1.18 g/cm³ |
| Melt Flow Rate | 10 g/10 min at 220 °C/10 kg |
| Tensile Strength | 44 MPa |
| Tensile Elongation At Break | 25% |
| Flexural Modulus | 2350 MPa |
| Flexural Strength | 70 MPa |
| Izod Notched Impact Strength | 15 kJ/m² at 23 °C |
| Rockwell Hardness | 100 R |
| Heat Deflection Temperature | 85 °C at 1.82 MPa |
| Vicat Softening Temperature | 95 °C |
| Ul94 Flammability Rating | V-0 at 1.5 mm |
| Molding Shrinkage | 0.4–0.7% |
As an accredited CHIMEI (Chi Mei) ABS PA-746 factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.
| Packing | CHIMEI ABS PA-746 is supplied in 25 kg moisture-barrier paper bags, typically palletized for bulk shipment and storage. |
| Container Loading (20′ FCL) | CHIMEI ABS PA-746 in 25 kg bags, palletized, loaded into 20′ FCL; typical payload approx. 18–20 MT, depending on packaging. |
| Shipping | CHIMEI (Chi Mei) ABS PA-746 is shipped as non-hazardous thermoplastic resin pellets, typically in 25 kg bags or jumbo bags on pallets/containers. It is not regulated as dangerous goods for transport. Keep dry and away from heat, moisture, and direct sunlight under standard freight conditions. |
| Storage | Store CHIMEI ABS PA-746 in a cool, dry, well-ventilated warehouse away from direct sunlight, heat, moisture, and ignition sources. Keep original packaging sealed and palletized; prevent bag tearing and avoid static buildup. Separate from oxidizing agents and incompatible chemicals. Protect from rain, condensation, and mechanical damage. Use first-in, first-out rotation, maintain good housekeeping, and label containers clearly. |
| Shelf Life | Shelf life is approximately 2 years from manufacture when stored in original, unopened packaging in a cool, dry, well-ventilated area. |
In high-gloss kitchen appliance enclosures, PA-746 is processed through a closed-loop desiccant dryer until residual moisture falls below 0.05 wt%; drying temperature is held at 80 °C for 2 h to 4 h with a supply-air dew point below -40 °C. The injection unit is a reciprocating screw with an L/D of 20:1 to 24:1 and a compression ratio of 2.5:1; the melt is maintained at 230–240 °C and the mould cooling circuit is set to 60–80 °C with cavity surface temperature uniformity of ±2 °C. The high-gloss surface is cut to SPI A-2 or SPI A-3 diamond polish and is measured under ISO 2813 at 60°. When cavity temperature falls below 50 °C, the frozen skin layer forms before the microtexture of the polished cavity is replicated, producing flow chill marks around the gate; gloss loss in that zone is not recoverable through packing pressure. Point gates smaller than 0.8 mm freeze before the holding phase, causing sink marks at bosses and a visible gate halo on the show surface. Valve-gated hot-runner tips of 1.0–1.5 mm are preferred for walls of 2.0–2.5 mm. Holding pressure is set at 60–80 % of peak injection pressure, with a screw cushion of 3–5 mm to compensate for check-ring leakage.
The fill pattern for a high-gloss outer shell is staged with an initial fast injection to push the melt front through the stiffening ribs and a second slower stage across the show surface to prevent jetting and silver streaking. A closed-loop switchover from injection to packing is triggered at 95 % of cushion volume, not by position alone, because melt viscosity shifts with ambient moisture and regrind load. The plasticising screw speed is limited to 60–90 min⁻¹ at a back pressure of 0.5–1.0 MPa; lower back pressure fails to homogenise pigment in the pre-mixed natural-plus-colour masterbatch, causing streaky gloss under high-angle inspection. Batch-to-batch variation in pellet size and colour masterbatch carrier resin changes the plastication time by 2–5 % on a 1100 kN machine; the moulder compensates by adjusting the metering stroke rather than the screw speed, because screw speed changes alter melt temperature and gloss consistency. Compliance with IEC 60335-1 for the final appliance includes the ball-pressure test and glow-wire tests; PA-746’s general-purpose classification under UL 94 does not replace the end-product test on a housing wall adjacent to a heater. Mould release agents are not used on the polished cavity; any external release reduces surface energy and creates adhesive bonding failures after downstream coating or labelling.
Pre-drying of PA-746 in a desiccant hopper dryer is mandatory at 80 °C for 4 h when ambient relative humidity exceeds 60 %; the desiccant bed is equipped with a dew-point meter that must read below -40 °C at the air supply. Residual moisture above 0.05 wt% hydrolyses the grafted interphase of the polybutadiene phase during plastication, producing splay at the gate and reducing notched impact strength. In unpainted lower interior trim such as B-pillar covers, seat side shields, glove box surrounds, and door pull panels, the melt temperature is restricted to 210–230 °C and the mould temperature is set between 40 °C and 55 °C to limit odour-forming volatile species and to retain medium-gloss grain transfer. The parts are gated through open-pin or tunnel gates with a land length of 0.8–1.0 mm and a gate diameter of 0.8–1.2 mm to avoid jetting. Cavity pressure transducers in the moving half are used to trigger the switchover from injection to holding at 35–50 MPa cavity pressure; the holding phase is maintained for 3–5 s after the gate freezes, then the pressure is decayed over 1 s to avoid overpacking at the gate.
Interior trim specifications use cabin air quality testing rather than ISO 6452:2021 alone; gravimetric fogging under ISO 6452:2021 and emission measurement under ISO 12219-4 are applied after the moulded parts are conditioned for 24 h at 70 °C to simulate early-use outgassing. PA-746 is not suitable for upper dashboard surfaces when dark colours in solar soak exceed 90 °C; deflection temperature under load measured by ISO 75-2:2013 at 1.8 MPa must be evaluated against the maximum local surface temperature for the specific geometry. Mould texturing for lower interior components uses VDI 24 to VDI 30 grain depth; shallow grains replicate poorly at mould temperatures below 40 °C, while deeper grains cause ejection scuffing when draft angles are below 1°. Venting for these large flat panels is designed at 0.02–0.03 mm along the parting line and at the end-of-fill areas to avoid burn marks from compressed air held in the grain. Flash at the vents indicates excessive clamp force or uneven platen parallelism; it is corrected with flatness measurement of the platens under load rather than reducing vent depth.
Weld lines in PA-746 business machine panels form when two melt fronts meet at a temperature below the effective interdiffusion threshold of the styrene-acrylonitrile matrix and fail to entangle across the interface. In a printer front bezel or copier access panel, the gating layout is developed with a Cross-WLF viscosity model calibrated to the supplier’s melt-flow-rate data under ISO 1133-1:2022 at 220 °C and 10 kg. A gate placed in a visible show surface forces the weld into a thin boss or rib, while a gate placed in a low-stress edge produces a long flow path and a melt-front temperature drop below 200 °C at the convergence point. Published data for PA-746-specific weld-line retention in the cited configuration are limited; the 70–90 % tensile retention range is representative of unfilled ABS under ISO 527-2. The lower boundary corresponds to melt-front temperature below 200 °C and packing pressure below 40 MPa. For wall sections below 2.0 mm, the flow-length-to-thickness ratio is kept under 160:1 because a thicker frozen skin at the weld prevents adequate pack pressure transmission. Venting at the weld zone is cut to 0.02–0.03 mm; an unvented weld traps gas and produces a visible notch that reduces the effective cross-section carrying tensile load.
| Directive/Standard | Parameter | Test condition or limit |
|---|---|---|
| RoHS 2011/65/EU Annex II | Lead, mercury, hexavalent chromium, polybrominated biphenyls, polybrominated diphenyl ethers | 1000 mg/kg homogeneous material |
| RoHS 2011/65/EU Annex II | Cadmium | 100 mg/kg homogeneous material |
| UL 94 | Flammability class for general-purpose ABS | HB at 3.0 mm when specified on supplier yellow card |
| IEC 62368-1 | Enclosure internal and external material resistance | Class determined by end-product electrical energy levels and spacing |
| REACH Candidate List | Declarable SVHC content above threshold | 0.1 wt% per article under Article 33 |
Flame performance for PA-746 is that of a general-purpose grade, so enclosures containing power supplies above 100 VA and requiring V-2 or better under UL 94 must switch to a flame-retarded ABS or use a barrier design. For listed business equipment, the end-product enclosure must satisfy IEC 62368-1 requirements for resistance to internal ignition and mechanical enclosure integrity; the material alone does not guarantee compliance. The gate layout is therefore not a cosmetic choice; moving a gate to a hidden edge can reduce weld-line tensile strength enough to fail the corner-drop test of a copier access panel after 3 drops from 0.5 m. In such cases, a dual-gate layout with a central hot tip and two opposing edge restrictors produces a weld location in a low-stress membrane rather than a loaded snap-fit tower.
For toy shells intended to survive repeated drop loading from 1.0 m onto a tile surface, PA-746 is processed at a melt temperature of 210–220 °C to preserve the polybutadiene impact modifier and at a mould temperature of 40–50 °C to reduce cycle time while maintaining an acceptable surface finish. The shell wall is kept between 1.8 mm and 2.5 mm; rib thickness is restricted to 60 % of nominal wall, and core features are solidified with a draft angle of 0.5–1° to avoid ejection scuffing. Gate placement avoids highly loaded snap-fit retention features and screw bosses; the gate diameter is limited to 0.8–1.0 mm so that gate vestige does not create a hard point that initiates fracture under EN 71-1:2014+A1:2018 torsion and tension clauses. Post-mould trimming of the gate remnant is followed by a 2 h anneal at 70 °C when the moulded shell retains frozen stress from fast filling; unannealed parts show lower notched impact retention at -30 °C under ISO 180 because the residual stress adds to the applied impact load.
Chemical safety for toy applications is established through migration testing under EN 71-3:2019+A1:2021, with extraction in 0.07 mol/L hydrochloric acid at 37 °C for 2 h and reporting of elements per milligram of toy material mass. PA-746 does not require phthalate plasticisers for melt processing; nevertheless, masterbatch carriers, processing aids, and external lubricants must be verified against REACH Annex XVII Entry 51 when the toy is intended for children under 3 years and can be placed in the mouth. The EU Toy Safety Directive applies material-category-dependent migration limits; certification for Category III scraped-off material is reviewed rather than relying on total composition alone. Light-coloured toy shells exposed to high-humidity shipping containers should be dried to below 0.05 wt% before moulding and sealed in poly-lined packaging after cooling to prevent moisture regain at the polar nitrile surface, which appears as surface haze and can lower gloss retention under sunlight exposure testing.
When a molder reintroduces more than 25 wt% of in-plant regrind into PA-746 for office equipment side panels, the blend is not virgin-equivalent without controlled re-pelletising or a closed-loop material-handling system. The regrind stream from sprue and reject parts has irregular particle size, lower bulk density, and higher surface moisture than virgin pellets; a gravimetric blender with ±0.5 % accuracy and a desiccant dryer operating at 80 °C for 4 h are required to prevent shot-weight drift and gas splay. The regrind source is dedicated to PA-746 and is not mixed with flame-retarded ABS from other products, because brominated retardant carryover invalidates the RoHS 2011/65/EU self-declaration and the UL 94 listing. Melt-flow index measured under ISO 1133-1:2022 at 220 °C and 10 kg shifts upward with repeated heat histories; if the regrind fraction exceeds 25 wt%, the moulder should compare melt-flow between virgin and blended feed and adjust holding pressure rather than lowering melt temperature to compensate for lower viscosity. Failure to do so produces sink marks at rear-panel bosses and an increase in notched Izod impact variation under ISO 180 at 23 °C across a production shift.
Published data for PA-746 containing exactly 25 wt% post-industrial regrind are limited; the practical failure boundary on a 1600 kN injection machine is identified by monitoring cushion stability, part weight, and impact retention. At regrind fractions above 25 wt%, the butadiene phase undergoes thermo-oxidative crosslinking during repeated plastication, which raises melt viscosity locally and produces an irregular flow front in thin ribs. In-line rheological measurement or offline capillary rheometry is specified when the regrind source includes parts with visible splay, mould oil contamination, or mixed colourant batches. Incorporation of more than 50 wt% regrind is not recommended for office equipment panels requiring uniform colour, because the colour shift measured under ISO 11664-4 is uncontrolled when feedstock composition varies. The moulder logs the percentage of regrind per lot, the number of heat histories, and the break-in duration of the non-return valve; a worn check ring reduces melt temperature control and mimics regrind-induced viscosity variation.
Post-molding assembly of PA-746 appliance subassemblies introduces a combination of adhesives, solvents, and mechanical fasteners. The material is sensitive to environmental stress cracking in the presence of ketones, esters, and aromatic hydrocarbons under moulded-in stress. For solvent welding with methyl ethyl ketone or cyclohexanone, the joint surface is wetted only after annealing at 70 °C for 2 h and after a chemical resistance check under ASTM D543, because frozen orientation at the gate area accelerates crazing at weld fillets. Cyanoacrylate adhesives bond rapidly but are evaluated under ISO 4587 lap-shear conditions; a lap-shear strength below 5 MPa on an unprimed PA-746 coupon indicates contamination or excessive bond-line thickness. Solvent-based adhesives containing toluene or xylene are not used on PA-746 because they attack the SAN matrix at the surface and lower the molecular weight of the bond line, producing a brittle interphase that fails under operational vibration.
Threaded bosses are designed with a boss outer diameter of 2.0–2.5 times the screw external diameter and a thread engagement length of 2.0–3.0 times the screw diameter to avoid hoop stress cracking. When self-tapping thread-forming screws are driven into PA-746 at continuous speeds above 600 min⁻¹, frictional heating raises the local boss temperature beyond the Vicat softening point under ISO 306 and produces thread melt-back; pilot-hole diameter is set to 60–70 % of the screw root diameter for thread-forming fasteners. For bonded joints, the adhesive supplier’s shear-strength data are confirmed on parts moulded with the production gate location, because high-energy needle-gate areas contain higher frozen orientation than low-shear edge gates and alter the solvent-induced ESC threshold. Cracking of boss assemblies evaluated under ISO 22088-3 constant-strain conditions originates at the boss-base-to-nominal-wall junction when the radius is below 0.3 mm; a rib boss with a 0.5 mm radius and a venting groove at the base reduces the crack initiation rate.
The bonded enclosure is conditioned at 23 °C and 50 % RH for 48 h before adhesive joint testing to allow moisture equilibration at the bond interface; PA-746 is not hygroscopic like polyamide but residual moisture from the moulding plant can interfere with cyanoacrylate cure uniformity. For ultrasonic welding, near-field horn contact is kept 2–3 mm from the joint, and shear joints are designed with a 0.25–0.40 mm interference and a 6 mm wall height to contain the melt pool. This assembly method is acceptable only when the moulded stress is low and the parts are free from mould release; otherwise the high-frequency energy releases frozen orientation and cracks at the weld.
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CHIMEI (Chi Mei) ABS PA-746 is an acrylonitrile-butadiene-styrene pellet grade positioned for injection-moulded enclosures, appliance trim, toys, and light-duty structural components. The material is based on a continuous styrene-acrylonitrile matrix with dispersed polybutadiene rubber particles. Published melt mass-flow rate at 200 °C under 5.0 kg piston load is approximately 2.0 g/10 min–3.0 g/10 min according to ASTM D1238, while density is 1.04 g/cm³ by ISO 1183-1. PA-746 is not a high-impact or heat-resistant ABS; it is selected when cavity filling, thin-wall penetration, and cycle-time reduction are more critical than maximum impact energy absorption.
The grade should be understood as a flow-adjusted ABS rather than a material with enhanced toughness. Compared with Chi Mei PA-747 or PA-757, PA-746 reduces injection-pressure demand in shear-limited tooling but gives lower weld-line energy absorption and lower notched impact. The product is therefore unsuitable for thick-section structural brackets, safety-relevant snap-fits, or components subjected to sub-zero impact unless specific tests on welded areas and gate regions confirm adequate reserve.
The published property envelope is best interpreted against the test methods in Table 1. The values are typical ranges from Chi Mei technical bulletins and reprocessor datasheets; they are not batch certificates. For processing, the most relevant value is not tensile strength but the melt mass-flow rate under the 200 °C/5.0 kg condition because it indicates low-rate flow behaviour in the pellet standard and does not replace capillary or spiral-flow verification at injection shear rates.
| Property | Test method | Typical range |
|---|---|---|
| Density | ISO 1183-1 | 1.04 g/cm³ |
| Melt mass-flow rate | ASTM D1238, 200 °C/5.0 kg | 2.0–3.0 g/10 min |
| Tensile stress at yield | ISO 527-2/1A | 38–45 MPa |
| Tensile strain at break | ISO 527-2/1A | 10–30 % |
| Flexural modulus | ISO 178 | 2100–2500 MPa |
| Flexural strength | ISO 178 | 55–70 MPa |
| Notched Izod impact, 23 °C | ISO 180/1A | 15–25 kJ/m² |
| Notched Izod impact, -30 °C | ISO 180/1A | 6–10 kJ/m² |
| Rockwell hardness | ISO 2039-2 | 105–115 R |
| Vicat softening temperature | ISO 306/B50 | 92–108 °C |
| Heat deflection temperature, 1.8 MPa | ISO 75-2/A | 82–92 °C |
| Mould shrinkage | ISO 294-4 | 0.4–0.7 % |
| Flammability, 1.5 mm thickness | UL 94 | HB |
Across these ranges, the critical mechanical boundary is the ductile-to-brittle transition in notched regions. At -30 °C, notched Izod values fall to 6–10 kJ/m². This means PA-746 should not be used in snap-fit arms or latch features assembled inside freezer compartments unless the part geometry reduces notch sensitivity and the assembly speed is controlled. Published data for specific colourant-induced shifts is limited; custom colours can alter heat deflection temperature and notched impact by up to 5 % relative to natural material.
Moisture handling is a boundary condition before the heating cylinder. Dehumidified hopper drying at 80 °C for 2 h–4 h is required to reduce moisture below 0.02 %. At ambient relative humidity above 60 %, open storage or uncovered machine hoppers permit sufficient surface moisture regain to generate splay on polished mould surfaces. A closed conveyor feed or hopper dryer with a dew point below -20 °C is preferred over hot-air tray drying. On production-scale reciprocating screw injection machines with screw diameters from 30 mm to 60 mm, general-purpose screws with L/D ratios of 20:1–24:1, compression ratios of 2.0:1–2.5:1, and sliding check rings are standard for PA-746. Low-compression screws may generate insufficient shear heat and require barrel set temperatures increased by 5–10 °C to maintain melt homogeneity.
Replacing PA-747 with PA-746 in a tool designed with wall thickness between 1.5 mm and 2.0 mm can reduce pressure loss across the runner and gate by approximately 15 %–25 % at a nominal melt temperature of 220 °C and injection speed of 100 mm/s, based on cavity-pressure transfer behaviour on clamp-force-limited machines of 800–1,500 kN. The lower melt viscosity permits higher cavity counts or shorter fill times on a fixed clamp force, but the trade-off is lower weld-line energy absorption and reduced rib-impact toughness. If the part contains living hinges, snap-fit hooks, or ribbed C-sections, replacement must be confirmed by notched ISO 180/1A measurements on specimens cut from gate areas and weld lines because bulk datasheet impact does not represent weld-line performance.
| Chi Mei ABS grade | MFR, 200 °C/5.0 kg, ASTM D1238 | Notched Izod, 23 °C, ISO 180/1A | HDT, 1.8 MPa, ISO 75-2/A | Portfolio position |
|---|---|---|---|---|
| PA-746 | 2.0–3.0 g/10 min | 15–25 kJ/m² | 82–92 °C | High-flow injection grade |
| PA-747 | 0.5–0.9 g/10 min | 28–40 kJ/m² | 85–94 °C | High-impact grade |
| PA-757 | 1.0–1.9 g/10 min | 20–30 kJ/m² | 84–95 °C | General-purpose balance |
Gate and runner design must be adjusted for the higher flow of PA-746. Gate diameters below 0.8 mm at a nominal wall of 1.5 mm create high shear heating and can raise local melt temperature by 10–20 °C; if nozzle melt temperature is already 235 °C, gate blush and yellowing may appear. Submarine or tunnel gates with land lengths of 0.5–1.0 mm are preferred for automatic degating, but the gate insert must be monitored for wear because the higher flow grade can erode sharp edges and increase gate vestige variation over runs exceeding 50,000 cycles. Cavity balance is especially important with PA-746 because its lower viscosity amplifies the effect of small runner-diameter differences; shot-to-shot mass variation in unbalanced multi-cavity tooling can exceed 0.5 % when hot-runner tip temperatures vary by ±5 °C.
Recommended barrel set temperatures for PA-746 are feed zone 180–200 °C, compression zone 210–230 °C, metering zone 220–240 °C, and nozzle 220–235 °C. Mould temperature should be held between 40 °C and 70 °C for dimensional repeatability. Lower mould temperatures reduce gloss and increase moulded-in stress; higher mould temperatures extend cycle time and can reduce ejection stability on untextured cores. Injection pressure should be set at the minimum required for full packing, typically 60–120 MPa melt pressure, with hold pressure at 50 %–80 % of injection pressure. Hold time should be tied to gate freeze-off verified by part-weight stability rather than a fixed timer.
Residence time in the barrel beyond 15 min at 240 °C can accelerate thermo-oxidative yellowing and polybutadiene crosslinking. If the same melt remains past 30 min, surface splay is not the only indicator of degradation; melt viscosity may increase and charred black specks can appear at the gate. Short-shot parts with burnt streaks after an interruption should trigger purging with cast acrylic or a general-purpose ABS purging compound before production resumes. A lower melt temperature near 200 °C reduces degradation risk but may increase weld-line visibility and require higher injection speed to avoid flow marks in thin sections.
Post-mould joining and decorating are not independent of grade selection. PA-746 can be solvent-welded with methyl ethyl ketone or dichloromethane-based mixtures, but these solvent classes also induce environmental stress cracking; bonded joints must remain unstressed after assembly. Ultrasonic welding to itself requires shear joints rather than energy directors when using 20 kHz equipment with amplitude 40–60 µm; ABS energy directors often degrade before full melt formation and produce weak welds. Electroplating is possible in conventional ABS chrome-etch systems, but adhesion values are lower than high-impact ABS because the polybutadiene surface concentration is reduced. Published data for plating adhesion on this specific PA-746 configuration is limited, so cross-cut or peel adhesion testing is required before specifying plated parts.
Supplier declarations for PA-746 typically include compliance with RoHS 2011/65/EU Annex II restrictions for lead, mercury, cadmium, hexavalent chromium, PBB, and PBDE, but the material is not inherently flame-retardant. The standard flammability classification at 1.5 mm is UL 94 HB; thin-wall sections at 0.8 mm may require additional evaluation before use in unattended appliance enclosures. Food-contact status under FDA or EU 10/2020 depends on colour package and processing aids. Natural unpigmented resin may satisfy certain overall migration limits, but custom colour concentrates can alter migration behaviour and must be revalidated for each formulation. REACH SVHC content is subject to batch-specific declarations and should be confirmed against the latest candidate list.
Chemical resistance follows the SAN-phase behaviour of general-purpose ABS. Ketones, esters, chlorinated solvents, and aromatic hydrocarbons can produce environmental stress cracking at moulded-in strain above 0.5 %; validation under ISO 22088-3 is required for any solvent-wipe or cleaning agent application. PA-746 is unsuitable for continuous contact with brake fluid or high-aromatic fuels at temperatures above 23 °C. Dilute aqueous acids and aliphatic hydrocarbons are tolerated for short-term low-strain exposure, but dimensional stability varies with part thickness and gate-induced orientation.
For appliance housings, PA-746 is generally processed with mould shrinkage allowances of 0.4 %–0.7 % according to ISO 294-4, with transverse shrinkage slightly higher than flow-direction shrinkage. Multi-cavity tooling with unbalanced runner systems can exhibit shot-to-shot mass variation of 0.2 %–0.5 % when hot-runner tip temperatures vary by ±5 °C. Cavity pressure sensors rated to 100 MPa are recommended for holding-pressure transfer in high-speed cycles below 30 s because they provide a more direct packing signal than screw position alone. Moulds with polished surfaces require vent depths of 0.02–0.03 mm to prevent gas burn at the end of fill; insufficient venting is a frequent cause of short shots despite the high flow of PA-746.