| HS Code | 796883 |
| Product Name | Chevron Phillips Marlex MDPE HMN TR-938 |
| Manufacturer | Chevron Phillips Chemical Company |
| Polymer Type | Medium Density Polyethylene (MDPE), Hexene Copolymer |
| Density | 0.938 g/cm³ |
| Melt Index 190 C 2 16 Kg | 0.28 g/10 min |
| Melting Point | 126 °C |
| Vicat Softening Point | 121 °C |
| Tensile Strength At Yield | 20.7 MPa |
| Ultimate Tensile Strength | 31 MPa |
| Elongation At Break | 800 % |
| Flexural Modulus | 827 MPa |
| Environmental Stress Crack Resistance 100 Igepal F50 | >1000 h |
| Brittleness Temperature | < -70 °C |
| Hardness Shore D | 60 |
| Linear Thermal Expansion Coefficient | 1.3E-4 cm/cm/°C |
| Water Absorption | <0.01 % |
As an accredited Chevron Phillips Marlex MDPE HMN TR-938 factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.
| Packing | Packed in 25 kg sealed polyethylene bags, palletized, protecting Marlex MDPE HMN TR-938 resin pellets during storage and transport. |
| Container Loading (20′ FCL) | Chevron Phillips Marlex MDPE HMN TR-938 is bagged, palletized, and securely loaded into a 20-foot FCL container for export. |
| Shipping | Chevron Phillips Marlex MDPE HMN TR-938 is a non-hazardous polyethylene resin supplied as pellets, typically in 25 kg bags, octabins, or bulk. Ship under dry, ambient conditions, protected from moisture, sunlight, and contamination. Use clean, closed containers and avoid punctures or spills; no special dangerous-goods labeling required. |
| Storage | Store Chevron Phillips Marlex MDPE HMN TR-938 in a cool, dry, well-ventilated area away from direct sunlight, heat, flames, and strong oxidizers. Keep containers tightly closed to prevent contamination and moisture pickup. Avoid prolonged UV exposure and dust accumulation. Follow the manufacturer’s SDS and local regulations for safe handling and storage. |
| Shelf Life | Chevron Phillips Marlex MDPE HMN TR-938 has an indefinite shelf life when stored cool, dry, and away from direct sunlight. |
Pipe extrusion campaigns using Marlex MDPE HMN TR-938 are configured around a single-screw extruder with a grooved-barrel feed section and an L/D ratio of 30:1 to 36:1. The resin is a high-molecular-weight medium-density polyethylene with a nominal density of 0.938 g/cm³ per ASTM D1505 and a melt index of 0.18 g/10 min per ASTM D1238 at 190°C and 2.16 kg. The gas-pipe compound is produced by blending the natural resin with a carbon black masterbatch at a letdown ratio of 6.0 wt% to 6.5 wt%; the final extrudate is verified at 2.0 wt% to 2.5 wt% carbon black by ASTM D1603 or ISO 6964. Barrel set points begin at 180°C in the feed zone and rise to 200°C at the die adapter. Melt temperature measured at the breaker plate is held between 195°C and 210°C; a melt temperature below 185°C drives melt pressure upward and produces visible carbon black agglomerates in the outer skin, while a melt temperature above 215°C combined with a residence time greater than 15 minutes shifts the pipe body toward amber oxidation. The die is a spiral mandrel design with a die land ratio of 12:1; the melt enters the vacuum sizing tank at 0.03 MPa to 0.05 MPa closed-loop vacuum and spray water at 15°C to 20°C. Wall thickness is controlled on 63 mm SDR 11 pipe to ±0.2 mm by a non-contact ultrasonic scanning station. The finished pipe is marked under ASTM D2513, 49 CFR §192.63, and is listed in PPI TR-4 as a PE 2708 material with a hydrostatic design basis of 1250 psi at 23°C. Butt fusion is performed under ASTM F2620; the heater facing temperature is 204°C to 232°C, heat-soak interfacial pressure is 0.15 MPa, and the final bead rollback must not fall below the pipe outside diameter.
| Parameter | Test method / code | Published target |
|---|---|---|
| Nominal density | ASTM D1505 | 0.938 g/cm³ |
| Melt index | ASTM D1238 at 190°C, 2.16 kg | 0.18 g/10 min |
| Carbon black content | ASTM D1603, ISO 6964 | 2.0 wt% to 2.5 wt% |
| Environmental stress crack resistance | ASTM D1693, Condition C, 100% Igepal CO-630 | F50 > 5000 h |
| Slow crack growth resistance | ASTM F1473, 2.4 MPa, 80°C | > 1000 h |
| Hydrostatic design basis | ASTM D2837, ISO 9080 | 1250 psi at 23°C |
| Final pipe specification | ASTM D2513, 49 CFR §192.63, ISO 4437-2, EN 1555-2 | PE 2708 listed in PPI TR-4 |
| Butt fusion procedure | ASTM F2620, ISO 21307 | Double-bead geometry per joint |
Residual wall stress in a 315 mm SDR 11 gas main arises from differential cooling between the outer skin and the inner wall during vacuum sizing. With Marlex MDPE HMN TR-938, a high-molecular-weight polyethylene, the outer layer freezes first and forms a compressive shell, while the inner wall cools more slowly and develops tensile stress. In a wet trench subject to clay settlement, this stress interacts with the hoop stress from operating pressure and bending strain from soil movement. Slow crack growth is the failure mode of concern, not tensile yield. The resin is tested by ASTM F1473 at 80°C and 2.4 MPa; published values for this grade indicate a PENT failure time exceeding 1000 h, but published data for full-scale cracked-round fatigue in this specific configuration is limited. The practical mitigation is a three-zone water-cooling profile in the sizing tunnel: zone one at 22°C, zone two at 35°C, zone three at 40°C, which lowers the thermal gradient across the wall by 10°C to 12°C and reduces residual tensile stress near the inner diameter. Pipe produced for horizontal directional drilling is additionally conditioned at 23°C for 24 hours before notched tensile testing; a post-extrusion oven anneal at 70°C for 90 minutes is used only when the line speed drops below 0.5 m/min. Failure to control residual stress in the field appears as a longitudinal split initiating at the inner wall in a butt-fusion zone during pressure cycling between 0.2 MPa and 0.6 MPa.
Within active and closed municipal solid waste cells, landfill gas collection headers are subjected to methane, carbon dioxide, oxygen, hydrogen sulfide, and liquid condensate at vacuum pressures of −2 kPa to −5 kPa. Marlex MDPE HMN TR-938 is selected because its density of 0.938 g/cm³ and high-molecular-weight structure provide slow crack growth resistance under long-term bending from waste settlement. The collection header is not a pressure vessel; it operates at low vacuum, but the failure mechanism is stress cracking caused by leachate drainage and differential settlement. Designers specify SDR 11 or SDR 13.5 for vertical wells and SDR 17 for horizontal collectors, with a design factor below 0.25 on the hydrostatic design basis. Perforations are cut with a slot width of 1.5 mm to 2.0 mm and a slot length of 25 mm; the open area is kept between 5% and 10% of the pipe surface to avoid a significant flexural modulus drop. Jointing in the field is electrofusion per ASTM F1055 or ISO 12176-2, with a proven peel-decohesion failure mode requiring 70% of the fused area to be intact. The resin’s high molecular weight increases melt viscosity in butt fusion, so electrofusion couplers with a maximum fusion time of 360 s are preferred for small-diameter headers.
Flowlines transporting produced water from unlined well pads in the Permian Basin and Eagle Ford require a pipe resin with high environmental stress crack resistance, because the aqueous phase contains sodium chloride at 60,000 mg/L to 180,000 mg/L, dissolved carbon dioxide, hydrogen sulfide partial pressures up to 0.2 bar, and occasional hydrocarbon carryover at 40°C to 60°C. Marlex MDPE HMN TR-938 is qualified in this service class under API RP 15LE for polyethylene line pipe and is often specified as an alternative to crosslinked polyethylene when fusion integrity and rapid repair are primary. The resin’s density of 0.938 g/cm³ maintains a lower flexural modulus than a 0.949 g/cm³ HDPE, which reduces the bending stress at saddle connections and minimizes the initiation of slow crack growth at internal notches. The pipeline is manufactured to SDR 11 or SDR 13.5, designed with a service factor of 0.4 on the 23°C hydrostatic design basis, and is hydrostatically tested at 1.5 times the maximum operating pressure for 4 hours before commissioning. For sour brine at pH 5.0 or higher, no chemical degradation of the polyethylene backbone is observed; at pH below 3.5 with free sulfuric acid, the operator must confirm temperature derating because the hydrolytic stability of the resin is less documented. The extrusion process uses a 38D single-screw extruder with a grooved feed section and a screen pack of 80/100/80 mesh to trap carbon black agglomerates above 100 µm. Butt-fused joints are inspected to ASTM F2620 fusion criteria and then hydrotested. The resin is not recommended for gas gathering with free hydrocarbon liquids above 5% by volume, because the additional permeation and swelling environment falls outside the qualified operating envelope.
Tailings transport at a flow velocity of 2.5 m/s to 3.5 m/s subjects the pipe wall to three simultaneous attacks: abrasion from sub-angular quartz particles with a D50 of 350 µm, stress cracking from pressure surges at pump start-up, and external notching from rocky backfill. Under these conditions Marlex MDPE HMN TR-938 is specified not because it has the highest hardness but because its slow crack growth resistance prevents an internal scratch from becoming a fast-running leak. The resin is typically extruded into 160 mm to 315 mm SDR 11 pipelines; the inner surface is not flame-hardened, and steel-backed wear plates are not required. Design practice is to derate the pipe wall by adding 2 mm to the calculated wall thickness for abrasive wear over a 10-year service interval, then to use the remaining wall for slow crack growth life prediction. This is the correct load path. A velocity above 4.0 m/s with sharp silica sand can remove 0.2 mm/year from the pipe invert under full-pipe turbulent flow; elbows are armored with ceramic-lined steel or high-chromium iron fittings. The pipe is jointed by butt fusion per ASTM F2620; large-diameter sections are anchored at 20 m intervals to reduce the axial strain from slurry pulsation. The grade is preferred over a 0.954 g/cm³ HDPE for this class of service because the lower crystallinity reduces notch sensitivity under point loads from a 12 mm stone in compacted backfill.
Copper heap leach pads convey dilute sulfuric acid at pH 1.5 to 2.5 from the solvent extraction plant to the drip-irrigation manifold. The pipe operates at low pressure, often below 0.4 MPa, and is exposed to acid, dissolved copper sulfate, and ultraviolet radiation. Marlex MDPE HMN TR-938 pipe is used in this service because the polyethylene backbone resists acid attack and the black compound contains UV stabilizer sufficient for outdoor exposure under ASTM D3350 carbon black dispersion requirements. The pipe is specified to SDR 17 or SDR 21 to reduce raw material use, with the thermal derating factor at 40°C applied to the 23°C hydrostatic design basis. Solvent extraction plants impose a specific hazard: entrained organic phase containing kerosene and hydroxyoxime extractant can soften polyethylene if concentrated, so designers avoid continuous organic carryover above 5% by volume and specify fluoropolymer-lined valves at the solvent interface. Field fusion is carried out with a reverse-bead qualification on every 20th joint; the heater temperature is reduced to 200°C from the standard 210°C when ambient temperature exceeds 38°C to slow bead cooling.
Closed-loop geothermal boreholes require a pipe material that can remain leak-free for 50 years at a circulating water temperature of −5°C to 40°C and a maximum operating pressure of 80 psi to 100 psi. Marlex MDPE HMN TR-938 is qualified in this class where the designer accepts a hydrostatic design stress of 800 psi at 60°C and applies a service factor of 0.32, giving an allowable hoop stress of 256 psi at 60°C; the actual loop pressure remains below 160 psi, which provides an additional safety margin. The controlling material property is not short-term burst but slow crack growth resistance under cyclic thermal strain. The pipe is extruded as 32 mm SDR 11 U-bends and joined by socket fusion or butt fusion in the field; socket fusion times are extended by 25% relative to standard HDPE because the high-molecular-weight MDPE melt has a lower melt index of 0.18 g/10 min and requires additional time to form a homogeneous melt bead. The external trench environment includes bentonite grout with a thermal conductivity of 0.75 W/m·K; the pipe wall does not require an oxygen barrier at temperatures below 60°C, but in systems with ferrous components an additional EVOH or PVDC barrier layer is mandated to prevent oxygen ingress through the polyethylene wall. Pressure testing is performed at 1.5 times the design pressure for 30 minutes, followed by a 24-hour static hold at design pressure to detect slow crack openings in socketed joints.
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