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Chevron Phillips Marlex® 7308FK Polyethylene; LLDPE

    • Product Name: Chevron Phillips Marlex® 7308FK Polyethylene; LLDPE
    • Factroy Site: Yudu County, Ganzhou, Jiangxi, China
    • Price Inquiry: admin@ascent-chem.com
    • Manufacturer: Ascent Petrochem Holdings Co., Limited
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    Specifications
    HS Code 644549
    Polymer Type Linear Low Density Polyethylene (LLDPE)
    Comonomer Hexene-1
    Density 0.930 g/cm3
    Melt Index 0.8 g/10 min (190°C/2.16 kg)
    Melting Point 125 °C
    Vicat Softening Point 108 °C
    Tensile Strength At Yield 12 MPa
    Tensile Strength At Break 24 MPa
    Elongation At Break 800%
    Flexural Modulus 550 MPa
    Hardness Shore D 55
    Brittleness Temperature < -70 °C
    Environmental Stress Crack Resistance > 1000 h
    Thermal Expansion Coefficient 1.5e-4 /°C
    Thermal Conductivity 0.35 W/m·K
    Specific Heat Capacity 2.0 J/g·°C
    Water Absorption < 0.01%

    As an accredited Chevron Phillips Marlex® 7308FK Polyethylene; LLDPE factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

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    Application of Chevron Phillips Marlex® 7308FK Polyethylene; LLDPE

    High-stalk tubular film extrusion of Marlex 7308FK at a die gap of 1.6–2.0 mm and a blow-up ratio of 2.3:1–2.8:1 is the standard monolayer route for hygiene overwrap and tissue bundling. The addition ratio is 100 wt% Marlex 7308FK in monolayer constructions; when bubble instability occurs on lines with stalk heights above 8 die diameters, up to 20 wt% high-pressure LDPE with melt index 0.25–0.5 g/10 min is introduced to increase melt tension without reducing dart impact below the specified acceptance floor. Compliance for direct food-contact overwrap is governed by FDA 21 CFR 177.1520(c) for olefin polymers and by EU Regulation (EU) No 10/2011 Annex I, with specific migration of hexene-derived oligomers verified under EN 1186-14 migration testing at 40 °C for 10 days. The production process employs a grooved-feed extruder with L/D 30:1, screen pack 60/80/100 mesh, and die temperature set between 190 °C and 215 °C to avoid surface oxidation while maintaining melt pressure below 550 bar; a dual-lip air ring with internal bubble cooling is configured to balance frost line height at 55–65% of stalk height. Terminal finished product types include lightweight produce bags, tissue-spiral bundling film, and textile drape overwrap at 18–35 µm nominal thickness. On high-output lines above 350 kg/h, gauge band formation associated with port-line die deflection is controlled by reducing die gap to 1.4 mm and increasing die temperature uniformity to ±1 °C across the circumference.

    What Limits Chill-Roll Output When Marlex 7308FK Is Drawn Down to 12 µm on Cast Film Lines?

    Cast-film palletization film based on Marlex 7308FK is processed at a melt temperature of 205–230 °C through a flat die with lip gap 0.8–1.2 mm onto a chill roll controlled at 24–28 °C. The formulation addition ratio for machine-grade stretch film is 93–96 wt% Marlex 7308FK, 3–5 wt% metallocene LLDPE with density 0.902–0.908 g/cm³, and 0.5–1.2 wt% polyisobutylene-based cling additive in a letdown concentrate; hand-grade film replaces the metallocene with 5–8 wt% lower-MI LLDPE to reduce force-to-stretch. When draw-down to 12–15 µm is performed, the primary process bottleneck is not melt delivery but edge-neck-in and draw resonance, which are controlled by reducing chill-roll speed differential and maintaining air gap at 100–160 mm. Compliance for pallet wrap is evaluated under ASTM D5748-19 for puncture resistance, ASTM D5458-95(2020) for cling, and ISO 527-3 for tensile elongation; EU food-contact packaging variants require EU Regulation (EU) No 10/2011 compliance. Downstream production employs an extruder with L/D 30:1, barrier screw, and deckle width 2.4–3.2 m, with target frost-free chill roll after 3–5 mm of web contact. Terminal products include pre-stretched machine film at 8–12 µm, coreless hand wrap, and agricultural bale-securing film. Draw resonance onset on wide lines is typically observed when the film thickness drops below 9 µm and the melt temperature exceeds 232 °C, at which point edge instability propagates toward the centerline and produces alternating thick-thin bands measured by online capacitance gauges.

    Sealant Skin Coextrusion with Biaxially Oriented Polypropylene Substrates

    Three-layer cast coextrusion positions Marlex 7308FK as the heat-sealant skin on biaxially oriented polypropylene lamination webs. The addition ratio for the sealant layer is 100 wt% Marlex 7308FK or 70–80 wt% with 20–30 wt% plastomer at density 0.902 g/cm³ to lower seal initiation temperature from 105 °C to 88–95 °C for high-speed vertical form-fill-seal machines. The skin layer is maintained at 12–20% of total film thickness, with core polypropylene homopolymer at 60–70% and tie resin at 8–10%. Compliance for food-contact laminates is verified under FDA 21 CFR 177.1520(c) and EU Regulation (EU) No 10/2011, with total migration below 10 mg/dm² when tested according to EN 1186-1. Downstream processing uses a three-extruder cast line with die temperature 205–225 °C, air gap 80–120 mm, and chill roll temperature 18–22 °C to suppress post-crystallization haze; corona treatment elevates surface tension from 31 dyn/cm to 38–42 dyn/cm before lamination. Finished goods include biscuit wrappers, powdered beverage sachets, and frozen vegetable pouches requiring seal-through-contamination resistance. Seal strength on contaminated jaw faces is maintained only when the skin layer remains above 15 µm; below that gauge, sealant thinning over core-layer gauge variation produces channel defects and increases oxygen transmission above 60 cm³/m²·day·atm under ASTM D3985-17.

    In heavy-duty liner extrusion for bulk chemical packaging, a grooved-feed single-screw extruder with screw diameter 75 mm and L/D 30:1 delivers melt at 190–210 °C through a die gap of 2.0–2.4 mm to a bubble with blow-up ratio 2.0:1–2.6:1. The addition ratio in the dry blend is 70 wt% Marlex 7308FK and 30 wt% LDPE film resin with melt index 0.25–0.4 g/10 min; this composition raises low-temperature dart impact on 100 µm film above 200 g under ASTM D1709-16a while maintaining tear propagation resistance above 12 N under ASTM D1922-15. Compliance for flexible intermediate bulk container liners references ISO 21898:2004 for packaging containment and, where food-grade contents are packed, FDA 21 CFR 177.1520(c). The production process requires melt pressure at the breaker plate to remain below 600 bar; pressure spikes above 620 bar on extruders with worn grooved bushings cause feed port melt-back and require liner replacement at 10,000–12,000 h intervals. Terminal products include 200–500 µm FIBC liners, mineral concentrate liners, and oil-absorbent pouch liners. Batch-to-batch variance in film blocking is reduced by maintaining the outer bubble surface temperature below 35 °C at the collapsion nip; operator feedback from production-scale lines indicates that blocking-related roll telescoping increases sharply when the nip temperature exceeds 38 °C during summer operations.

    Oxygen Ingress at the Bale-Fold Crease in Agricultural Silage Film

    For round-bale silage wrapping, Marlex 7308FK is processed at a melt temperature of 195–215 °C with UV stabilizer masterbatch addition at 3–5 wt% because the base resin is supplied without a light-stabilizer package. The masterbatch carrier is an LLDPE with melt index 2.0–4.0 g/10 min, and the final addition ratio is 95–97 wt% Marlex 7308FK to 3–5 wt% UV masterbatch; carbon black pigmentation at 1.5–2.5 wt% is added only for opaque silage covers exposed to high-UV regions. Compliance is set by EN 13207:2018 for thermoplastic silage films and by ISO 527-3 for tensile modulus in machine direction after 1,500 h of accelerated weathering. Blown-film processing uses die gap 1.8–2.2 mm, blow-up ratio 2.8:1–3.2:1, and dual-lip air ring to produce 25–40 µm film with machine-direction elongation above 500%. The folding crease in round-bale wrapping is the primary failure initiation point; oxygen ingress at the crease increases from 0.4 cm³/m²·day·atm on flat film to 1.1–1.8 cm³/m²·day·atm after 50 mechanical fold cycles when measured under ASTM D3985-17. Terminal finished goods include bale wrap, silo bag liner, and clamp silage cover. On production-scale calendering stacks, film with thickness variation greater than ±3 µm across the web creates inconsistent stretch at the bale edge and produces localized whitening at the fold line after 24 h of outdoor exposure.

    When Extrusion Coating onto 40 g/m² Kraft Paper Replaces LDPE Skin Layers

    On extrusion coating lines handling 40 g/m² kraft paper and aluminum foil substrates, Marlex 7308FK is processed at melt temperatures of 260–300 °C, with die gap 0.6–0.8 mm and air gap 150–250 mm to maximize adhesion before the chill-roll nip. The addition ratio for the coating layer is 100 wt% Marlex 7308FK when adhesion to metallic foil is required; for paper substrates, 15–20 wt% high-pressure LDPE is added to reduce neck-in and improve fiber tear under high-speed web tension. Compliance for coated food-contact papers follows FDA 21 CFR 177.1520(c) and EU Regulation (EU) No 10/2011, with chloroform-soluble extractives tested under 21 CFR 177.1520(d) not exceeding 5.5% at 121 °C for 2 h. Process conditions require a cooling roll temperature of 10–15 °C and substrate pre-treatment via corona to 38–44 dyn/cm; line speed is limited to 120–180 m/min because higher speeds produce interfacial voids at the paper-fiber boundary. Terminal products include release liner base papers, aseptic carton barrier layers, and foil-based pharmaceutical strip packaging. Melt curtain instability occurs when the air-gap melt temperature drops below 255 °C at line speeds above 160 m/min, producing edge wave and intermittent coating voids that are detectable with online pinhole cameras positioned before the chill-roll nip.

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