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Chevron Phillips MarFlex® 7120 LLDPE Blown & Cast Film Resin

    • Product Name: Chevron Phillips MarFlex® 7120 LLDPE Blown & Cast Film Resin
    • Factroy Site: Yudu County, Ganzhou, Jiangxi, China
    • Price Inquiry: admin@ascent-chem.com
    • Manufacturer: Ascent Petrochem Holdings Co., Limited
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    Specifications
    HS Code 454725
    Density 0.918 g/cm³
    Melt Index 2.0 g/10 min
    Melting Point 123 °C
    Vicat Softening Point 100 °C
    Tensile Strength At Yield Md 13.8 MPa
    Tensile Strength At Yield Td 12.4 MPa
    Tensile Strength At Break Md 31.0 MPa
    Tensile Strength At Break Td 27.6 MPa
    Elongation At Break Md 500 %
    Elongation At Break Td 700 %
    Dart Drop Impact 125 g
    Elmendorf Tear Strength Md 250 g
    Elmendorf Tear Strength Td 400 g
    Haze 11 %
    Gloss 60 %
    Coefficient Of Friction 0.2

    As an accredited Chevron Phillips MarFlex® 7120 LLDPE Blown & Cast Film Resin factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

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    Application of Chevron Phillips MarFlex® 7120 LLDPE Blown & Cast Film Resin

    In heavy-duty industrial sack and flexible intermediate bulk container liner conversion, the resin is processed on mono layer blown-film lines equipped with grooved-feed extruders in the 75–120 mm diameter range and L/D ratios of 24:1–30:1. The specified density of 0.912 g/cm³ under ASTM D1505-18 and a melt index of 2.0 g/10 min under ASTM D1238-20 at 190°C/2.16 kg place the material in the hexene-comonomer linear low-density polyethylene class; this comonomer architecture suppresses excessive lamellar thickening and yields the machine-direction tear resistance that blown-film converters exploit. Die gaps of 1.6–2.0 mm, blow-up ratios of 2.2:1–2.8:1, and melt temperatures of 195–220°C are maintained on conventional spiral mandrel dies; under these conditions, sharkskin melt fracture is not observed at shear rates below 200 s⁻¹ because the critical shear stress at the die lip remains below the resin’s slip threshold. Film gauges in 80–120 µm are tested to ASTM D1709-16A for dart impact, ASTM D1922-15 for Elmendorf tear, and ASTM D5748-95(2019) for slow probe puncture; procurement specifications for FIBC liners frequently set minimum dart impact values between 350 g and 500 g for 100 µm film, machine-direction tear values above 150 g, and transverse-direction tear values above 200 g. Secant modulus at 1% elongation under ASTM D882-18 is controlled in the 140–180 MPa range for monolayer structures; where higher bending stiffness is required, dry blending with 20–30 wt% HDPE at 0.956 g/cm³ density raises secant modulus to 220–280 MPa while retaining tear propagation resistance. On production lines with 250–350 mm die diameters, frost line height is held between 3 and 5 die diameters to prevent excessive transverse-direction orientation; thickness variation measured by beta gauge after calendering and winding is specified below ±6% to avoid localized stress concentration at bag seams. Batch-to-batch variation in melt index must be limited to ±0.15 g/10 min to avoid screw speed fluctuations and backpressure shifts on gravimetric feeders.

    What Limits Draw Resonance on Cast Stretch Film Lines?

    On cast stretch film lines running at widths of 1.5–3.0 m, the resin is extruded through a coat-hanger flat die with die gap of 0.5–0.8 mm at melt temperatures of 235–260°C and quenched on a polished chrome chill roll held at 18–24°C. Draw resonance, which appears as periodic thickness bands parallel to the machine direction, is the main operational boundary; it is triggered when the film draw ratio exceeds 6:1 and melt extension viscosity drops too steeply. The density of 0.912 g/cm³ and the 2.0 g/10 min melt flow index permit stable draw ratios up to 6:1 on conventional single-screw extruders with L/D 30:1; above 6:1, it becomes necessary to increase melt temperature above 250°C or reduce air gap to below 15 mm to remove the instability. Machine-direction ultimate elongation is measured under ASTM D882-18 at 500 mm/min; fully formulated cast stretch film of this resin class typically exhibits elongation at break above 400% in machine direction and tensile strength at break above 25 MPa. Puncture resistance is evaluated with ASTM D5748-95(2019) using a 0.75-inch probe at 23°C; stretch film procurement specifications for A-grade machine film often require slow puncture force above 25 N at 20 µm gauge. Cling force is measured by ASTM D5458-17 for cast film surfaces; with a 0.5–1.5 wt% polyisobutylene tackifier or a 2–4 wt% ultra-low-density polyethylene blended into the skin layer, cling force to a standard test plate at 23°C falls between 0.5 N/cm and 1.5 N/cm after film has been aged 24 h. Line speeds on cast stretch film mono lines are run between 250 and 600 m/min; at speeds above 600 m/min, extruder backpressure can fluctuate more than 5 bar if the melt pump is not isolated from die pressure swings. Neck-in measured at the die exit increases from 2–5% of web width at 4:1 draw ratio to 8–12% at 6:1; deckle rails are set accordingly to preserve edge trim allowance.

    ParameterBlown FilmCast FilmReference Method
    Die gap1.6–2.0 mm0.5–0.8 mmmechanical setting
    Melt temperature195–220°C235–260°Cinfrared pyrometer
    Blow-up ratio2.2:1–2.8:1not applicable—
    Draw ratio10:1–15:14:1–6:1line speed / die gap
    Frost line / chill roll3–5 die diameters above die18–24°C chill rolloptical surface thermometer
    Output rate150–250 kg/h600–1,200 kg/hgravimetric controller
    Typical failure modebubble instability at BUR >3.0draw resonance at draw ratio >6:1line observation

    Agricultural Silage Covers, Greenhouse Film, and UV Stabilization

    Agricultural silage and greenhouse cover films manufactured from this resin family require a UV stabilizer package that balances hindered amine light stabilizer loading against plate-out on the die lip. HALS 944 or HALS 622 at 0.3–0.6 wt% and a benzotriazole UV absorber at 0.1–0.3 wt% are dry-blended before film extrusion; total stabilizer loading is kept below 1.0 wt% to avoid die-lip plate-out on 8-hour run lengths. Greenhouse films are processed at 100–200 µm gauge on blown-film dies with 2.0–2.5 mm die gaps, 2.5:1–3.0:1 blow-up ratios, and melt temperatures of 200–220°C; silage cover sheet requirements push the same process toward 80–120 µm gauge with a stronger emphasis on puncture propagation resistance. Accelerated weathering is performed under ASTM G154 Cycle 1 using fluorescent UV-B 313 lamps; agricultural film specifications frequently require retention of more than 50% of original elongation after 2,000 h exposure when tested under ISO 527-3. The presence of amine-based antifog additives in greenhouse structures can compete with the HALS radical-scavenging mechanism, so additive compatibility must be verified by sequential Soxhlet extraction and retained tensile elongation testing before full production. Dart impact for 100 µm silage cover is specified above 300 g under ASTM D1709-16A; Elonmdorf tear values above 120 g in machine direction and 150 g in transverse direction under ASTM D1922-15 are used to reduce cover propagation after hail or wind abrasion. Film extrusion at 2.5:1 blow-up ratio produces a more balanced orientation profile than 3.5:1, which is chosen only when transverse stretch during bale wrapping demands higher TD extensibility; the trade-off appears as a measurable reduction in machine-direction tear strength and an increase in gauge banding across the web.

    At frozen-food packing operations where fill temperatures drop to −25°C, the coefficient of friction and low-temperature puncture resistance determine whether a 50 µm blown film runs on vertical form-fill-seal equipment without jaw folding or seal-area contamination. Films fabricated from this olefin polymer are reviewed for food-contact compliance under 21 CFR 177.1520(c), which requires that the finished article meet density, melt index, and extractable fraction specifications and remain within applicable conditions of use; parallel European Union compliance is assessed under Regulation (EU) No 10/2011, with overall migration limit of 10 mg/dm² and specific migration limits for authorized monomers and additives. Erucamide slip additive at 500–1,000 ppm and synthetic amorphous silica antiblock at 1,000–3,000 ppm are used in the sealant region; kinetic coefficient of friction is measured after 72 h slip bloom under ASTM D1894-14 and is typically held between 0.10 and 0.25. Low-temperature toughness is qualified by conditioning film at −18°C for 24 h before ASTM D1709-16A dart impact; 50 µm film of this density class commonly delivers 80–150 g dart impact at −18°C, compared with 150–250 g at 23°C. Heat-seal strength is measured with ASTM F88-21 at 40 psi jaw pressure, 0.5 s dwell, and 15 mm specimen width; the seal plateau reaches 8–14 N/15 mm by 130°C, while seal initiation is observed between 85°C and 105°C. Film stored at relative humidity above 85% should be pre-dried at 20–25°C for 4 h before extrusion to prevent hydrolytic surface gel formation from condensation on pellet surfaces.

    RequirementStandard / RegulationParameterAcceptance Window / Limit
    U.S. food contact21 CFR 177.1520(c)olefin polymer specificationdensity, melt index, extractable fraction as specified
    EU food contactRegulation (EU) No 10/2011overall migration<10 mg/dm²
    REACH SVHCRegulation (EC) No 1907/2006SVHC content per article<0.1 wt%
    Dart impactASTM D1709-16Apuncture fail mode80–150 g at −18°C, 50 µm
    Coefficient of frictionASTM D1894-14kinetic COF0.10–0.25 after 72 h slip bloom
    Heat seal strengthASTM F88-21seal plateau at 0.5 s dwell8–14 N/15 mm at 130°C, 40 psi

    Hot-tack latitude becomes the controlling sealant-web parameter in high-speed pouch lines.

    High-speed form-fill-seal laminates demand a heat-seal layer that maintains hot-tack strength before full cooling; the resin is coextruded as a 15–25 µm sealant skin on 80–120 µm pouch backings and tested on vertical or horizontal machines. Hot-tack is evaluated under ASTM F1921-12(2018) using 25.4 mm wide specimens, 0.5 s dwell, 0.3 N/mm² seal pressure, and 200 mm/s separation speed; values of 1.5–3.0 N/25.4 mm are typical for hexene LLDPE sealant webs of this density at 105–125°C. Differential scanning calorimetry under ASTM D3418-17 shows the main melting endotherm between 120°C and 124°C; seal initiation at 85–95°C occurs because surface chains melt before full crystalline collapse, widening the operating window on pouch lines. Adhesive lamination to oriented polypropylene or polyester is performed with a polyurethane adhesive coat weight of 2.5–3.5 g/m²; interlayer adhesion is specified above 3 N/15 mm to prevent tunneling in hot-filled retort simulations. Corona treatment to 38–42 mN/m under ASTM D2578-17 is applied online to the sealant film before lamination; dyne level uniformity must remain within ±2 mN/m across the web to avoid adhesive strikethrough. Gel count is another release criterion for high-speed pouch films; gels larger than 200 µm must be fewer than 10 per m² in cast film, as detected by high-speed optical surface scanning, because a single gel in the seal area can create a leak channel through the pouch. The film’s low seal initiation temperature permits line dwell reduction of 20–50 ms on microprocessor-controlled seal jaws, but jaw temperature setpoint must not exceed 150°C because film thinning at the seal edge can reduce burst strength under ASTM F2054 by more than 25%.

    When Surface Protection Films Require Controlled Peel Strength

    When a coextruded surface protection film is produced for temporary protective masking of laminated panels, the resin functions as a backing or core layer, not as the adhesive skin; the backing must elongate uniformly without splitting while allowing corona treatment and coating. Cast film lines with 0.5 mm die gaps and chill roll temperatures of 18–22°C produce 30–60 µm backing at line speeds of 150–250 m/min; at higher line speeds, web tension must be maintained below 5 N/cm to avoid film stretching and subsequent die-cut misregistration. Secant modulus under ASTM D882-18 at 1% elongation is kept between 120 MPa and 170 MPa; this ensures that the finished protection film can be peeled manually but does not leave adhesive residue. Corona treatment to 38–42 mN/m using an atmospheric corona unit at 1.0–1.5 kW per meter of electrode coverage is applied inline before coating; surface wetting is measured with ASTM D2578-17 dyne solutions and must be uniform within ±2 mN/m across the web. Solvent-free or water-based pressure-sensitive adhesive coating weights of 3–8 g/m² are applied on a separate line; adhesion build to stainless steel under ASTM D3330/D3330M-18 Method A is controlled between 0.5 N/25 mm and 3.0 N/25 mm after 24 h dwell. At 60 µm thickness, the backing contributes tensile strength above 2.5 kN/m and elongation at break above 400%, which reduces the risk of edge tear during machine-assisted panel installation. Low gel content is critical: film gels larger than 150 µm cause visible defects in the protected surface, so melt filter screens of 100–150 µm mesh are installed at the breaker plate on cast film extruders; pressure build-up across the screen pack is monitored and screen changes are scheduled when differential pressure exceeds 35 bar.

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