| HS Code | 121741 |
| Product | Chevron Phillips Chemical HDPE HMN 55180 |
| Polymer Type | High Density Polyethylene (HDPE) |
| Density | 0.955 g/cm³ |
| Melt Index 190 C 2 16 Kg | 0.18 g/10 min |
| Melting Point | 134 °C |
| Vicat Softening Point | 126 °C |
| Tensile Strength At Yield | 26 MPa |
| Tensile Strength At Break | 34 MPa |
| Elongation At Break | 600% |
| Flexural Modulus | 1200 MPa |
| Notched Izod Impact | 0.53 J/cm |
| Escr 10 Igepal | >1000 h |
| Hardness Shore D | 66 |
| Thermal Conductivity | 0.45 W/m·K |
| Specific Heat | 1.9 kJ/kg·K |
| Water Absorption | <0.01% |
| Coefficient Of Linear Thermal Expansion | 1.2E-4 cm/cm/°C |
| Dielectric Constant | 2.3 |
| Volume Resistivity | >1E15 ohm·cm |
| Melt Temperature | 180-220 °C |
| Mold Shrinkage | 1.5-3.5% |
As an accredited Chevron Phillips Chemical HDPE HMN 55180 factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.
| Packing | Chevron Phillips Chemical HDPE HMN 55180 is packaged in 25 kg polyethylene-lined paper bags or 1,000 kg bulk bags. |
| Container Loading (20′ FCL) | 20′ FCL loaded with 25 kg bags of Chevron Phillips HDPE HMN 55180, palletized, shrink-wrapped, and secured for ocean shipment. |
| Shipping | Chevron Phillips Chemical HDPE HMN 55180 is a non-hazardous polyethylene resin and is not regulated for transport by DOT, IMDG, or IATA. It typically ships in sealed 25 kg bags, bulk bags, boxes, or bulk trucks/railcars. Store dry, away from heat, moisture, and contamination; no special placards are required. |
| Storage | Store Chevron Phillips Chemical HDPE HMN 55180 in original, closed containers in a cool, dry, well-ventilated area. Protect from direct sunlight, moisture, dust, heat, sparks, flames, and strong oxidizers. Avoid prolonged elevated temperatures. Keep bags sealed and off the floor to prevent contamination. Use first-in, first-out stock rotation and follow the SDS and local regulations. |
| Shelf Life | Store in original packaging in a cool, dry, well-ventilated area; typical shelf life is 24 months from date of manufacture. |
In thin-gauge T-shirt sack conversion, HMN 55180 is processed on monolayer blown film lines at finished gauge between 12.5 µm and 25 µm, with a nominal resin density of 0.955 g/cm³ reported under ASTM D1505-18 and nominal melt index of 0.18 g/10 min at 190°C/2.16 kg under ASTM D1238-23a. The high-load melt index of 18 g/10 min at 190°C/21.6 kg gives a flow ratio near 100:1, indicating a shear-thinning response suitable for long-stalk high-density polyethylene film extrusion. Production equipment for this segment typically includes a grooved-feed extruder with L/D between 30:1 and 36:1, a spiral mandrel die of 150–250 mm diameter, and a dual-lip air ring. A die gap of 1.4–1.8 mm is combined with a blow-up ratio of 4:1 to 5:1 and stalk height of 5–8 die diameters before the frost line. Melt temperature is held within 204–216°C because lower temperatures are insufficient to eliminate melt fracture and higher temperatures accelerate oxidation of the extrusion stabilizer package. Corona treatment is controlled to a minimum wetting tension of 38 mN/m under ASTM D2578-23 for print adhesion on high-speed bag converting lines. Erucamide slip masterbatch is added at 500–1500 ppm active concentration, while synthetic silica antiblock is added at 1500–3000 ppm active concentration, with kinetic coefficient of friction tested under ASTM D1894-14 and blocking force measured under ASTM D3354-21. Food-contact applications require converter verification that the finished film meets olefin polymer requirements in 21 CFR 177.1520, and that all additives fall within appropriate sections of 21 CFR 178. The main line-side failure modes are bubble oscillation from turbulent air-ring flow, die-lip deposit formation from slip masterbatch exudation, and film tears at the gusset fold during bag conversion.
Downgauging below 10 µm with HMN 55180 shifts the process out of the stable long-stalk envelope unless internal bubble cooling and automated die-gauge control are available. The critical instability is not melt strength alone but the interaction among die exit temperature differences, air-ring turbulence, and frost line height oscillation. When finished film thickness drops below 10 µm, a thickness variance greater than ±5% around the circumference propagates into bag-converting defects such as diagonal wrinkles, seal nonuniformity, and web break at high-speed bottom-seal stations. On a 75 mm grooved-feed extruder, feed-throat temperature above 50°C can cause pellet arching in the groove zone, producing screw pressure oscillation of ±1.5 MPa or more and corresponding thickness bands. Feed-throat water temperature is therefore controlled to 35–40°C. Melt temperature is raised toward 216–218°C to reduce viscosity at high drawdown, but the upper limit is set by the induction time of the phosphite stabilizer system measured by ASTM D3895-19 oxidative induction time. A dual-lip air ring is operated with the lower-lip volume fraction reduced to 40–60% of total cooling air, and the frost line is stabilized at 200–300 mm above the die face. Thickness profile is monitored by ASTM D6988-21, and dart drop impact by ASTM D1709-16a method B. Published data for the exact 10 µm configuration with this specific resin is limited; converters with 25 mm screw diameters and narrow dies may require additional fluoropolymer processing aid at 200–800 ppm to delay die-line buildup.
For industrial can liners and institutional waste bags in the 45–120 L range, HMN 55180 is processed at 25–75 µm film thickness with a focus on tear resistance and split resistance at side seams rather than optical clarity. The blown film line uses a die gap of 1.8–2.2 mm and a blow-up ratio of 3:1 to 4:1, which shifts molecular orientation less severely in the transverse direction and improves balanced tear. The long-stalk configuration remains, but stalk height is shortened to 3–5 die diameters to reduce melt drawdown and increase dart drop impact. High-density polyethylene film produced from HMW grades typically shows pronounced anisotropic tear behavior; the machine-direction Elmendorf tear is lower than transverse-direction tear, and this anisotropy can produce linear tears when a loaded liner is pulled across sharp waste edges. Addition of linear low-density polyethylene in the range of 15–30 wt%, either as a dry blend in monolayer extrusion or as a skin layer in coextrusion, increases machine-direction tear by a factor of 2–5 and lowers seal initiation temperature. The following additive and test matrix is used at production scale.
| Component | Typical addition range | Function | Test designation |
|---|---|---|---|
| HMN 55180 | 100 parts | base resin | ASTM D1238-23a, ASTM D1505-18 |
| LLDPE modifier | 15–30 wt% | machine-direction tear, seal | ASTM D1922-23, ASTM F88/F88M-23 |
| Erucamide slip masterbatch | 500–1500 ppm active | surface slip | ASTM D1894-14 |
| Synthetic silica antiblock | 1500–3000 ppm active | blocking resistance | ASTM D3354-21 |
| Fluoroelastomer processing aid | 200–800 ppm active | melt fracture, die lines | internal die pressure transducer |
The masterbatches are metered at the feed throat with gravimetric feeders. A processing aid masterbatch based on fluoroelastomer is introduced at 200–800 ppm active when die lip build-up creates sharkskin or when backpressure exceeds 35 MPa. Under these conditions the stabilizer package must have sufficient retention time to survive repeated regrind; oxidative induction time of the regrind-containing film is checked by ASTM D3895-19, and a drop below 20 min at 200°C indicates stabilizer depletion. Regrind levels up to 20 wt% are common in heavy-gauge can liner production, but higher fractions reduce dart drop impact and environmental stress crack resistance under ASTM D1709-16a and ASTM D1693-15.
The die gap in HMN 55180 film extrusion is not a fixed parameter; it is adjusted against target gauge and end-use surface requirements. For thin film below 25 µm, a die gap of 1.2–1.5 mm creates higher drawdown and promotes machine-direction orientation, but it also concentrates shear stress at the die lip and increases the probability of sharkskin when the die lip temperature is below 200°C. For heavy-gauge industrial film above 50 µm, a die gap of 1.8–2.2 mm preserves melt relaxation and improves puncture resistance. Antiblock dispersion governs visual quality and blocking performance; synthetic silica with median particle size between 3 µm and 5 µm is preferred over natural diatomaceous silica because oversized particles above 15 µm become visible specks in thin film and can induce pinholes during high-elongation stretching. Blocking force is measured under ASTM D3354-21 at 60°C after 24 h, with maximum acceptable blocking load often set below 40 g/25 mm for high-speed bag converting. Surface coefficient control is achieved by erucamide migration; kinetic coefficient of friction under ASTM D1894-14 targets 0.15–0.30, but the migration rate is temperature-dependent. Film stored below 15°C can require several days to reach stable slip, while warehouse storage above 30°C accelerates migration and may increase die-lip deposit on subsequent film runs. Die lip deposit is managed by intermittent purge with a cast acrylic compound containing mild abrasive, and by limiting erucamide active addition to no more than 1500 ppm in formulations without a fluoropolymer processing aid.
Heavy-duty shipping sacks and industrial bag-in-box liners frequently use a three-layer coextruded structure in which HMN 55180 forms the core and metallocene linear low-density polyethylene forms the sealant skins. A typical layer distribution is 20/60/20 or 30/50/20 by thickness, with the HDPE core providing stiffness and tear propagation resistance while the mLLDPE skins reduce seal initiation temperature to 95–110°C versus 120–135°C for unmodified high-density polyethylene. Viscosity compatibility is critical because the high molecular weight of HMN 55180 produces higher backpressure than typical film-grade LLDPE. Skin resins with melt index between 0.5 g/10 min and 1.0 g/10 min and density between 0.912 g/cm³ and 0.918 g/cm³ are chosen to keep interfacial flow separation from creating layer thickness variation or corrugated surface defects. The extrusion line uses a 300 mm spiral mandrel die with die gap 1.8–2.0 mm, a blow-up ratio of 3.5:1 to 4.5:1, and separate melt temperatures for core and skins; the core is held at 204–216°C while the mLLDPE skins are kept at 190–205°C to avoid thermal degradation of the metallocene resin. Seal performance is tested under ASTM F88/F88M-23 with a heat-seal pressure of 0.28 MPa and dwell time of 0.5 s. Tear resistance of the coextruded film is tested under ASTM D1922-23, and dart drop impact under ASTM D1709-16a method B. A known limitation is interlayer adhesion at the interface between the HDPE core and mLLDPE skins; if the skin melt temperature is too low or the skin layer is below 10% of total film thickness, low-plasticizing tie-layer-free adhesion can create delamination during heavy load drop tests conducted according to end-user packed-bag test protocols.
In temporary construction enclosures, surface protection sheeting, and abatement containment, HMN 55180 is extruded into film thicknesses between 100 µm and 250 µm on high-output blown film or cast-film lines. The application requires puncture resistance from dropped metal fasteners and wheeled equipment traffic, low water vapor permeability for concrete curing blankets, and chemical resistance to dilute acids and alkalis typical of job-site environments. Blown film processing for this segment uses a die gap of 2.0–2.5 mm and a blow-up ratio of 3:1 to 4:1; at this thickness the frost line is lowered relative to thin film to preserve impact strength. Polyethylene construction sheeting is specified under ASTM D2103-15 for density, thickness, and tensile properties, while tensile yield and break are measured by ASTM D882-22 at a crosshead speed of 500 mm/min. UV resistance of unmodified HMN 55180 is limited; continuous outdoor exposure without carbon black or hindered amine stabilization can cause embrittlement within a few months depending on solar irradiance. For outdoor service beyond 6 months, addition of 2–4 wt% carbon black masterbatch or a UV stabilizer system is required, and the stabilizer system must be evaluated by accelerated weathering under ASTM G154-23 or ISO 4892-2:2021. This film is not a primary containment geomembrane; the small thickness and low stress-crack resistance relative to dedicated high-molecular-weight geomembrane grades make it unsuitable for continuous chemical impoundment or landfill liner service. In abatement enclosures, the film must be supplemented with pressure differential controls and flame spread requirements determined by local building codes rather than by the resin datasheet alone.
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Chevron Phillips Chemical HDPE HMN 55180 is a pelletized high-density polyethylene injection molding resin. The grade is characterized by a nominal density of 0.955 g/cm³ when determined in accordance with ASTM D1505 and a melt flow index of 18 g/10 min at 190°C/2.16 kg when determined in accordance with ASTM D1238 or ISO 1133-1:2022. Manufacturer-published typical values include a tensile yield strength of 28 MPa according to ASTM D638, a flexural modulus of 1,380 MPa according to ASTM D790, a notched Izod impact value of 1.1 J/cm at 23°C according to ASTM D256, elongation at break greater than 300% according to ASTM D638, heat deflection temperature of 78°C under 0.455 MPa according to ASTM D648, Vicat softening temperature of 124°C according to ASTM D1525, and Shore D hardness of 65 according to ASTM D2240. These values are typical data and do not function as release specifications for every production lot.
| Property | Test Method | Nominal Value |
|---|---|---|
| Density | ASTM D1505 | 0.955 g/cm³ |
| Melt flow index | ASTM D1238 / ISO 1133-1:2022 | 18 g/10 min |
| Tensile yield strength | ASTM D638 | 28 MPa |
| Elongation at break | ASTM D638 | >300% |
| Flexural modulus | ASTM D790 | 1,380 MPa |
| Notched Izod impact | ASTM D256 | 1.1 J/cm |
| Heat deflection temperature | ASTM D648 | 78°C |
| Vicat softening temperature | ASTM D1525 | 124°C |
| Shore D hardness | ASTM D2240 | 65 |
Incoming quality control at injection molding facilities typically records melt flow index, density, pellet appearance, and part weight after first-article approval. A production lot at the upper end of the melt flow specification may fill thin-wall sections with lower pressure but can increase flash formation on clamp-force-limited machines. The density influences part stiffness, mold shrinkage, and creep resistance under sustained top load. Pellets should be inspected for size distribution and contamination because irregular pellet geometry can affect feed stability in single-screw plasticating units. Certificates of analysis should be matched to the specific lot number before release to production.
The 18 g/10 min melt flow index of HMN 55180 is not solely a low-shear viscosity indicator. In thin-wall cavities with wall stock below 0.8 mm, apparent shear rates may exceed 10,000 s⁻¹. Under these conditions, a density-matched injection grade with a melt flow index near 6 g/10 min generally produces higher pressure drop through gates and runners. The difference is most evident at apparent shear rates from 100 s⁻¹ to 1,000 s⁻¹, where the higher-melt-flow resin exhibits lower apparent viscosity. Published capillary rheometry data for this specific grade under ISO 11443 is limited in public datasheets, and molders designing hot runner systems should obtain supplier viscosity curves for the exact lot.
The higher melt flow index reflects a lower average molecular weight and reduced chain entanglement. This molecular difference reduces notched Izod impact and generally shortens environmental stress crack resistance under ASTM D1693 condition B when compared with lower-melt-flow HDPE injection grades. The resin should not be considered interchangeable with a 6 g/10 min injection grade in aggressive chemical storage or in applications requiring maximum hinge flex life. For detergent, surfactant, or fatty food contact, environmental stress crack resistance data for the specific chemical and molded stress state must be obtained from the manufacturer or a qualified laboratory. HMN 55180 also differs from high-molecular-weight film and blow molding HDPE grades in that melt strength is lower; parison sag resistance and bubble stability are not design targets.
The product differs from a blow molding resin such as a 0.955 g/cm³ high-molecular-weight film grade in molecular weight distribution and intended processing window. Blow molding grades are formulated for sag resistance and swell, while HMN 55180 is formulated for short injection cycles and high-cavitation filling. The same property that reduces injection pressure also reduces melt tension, so forming processes that depend on melt strength are outside the operational boundary.
On a 300 t hydraulic reciprocating-screw injection molding machine with a 24:1 L/D general-purpose polyolefin screw and shot size between 30% and 70% of barrel capacity, HMN 55180 is processed with a nozzle melt temperature of 190°C to 230°C. Mold temperature is normally controlled at 10°C to 40°C. Lower mold temperatures shorten cooling time but can reduce surface gloss and alter crystallinity. Back pressure of 0.3–0.7 MPa is used to maintain a stable screw cushion of 3–5 mm. Screw rotation should recover the shot at least 2–3 seconds before the cooling timer expires; otherwise, recovery time becomes the cycle-limiting step. Injection speeds of 100–150 mm/s are common for thin-wall hot runner tools, but the value must be adjusted to gate geometry, wall thickness, and part volume. Hold pressure of 40–60 MPa is used in many production tools. Inadequate hold pressure increases sink marks and dimensional variation; excessive hold pressure can overpack gates and increase molded-in stress.
The melt should not be held above 240°C for more than 10 minutes. Chain scission under prolonged high-temperature residence shifts the melt flow index upward and reduces notched Izod impact. Idle periods should be managed by purging with a lower-melt-flow HDPE or a commercial purging compound. Screw and barrel wear rates are comparable to other HDPE grades of similar density, but abrasive pigments, mineral fillers, or recovered post-industrial material will accelerate wear. Barrier screws are not mandatory but may improve melt homogeneity in high-output operations.
Bulk moisture absorption is not the primary moisture-related boundary for HMN 55180. Polyolefins are non-hygroscopic, and equilibrium moisture content at 23°C and 50% relative humidity is below 0.01% by weight; published data for this exact grade is limited but consistent with HDPE. The operational failure mode is condensation. When cold pellets are transferred into a warm, humid molding bay, water films form on pellet surfaces. Surface water converts to steam in the feed throat and can produce splay, dimensional variation, or visible surface defects in thin sections. Condensation is likely when pellet temperature is below the ambient dew point or when relative humidity exceeds 60%.
Bags should remain sealed until the resin reaches the molding area temperature. If surface moisture is suspected, drying at 70–80°C for 1–2 hours in a desiccant or hot-air dryer is sufficient. Drying above 90°C is not recommended because pellet agglomeration can occur in the hopper or feed throat. Direct-flame or oxidation-promoting drying conditions should be avoided. Minor contamination with a 0.2 g/10 min blow molding grade can distort viscosity profiles in hot runner systems, even if the blend visually appears acceptable.
| Processing Parameter | Range | Unit |
|---|---|---|
| Melt temperature | 190–230 | °C |
| Mold temperature | 10–40 | °C |
| Back pressure | 0.3–0.7 | MPa |
| Hold pressure | 40–60 | MPa |
| Screw cushion | 3–5 | mm |
| Pre-drying | Not normally required unless condensation is present | — |
Thermal degradation is evaluated by melt flow index shift after multiple passes and by oxidation induction time under ASTM D3895. Published multi-pass data for HMN 55180 is limited. Repeated processing of any HDPE reduces molecular weight and notched Izod impact. Molders using regrind should conduct periodic ASTM D1238 and ASTM D256 testing to verify property retention. The proportion of regrind should be determined by end-use testing, particularly for food-contact packaging where migration limits depend on the finished article rather than the virgin resin alone. Regrind should be sieved to remove fines and should not be contaminated with polypropylene, polystyrene, or paper labels.
Food-contact status is governed by the finished article, not the resin alone. For olefin polymers, FDA 21 CFR 177.1520 sets requirements for density, extractables, and intended use conditions. HMN 55180 may be considered for food-contact applications when the final formulation and processing conditions do not cause noncompliance under the applicable use condition. The manufacturer’s compliance statement should be obtained for the specific lot. EU Regulation 10/2011 requires overall migration testing and specific migration limits for additives and degradation products. REACH registration for the polymer is normally maintained by the manufacturer, but downstream users must confirm that color masterbatches or additives do not introduce a Substance of Very High Concern above 0.1% w/w. RoHS restrictions apply to electrical and electronic equipment; unpigmented HDPE generally meets RoHS restrictions, but pigmented or compounded versions require verification. The Safety Data Sheet provides handling, disposal, and transportation information.
Thin-wall food containers, dairy tubs, overcaps, closures, housewares, toys, and open-top pails are typical injection molding applications for this melt flow index range. For caps and closures, thread stability, seal strength, and environmental stress crack resistance in contact with oils or flavors require article-level validation. The flexural modulus of 1,380 MPa contributes to stiffness, but top-load strength depends on wall thickness, base design, and hold pressure. For thick-walled parts above 3 mm, sink marks and dimensional variation must be addressed through packing pressure and cooling time. Published mold shrinkage data for HMN 55180 is not uniformly available for all cavity geometries; molders should conduct tool trials to determine cavity-specific shrinkage. The product should not be used for continuous service above 60°C without evaluating long-term oxidative stability and mechanical property retention. Parts under load in contact with strong oxidizers, chlorinated hydrocarbons, or aromatic solvents should be qualified with chemical compatibility testing before production release.