| HS Code | 920482 |
| Density | 0.952 g/cm³ |
| Melt Mass Flow Rate 190 C 2 16 Kg | 0.35 g/10 min |
| Tensile Strength At Yield | 26 MPa |
| Tensile Strength At Break | 31 MPa |
| Elongation At Break | 700% |
| Flexural Modulus | 1200 MPa |
| Vicat Softening Temperature | 122 °C |
| Brittleness Temperature | -70 °C |
| Environmental Stress Crack Resistance F50 | >1000 h |
| Shore D Hardness | 66 |
| Melting Point | 130 °C |
| Thermal Conductivity | 0.44 W/m·K |
As an accredited Chevron Phillips Chemical HDPE HHM 5202 factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.
| Packing | Chevron Phillips HDPE HHM 5202 is supplied in 25 kg (55 lb) polyethylene bags, palletized, with bulk truck and railcar options available. |
| Container Loading (20′ FCL) | Container Loading (20′ FCL): approximately 20–22 metric tons of Chevron Phillips Chemical HDPE HHM 5202 in 25 kg bags, floor-loaded. |
| Shipping | Chevron Phillips Chemical HDPE HHM 5202 is a non-hazardous solid polyethylene resin. It is typically shipped in 25 kg bags, 1,000 kg bulk bags, or bulk trucks/railcars. Store in a dry, cool area, away from direct sunlight and ignition sources. No special hazardous transport classification required. |
| Storage | Store Chevron Phillips Chemical HDPE HHM 5202 in a cool, dry, clean, well-ventilated warehouse at ambient temperature, away from direct sunlight, heat, moisture, and incompatible materials such as oxidizers. Keep sealed in original packaging on pallets, off the floor, to prevent contamination and moisture pickup. Observe FIFO, avoid excessive stacking, and protect from physical damage. |
| Shelf Life | Shelf life is 12 months from date of manufacture when stored in dry, covered, ambient conditions in unopened original packaging. |
In thin-gauge T-shirt grocery sack conversion on spiral mandrel blown film lines, Chevron Phillips Chemical HDPE HHM 5202 represents the highest-volume downstream route for the grade. The resin’s nominal density of 0.951 g/cm³ measured under ASTM D1505 and its melt index of 0.05 g/10 min at 190°C/2.16 kg under ASTM D1238 place it in the high-molecular-weight HDPE film class, where melt viscosity at typical shear rates remains high enough to generate head pressures above 35 MPa on grooved-feed extruders with 65 mm screw diameters. Bubble formation is stable only when the die gap is held between 1.5 mm and 2.0 mm because narrower gaps trigger sharkskin melt fracture at the outer bubble surface, while wider gaps reduce transverse-to-machine-direction orientation balance and produce film with high machine-direction shrinkage after bag conversion. The blow-up ratio is normally set at 4:1 to 5:1, and the frost line height is controlled at 6 to 10 die diameters to prevent bubble sag and optimize gauge uniformity; oscillating haul-off units are required to distribute thick bands created by ambient air temperature fluctuations across the roll. Film thickness for grocery sacks is typically 10 µm to 16 µm, and the limiting quality parameter is dart drop impact strength tested under ASTM D1709 Method A, with tensile yield and elongation in the machine direction evaluated under ASTM D882 at 500 mm/min crosshead speed. Published data for HHM 5202-specific film properties under line-specific cooling configurations is limited; converters should establish internal process capability indices with a minimum gauge coefficient of variation below ±8% to avoid handle-cut splitting on automatic wicketing lines.
Extruder output on HMW-HDPE grocery sack film is not limited solely by screw speed; the air ring cooling capacity and the melt pressure envelope interact. A grooved-feed extruder with 60 mm to 90 mm diameter operating with a dual-lip air ring can reach a plateau where additional screw speed above 90 rpm to 110 rpm produces shear heating rather than proportional output, reducing melt strength and causing bubble wander at the frost line. In those conditions, the internal bubble cooling system, if fitted, stabilizes the bubble and improves heat removal by up to 20% to 30% relative to external air ring cooling alone, but only when the die pressure drop is maintained above 15 MPa to prevent port-line flow marks in the film. Slip and antiblock performance for retail grocery sacks is controlled by a converter-added masterbatch at 0.5 wt% to 2.0 wt%; masterbatch loading above 3 wt% typically degrades dart drop and seal strength because the inorganic antiblock particles act as stress concentrators at the film surface. The end-product bag is sealed on a wicketed bag machine with a heated side-seal jaw; seal initiation temperatures for HDPE film in this density class are generally from 120°C to 150°C at 0.3 s dwell and 0.2 MPa to 0.5 MPa jaw pressure. Handle punch geometry and die sharpness must be maintained because the high molecular weight fraction increases cutting force demand compared with lower-molecular-weight HDPE film grades, and dull punch blades create stress whitening that reduces sack opening reliability.
When heavy-duty refuse sacks and can liners are converted in thicknesses between 20 µm and 50 µm from HHM 5202, the primary technical risk is not room-temperature tensile failure but the retention of puncture and tear resistance when the film is handled at low ambient temperatures or when sharp waste particles concentrate stress at gauge-thin regions. Quasi-static puncture resistance is evaluated under ASTM F1306, Elmendorf tear under ASTM D1922, and tensile properties under ASTM D882; the relative balance between these values depends on blow-up ratio, stalk height, and drawdown ratio. To maximize puncture toughness in heavy-gauge HMW-HDPE film, the bubble is often run with a shorter stalk and a blow-up ratio of 2.5:1 to 3.5:1, which shifts orientation toward a biaxial balance and reduces the machine-direction tear weakness that occurs in highly stalk-oriented film. Gauge uniformity is maintained with an oscillating haul-off and dual-nip collapsing frames; film thickness variation measured after slitting should be held below ±6% at a 25 µm target thickness to prevent localized puncture failure at the lower end of the distribution.
On heavy-duty refuse sack extrusion lines with 75 mm to 100 mm spiral mandrel dies, internal bubble cooling is used because the thicker film carries more heat from the die and would otherwise require excessively tall towers. The die gap is generally 1.8 mm to 2.2 mm to avoid melt fracture while preserving surface quality; increasing the die gap above 2.5 mm reduces melt strength at the frost line and leads to bubble breathing, which appears as cyclical gauge bands on the finished roll. If the bag is intended for frozen or outdoor waste collection, converters commonly blend 10 wt% to 20 wt% of a hexene- or octene-based linear low density polyethylene to improve low-temperature puncture properties; published data for HHM 5202-specific low-temperature performance is limited, and each converter must verify dart drop at -18°C under ASTM D1709 Method B because HDPE film toughness can decline sharply below 0°C depending on orientation state and additive package. The finished sacks are sealed on bottom-seal bag machines or continuous side-seal lines with impulse sealing; the seal must withstand a 1.0 kg to 2.0 kg drop weight test without splitting when the bag is filled with 50% of its rated volume, but the exact drop specification is customer-defined and no universal ASTM pass criterion exists for refuse sack seal integrity.
For food-contact produce bags and deli film applications, a documented regulatory basis must be established before commercial use of HHM 5202, and the converter cannot rely solely on the resin density or melt index data. In the United States, the base olefin polymer falls within the scope of FDA 21 CFR 177.1520 when the finished article meets the applicable extractable fraction limits and end-use conditions set out in the regulation; the supplier’s food-contact compliance statement must confirm that the specific grade and its antioxidant stabilizer system are cleared for the intended conditions of use. For the European Union, compliance is assessed under Regulation (EU) No 10/2011, with overall migration measured according to EN 1186 and specific migration for any additives evaluated by the methods referenced in the positive list. A compliance matrix for this segment is presented below because the documentation burden varies by jurisdiction and is often the release gate for commercial shipment.
| Jurisdiction | Material regulation | Test standard | Limiting requirement | Documentation |
|---|---|---|---|---|
| United States | FDA 21 CFR 177.1520 | Extraction testing per 21 CFR 177.1520 | Applicable end-use conditions A through H | Supplier FDA status letter |
| European Union | Regulation (EU) No 10/2011 | EN 1186-1 | Overall migration limit 10 mg/dm² | Declaration of Compliance |
| China | GB 4806.7-2016 and GB 9685-2016 | GB 31604.1 and GB 31604.8 | Overall migration 10 mg/dm² | Conformity declaration |
Produce bag film is extruded at 8 µm to 15 µm thickness and surface-treated on the print side to at least 38 mN/m for flexographic ink adhesion. Because this gauge range magnifies any melt fracture or port-line defect into visible streaks on the filled bag, the converter maintains melt temperature between 200°C and 230°C and uses a die gap of 1.4 mm to 1.8 mm with a blow-up ratio of 3:1 to 4:1. On high-speed produce bag conversion lines, the film is perforated with hot needles after bubble collapse; perforation diameter and spacing are set to provide respiration without weakening the bag below the customer’s minimum tensile strength under ASTM D882. The wicketed bag seam is produced with an impulse sealer, and seal strength is measured under ASTM F88 to ensure that the seal does not fail before the film during loading; typical seal-to-film strength ratios above 0.70 are accepted, but the exact release criterion is set by the packer. Since HMW-HDPE film exhibits post-extrusion shrinkage, roll stock must be stored for a minimum of 24 h at controlled ambient temperature before slitting and bag conversion to stabilize dimensions and avoid wicker misalignment.
Industrial drum liners and rigid intermediate bulk container liners formed from HHM 5202 place the resin in direct contact with chemical formulations, and the selection decision rests on chemical resistance data rather than mechanical film properties alone. HDPE in this density range provides resistance to dilute mineral acids, alkaline solutions, and aqueous salt streams under ambient temperature, with chemical resistance evaluated under ASTM D543 as weight and dimension change after immersion. The film is typically extruded at 50 µm to 100 µm thickness, and the liner is fabricated by impulse sealing a lay-flat tube bottom and then leak-testing the finished liner under water head or air pressure. Published data for HHM 5202-specific chemical immersion performance is limited; when the storage application involves strong oxidizing acids, aromatic hydrocarbons, or chlorinated solvents, qualification must include immersion tests on the finished liner, not extrapolation from general HDPE compatibility tables. Aliphatic solvents and some short-chain alcohols may swell the film over extended contact periods even when no mechanical failure is observed in a 24 h screening test, and liner wall thickness must be increased if the chemical is classified as a permeant under the intended transport regulation.
For industrial drum liners and rigid intermediate bulk container liners formed from HHM 5202, the extrusion process differs from grocery sack film in the cooling configuration and collapsing geometry. Because thick HMW-HDPE film carries a high heat load, the tower height and air ring velocity are adjusted to keep the frost line at 5 to 8 die diameters; a frost line too close to the die produces a rough inner surface and poor gauge uniformity, while a frost line too high reduces transverse orientation and creates a lane of low puncture resistance along the bubble edge. The die gap is typically 1.8 mm to 2.4 mm, and the blow-up ratio is held between 2:1 and 3:1 because the heavy liner must retain a more balanced orientation to avoid splitting along machine-direction creases when the liner is inserted into a drum. The finished liner is often folded and stacked; slip-modified HMW-HDPE liners are difficult to separate on automated insertion equipment if the coefficient of friction is above 0.7, so a converter-added slip package may be required even though it slightly reduces seal strength under ASTM F88. Compatibility with closure ties and elastomeric bands must also be verified; low-molecular-weight plasticizers from PVC closure components can migrate into the HDPE film and swell the contact layer, a failure mode that is not detected by standard liner drop tests but appears as delayed wrinkling after 72 h of film-to-closure contact.
Post-consumer HDPE recyclate incorporation in thin-gauge sack and liner film is a distinct downstream route where HHM 5202 serves as the high-viscosity virgin fraction that restores bubble stability and dart drop. The recyclate stream in this segment typically carries a melt index above 0.1 g/10 min, higher gel contamination, and a wider molecular weight distribution than virgin HMW-HDPE; dry blending 20 wt% to 30 wt% PCR with HHM 5202 moves the blend into a processable range but does not fully recover the dart drop of the virgin film. Converters using this route report that screen pack changes become the dominant downtime factor when PCR content exceeds 30 wt%, and the extrusion line must be fitted with a screen changer capable of handling gel accumulation without interrupting bubble cooling. The film property cliff-edge in this segment is not linear: a PCR addition of 20 wt% may reduce dart drop by less than 15%, while an increase from 30 wt% to 40 wt% can produce a loss of more than 40% depending on the PCR source, and published data for HHM 5202-specific PCR blends is limited, requiring trial runs at each PCR lot.
Because post-consumer HDPE contains residual low-molecular-weight contaminants, the film extrusion temperature profile is often reduced by 5°C to 10°C relative to virgin HMW-HDPE settings to suppress smoke generation and seal-zone volatiles, but this adjustment narrows the melt-fracture-free operating window and forces the die gap to the upper end of the virgin range. The finished film is rarely used for direct food contact unless the PCR stream is certified under a food-grade recycling process; in most jurisdictions the recycled content is confined to refuse sacks, industrial liners, and non-food retail bags. Bag conversion speed on wicketed lines may also decline because PCR-induced gels create heat-seal defects and can reduce seal strength under ASTM F88 by an amount proportional to gel count in the seal area. To maintain acceptable seal integrity, the converter must install a 100 µm to 250 µm screen pack upstream of the die; finer screens improve gel removal but raise melt temperature and reduce output, so the screen configuration is chosen from pressure-drop data rather than cleanliness alone.
In coextruded film structures using HHM 5202 in the core or substrate layer, the resin contributes density-driven modulus and creep resistance for automatic bagging lines, freezer-grade sacks, and heavy-duty retail bags that require a low-seal-temperature skin without sacrificing stiffness. In a typical three-layer die configuration, the HHM 5202 layer carries the mechanical load while an LLDPE or mLLDPE skin provides a lower seal initiation temperature and improved hot-tack, with the melt flow ratios of the two resin families kept as close as possible to avoid interfacial instability. The interlayer flow channel in the spiral mandrel die must be balanced so that the high-viscosity HMW-HDPE layer does not displace the lower-viscosity skin at the die exit; if the viscosity ratio exceeds the stable coextrusion window, the layer distribution shifts across the bubble circumference and the seal layer becomes discontinuous on one edge. Layer thickness ratios for HDPE-core structures are commonly in the range of 70/10/20 or 60/20/20, with the HHM 5202 core layer carrying the mechanical load and the outer skins providing sealing or slip function. Published layer-adhesion data for HHM 5202-specific coextrusions is limited, but interlayer bond strength must be verified by the converter under ASTM F88 seal tests and under peel or tensile tests that expose delamination defects not visible on the finished roll.
Automatic bagging lines impose a separate set of requirements on the coextruded film: the bag must have a blocking resistance high enough to allow one-by-one pickup, a stiffness sufficient to remain open during product insertion, and a seal temperature window broad enough for continuous band sealing at line speeds above 40 bags/min. HHM 5202 in the core raises film stiffness and allows gauge reduction to 12 µm to 20 µm, but the sealed edge becomes less tolerant of contamination in the seal zone because the high-density layer contributes less low-temperature sealant flow than the skin. Hot-tack testing performed under ASTM F1921 is required to set the minimum seal jaw temperature and dwell time for the specific coextrusion, and the sealing window must include the actual line speed and film temperature, not the laboratory static condition. If the film is printed on the outer skin, corona treatment at 38 mN/m to 42 mN/m is applied before flexographic printing, and solvent retention must be monitored by gas chromatography to prevent odor carryover into packaged goods. The finished film is slit to width with razor or crush-cut slitting; crush-cut edges on HMW-HDPE coextrusions can produce fibrous debris that builds up on bagging line suction plates, so the edge configuration is specified by the bagging equipment manufacturer rather than by film tensile properties alone.
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