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Chevron Phillips Chemical HDPE H516HP

    • Product Name: Chevron Phillips Chemical HDPE H516HP
    • Factroy Site: Yudu County, Ganzhou, Jiangxi, China
    • Price Inquiry: admin@ascent-chem.com
    • Manufacturer: Ascent Petrochem Holdings Co., Limited
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    Specifications
    HS Code 556861
    Product Chevron Phillips Chemical HDPE H516HP
    Polymer Type High Density Polyethylene (HDPE)
    Comonomer 1-Hexene
    Density 0.951 g/cm³
    Melt Index 190 C 2 16 Kg 0.35 g/10 min
    Tensile Strength At Yield 27 MPa
    Tensile Strength At Break 30 MPa
    Elongation At Break >600%
    Flexural Modulus 1,200 MPa
    Vicat Softening Temperature 127 °C
    Brittleness Temperature < -70 °C
    Environmental Stress Crack Resistance Escr 100 Igepal F50 >1,000 h
    Hardness Shore D 65
    Coefficient Of Linear Thermal Expansion 1.2 × 10⁻⁴ /°C
    Thermal Conductivity 0.44 W/m·K
    Specific Heat Capacity 1.9 kJ/kg·K
    Water Absorption <0.01%
    Volume Resistivity >10^16 ohm·cm
    Dielectric Constant 1 Mhz 2.3
    Dissipation Factor 1 Mhz 0.0005
    Melt Temperature Range 180-230 °C
    Mold Shrinkage 1.5-3.0%

    As an accredited Chevron Phillips Chemical HDPE H516HP factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing Chevron Phillips Chemical HDPE H516HP is packaged in 25 kg polyethylene bags, palletized, with 1,000 kg bulk bags available.
    Container Loading (20′ FCL) Chevron Phillips Chemical HDPE H516HP loaded in 20′ FCL: 25 kg bags, palletized, shrink-wrapped, and securely stowed for transport.
    Shipping Chevron Phillips Chemical HDPE H516HP is shipped as non-hazardous polyethylene resin pellets in 25 kg bags, bulk bags, or bulk trucks/railcars. Store dry and closed, away from heat, moisture, and contaminants. Use appropriate handling to prevent package damage and spills. Follow local transport regulations. No special UN classification.
    Storage Store Chevron Phillips Chemical HDPE H516HP in a cool, dry, well-ventilated warehouse, away from direct sunlight, heat, sparks, flames, and strong oxidizers. Keep original bags or containers closed on pallets to prevent moisture, dust, and contamination. Avoid prolonged UV exposure and excessive stacking. Use first-in, first-out rotation and follow the SDS and local regulations.
    Shelf Life Chevron Phillips Chemical HDPE H516HP: no specific shelf life; stable under normal storage. Keep cool, dry, away from ignition.
    Application of Chevron Phillips Chemical HDPE H516HP

    In thin-wall injection moulding of dairy tubs, portion cups and tamper-evident lids, H516HP is processed at melt temperatures between 190 °C and 230 °C with a nominal melt flow rate of 16 g/10 min (ASTM D1238) and a density of 0.954 g/cm³ (ISO 1183-1). When wall sections are reduced below 1.5 mm, cavity fill is governed less by material viscosity than by injection velocity profile, gate design and melt cushion stability. High-speed accumulator machines equipped with 20:1 to 25:1 L/D general-purpose screws and non-return valves with ring-style check tips are standard. Injection pressures are typically maintained between 80 MPa and 120 MPa, with packing pressure at 50–70% of injection pressure and hold time adjusted to gate freeze-off rather than to a fixed timer. Valve-gated hot runners with tip diameters of 0.8–1.5 mm reduce gate blush and allow faster pressure cut-off in multi-cavity tools. Mould temperatures of 10–30 °C balance sink-mark reduction against cycle-time creep; at a 30 °C mould surface, a 1.2 mm polyethylene wall typically requires 8–12 s cooling before ejection, though H516HP-specific published data for this configuration is limited. Shrinkage allowances of 1.5–2.0% in the flow direction and 1.8–2.5% transverse are common for cavity dimensions validated by first-shot trials coordinated with ISO 294-4 shrinkage determination.

    Food-contact compliance is established through the olefin polymer provisions of FDA 21 CFR 177.1520(c), with end-use migration obligations defined under EU 10/2011 as amended by Regulation (EU) 2020/1245. No predrying is required at ambient humidity below 60% RH, but condensation on cold pellet surfaces after outdoor storage has been observed to generate surface splay and should be addressed by silo dry-air purge at 60 °C for 1 h before processing. Additive packages containing amine-based slip or antistatic compounds should be avoided where sensory evaluation under ISO 13302 is part of the end-use specification, because such additives can migrate and alter taste and odour profiles in high-surface-area containers. Hot-fill duty is limited; continuous deflection under load becomes measurable above 50 °C at applied stresses approaching 10 MPa, so the grade is not specified for retort or pasteurisation cycles above 80 °C.

    What Process Variables Control Cold-Drop Performance in Industrial Pails?

    Open-head pails in the 5 L to 25 L range with wall thicknesses of 2.5–4.0 mm place impact resistance at weld-line positions above bulk material toughness. H516HP has sufficient melt flow to fill long radial flow paths from a central sprue, but the flow pattern creates a weld line at the handle boss on the opposite side of the gate. When the mould is operated below 20 °C with fill times shorter than 1.5 s, that weld line can retain orientation stress and fail under UN drop testing. Standard practice is to increase melt temperature to the upper range of 220–235 °C, raise mould temperature at the handle insert to 30–35 °C, and delay packing-pressure decay until gate freeze-off. These adjustments shift the failure mode from brittle splitting at the weld line to ductile hinge deformation in pail drop tests. In UN-rated packaging, drop testing at -18 °C after conditioning for 24 h is the critical threshold, with packing group II requiring a 1.2 m drop height and packing group III requiring 0.8 m per UN Model Regulations Chapter 6.1. Stacking load at 40 °C for 28 days under UN 6.1.5.6 imposes a secondary creep requirement sensitive to sidewall cooling uniformity; differential shrinkage exceeding 0.5% between reinforced areas and plain walls produces out-of-roundness that reduces stacking stiffness.

    Environmental stress cracking resistance, measured under ASTM D1693 condition B with 10% Igepal CO-630 at 50 °C, is the more common failure mechanism in field-returned pails exposed to hydrocarbons, paints, or cleaning concentrates. The processing link is real: low melt temperatures below 190 °C and low packing pressures leave frozen-in orientation and surface microcracks at the gate, which act as ESCR initiation sites. H516HP therefore requires a deliberate process discipline: barrel profile from feed to nozzle of 180 °C, 200 °C, 210 °C, 215 °C, with nozzle at 215 °C, and screw backpressure of 0.5–1.0 MPa for masterbatch dispersion. Screw recovery time should not exceed 8 s, because material residence time beyond 3 min at 230 °C produces local oxidation that lowers impact strength. Cooling time scales with the square of nominal wall thickness; for a 3.0 mm pail wall at 20 °C mould temperature, required cooling time is typically 18–25 s, and raising mould temperature to 30 °C extends that window by 20–30%. For pails with integrally moulded metal or plastic wire handles, the insertion step must be completed before the gate freezes; insert temperatures below 40 °C cause premature solidification and weak encapsulation. This is a process boundary, not a material boundary, and is often misdiagnosed as a resin batch defect.

    Returnable distribution crates, ventilated totes and modular logistics containers place a different demand on H516HP: the moulded part must survive repeated stacked, humid, wash-down cycles without dimensional drift. Wall stock typically ranges from 3.0 mm to 5.0 mm, with open-grid side panels creating local L/t ratios that can exceed 150:1 in thin rib sections. Melt temperatures in the 190–225 °C band are sufficient, but the packing phase determines shrinkage uniformity. Packing pressure of 50–70 MPa held for 2–4 s after volumetric filling and a screw-forward melt cushion of 3–6 mm are standard. Mould cooling must account for the difference between wall intersections and open grid ribs; differential cooling rates between a 5.0 mm boss and a 2.0 mm rib can create a shrinkage gradient of 0.3–0.6%, producing toe-in warpage that interferes with automated conveyor sorting. Post-mould warpage is typically evaluated after 48 h at 23 °C and 50% RH using a flatness tolerance of 0.8 mm per 100 mm profile length.

    Stacking creep is the governing long-term failure mode. When a loaded crate stack imposes 2,500 N on the bottom crate at 40 °C, polyethylene side columns undergo compressive creep that can exceed 2% strain over 28 days unless the design includes vertical gussets and full perimeter contact at the stacking interface. The relevant laboratory methods are ISO 2234 for stacking resistance of complete filled transport packages and ASTM D2990 for compressive creep of plastics. In humid or condensation-prone wash-down environments, moisture absorption is negligible for HDPE, but detergent stress cracking at high pH above 9 and temperature above 60 °C can initiate fracture at gate vestiges and sharp internal corners. Clean in-house regrind is commonly limited to 15–20% for black totes and crates where impact and ESCR values remain within specification, but food-contact packaging must use controlled-source regrind per FDA 21 CFR 177.1520 conditions and EU 10/2011 traceability.

    Closure and Overcap Torque Retention Without Amine-Based Process Aids

    In multi-cavity tools for continuous-thread closures, snap-overcap lids and dispensing plugs in the 28–63 mm diameter range, dimensional repeatability of the thread minor diameter is the quality target. H516HP’s 16 g/10 min melt flow allows filling of 0.8–1.5 mm cap skirts at moderate injection pressure, but shrinkage anisotropy between the thick tamper-evident band and the thin skirt produces roundness errors if the part is ejected before sufficient cooling. The correction is not lower melt temperature but longer hold time at gate frost. A typical closure tool may run with melt temperature 200–235 °C, mould temperature 15–30 °C, packing pressure 45–65 MPa, and total cycle time of 12–18 s for a 1.2 mm skirt. Gate location at the top centre of the cap creates radial flow and a weld line at the thread interruption; that weld line is the primary leak path under top-load compression of 300 N applied at 10 mm/min crosshead speed.

    Torque behaviour is a function of thread geometry, material modulus, and creep under hoop stress. The application torque for a 28 mm closure on an HDPE bottle neck is typically 1.5–2.5 N·m, and removal torque after 24 h at 23 °C should remain within 0.8–1.5 N·m to avoid consumer rejection. Because H516HP has a relatively low flexural modulus compared with mineral-filled polypropylene, thread stripping torque is lower, and cap-thread designs must not exceed flank depths of 1.0 mm at pitch 2.7 mm without verifying retention under ASTM D3475 child-resistant closure protocols where applicable. The material should not be combined with amine-based torque-release additives or high-polish surface sprays that migrate to the thread surface; such contamination creates a reduction in apparent coefficient of friction that is not captured by standard dry torque tests. For food and detergent closures, FDA 21 CFR 177.1520 and EU 10/2011 apply, and sensory screening under ISO 13302 is standard for dairy, water and household chemical packaging. Closures for carbonated soft drinks are outside the operational boundary because long-term CO₂ pressure retention requires barrier and creep behaviour beyond an unfilled HDPE grade.

    When Appliance and Houseware Components Require Low-Temperature Impact After Stacking

    Storage bins, drawer frames, appliance bases and mixer bowls made from H516HP are usually designed with nominal walls of 2.0–3.5 mm, which places them inside the material’s process window but exposes them to a conflict between flow and impact. Lower melt temperatures of 190–205 °C reduce odour and colour shift but increase residual shear stress; subsequent low-temperature drop tests at -5 °C or 0 °C can then produce brittle failure at the gate or at sharp corners. The practical resolution on production lines is to maintain melt temperature at 210–225 °C while using a short flow path from a sub-gate positioned in a non-appearance area, with packing pressure decay over 3–5 s. This reduces frozen-in orientation without extending cycle time. Mould shrinkage for such parts is commonly set at 1.6–2.2% along flow and 1.8–2.4% across flow, but only after post-mould dimensional stabilisation for 24 h at 23 °C ± 2 °C to allow secondary crystallisation to settle. Shrinkage values below 1.4% are normally associated with overpacked parts, which exhibit elevated residual stress and increased warpage after exposure to a 60 °C warehouse environment.

    Heat deflection temperature under 0.455 MPa is the standard reference for occasional hot-surface contact. Unfilled HDPE of this density generally falls between 65 °C and 80 °C under ASTM D648 or ISO 75-2, which means continuous load-bearing use above 50 °C is not appropriate for parts with tight dimensional stability requirements. In appliance bases near compressor housings, the local surface temperature may exceed 60 °C, but the component is not under continuous structural stress. The polymer’s strain hardening after yielding provides ductile failure under moderate impact, measured as notched Izod impact or notched Charpy impact under ISO 180/A or ISO 179-1/1eA; laboratory values from HDPE injection grades with 16 g/10 min melt flow typically occupy the 3–6 kJ/m² range at 23 °C, though H516HP-specific published figures should be verified against the certificate of analysis for the specific lot. UV exposure in outdoor storage bins is a separate limitation: natural HDPE photo-oxidation requires a UV stabiliser package such as hindered amine light stabiliser and carbon black, and the resin alone is not suitable for prolonged outdoor deployment without a total carbon black loading above 2% by mass for UV opacity per ASTM D2565 practice.

    Application segmentReference standard or regulationCritical test/control
    Thin-wall food containersFDA 21 CFR 177.1520, EU 10/2011, ISO 13302Overall migration limit 10 mg/dm² for food contact
    Industrial pailsUN Model Regulations Chapter 6.1, ADR 6.1.5, ISO 2248-18 °C drop at 1.2 m / 0.8 m; stacking 40 °C/28 days
    Crates and totesISO 2234, ASTM D2990, ASTM D1693Compressive creep below 2% strain; ESCR condition B
    ClosuresFDA 21 CFR 177.1520, ASTM D2063, ASTM D3475Removal torque after 24 h; child-resistant protocols where required
    Housewares and appliancesISO 75-2, ISO 180/A, REACH, RoHSHDT at 0.455 MPa; notched impact; SVHC screening
    Toys and consumer goodsEN 71-3, ASTM F963-23, REACH Annex XVIIElement migration, phthalate limits, 1.5 m drop

    Injection moulded toy structural parts, construction blocks and consumer storage accessories use H516HP when the mechanical demand is limited to drop survival and moderate load. Wall sections from 1.5 mm to 3.0 mm allow cycle times below 25 s, and the high melt flow reduces short-shot frequency in multi-cavity family tools with hot-runner imbalance. The main process risk is gate blush on high-gloss surfaces; this is controlled by valve-gated hot tips with tip temperatures at 200–220 °C, and by injecting at the lower end of the pressure window once the melt temperature is raised above 210 °C. Weld lines formed behind thick bosses do not normally govern toy drop performance at 23 °C, but at -10 °C the same weld line can become the path of lowest energy release. The specification for cold drop is often 1.5 m onto concrete without visible cracks under ISO 8124-1 or ASTM F963-23; impact modifier addition is not necessary if packing hold time is sufficient and gate location avoids flow-front stagnation.

    Regulatory compliance for toy and consumer product applications requires absence of heavy metals and plasticisers above the limits of EN 71-3 and ASTM F963-23, with phthalate restrictions under REACH Annex XVII entries 51 and 52 and CPSIA section 108. H516HP does not require phthalate plasticisers for flow because the high melt flow is intrinsic to the base resin. However, pigments and masterbatches added during moulding must be selected from approved suppliers because heavy-metal-based colourants can push the finished article outside the 19-element migration limits of EN 71-3. Sterilisation by steam autoclave above 110 °C is outside the grade’s operating envelope and is known to create permanent dimension change in HDPE parts unless the tool design compensates with post-mould annealing at 100 °C for 30 min, which itself is not standard for high-volume toy production.

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