| HS Code | 768174 |
| Grade | Chevron Phillips Chemical HDPE 9509HF |
| Polymer Type | High Density Polyethylene (HDPE) |
| Density | 0.950 g/cm³ |
| Melt Index 190 C 2 16 Kg | 9.0 g/10 min |
| Tensile Strength At Yield | 25.5 MPa |
| Tensile Strength At Break | 22.1 MPa |
| Elongation At Break | 1000% |
| Flexural Modulus | 1.10 GPa |
| Izod Impact Notched | 0.530 J/cm |
| Hardness Shore D | 64 |
| Vicat Softening Point | 124 °C |
| Heat Deflection Temperature At 0 46 Mpa | 71 °C |
| Heat Deflection Temperature At 1 8 Mpa | 43 °C |
| Brittleness Temperature | -70 °C |
As an accredited Chevron Phillips Chemical HDPE 9509HF factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.
| Packing | Chevron Phillips Chemical HDPE 9509HF is packaged in 25 kg moisture-resistant bags, palletized for shipment, with bulk options available. |
| Container Loading (20′ FCL) | 20′ FCL container loaded with Chevron Phillips Chemical HDPE 9509HF polyethylene resin in 25 kg bags, palletized and secured for transport. |
| Shipping | Chevron Phillips Chemical HDPE 9509HF is shipped as non-hazardous high-density polyethylene pellets, usually in 25 kg bags, octabins, or bulk trucks/railcars. Store in a cool, dry area away from UV/heat. Not DOT regulated; use standard material handling. Ensure containers remain sealed and palletized during transport to prevent moisture contamination and spillage. |
| Storage | Store Chevron Phillips Chemical HDPE 9509HF in a cool, dry, well-ventilated area away from direct sunlight, heat, sparks, and open flames. Keep containers tightly closed and labeled, on pallets off the floor. Prevent moisture, dust, and contamination. Avoid prolonged UV exposure and excessive heat. Use first-in, first-out stock rotation and comply with local regulations. Store in original packaging. Handle carefully. |
| Shelf Life | Shelf life: typically at least 12 months when stored in original, unopened packaging, cool, dry, and away from direct sunlight. |
In thin-wall injection moulding of dairy packaging, the 9 g/10 min melt flow rate of Chevron Phillips Chemical HDPE 9509HF under ASTM D1238-23 at 190°C/2.16 kg and the manufacturer-published nominal density of 0.953 g/cm3 under ASTM D1505 are used to fill stack-mould cavities with wall stocks as low as 0.45 mm. The food-contact status of this grade is supported by the manufacturer’s food-contact compliance statement under FDA 21 CFR 177.1520(c) for olefin polymers, and the finished article must comply with EU Regulation (EU) No 10/2011, including an overall migration limit of 10 mg/dm2 for food-contact surfaces; resin compliance does not override downstream colourant or processing aid contributions. The formulation typically remains 100 wt% virgin HDPE 9509HF. When pigmentation is required, PE-carrier masterbatch is introduced at 2–4 wt%, and a 50% TiO2 white masterbatch may require 4–6 wt% to achieve opacity above 92%. External lubricant packages are held below 0.05 wt% to avoid surface residue that can interfere with lid sealing, and antistatic additives, if used for high-speed handling, are limited to 0.1–0.3 wt% and must carry food-contact clearance. In production, high-speed injection moulding machines with clamp forces from 1,500 kN to 3,500 kN operate stack tools with 4+4 or 8+8 cavities; general-purpose polyolefin screws with 20:1 L/D and compression ratios near 2.5:1 deliver melt temperatures of 200–230°C at the nozzle, while mould coolant is maintained at 10–20°C. Fill times below 0.6 s are required for 0.6 mm wall stock, and injection pressures can reach 100 MPa without substituting for adequate gate sizing. Terminal product types include dairy tubs, yogurt cups, deli containers, single-serve condiment cups, tamper-evident dairy lids, frozen dessert cups, and thin overcap lids. Moulded flatness across a 500 mm lid span is maintained by keeping differential shrinkage below 1.2% between flow and transverse directions as measured per ASTM D955-21; hot-runner valve gate tips are held below 240°C to prevent stringing and discolouration. Pre-drying is unnecessary when ambient relative humidity remains below 60%; if surface condensation has occurred, a desiccant dryer at 80°C for 2 h is applied to prevent splay. The grade should not be processed above 270°C, and residence time above 8 min at 250°C can initiate chain scission, producing odour and a measurable reduction in melt viscosity.
Across 32- and 64-cavity closure tooling, HDPE 9509HF is selected not only for its 9 g/10 min melt flow rate under ASTM D1238-23, but because its narrow molecular weight distribution reduces differential shrinkage between the hinge axis and the neighbouring cap deck when dimensional checks are performed per ASTM D955-21. The finished part falls under food-contact regulation FDA 21 CFR 177.1520(c) and EU Commission Regulation (EU) No 10/2011 when used on food and beverage packages, with overall migration testing required on the finished closure at the intended fill temperature and simulant. Formulation is normally 100 wt% virgin resin with PE-carrier colour masterbatch added at 1–3 wt%; slip agents such as erucamide masterbatch are used at 0.05–0.15 wt% to control opening torque, but higher slip loadings can cause environmental stress-cracking in the hinge root when tested under ASTM D1693 condition B. In production, valve-gated hot-runner systems operate at nozzle temperatures of 200–230°C and valve-stem closure cycles below 1.5 s to prevent gate vestige interference with cap fitment. Mould coolant at 8–15°C is maintained through 3D-printed conformal cooling channels or gun-drilled steel inserts, because the solidification rate at the hinge cross-section governs post-demoulding flatness. Cavity pressure sensors set to hold at 30–60 MPa after switch-over from velocity-controlled filling prevent overpacking the hinge web; overpack at the hinge can reduce flexural crack initiation life in cyclic closure testing. Terminal products include flip-top beverage caps, disc-top dispensing caps for sauces and personal care products, aerosol overcaps, trigger sprayer shrouds, and tamper-evident snap caps. The living hinge itself is typically moulded at 0.25–0.40 mm thickness with the hinge axis perpendicular to primary flow to avoid a weld line at the flexural neutral zone. Processing below 190°C melt temperature can inhibit complete filling of the hinge and cap skirt; above 250°C, oxidation can increase odour and discolouration. Batch-to-batch melt flow variation within the manufacturer’s specification may shift filling pressure by 5–8%, so cavity pressure control algorithms are preferred over fixed injection velocity settings. No pre-drying is required below 60% ambient relative humidity; desiccant drying at 80°C for 2 h is applied only if surface condensation is observed. Stress whitening after 100 flexural cycles is not a pass/fail standard but indicates excessive hinge thickness reduction or polymer orientation, prompting tooling correction.
When flatness across a 600 mm span dominates part acceptance, HDPE 9509HF is used for injection-moulded storage crates, utility baskets, ventilated stacking trays, and garment hangers. Regulatory compliance for housewares in North America and Europe is anchored to FDA 21 CFR 177.1520(c) where incidental or repeated food contact occurs during refrigerated storage, and to REACH (EC) No 1907/2006 for substances of very high concern in the EU market. Formulation remains 100 wt% virgin resin; colour loading is typically 2–4 wt% PE-carrier masterbatch for solid colours, 2–2.5 wt% carbon black masterbatch for prolonged outdoor service, or 0.2–0.5 wt% HALS/UV stabilizer masterbatch for pigmented outdoor products. Injection moulding uses hydraulic or hybrid machines rated at 6,000–12,000 kN clamp force for multi-cavity crate tools, with melt temperature controlled at 200–230°C, mould coolant at 15–30°C, and hydraulic injection pressure at 70–100 MPa. Cycle times for 2–3 mm wall stock typically fall between 25 s and 45 s; hold pressure is set to the lower edge of the gate freeze window to minimise moulded-in stress at the rib-to-floor junctions. Terminal parts include rectangular storage bins, crates, shelf trays, garment hangers, stacking totes, and waste container bodies. The grade’s nominal 1,100–1,200 MPa flexural modulus under ASTM D790-17 provides stacking stiffness, but continuous service above 60°C or contact with strong detergents requires ESCR validation under ASTM D1693 condition B in 10% Igepal solution. High ambient humidity above 60% does not typically require drying of sealed virgin pellets, but open storage of regrind can introduce surface moisture that creates splay at high injection speeds.
For 10 L to 25 L open-head pails, snap-on lids, and tamper-evident covers, the high flow of HDPE 9509HF allows short injection times across wall thicknesses from 1.2 mm to 2.5 mm but does not by itself guarantee dangerous goods certification. The applicable transport compliance framework is UN 3H1 for open-head HDPE containers and UN 3H2 for closed-head configurations, with qualification requiring leak-proofness, stack compression, and drop testing at -18°C under the relevant packing group. Food-grade pails additionally reference FDA 21 CFR 177.1520(c) and EU Regulation (EU) No 10/2011, while REACH (EC) No 1907/2006 applies to EU sale. The base formulation is 100 wt% virgin HDPE 9509HF; for UV-exposed outdoor storage, processors compound 2–2.5 wt% carbon black masterbatch or 0.2–0.4 wt% HALS/UV stabilizer masterbatch. If cold-crack resistance below -20°C is specified, metallocene LLDPE is added at 10–15 wt%, which lowers flexural modulus and can reduce top-load capacity; this trade-off must be tested per the final pail specification. Production-scale tooling uses two-platen injection moulding machines with clamp forces from 10,000 kN to 25,000 kN depending on pail diameter and cavitation, melt temperatures of 200–230°C, mould coolant at 10–20°C, and injection pressures up to 120 MPa for handle boss packing. The gate is placed at the centre of the pail base to create radial flow and reduce weld-line weakness at the handle bridge; handle hinge-out failure is the most common production defect when the fill speed is reduced below 60% of machine maximum. Terminal products include open-head industrial pails, paint and adhesive cans, grease cartridge shells, and tamper-evident lid covers. Published data for this exact grade under UN 3H1 qualification is limited; processors must qualify the finished pail with the complete handle and lid assembly because resin type alone is not a certification basis. The grade should not be used for continuous transport of strong oxidizers, aromatic hydrocarbons, or hot-fill media above 60°C without permeation and stress-cracking validation.
For medical device secondary packaging trays and diagnostic transport boxes, HDPE 9509HF is processed under cleanroom-compatible injection moulding conditions, with the moulded component functioning primarily as a rigid outer enclosure rather than a primary sterile barrier. Regulatory evaluation is governed by ISO 10993-1:2018 when the plastic contacts body surfaces directly, and by USP <661.1> for plastic packaging components used with pharmaceutical preparations; sterile barrier packaging systems are validated under ISO 11607-1:2019 only when the tray is sealed with sterile barrier lidding. The formulation is typically 100 wt% virgin resin with 1–2 wt% heavy-metal-free colour masterbatch and no external processing lubricants, because surface residues can interfere with tray sealing or analytical testing. Injection moulding is performed on electric screw machines with 800–3,000 kN clamp force, melt temperature 200–220°C, mould coolant at 10–20°C, and high-pressure filling for wall thicknesses down to 1.0 mm. The mould is cleaned and dried after each lot, and air ejection is supplied through 0.2 μm filtered compressed air to avoid lubricant contamination. Terminal product categories include surgical instrument trays, sharps container bodies, diagnostic reagent transport boxes, secondary overpack shells, and pipette rack bases. Gamma sterilisation at 25–40 kGy can cause measurable yellowing and a reduction in notched impact strength; processors should conduct post-sterilisation functional testing rather than rely on virgin resin data. Exposure to alcohol-based disinfectants may reduce environmental stress-crack resistance, so compatibility testing under hospital cleaning protocols is required before clinical deployment.
Injection-moulded toy components such as building blocks, wheeled vehicle bodies, sorting blocks, and playhouse panels are produced from HDPE 9509HF when snap-fit assembly and uniform wall colour are required. Regulatory compliance for the finished toy includes migration limits in EN 71-3:2019+A1:2021, mechanical and physical testing in ASTM F963-23, and lead and phthalate restrictions under 16 CFR 1303 and 16 CFR 1307 in the United States. The formulation is 100 wt% virgin HDPE 9509HF with 2–4 wt% heavy-metal-free colour masterbatch; calcium carbonate or talc fillers are avoided in building blocks because filler increases brittleness and reduces snap-fit flex fatigue. Production uses high-cavitation tools with melt temperature 200–220°C, mould coolant at 15–25°C, injection pressures of 80–100 MPa, and cycle times determined by the thickest rib intersection. Multiple submarine gates are positioned away from visible surfaces to prevent gate blush; weld lines are kept out of snap-fit beams by placing the gate centrally in the base plane. Terminal product types include interlocking building blocks, toy vehicle bodies, shape-sorting housings, playset panels, and outdoor play components. Outdoor toys require a UV stabilizer package or carbon black masterbatch at 2–2.5 wt%; indoor components exposed to repeated disinfection or detergent cleaning should be tested for ESCR under ASTM D1693. The grade should not be used for toy components requiring continuous service above 60°C, and it is not a substitute for engineering thermoplastics in high-impact protective gear.
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Chevron Phillips Chemical HDPE 9509HF is a high-density polyethylene injection-moulding resin supplied in pellet form. The grade is positioned in the high-melt-flow segment of the HDPE injection-moulding family. Melt mass-flow rate, determined at 190 °C under 2.16 kg according to ASTM D1238-20, is nominally 9.0 g/10 min. Density, measured under ASTM D1505, is nominally 0.955 g/cm³. The combination of density and flow enables fast cavity filling in multi-cavity tools with thin nominal walls while maintaining flexural stiffness sufficient for stackable containers, housewares, crates, pails, and general thin-wall packaging. The melt-flow rate is approximately two to three times that of conventional HDPE injection grades in the 3–5 g/10 min range, which influences filling pressure, orientation, shrinkage, impact behaviour, and stress-crack resistance. Substitution of this grade should therefore be evaluated through tool trials and not through melt index alone.
| Property | Test method | Typical value |
|---|---|---|
| Melt mass-flow rate at 190 °C/2.16 kg | ASTM D1238-20 / ISO 1133-1:2022 | 9.0 g/10 min |
| Density | ASTM D1505 | 0.955 g/cm³ |
| Tensile strength at yield | ASTM D638-14 | 27 MPa |
| Tensile elongation at break | ASTM D638-14 | 300% |
| Flexural modulus, 2% secant | ASTM D790-17 | 1240 MPa |
| Notched Izod impact strength at 23 °C | ASTM D256 | 55 J/m |
| Shore D hardness | ASTM D2240 | 66 |
| Deflection temperature under load at 0.455 MPa | ASTM D648 | 78 °C |
| Vicat softening temperature | ASTM D1525 | 126 °C |
| Environmental stress crack resistance, 100% Igepal, F50 | ASTM D1693 | Not intended for ESCR-critical service |
The values in the table are typical for injection-moulded test specimens and are not certified release limits. Lot-to-lot variation, specimen conditioning, and laboratory bias can shift individual measurements. For specification conformance, a certificate of analysis should be requested from the manufacturer.
Injection moulding of HDPE 9509HF on reciprocating-screw machines is conventional. Screws with 20:1 to 24:1 L/D ratios and compression ratios between 2.5:1 and 3.0:1 are suitable. A general-purpose metering profile is acceptable; high-shear barrier screws may generate unnecessary melt-temperature overshoot above 230 °C. The hopper should remain closed when ambient humidity exceeds 60% RH. Although polyolefins are not hygroscopic in the manner of polyamides, surface moisture from condensation can produce splay and intermittent flow in high-velocity thin-wall moulding. If splay is observed, hopper drying at 80 °C for 2 h is effective. Start-up barrel settings normally range from 180 °C at the rear zone to 220 °C at the metering zone and nozzle. Melt temperature should be verified by an insertion pyrometer rather than inferred from barrel set points. Mold temperatures of 20–35 °C are typical for fast-cycle operation. Holding pressure must be established by gate-seal testing: hold pressure is stepped downward until part mass decreases, then final hold pressure is set 5–10% above the gate-seal threshold. This procedure prevents sink marks and hold-time-related warpage on thin ribs and boss features.
At nominal wall thickness below 0.8 mm, practical filling length is controlled by cavity thickness, melt temperature, and available injection pressure at the screw tip. Thin-wall tools require high volumetric flow rates, and the resin must enter the cavity before the frozen layer closes the flow channel. In moulds with wall sections of 0.6–1.0 mm, melt temperature below 190 °C causes premature solidification and rising screw-tip pressure. Melt temperature above 230 °C can generate degradation by-products, off-odors, and brown streaks in hot-runner manifolds. The moulding technician must monitor actual melt temperature, injection time, and transfer position. Cycle-to-cycle variability in switchover position exceeding 0.5 mm on a 250 mm stroke indicates check-ring leakage or inconsistent plastication. For thin-walled containers, clamp tonnage is typically set to 0.3–0.5 kN per square centimetre of projected area depending on cavity thickness and flow length. Higher clamping does not compensate for inadequate venting or slow injection speed.
Thermal stability of high-flow HDPE is acceptable at melt temperatures up to 260 °C for short residence times, but the recommended melt temperature is 190–230 °C. Residence time in the barrel should be kept below 5 min; longer residence at elevated temperature increases gel formation and black speck contamination. Purging with low-density polyethylene or a commercial purging compound should be performed when transitioning from coloured or filled resins. Screw and barrel wear in the metering zone should be monitored; a uniform clearance increase above 0.2 mm can cause melt-temperature variation. Oil or water thermolators should control cavity and core independently within ±2 °C. Differences above 5 °C across the tool face produce differential shrinkage and warpage. For thin-wall tools, water flow per circuit is commonly maintained between 8–12 L/min.
The grade is not intended for blown film or sheet extrusion where high melt strength and stable bubble geometry are required. In blown film, low viscosity destabilises the bubble and reduces tensile orientation. The product also differs from high-density polyethylenes with bimodal molecular weight distribution used for pipe and blow moulding. Such grades typically have melt indices of 0.2–1.5 g/10 min and substantially higher environmental stress crack resistance under ASTM D1693. HDPE 9509HF offers the inverse profile: high flow and high stiffness but lower ESCR. It should not be used in gas or water pressure pipe applications requiring long-term hydrostatic strength under ISO 1167 and ISO 9080. For large-part blow moulding, a low-melt-index or bimodal blow-moulding grade is required to maintain parison sag resistance.
Shrinkage in HDPE 9509HF is anisotropic and depends on wall thickness, gate type, and hold pressure. Because the grade flows readily, it orients more than a lower-melt-index HDPE at identical injection speed. In cold-runner tools with restricted gates, high shear produces residual stress. Post-mould shrinkage in the flow direction may exceed cross-flow shrinkage by 0.3–0.6% after 48 h at ambient temperature, so tooling design should compensate for differential shrinkage. Regrind tolerance is generally acceptable for non-food industrial articles up to 20 wt% regrind, provided that the regrind is free of contamination, dried to below 0.02 wt% moisture, and uniformly blended with virgin resin in a gravimetric metering blender. Higher regrind percentages reduce impact strength and increase black speck risk. In food-contact packaging, regrind use must be evaluated under 21 CFR 177.1520 and, where applicable, EU Regulation 10/2011. Recycled content may not be introduced without control of previous feedstock.
The most common defects on production lines are short shots, flow marks, sink marks, and warpage. Short shots in thin-wall tools are usually caused by insufficient melt temperature or low injection speed, not by clamp force alone. Flow marks are linked to melt temperature below 190 °C and nozzle-to-sprue temperature mismatch. Sink marks indicate gate seal too early or hold pressure too low. Warpage indicates uneven mold temperature, gate imbalance, or excessive orientation from high injection speed. Because high-flow HDPE exhibits relatively low melt strength, weld-line strength in thin-wall parts may be lower than in lower-flow grades of equivalent density. Gate location trials should therefore include weld-line bending or tensile testing according to ASTM D638 on specimens cut from moulded parts.
For regulatory compliance, the final article should be verified rather than relying solely on the resin grade. HDPE produced from ethylene is generally described under 21 CFR 177.1520 for food-contact use, but final compliance depends on additives, masterbatches, processing aids, and extraction testing. The natural, uncoloured resin does not intentionally contain heavy metals, phthalates, or bisphenol A. For European applications, the material must be assessed under EU Regulation 10/2011 for plastic food-contact articles when intended for that service. Under RoHS Directive 2011/65/EU, typical unfilled natural HDPE has lead and cadmium levels below the homogeneous-material thresholds, but coloured or recycled compounds must be verified by X-ray fluorescence or certified supplier data. The product is not intended for medical devices subject to ISO 10993 without additional biocompatibility evaluation.