| HS Code | 190475 |
| Polymer Type | High Density Polyethylene (HDPE) |
| Density | 0.943 g/cm³ |
| Melt Index | 12 g/10 min (190°C/2.16 kg) |
| Tensile Strength At Yield | 25 MPa |
| Tensile Elongation At Break | 800% |
| Flexural Modulus | 1100 MPa |
| Notched Izod Impact | 53 J/m |
| Shore D Hardness | 66 |
| Vicat Softening Point | 121°C |
| Melting Point | 130°C |
| Heat Deflection Temperature At 0 45 Mpa | 71°C |
| Heat Deflection Temperature At 1 8 Mpa | 48°C |
| Escr 100 Igepal | 20 h |
| Mold Shrinkage | 1.5-3.0% |
| Melt Temperature | 200-230°C |
| Mold Temperature | 20-60°C |
| Coefficient Of Linear Thermal Expansion | 1.2E-4 /°C |
| Water Absorption | <0.01% |
| Specific Gravity | 0.943 |
| Volume Resistivity | >1E16 ohm-cm |
| Dielectric Strength | 20 kV/mm |
| Brittleness Temperature | <-70°C |
As an accredited Chevron Phillips Chemical HDPE 94312 factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.
| Packing | Chevron Phillips Chemical HDPE 94312 is supplied in 25 kg polyethylene-lined paper bags, palletized, with 1,000 kg bulk bags available. |
| Container Loading (20′ FCL) | 20′ FCL container loading: Chevron Phillips Chemical HDPE 94312 in 25 kg bags, palletized, stretch-wrapped, and secured for ocean transport. |
| Shipping | Chevron Phillips Chemical HDPE 94312 ships as a non-hazardous, non-regulated polyethylene resin in pellet form. It is typically packaged in 25-kg bags, octabins, or bulk trucks/railcars. Store dry and protect from moisture, heat, and contamination. No UN number or dangerous goods placards required. |
| Storage | Store Chevron Phillips Chemical HDPE 94312 in a cool, dry, well-ventilated area away from direct sunlight, heat, ignition sources, and incompatible oxidizers. Keep original containers or bags closed to prevent moisture, dust, and contamination. Protect from physical damage and extreme temperatures. Maintain good housekeeping to avoid pellet spills and slipping hazards. Follow the supplier’s SDS and local regulations. |
| Shelf Life | Chevron Phillips Chemical HDPE 94312 has no established shelf life; stable under normal storage, cool, dry, away from sunlight and contaminants. |
Chevron Phillips Chemical HDPE 94312 is an injection-molding grade with a nominal melt flow rate of 12 g/10 min at 190°C/2.16 kg (ASTM D1238) and a nominal density of 0.943 g/cm³ (ASTM D1505). The flow-to-density balance places the material in high-speed, thin-wall injection molding rather than extrusion blow molding, sheet extrusion, or rotational molding. Screw plastication units with an L/D ratio of 20:1 to 25:1 and a compression ratio of 2.5:1 to 3.0:1 are typical for this grade. The following scenarios are separated by tooling configuration, section thickness, and end-use performance requirements rather than by generic market category.
Table 1 summarizes startup processing windows by segment; actual settings depend on tool geometry, hot runner balance, and machine condition.
| Application segment | Melt temperature (°C) | Mold temperature (°C) | Typical wall thickness (mm) | Clamp force range (tonnes) |
|---|---|---|---|---|
| Thin-wall dairy tubs | 200–230 | 15–35 | 0.45–1.20 | 150–400 |
| Crates and stackable totes | 190–220 | 10–30 | 2.5–4.0 | 300–600 |
| Open-top pails | 190–220 | 15–30 | 1.8–3.0 | 450–800 |
| Closures | 190–220 | 10–25 | 0.35–1.50 | 150–300 |
For thin-wall dairy and spread tubs in the 150 mL to 500 mL range, HDPE 94312 is molded on high-cavitation stack tools with 8 to 16 cavities. The sidewall and bottom thickness is 0.45–1.20 mm, which requires a flow-length-to-wall-thickness ratio above 180:1 in many four-cavity to eight-cavity layouts. Valve-gated hot runner tips of 1.0–1.5 mm prevent stringing and reduce shear-heat variation across the manifold. Clamp tonnage is calculated on a basis of 3–5 kN/cm² of projected part and runner area. Injection speed is profiled from 80–120 mm/s during initial filling to 30–50 mm/s before gate freeze; pack pressure is held at 45–60% of peak injection pressure for 0.5–1.0 s. Cooling time is typically 4–7 s per 0.8 mm wall section, and mold temperature is maintained between 15°C and 35°C. After demolding, corona treatment is used only when printing or adhesive labelling is specified. Monolayer HDPE has no oxygen barrier; EVOH or polyketone barrier structures require separate coextrusion tooling and revalidation under EU Regulation 10/2011 and FDA 21 CFR 177.1520 for olefin polymers. Terminal containers include margarine tubs, yogurt cups, and cold-fill spread cups; hot-fill above 75°C requires part-specific heat deflection validation under ASTM D648 or ISO 75-1.
Beverage crates, dairy crates, fish boxes, and industrial stack totes are processed on 300–600 tonne clamps, typically with an accumulator-assisted injection unit to sustain filling speed in thick-to-thin transition zones. Melt temperature at the nozzle is held to 190–220°C, while coolant inlet temperature to the mold is set between 10°C and 30°C depending on wall-stock uniformity. Nominal wall thickness in the load-bearing sidewalls is 2.5–4.0 mm; rib intersections are designed with a rib-to-wall ratio not exceeding 0.65 to prevent sink marks and internal voids. Gate placement is a critical variable: a two-gate arrangement on diagonal corners of the sidewall reduces anisotropic shrinkage compared with center sprue gating, but it increases weld line formation at the gate merge zones. Weld lines are located away from handle and foot-pad regions because the simultaneous melt fronts leave oriented skins with reduced impact resistance in those zones. The material’s density of 0.943 g/cm³ supplies lower flexural modulus than 0.955 g/cm³ HDPE grades; full-crate drop testing at -20°C is required for fish boxes and freezer distribution totes. If a defined flexural modulus is needed, measure according to ASTM D790 or ISO 178 on specimens cut parallel and perpendicular to flow. Published data for this exact configuration is limited; batch-specific certificates of analysis should be used for lot acceptance.
For open-top pails in the 5 L to 20 L range, HDPE 94312 is injection molded on 450–800 tonne machines using single- or two-cavity tools. The section profile is 1.8–3.0 mm in the sidewall and 2.5–4.0 mm at the top rim and base chime. A direct sprue gate into the center of the base produces radial flow; a film gate near the handle lug avoids short shots in the rim. Injection speed is profiled slow-to-fast through the base, then decelerated before handle lugs are filled. Hold pressure is set at 50–70% of peak injection pressure and held until the sprue freezes. Mold temperature is maintained at 15–30°C. The density of 0.943 g/cm³ lowers flexural stiffness relative to 0.955 g/cm³ HDPE and can delay buckling under top-load testing; chemical compatibility must still be evaluated within the target filling system. Oxidizing agents, strong surfactants, and some fatty acid emulsions can reduce environmental stress crack resistance; compatibility testing should use ASTM D1693 condition B or ISO 22088-1 with the actual filling product. For pails marketed under UN 1H2/3H2 package codes for non-flammable liquids, the design certification must include drop testing at -18°C, hydraulic pressure testing, and stack testing; these package-level data are separate from resin datasheet values. The grade is suitable for neutral aqueous formulations, dry goods, and non-aggressive chemical concentrates; it is not a universal chemical packaging resin.
Closure tools with 16 to 64 cavities use HDPE 94312 for dairy closures, personal care caps, pharmaceutical overcap components, and non-carbonated beverage closures. The high melt flow rate allows valve gate diameters of 0.5–1.0 mm and melt temperatures of 190–220°C, with mold temperatures between 10°C and 25°C. Thin tamper-evident band sections (0.35–0.70 mm) fill without excessive injection pressure, but the process window narrows at the bridge and band fold. Closures are demolded and then held in ambient cooling tunnels for 15–30 min before band slitting or liner insertion because post-mold shrinkage continues for up to 24 h; early assembly shifts strip torque and interferes with tamper-evident band bridge rupture. Torque retention is influenced by mold temperature uniformity, gate freeze, and cooling geometry more than by melt flow rate alone. A closure mold with non-uniform cooling across the cavitation block will produce variable thread diameter and corresponding strip torque drift. Compliance for food contact closures is evaluated under FDA 21 CFR 177.1520 and EU Regulation 10/2011. For pharmaceutical or nutritional closures, testing under USP <661.1> may be required for the finished closure system. This grade is not recommended for carbonated soft drink closures requiring sustained gas pressure retention and high environmental stress crack resistance; published data for carbonation retention on this exact configuration is limited.
When wall stock exceeds 2.0 mm, the grade is processed into housewares, storage bins, waste containers, and utility organizers on 120–250 tonne clamps. Melt temperature is typically 180–200°C; mold temperature may be raised to 20–40°C for textured surfaces. Unsupported panel sections should not exceed 150 mm without a rib, return edge, or texture break because the lower-density HDPE has lower flexural stiffness than 0.950–0.955 g/cm³ grades. Surface gloss is controlled by the cavity finish; SPI A-2 polishing produces high-reflectance surfaces, while VDI 24–30 texture reduces visible sink marks at boss intersections. Screw-recovery time and cycle time decrease with the 12 g/10 min MFR, but large storage bins with deep draw require careful ejection design because the low-density high-flow resin may retain heat in thick ribs and bases. Ejector area and draft angle should be increased; a draft angle below 1° on textured sidewalls can cause ejection marks. Recyclate content in open-loop houseware streams is possible up to 25 wt% if melt filtration and regrind particle size are controlled; higher reclaim fractions shift viscosity and may reduce impact performance. End-use products include stackable storage totes, laundry baskets, pedal-bin bodies, and freezer storage containers that do not require hot-fill sterilization.
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Chevron Phillips Chemical HDPE 94312 is a high-density polyethylene resin supplied for extrusion and blow molding processes. The grade is specified with a nominal density of 0.943 g/cm³ when measured by ASTM D1505. Melt flow rate, determined by ASTM D1238 at 190 °C and 2.16 kg, places the material in the fractional-melt range below 1.0 g/10 min. Compared with medium-density polyethylene at 0.935 g/cm³, the resin has higher secant modulus and lower gas permeability. Compared with high-density polyethylene at 0.953 g/cm³, it trades a portion of stiffness and top-load strength for improved environmental stress crack resistance. The balance is used in large-part blow molding, industrial sheet, and thermoformed dunnage where parts must survive repeated contact with aqueous chemical formulations and variable outdoor temperatures.
Injection-molding grades of HDPE typically require melt flow rates above 10 g/10 min to fill thin-wall cavities at practical injection pressures. HDPE 94312 does not meet that requirement. The fractional-melt rheology creates high shear viscosity, restricts melt flow length, and raises clamping-force demand if the material is forced through narrow gates. As a result, the product is not specified for high-flow injection molding; it is directed to extrusion blow molding, sheet extrusion, profile extrusion, and thermoforming operations. Continuous extrusion lines for this product class use a single-screw extruder with an L/D ratio of 24:1 to 30:1, a barrier screw, and a grooved feed throat. Melt temperature at the screw tip is controlled between 175 °C and 220 °C. Discharge temperatures above 230 °C promote oxidation, reduce environmental stress crack resistance, and can generate gel particles that appear as surface defects in sheet and parison surfaces. Head pressure is typically maintained between 10 MPa and 25 MPa at the die inlet. Pressure fluctuations greater than 0.2 MPa at constant screw speed indicate bridging, feed instability, or screen-pack blinding. Screen packs with 20/40/80 mesh arrangement remove contaminants but increase melt residence time; pressure drop across the screen pack is limited to 5 MPa to avoid excessive shear heating.
On accumulator-head blow molding machines, the parison is typically extruded through a diverging die bushing with an included angle of 45° to 60° and a land length of 20 mm to 30 mm. Die gap settings between 1.5 mm and 4.0 mm are adjusted according to part weight, parison programming, and die swell. Clamp force is calculated at 2.5 kN/cm² of projected part area, and blow air is introduced at 0.6 MPa to 1.0 MPa. Mold temperatures are held between 20 °C and 35 °C; cooling time scales with nominal wall thickness at 1.5 s/mm to 2.5 s/mm. The same parison-rupture and sag behavior differs from lower-molecular-weight HDPE grades. A 0.40 g/10 min fractional-melt grade may provide additional sag resistance, but at lower extrusion output. HDPE 94312 is positioned for improved processability while retaining sufficient melt strength for intermediate part sizes. Exact output rates must be established on the production line because accumulator head design, shot size, and regrind loading shift the usable melt-temperature window.
Sheet extrusion of HDPE 94312 uses a barrel profile from 160 °C to 200 °C and a die temperature of 205 °C to 230 °C. A polished three-roll stack between 80 °C and 95 °C yields sheet thickness from 0.5 mm to 6.0 mm. The lower density of 0.943 g/cm³ reduces melt stiffness and allows lower melt temperatures than higher-density HDPE, but it also lowers flexural modulus. Thermoforming lines compensate with increased sheet thickness or ribbing. Plug-assisted thermoforming uses plug speeds of 30 mm/s to 60 mm/s and plug temperatures of 90 °C to 110 °C. Sheet surface temperature at forming is held at 145 °C to 165 °C. A deviation of ±5 °C in sheet surface temperature is sufficient to shift wall-thickness distribution and alter local draw ratios in corners. Below 140 °C, mold texture reproduction is incomplete; above 170 °C, sag and web defects increase. The resin’s fractional-melt character maintains melt cohesion during sheet transport, but it requires careful control of roll gap, draw ratio, and edge trim recycling. Regrind levels above 20 wt% may reduce tear resistance and should be validated with ASTM D1922 for sheet tear and ASTM D638 for tensile yield.
| Parameter | Sheet extrusion | Blow molding |
|---|---|---|
| Barrel feed zone temperature | 160 °C–200 °C | 160 °C–210 °C |
| Melt temperature at die | 205 °C–230 °C | 175 °C–220 °C |
| Head pressure | 10 MPa–25 MPa | 10 MPa–25 MPa |
| Cooling medium temperature | 80 °C–95 °C roll stack | 20 °C–35 °C mold |
| Blow air pressure | Not applicable | 0.6 MPa–1.0 MPa |
| Plug speed | 30 mm/s–60 mm/s | Not applicable |
Black blow molded containers and sheet produced from HDPE 94312 are evaluated for slow crack growth under ASTM D1693, condition B, using 100% Igepal CO-630 at 50 °C. The test ranks environmentally induced cracks but does not directly predict field lifetime; notched constant tensile load tested under ASTM D5397 at 80 °C is used for service-relevant ranking of slow crack growth and container durability. Published F50 data for this specific grade should be taken from the current manufacturer technical bulletin, because batch-to-batch variation in comonomer distribution and molecular weight alters the value. Density confirmation by ASTM D1505, melt flow rate by ASTM D1238, and tensile yield by ASTM D638 are used for lot release and for verifying cell classification under ASTM D4976. The equivalent ISO 1133-1:2022 melt mass-flow rate method is used for global trade. Compliance for food-contact use is evaluated under FDA 21 CFR 177.1520 for olefin polymers, subject to end-use conditions. European food-contact compliance is assessed under EU No 10/2011, with overall migration limit 10 mg/dm². REACH declarations for substances of very high concern use a threshold of 0.1% w/w in articles. RoHS compliance is verified by IEC 62321 methods, with cadmium limited to 100 mg/kg and lead, mercury, and hexavalent chromium each limited to 1000 mg/kg.
| Regulatory reference | Parameter | Limit / status |
|---|---|---|
| FDA 21 CFR 177.1520 | Olefin polymer food contact | Conditions of use apply |
| EU No 10/2011 | Overall migration | 10 mg/dm² |
| REACH | SVHC in articles | 0.1% w/w |
| RoHS 2011/65/EU | Lead, mercury, hexavalent chromium | 1000 mg/kg |
| RoHS 2011/65/EU | Cadmium | 100 mg/kg |
| ASTM D4976 | HDPE specification | Cell classification verified by lot testing |
Chemical container applications exploit the ESCR advantage of 0.943 g/cm³ HDPE relative to higher-density HDPE grades. A 0.953 g/cm³ HDPE typically provides higher top-load strength and lower oxygen transmission coefficient but shows reduced ESCR under the same ASTM D1693 condition. HDPE 94312 shifts the balance toward slow-crack-growth resistance, making it suited to packaging of aqueous surfactant formulations, certain agricultural chemicals, and industrial liquids where paneling, stress whitening, and environmental stress cracking dominate field failures. Resistance to a specific chemical mixture should be evaluated by ASTM D543 at the intended concentration and service temperature, because minor formulation changes in the packaged liquid can alter the environmental stress crack response. Published data for aggressive hydrocarbon systems in this specific grade is limited; container qualification should include closure torque retention, top-load creep, and paneling exposure. Oxygen transmission is measured by ASTM D3985 at 23 °C and 0% RH or standard conditions, and water vapor transmission by ASTM F1249. The lower crystallinity of 0.943 g/cm³ HDPE slightly increases oxygen transmission relative to 0.953 g/cm³ HDPE, but the difference is small relative to wall-thickness effects. Blow molded containers above 20 L require parison programming to control wall-thinning near the pinch-off; top-load strength is measured according to ASTM D2659 or ISO 12048. The product is not recommended for continuous service above 60 °C with strong oxidizing agents or aromatic hydrocarbon solvents, and outdoor storage of unfilled containers should include UV stabilizer because photo-oxidation reduces ESCR and impact resistance.