| HS Code | 319354 |
| Density | 0.955 g/cm³ |
| Melt Index | 0.10 g/10 min |
| Environmental Stress Crack Resistance | >5000 hr |
| Tensile Strength At Yield | 27 MPa |
| Tensile Strength At Break | 33 MPa |
| Elongation At Break | >600% |
| Flexural Modulus | 1.10 GPa |
| Hardness Shore D | 65 |
| Vicat Softening Point | 125 °C |
| Brittleness Temperature | -70 °C |
| Thermal Expansion Coefficient | 1.2E-4 /°C |
| Thermal Conductivity | 0.38 W/m-K |
| Dielectric Constant | 2.3 |
| Dielectric Strength | 18 kV/mm |
| Volume Resistivity | >1E15 ohm-cm |
| Water Absorption | <0.01% |
As an accredited Chevron Phillips Chemical HDPE 4100 (IPS) FM / 4000 factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.
| Packing | Chevron Phillips HDPE 4100 (IPS) FM / 4000 is supplied in 25 kg polyethylene bags, 40 bags per pallet (1,000 kg). |
| Container Loading (20′ FCL) | Chevron Phillips Chemical HDPE 4100 (IPS) FM / 4000 resin in 25 kg bags, palletized, loaded into 20′ FCL, securely stowed. |
| Shipping | Chevron Phillips Chemical HDPE 4100 (IPS) FM / 4000 is a non-hazardous high-density polyethylene resin. It typically ships in 25 kg bags, octabins, or bulk trucks/railcars. Store in a cool, dry area away from sunlight, moisture, and ignition sources. Not regulated for transport. |
| Storage | Store Chevron Phillips Chemical HDPE 4100 (IPS) FM / 4000 in a cool, dry, well-ventilated warehouse, away from direct sunlight, heat, flames, and strong oxidizers. Keep original bags or containers closed, palletized, and off the floor. Avoid moisture, dust, and contamination. Protect from UV exposure and excessive stacking. Use first-in, first-out rotation; inspect containers regularly. Follow the manufacturer’s SDS and local regulations. |
| Shelf Life | Shelf life is 24 months from date of manufacture when stored in original packaging under cool, dry, well-ventilated conditions. |
Preliminary hydraulic design for large-diameter potable water transmission lines using Chevron Phillips Chemical HDPE 4100 (IPS) FM/4000 begins not with a generic mixing step but with long-term hydrostatic strength validation under ASTM D2837 and ISO 9080. The resin is classified as PE4710, carrying a hydrostatic design stress of 1600 psi (11.0 MPa) at 23 °C and 1000 psi (6.9 MPa) at 60 °C. That classification permits potable water mains in DR 11 at 200 psi and DR 17 at 125 psi at ambient temperature, with surge allowance and temperature derating applied according to AWWA C906 and ASTM F714. The finished pipe must also satisfy the extractables and leachate screening requirements of NSF/ANSI 61, which is a site-specific approval condition rather than a resin property.
Pipe production for this service is carried out on single-screw extruders equipped with 30:1 to 33:1 L/D barrels, grooved feed sections, and barrier screws. Melt temperature is controlled at the die entry between 200 °C and 230 °C; operation below 190 °C raises melt viscosity sufficiently to produce melt fracture on thin-wall SDR 17 pipe, while sustained operation above 245 °C accelerates depletion of the hindered phenolic stabilizer package and narrows the oxidative induction time margin. Vacuum tank cooling with water at 15 °C to 25 °C is used to set outside diameter, followed by ultrasonic wall-thickness scanning and a final hydrostatic proof test under ASTM F714.
For potable water conversion, the as-supplied black compound is processed without additional carbon black concentrate. If a converter dry-blends a natural lot to obtain the required UV stabilization for outdoor storage, 2.0–2.5 wt% of a 40% carbon black masterbatch is used, and the masterbatch carrier must itself be certified for potable water contact. Clean in-house regrind generated from the same production lot is limited to 15 wt%; no post-consumer reclaimed polyethylene is permitted in NSF/ANSI 61 systems. Terminal finished product types include IPS pressure pipes from DN 90 through DN 1600, butt-fused spools, electrofusion couplers, stub ends, reducing tees, and transition fittings connecting to ductile-iron or PVC networks.
The separating condition is not melt flow or density but the approval test sequence of FM 1613, which evaluates flexible underground fire service pipe under sustained internal pressure, tensile pull, impact, and environmental exposure. When HDPE 4100 (IPS) FM/4000 is used below grade, NFPA 24 governs burial depth, thrust restraint, and hydrant branch placement; the resin is not listed for above-ground fire service because it is combustible and loses pressure-retaining capacity at temperatures well below structural steel. Underground fire mains therefore use the same pipe body as potable water lines, but the production lot traceability, black masterbatch content, and regrind handling differ.
On an FM 1613-listed extrusion line, online ovality sensors record circumference at 1° increments and reject pipe with out-of-roundness exceeding the standard’s installation tolerance. Gravimetric feeding holds the virgin compound feed within ±0.5 wt% of setpoint, and the line performs a hydrostatic proof test at 1.5 times the pressure class for 5 s per ASTM F714. Because FM approval is lot-specific, a converter cannot substitute another PE4710 resin without repeating the approval audit.
Formulation constraints are tighter than potable water work. Carbon black concentration is held between 2.0 wt% and 3.0 wt% to protect above-ground storage from UV embrittlement before burial, and in-house regrind from the same FM-listed lot is capped at 5 wt%. Trim or sweepings from non-listed pipe, post-consumer rework, foaming agents, and mineral fillers are excluded because they compromise traceability and impact the approval basis. Terminal product types are FM-listed underground pipe spools, hydrant branch saddles, mechanical joint restraint glands, flange adapters, and transition connections to ductile-iron or steel fire headers.
| Standard | Application-specific criterion | Production verification |
|---|---|---|
| FM 1613 | Approval of flexible underground fire service pipe; sustained pressure, impact, tension, and environmental exposure | Approval audit; lot traceability |
| NFPA 24 | Underground installation of private fire service mains; burial depth, thrust restraint | Field inspection of depth and joint restraint |
| ASTM F714 | IPS outside diameter, wall thickness, and hydrostatic proof test | Online dimensional scan; proof test |
| AWWA C906 | PE pressure pipe for waterworks; fusion quality | Butt fusion destruct test per project specification |
In chemical transfer service, the dominant long-term failure mechanism shifts from tensile yield to slow crack growth under sustained hoop stress. The pigmented PE4710 classification of HDPE 4100 (IPS) FM/4000 is evaluated by ASTM F1473, where the notched pipe test at 80 °C and 2.4 MPa can require failure times exceeding 500 h for properly selected PE4710 compounds. Published data for this specific configuration is limited; therefore a converter qualifying an aggressive chemical stream should run ISO 16770 full-notch creep tests on extruded pipe samples and compare the ductile-to-brittle transition time against the design lifetime.
Chemical transfer pipe is produced as single-wall and dual-containment pipe. The inner carrier pipe is extruded on a grooved-feed extruder with melt temperature controlled between 200 °C and 230 °C, then passed through a vacuum calibration bath and cut into spools. Field assembly is performed by socket fusion for small-diameter above-ground runs and butt fusion per ISO 21307 for buried lines. For thin-wall carrier pipe below 32 mm outside diameter, 0.02–0.05 wt% of a fluoropolymer processing aid is dry-blended to suppress melt fracture; this additive must be selected to avoid interfering with fusion bead formation.
External wax-based lubricants and metallic stearates are not recommended because they can migrate to the weld interface and reduce fusion joint strength. Clean in-house regrind is limited to 10 wt% to preserve slow crack growth resistance; post-consumer rework is excluded. Carbon black content is maintained at 2.0–2.5 wt% for UV resistance, and no organic pigment colorants are added because they can mask stress-crack initiation and introduce compatibility uncertainty in solvent-rich streams. Finished products include above-ground and buried chemical transfer pipes, double-wall containment pipe with leak detection ports, electrofusion couplers, flanged adapters, and custom fabricated spools for tank farm connections.
For tailings and slurry transport circuits in base-metal and mineral processing, the selection of HDPE 4100 (IPS) FM/4000 centres on abrasion resistance and resistance to rapid crack propagation under cyclic pressure pulsation from positive-displacement pumps. Slurry pipe specifications commonly reference ISO 4427-1 for PE100 pressure pipe materials, ASTM D3350 for cell classification, and AS 4130 for polyethylene pipe in mining and general pressure applications. The design does not rely on a single abrasion-resistance number; instead, wall thickness is increased by a wear allowance that depends on particle size distribution, solids concentration, flow velocity, and pipe orientation.
Thick-wall slurry pipe is extruded with wall thicknesses commonly between 20 mm and 100 mm, requiring a high-torque extruder with 33:1 L/D, internal pipe cooling, and a spiral mandrel die with adjustable centering. Barrel temperatures are ramped downward from 210 °C at the feed section to 185 °C at the die to increase melt strength and reduce sag in heavy walls. The extruder output is controlled gravimetrically, and wall-thickness variation is held below ±1 mm on the invert of the pipe for wear-sensitive slurries. Slurry transport velocity is maintained above 1.5 m/s to prevent solids settling and below 7 m/s to limit internal wear.
Formulation for slurry service permits clean in-house regrind at up to 10 wt%. Regrind above this level reduces the high-molecular-mass fraction and produces a measurable drop in slurry abrasion resistance and slow crack growth resistance. No fine mineral filler such as calcium carbonate or talc is added because hard filler increases the coefficient of sliding wear against coarse slurry particles. Carbon black masterbatch is fed at 2.0–2.5 wt% to prevent outdoor storage degradation, and no post-consumer recycled material is permitted. Finished product types include tailings transfer mains, dredge discharge lines, slurry header pipes, pump station flanged spools, and wear-resistant pipe with additional invert thickness for gravity flow sections.
Horizontal directional drilling places axial loads on the pipe string that are not present in open-trench service, and the allowable pullback stress is calculated under ASTM F1962 using bore path curvature, buoyant weight, drilling fluid density, and soil friction. HDPE 4100 (IPS) FM/4000 pressure pipe is selected for HDD when the pipe body must also meet AWWA C906 or ASTM F714 after installation. The resin’s yield strength and flexural modulus are used to determine the maximum safe pullback force, with a typical design safety factor not less than 2.0 against tensile yield of the fused pipe string.
Field construction begins with butt fusion of individual pipe sticks into a continuous string using ISO 21307 single-pressure low-pressure parameters. The heater plate temperature is held at 225 °C, and interfacial pressure is controlled at 0.15 MPa during the fusion sequence. Pullback speed is limited to 1–2 m/min to prevent stress concentrations at the fused joints and to allow drilling fluid returns to maintain borehole stability. During pullback, pipe surface temperature and pulling head force are logged continuously to detect overbending or excessive friction. Collapse pressure under groundwater is calculated as part of the ASTM F1962 sequence, and the selected wall thickness is verified against the buoyant empty-pipe condition.
Formulation for HDD service is deliberately conservative: clean in-house regrind is capped at 8 wt%, lower than open-trench potable water pipe, because HDD pullback imposes axial tensile stress and any low-molecular-weight region can initiate brittle fracture at a fusion bead. Carbon black content is maintained at 2.0–2.5 wt% for UV resistance during staging, and no post-consumer resin, reprocessed pipe from unknown service, or mineral filler is added. Terminal products are continuous fused pipe strings installed as river crossings, roadway undercrossings, wetland force mains, and gravity sewer crossings, supplied in 40 ft or 50 ft sticks that are joined in the field.
Landfill leachate collection and force main systems use the PE4710 resin where aqueous chemical resistance to volatile fatty acids, ammonia, chlorides, and trace organics is required. 40 CFR 258.40 requires collected leachate to be removed so that the head on the liner remains below 30 cm; the pipe material must maintain its pressure rating under the low-pH, high-organic-loading conditions of acidogenic leachate and the more neutral, ammonia-rich conditions of methanogenic-phase leachate. Compatibility is normally confirmed by EPA Method 9090 testing using site-specific leachate, rather than by generic chemical resistance tables. Leachate temperature is typically below 60 °C, and the resin’s long-term hydrostatic strength at that temperature must be applied to the pressure rating.
Leachate forcemains are extruded as DR 11 or DR 17 IPS pipe and are joined by butt fusion using ISO 21307 parameters. Electrofusion is used where access prevents butt fusion, and destruct testing of electrofusion couplers is performed under ISO 13954. The pipe is produced on a single-screw grooved-feed extruder with melt temperature between 200 °C and 230 °C, followed by vacuum calibration and ultrasonic thickness scanning. In dual-contained leachate systems, the inner and outer pipes are assembled with spacer clips, and the annulus is pressure-tested to verify leak detection capability.
Clean in-house regrind is allowed at up to 12 wt% for leachate forcemains under most state solid-waste regulations, because the failure mode is not governed primarily by tensile strength but by chemical compatibility and fusion integrity. Post-consumer reclaimed PE is excluded. Carbon black content is kept at 2.0–2.5 wt% to prevent UV degradation during surface staging before burial. Finished product types include leachate collection laterals, header pipes, force main spools, riser manhole connections, and dual-contained pipe for secondary containment at transfer stations.
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Chevron Phillips Chemical HDPE 4100 (IPS) FM / 4000 is a PE4710-class, carbon-black-stabilized high-density polyethylene compound supplied for the extrusion of iron pipe size pressure pipe. The grade is specified where a high long-term hydrostatic design stress is required in municipal water distribution, industrial process water, force mains, and Factory Mutual-approved underground fire-protection loops. Under ASTM D2837, PE4710 resins have a hydrostatic design basis of 1600 psi at 23°C; with the 0.63 water-service design factor, the resulting hydrostatic design stress is 1000 psi at 23°C. Extruded pipe is dimensioned to IPS outside diameters under ASTM D3035 and is joined predominantly by butt fusion under ASTM F2620.
Pressure rating is a function of dimension ratio, not wall thickness alone. For IPS pipe made from this PE4710 class, the nominal pressure rating at 23°C is calculated as P = 2 × 1000 psi / (DR − 1). This yields 200 psi for DR 11, 160 psi for DR 13.5, 125 psi for DR 17, and 100 psi for DR 21. These ratings apply to water service at 23°C; elevated temperatures and aggressive fluids lower the allowable design stress. The resin itself is not a finished pipe; the pressure rating is assigned by the pipe manufacturer after extrusion and cell-classification verification.
Representative physical properties for the PE4710 pipe-compound class are given below. The values are not specification limits; the supplier’s product bulletin and certificate of analysis govern for a specific lot.
| Property | Test method | Representative value |
|---|---|---|
| Density | ASTM D1505 | 0.949 g/cm³ |
| Melt index | ASTM D1238 at 190°C / 2.16 kg | 0.08 g/10 min |
| Tensile strength at yield | ASTM D638 | 23 MPa |
| Elongation at break | ASTM D638 | >800% |
| Flexural modulus | ASTM D790 | 1100 MPa |
| Carbon black content | ASTM D1603 | 2.2 wt% |
| Notched constant tensile load | ASTM F1473 at 2.4 MPa, 80°C | >1000 h |
| Vicat softening temperature | ASTM D1525 | 124°C |
| Brittleness temperature | ASTM D746 | < -75°C |
| Oxidative induction time | ASTM D3895 at 200°C | >20 min |
| Hydrostatic design basis | ASTM D2837 at 23°C | 1600 psi |
Pipe extrusion of the 4100 grade is normally carried out at melt temperatures between 200°C and 230°C. Barrel temperature profiles are typically set from 180°C in the feed zone to 220°C at the metering zone and die. A single-stage grooved-feed extruder with L/D between 24:1 and 30:1 and a compression ratio near 3:1 is common; screen packs of 20/40/60 mesh are used to raise back pressure and complete carbon black dispersion. Sustained melt temperatures above 260°C consume the stabilizer package and reduce oxidative induction time.
Oxidative induction time by ASTM D3895 at 200°C is typically above 20 min for virgin resin. After extrusion the value may be lower depending on residence time and melt temperature. Carbon black dispersion is a critical quality variable because agglomerates act as stress risers during slow crack growth. If the resin is stored under high humidity, surface moisture above 0.05% can produce splay or surface roughness; pre-drying at 80°C for 2 to 4 h in a desiccant dryer is recommended for suspect material.
The 0.08 g/10 min melt index reflects a high-molecular-weight, shear-thinning melt. This is required for sag resistance in large-diameter thick-wall pipe but demands high screw torque and substantial feed-zone cooling. Feed-zone temperatures above 70°C can reduce solids conveying and cause feed bridging in grooved-feed extruders; this is a recognized bottleneck on lines above 24 in outside diameter. Processors often reduce screw speed rather than raise melt temperature to achieve output.
Regrind addition up to 10% is typical on pipe lines, provided the regrind is dry and free of contaminants. Higher addition levels may reduce oxidative induction time below the pipe specification and should be validated by ASTM D3895 before use.
Field joining of extruded IPS pipe is normally performed by butt fusion with heater surface temperatures maintained between 204°C and 232°C per ASTM F2620. Socket fusion and electrofusion are used for smaller diameters and repair tie-ins; electrofusion joints are governed by ASTM F1290. Cold fusion from low heater temperature or insufficient bead-up pressure is a recognized failure initiator in buried service because it reduces slow-crack-growth resistance at the joint plane.
Slow crack growth resistance is the controlling failure mode in buried pressure pipe. The PE4710 classification requires high notched constant tensile load performance; typical production values exceed 1000 h at 2.4 MPa and 80°C under ASTM F1473. This test is more discriminating than single-point ESCR for predicting brittle crack propagation in field service.
The FM / 4000 designation identifies the product configuration supplied for Factory Mutual-listed underground fire-protection mains. Such installations are evaluated under FM 1613 for pipe and fitting listings and installed under NFPA 24 for private fire service mains. The listing imposes working-pressure limits derived from the pipe DR and may also require specific thrust restraint, cover depth, bedding, and tracer-wire provisions. Exposed indoor fire suppression piping is outside the intended use of this material.
For buried fire mains, hydraulic calculations must include static pressure, pump churn pressure, and surge. Occasional surge pressure should not exceed 1.5 to 2.0 times the static pressure rating, with the lower value applied where fatigue loading is uncertain. At 60°C, the PE4710 hydrostatic design stress is typically reduced to 500 psi; continuous service above this temperature is not recommended without additional long-term hydrostatic testing.
| Standard | Application |
|---|---|
| ASTM D3350 | Pipe-grade PE4710 cell classification |
| ASTM D2837 | Hydrostatic design basis at 23°C |
| ASTM D3035 | OD-controlled IPS pressure pipe dimensions |
| ANSI/AWWA C906 | Polyethylene pressure pipe and fittings for water service |
| NSF/ANSI 61 | Potable water contact |
| NSF/ANSI 14 | Plastic piping system components |
| FM 1613 | Underground fire service plastic pipe listing |
| NFPA 24 | Private fire service main installation |
Relative to PE3408 and PE3608, the 4100 grade increases the 23°C hydrostatic design stress from 800 psi to 1000 psi, a 25% increase. This allows higher operating pressure at equivalent DR or a reduced wall thickness at equal pressure. The improvement is attributed to bimodal molecular weight distribution and comonomer placement, which raises slow crack growth resistance as measured by ASTM F1473. Compared with ISO PE100 materials, PE4710 is broadly equivalent in long-term hydrostatic strength, but North American IPS dimensions and listing requirements differ from ISO metric pipe series. Pressure ratings should not be interchanged without recalculation.
Chemical resistance should be confirmed for the specific fluid using PPI TR-19 or equivalent. Strong oxidizing acids, chlorinated solvents, aromatic hydrocarbons, and hydrocarbon fuels can reduce long-term strength by accelerating oxidative or environmental stress cracking. The material is not recommended for service above 60°C or for aboveground fire-protection distribution piping inside buildings.
In buried pressure service, installation must use approved bedding and compaction. Unstable trenches, sharp rock, or inadequate side support can impose localized bending strains that exceed the long-term flexural capacity and initiate slow crack growth; AWWA M55 and the pipe manufacturer’s installation guide govern.