| HS Code | 877619 |
| Product Name | Chevron Phillips 7109DT LLDPE Blown Film Resin, Hexene Copolymer |
| Polymer Type | Linear Low Density Polyethylene (LLDPE) |
| Comonomer | Hexene-1 |
| Density | 0.918 g/cm³ |
| Melt Index 190 C 2 16 Kg | 0.7 g/10 min |
| Melting Point | 124 °C |
| Vicat Softening Point | 100 °C |
| Brittleness Temperature | -70 °C |
| Tensile Strength At Yield Md | 1400 psi |
| Tensile Strength At Break Md | 5000 psi |
| Tensile Strength At Break Td | 4500 psi |
| Elongation At Break Md | 600% |
| Elongation At Break Td | 700% |
| 1 Secant Modulus Md | 25000 psi |
| 1 Secant Modulus Td | 30000 psi |
| Elmendorf Tear Strength Md | 200 g |
| Elmendorf Tear Strength Td | 400 g |
| Dart Drop Impact F50 | 200 g |
| Haze | 12% |
| Gloss 45 | 60 |
| Coefficient Of Friction | 0.2 |
As an accredited Chevron Phillips 7109DT LLDPE Blown Film Resin, Hexene Copolymer factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.
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Primary-contact food packaging lines running Chevron Phillips 7109DT as a hexene-copolymer LLDPE typically operate monolayer blown-film extruders with 24:1–30:1 L/D barrier screws, a 1.5–2.5 mm die gap, and a melt temperature of 190–215 °C. The bubble is inflated at a blow-up ratio of 2.2–3.0 and collapsed through a Teflon nip with gauge variation held to ±5%; in-line corona treatment to 38–42 mN/m is specified before flexographic or rotogravure printing. The use of hexene comonomer rather than butene in the LLDPE backbone raises dart impact and Elmendorf tear when measured under ASTM D1709 and ASTM D1922, which permits downgauging of frozen food films without increasing puncture failures in vertical form-fill-seal machines. Incoming resin lots are checked for melt flow rate under ASTM D1238-20 at 190 °C/2.16 kg and density under ASTM D792-20 before release to extrusion.
For food-contact formulations, a representative blend is 65–85 wt% 7109DT with 15–35 wt% LDPE for bubble stability and melt strength, 2–4 wt% silica antiblock masterbatch, and 500–1000 ppm erucamide slip. The compounded film falls under FDA 21 CFR 177.1520(c) and EU Regulation (EU) No 10/2011, including the Annex V overall migration limit of 10 mg/dm². Terminal products manufactured from this configuration include pillow pouches for dry snacks, frozen food bags for IQF vegetables, bakery film for machine-twist closure, and light produce bags for loose leafy greens. The resin should not be specified for retort pouches or ovenable trays beyond 100 °C without separate migration and organoleptic testing.
Pinhole formation in heavy-duty industrial sacks is driven primarily by slow puncture under mass load and repeated flexing, not by tensile yield. Film converted from 7109DT at 100–180 µm is tested to ISO 7765-1:1988, ASTM D1709-15e1, ASTM D1922-09, and ASTM D882-18 before bag conversion. On a 90 mm grooved-feed extruder with 30:1 L/D, production-scale runs typically use a 2.5–3.0 mm die gap, a blow-up ratio of 3.5–4.5, internal bubble cooling, and a frost line height held at 25–40 cm. Bubble instability appears at high output when the collapse-frame approach angle drops below 20° or when the frost line is allowed to move more than ±5 cm, producing MD gauge bands and reduced dart impact at the edges. Melt temperature above 240 °C increases oxidative gel formation and must be avoided during extended stops.
Formulation for non-food heavy-duty sacks is commonly 100 wt% 7109DT for maximum puncture resistance, or 75–85 wt% with 15–25 wt% in-line edge trim regrind when bubble stability and die lines remain within specification. Black UV masterbatch is added at 2–4 wt% if the sacks are stored outdoors. For UN-certified dangerous goods sacks, the resin does not provide certification by itself; the converted sack must undergo the drop and stacking tests of the applicable packaging instruction and be marked with the UN specification code. Terminal types include liner bags inside woven polypropylene FIBCs, self-supporting rubble sacks for construction waste, and powder discharge liners for cement and mineral fillers.
In silage pit covers and greenhouse tunnel films, 7109DT is processed as the core or skin layer of 3-layer blown-film coextrusion lines with die diameters of 200–300 mm and layer ratios of 30/40/30 or 20/60/20. The die gap is typically 2.0–2.4 mm, the blow-up ratio 2.8–3.5, and the melt temperature 200–220 °C. Gauge control at ±6% is required for uniform UV additive distribution and to prevent early photodegradation at thin spots. The structure is collapsed, edge-slit, and wound on surface-center winders; anti-drip or antifog concentrates are dosed into the core layer only to limit bloom on the film surface. Field failures on agricultural lines are most often traced to uneven UV masterbatch distribution rather than base-resin mechanical loss.
Representative agricultural formulation: 60–75 wt% 7109DT, 15–25 wt% LDPE, 5–15 wt% EVA with 9–18% vinyl acetate, plus 0.2–0.8 wt% HALS, 0.1–0.3 wt% UV absorber, and 1–2 wt% anti-drip masterbatch. Compliance is assessed under EN 13206:2017 for agricultural covering films and, where relevant, the film must meet the national disposal and marking requirements under the EU Packaging and Packaging Waste Directive 94/62/EC. Finished articles include silage pit covers, greenhouse tunnel covers, low tunnels, and single-season mulching films. The resin without UV stabilization is not weatherable; outdoor service life cannot be predicted without accelerated weathering data referenced to ISO 4892-2 or EN 13206 exposure conditions.
The three-layer coextrusion route for opaque e-commerce mailers uses a core of post-consumer LLDPE recyclate between skins of 7109DT to preserve tear and seal performance while increasing recycled content. The layer ratio is commonly 20/60/20 with a total thickness of 50–80 µm; die gap is 2.0 mm, blow-up ratio 2.5–3.2, melt temperature 195–215 °C, and continuous screen changers with 150–250 µm screens protect the die from recyclate contaminants. Edge trim is re-pelletized in-line and returned to the core layer at up to 10–15 wt% without measured loss in machine-direction Elmendorf tear under ASTM D1922. Production bottlenecks include screen-pack plugging when post-consumer recyclate contains paper labels and melt fracture at the die lips when extruder barrel temperatures drop below 180 °C.
Representative formulation: 55–70 wt% 7109DT in the skin-plus-core matrix, 20–30 wt% post-consumer LLDPE recyclate, 10–15 wt% LDPE for bubble stability, and 3–5 wt% carbon black masterbatch. Because this application is non-food, regulatory compliance focuses on REACH Regulation (EC) No 1907/2006 and the EU Packaging and Packaging Waste Directive 94/62/EC, with heavy metals limits evaluated under 94/62/EC Article 11. Terminal products include opaque courier mailing bags, garment polybags, and protective void-fill pillow films. Incorporation of recyclate above 30 wt% may raise gel count and gauge variation; bubble cooling demand increases as melt strength drops.
At 25–50 µm, lamination sealant webs blown from 7109DT are specified for adhesive-laminated pouch structures where the sealant layer must deliver low seal initiation temperature, high puncture resistance, and acceptable clarity after lamination. The film is produced as a monolayer or coextruded web on a blown-film line with a die gap of 1.5–2.0 mm, blow-up ratio 2.0–2.8, melt temperature 190–210 °C, and corona treatment to 38–42 mN/m in line. It is then solventlessly laminated to BOPET, metallized PET, or aluminum foil at an adhesive coating weight of 2.0–3.5 g/m²; the laminate is cured at 40–50 °C for 24–48 h before slitting. Seal-strength testing is performed under ASTM F88/F88M-21, and the laminate is conditioned at 23 °C and 50% RH for at least 40 h before heat-seal measurement.
Formulation of the sealant web is 100 wt% 7109DT with 2–3 wt% antiblock masterbatch and 500–1000 ppm slip; for higher hot-tack requirements the addition of 10–20 wt% LDPE can lower seal initiation temperature but may reduce dart impact under ASTM D1709. Food-contact compliance is obtained under FDA 21 CFR 177.1520(c) and EU Regulation (EU) No 10/2011; the finished laminate must also account for the adhesive under FDA 21 CFR 175.105 or 21 CFR 175.300 if indirect contact is claimed. Terminal products include stand-up pouches for dry granular foods, frozen seafood pouches, and non-liquid sachets. The structure is not specified for retort or hot-fill above 95 °C because seal strength and laminate bond retention under thermal load require separate validation.
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