| HS Code | 598058 |
| Density | 0.930 g/cm³ |
| Water Absorption | 0.010% |
| Linear Mold Shrinkage | 0.020 cm/cm |
| Tensile Strength Yield | 17.0 MPa |
| Tensile Strength Ultimate | 20.0 MPa |
| Elongation At Break | 300% |
| Tensile Modulus | 0.700 GPa |
| Flexural Modulus | 0.800 GPa |
| Izod Impact Notched | 10.0 J/cm |
| Coefficient Of Friction | 0.15 |
| Thermal Conductivity | 0.410 W/m·K |
| Melting Point | 135 °C |
| Maximum Service Temperature Air | 80.0 °C |
| Electrical Resistivity | 1.00×10^15 Ω·cm |
| Dielectric Strength | 45.0 kV/mm |
| Dielectric Constant | 2.30 |
| Dissipation Factor | 0.00030 |
| Comparative Tracking Index | 600 V |
| Limiting Oxygen Index | 20.0% |
| Hardness Shore D | 60 |
As an accredited Celanese UHMW-PE 4530 CR factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.
| Packing | Celanese UHMW-PE 4530 CR is typically packaged in 25 kg multiwall paper bags with PE liner, 40 bags per pallet (1,000 kg). |
| Container Loading (20′ FCL) | Celanese UHMW-PE 4530 CR loads in a standard 20-foot FCL dry container, typically 25 kg bags on pallets, secured for transport. |
| Shipping | Celanese UHMW-PE 4530 CR is shipped as a non-hazardous solid polymer. It is not regulated as dangerous goods by DOT, IMDG, IATA, or ADR; no UN number, hazard class, or packing group is assigned. Transport in sealed moisture-barrier bags or drums, protected from heat, moisture, and contamination. |
| Storage | Store Celanese UHMW-PE 4530 CR in a cool, dry, well-ventilated area. Keep original containers sealed, upright, and protected from direct sunlight, heat, moisture, dust, and ignition sources. Avoid contact with strong oxidizing agents. Prevent contamination, use appropriate PPE, and follow local regulations. Keep away from food, feed, and drinking water. Ensure good housekeeping and dust control. Store at ambient temperature. |
| Shelf Life | Typically 24 months from date of manufacture when stored in original unopened packaging under cool, dry, dark conditions. |
In high-speed glass container conveying lines operating at 18,000–24,000 containers per hour, wear strips and chain guides cut from Celanese UHMW-PE 4530 CR transfer gravity and redirect forces from stainless steel chain into PET bottle sidewall contact zones. The grade is supplied as a controlled powder with no measurable melt flow rate under ISO 1133-1:2022 Procedure A. Powder is consolidated in a reciprocating ram extruder equipped with a heated die zone at 190–225 °C and a die land length to thickness ratio of 12:1 to 15:1. Ram hydraulic pressure is held at 10–15 MPa to eliminate interparticle porosity. The extruded profile exits at 0.2–0.8 m/min and is cooled by forced air before cutting. The compound is 100 phr unfilled 4530 CR. External lubricant addition is limited to 0.05–0.2 phr calcium stearate when powder feed bridging is observed in the hopper. Higher additions reduce interparticle sintering and create weld line porosity in sections thicker than 15 mm. The finished wear strip is machined on a CNC router with carbide tooling at 800–1,200 m/min surface speed. End components include T-slot wear strips, chain guide rails, and star wheel inserts. For unpigmented articles used as indirect food contact components, raw resin compliance is checked under FDA 21 CFR 177.1520 and EU 10/2011 Annex I with an overall migration limit of 10 mg/dm². Continuous service under load is restricted to 60 °C. Hot-fill lines above this temperature experience creep and loss of interference fit in dovetail grooves. Avoid contact with concentrated nitric acid above 50 °C. The fabricator must verify final article compliance because machining oils and guide lubricants can influence migration results.
The failure mode in bauxite and coal chute liners is not abrasive wear alone but plug-flow impact fatigue along the backing plane. A 30–50 mm sheet of 4530 CR is compression moulded in a hydraulic press with a platen force of 1,200–2,000 t. Powder is pre-dried at 80 °C for 2–4 h when ambient RH exceeds 60 %. The mould is charged, cold-pressed at 5–7 MPa to expel air, then heated to 210–220 °C. Specific pressure during sintering is maintained at 10–14 MPa. Hold time at melting temperature is extended until the core reaches 200 °C. The cooling cycle must be interrupted at 118–122 °C for 20–30 min to equalize crystallinity through the thickness. Uninterrupted cooling at the surface produces a dense skin of higher density and a low-crystallinity core. Subsequent drilling of bolt holes exposes internal stress as circumferential cracking. The sheet is demoulded below 45 °C. Formulation remains 100 phr unfilled. Carbon black masterbatch is used at 1.5–2.5 wt% only for outdoor installations. The end product is cut into hopper liners, impact panels, and skirt board seals. Compliance is specified under ASTM D4020 for UHMW-PE moulding and extrusion materials, with density checked under ASTM D792 and Shore D hardness under ISO 868. Do not specify this grade for continuous immersion in aromatic hydrocarbon streams. Swelling exceeds 1 % and mechanical retention drops in the clamped area. Published data for long-term wear in high-velocity silica slurries above 70 °C is limited.
| Sheet thickness | Press platen set point | Specific pressure | Hold time at peak temperature | Cooling rate | Demoulding temperature |
|---|---|---|---|---|---|
| 10 mm | 200–210 °C | 8–10 MPa | 10–14 min | 3–4 K/min | 60 °C |
| 20 mm | 205–215 °C | 10–12 MPa | 18–25 min | 2–3 K/min | 50 °C |
| 30 mm | 210–220 °C | 12–14 MPa | 30–40 min | 1–2 K/min | 45 °C |
| 50 mm | 215–220 °C | 12–14 MPa | 45–60 min | 0.5–1 K/min | 40 °C |
Zinc refinery filter press operations expose plate edges to feed pressures of 0.6–1.0 MPa and abrasive solids loadings up to 200 g/L. 4530 CR plates are machined from compression moulded block rather than injection moulded. The block is uniform because the powder is consolidated under vacuum-assisted press cycles at 210–220 °C and 10–12 MPa. A 60 mm block is held at peak temperature for 50–70 min to eliminate non-sintered powder veins. CNC milling of recessed drainage surfaces uses solid carbide end mills at 300–600 m/min cutting speed and low feed per tooth below 0.1 mm to avoid melting at the cut surface. The plate is inspected for internal voids by ultrasonic A-scan at 5 MHz. The polymer formulation is 100 phr 4530 CR. No plasticizer is used. Plate sealing surfaces must be machined flat to 0.3 mm/m. End use includes filter press plates, frames, and sludge dewatering plates. Compliance for industrial use is based on REACH registration and ASTM D4020. Maximum continuous operating temperature is 80 °C in aqueous service. At pH below 1 or above 12, the plate should be inspected at 500 h intervals for surface degradation. Avoid combination with strong oxidizing acids at temperatures above 50 °C because oxidative embrittlement occurs at bolt holes.
In wet-process lithium-ion battery separator manufacture, 4530 CR is mixed with mineral oil to form a paste-like gel. The first limit is the oil absorption capacity of the powder. Above 68 wt% the gel loses self-support during casting. Mixing is carried out in a twin-screw kneader at 150–180 °C under nitrogen. The gel is cast through a slot die onto a chill roll at 40–60 °C. Cast thickness ranges from 200 µm to 400 µm. The sheet is biaxially stretched in a two-stage tentering unit. Machine-direction draw ratio of 3–5 and transverse draw ratio of 3–5 create lamellar separation and micropore formation. Paraffinic oil is extracted with n-hexane or methylene chloride in a countercurrent extractor. The final separator thickness after extraction is 7–22 µm. The polymer fraction is 25–35 wt%. The remainder is paraffinic oil. No antioxidant is added in the casting formulation because residue affects electrolyte wetting. End product is a microporous polyolefin separator for lithium-ion cells. Compliance is assessed under REACH for solvent residues and RoHS Recast 2011/65/EU for electrical and electronic equipment. The process is sensitive to powder fines. A D50 below 100 µm improves gel homogeneity but increases dust explosion risk during charging. Published data for pore size distribution of 4530 CR in this configuration is limited. Separator trials require lot-by-lot dewetting tension and Gurley value verification.
| 4530 CR mass fraction | Paraffinic oil mass fraction | Cast gel thickness | Biaxial stretch ratio | Final separator thickness |
|---|---|---|---|---|
| 0.25 | 0.75 | 300 µm | 5 × 5 | 12 µm |
| 0.30 | 0.70 | 250 µm | 4 × 4 | 16 µm |
| 0.35 | 0.65 | 200 µm | 3 × 3 | 22 µm |
Bauxite slurry transfer pumps impose a combination of sliding abrasion and cavitation at the suction side. 4530 CR is compression moulded into 40 mm thick blocks and CNC-machined into wear rings, valve seats, and small impeller shims. The blank is moulded at 210–220 °C under 12–14 MPa. Machining uses carbide or polycrystalline diamond tooling with water-based coolant to prevent thermal expansion. The component is installed in a pump casing with interference fit of 0.2–0.4 % of diameter. Formulation is 100 phr unfilled. Filled variants with 5–10 wt% carbon fibre are not used because fibre orientation in machined parts causes anisotropic wear. The end product operates in slurries up to 200 g/L solids and 50 °C. Continuous use in caustic alumina liquor above 80 °C is outside the operational boundary. The part must not be exposed to aromatic process solvents during cleaning. Swelling destroys dimensional fit. Compliance is checked under ASTM D4020 for material specification and ISO 868 for hardness retention after 500 h immersion. Abrasion resistance is referenced to ASTM G65 Procedure A. Typical unfilled UHMW-PE homopolymer volume loss is below 0.1 mm³/min under dry sand/rubber wheel conditions, but direct lot values must be confirmed against the specific slurry. Published data for 4530 CR in cavitating pump suction conditions is limited.
Under sub-arctic berthing loads, marine fender face pads are compression moulded from 4530 CR as 50–100 mm thick panels with holes for corrosion-resistant fasteners. The powder is compounded with 1.5–2.5 wt% carbon black masterbatch for UV protection. The mould is charged and processed at 210–220 °C with specific pressure of 10–14 MPa. Holding time is extended to 60–90 min for 100 mm thickness. Cooling is controlled at 0.5–1 K/min to prevent warpage. The panel is machined flat to 0.5 mm/m. The end product is a low-friction face pad attached to steel fender panels at port berths. The coefficient of friction against wet stainless steel is below 0.20 under ASTM D1894. The service temperature window is from -50 °C to 60 °C. Embrittlement is not observed at -50 °C, but impact values decline with thickness. Compliance for port equipment is based on ASTM D4020 and ISO 868. The pad must not be exposed to hydrocarbon-based drilling mud or hydraulic oil on a repeated basis. Absorbed oil increases friction and eliminates the benefit of the surface. Fastener torque must be below 25 N·m for M12 bolts to avoid compressive yield at the hole edge. Published data for wave-frequency fatigue at -50 °C is limited.
Dough scraper blades in automated bakery lines operate against steel conveyor belts at line speeds up to 30 m/min. 4530 CR is machined from compression moulded sheet at 8–12 mm thickness. The edge is cut with a single-flute router at 800–1,000 m/min surface speed to avoid burr formation. The formulation is 100 phr unpigmented 4530 CR. No colourant is used because the part is in direct food contact. Edge retention is limited by abrasive contact with dough particulate and belt seam impact. The component is replaced when edge radius exceeds 0.5 mm. The sheet is annealed at 110 °C for 2 h after machining to reduce residual stress. Direct food contact compliance is validated under FDA 21 CFR 177.1520 and EU 10/2011 Annex I with overall migration below 10 mg/dm². The component is not suitable for oven temperatures above 80 °C. Cleaning with sodium hypochlorite solutions at 0.5 % active chlorine is acceptable for 15 min cycles. Repeated autoclaving is not permitted. Avoid formulation with external processing aids because the final article must demonstrate no organoleptic transfer in fatty food simulants. Published data for 4530 CR blade edge wear in high-speed dough sheeting is limited.
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Celanese UHMW-PE 4530 CR is a controlled-rheology grade of ultrahigh-molecular-weight polyethylene supplied as a free-flowing powder for ram extrusion and compression molding of thick-walled profiles, rod, slab, and machined parts. The controlled-rheology designation is not a general-purpose melt-flow modification but a powder morphology and molecular architecture adjustment directed at discontinuous melt consolidation. In practice, this means the grade is specified where die swell, axial ovality, internal voiding, and post-machining distortion are more critical than maximum molecular weight or maximum abrasion index. The material does not have a conventional melt flow index under ISO 1133-1:2022; UHMW-PE grades are characterized by dilute solution viscosity instead. Batch release documentation normally records sieve retention, bulk density by ISO 60, residual moisture, and viscosity number by ISO 1628-3:2010, with exact lot windows varying by production site. Published data for the precise viscosity window of Celanese UHMW-PE 4530 CR is limited; the product family typically falls above 2000 mL/g when measured in decalin at 135 °C.
Ultrahigh-molecular-weight polyethylene grades are not processed by twin-screw plasticizing extrusion because the extremely high entangled network prevents stable starve-fed transport. Celanese UHMW-PE 4530 CR is therefore directed to ram extruders with hydraulic piston drives, heated die blocks, and downstream controlled cooling zones. The product can also be compression molded as stock shapes. The controlled-rheology package differs from standard ram-extrusion grades such as GUR 4120 and GUR 4130 in that it is adjusted to reduce elastic memory after the die exit while maintaining a densified melt front under intermittent piston return. The result is lower reject rates for internal cold beads and surface roughness in rod diameters above 40 mm, although published production-line data for this specific configuration is limited.
Ram extrusion of UHMW-PE 4530 CR is pressure-limited rather than shear-rate-limited. Barrel compaction pressures are commonly maintained between 20 MPa and 40 MPa, while die block temperatures are typically set from 180 °C to 220 °C. Forward stroke speed is normally reduced as section thickness increases; for rod diameters from 50 mm to 200 mm, production speed frequently ranges from 0.5 mm/s to 2.0 mm/s. If the die pressure signature shows repeated high-frequency spikes above 5 MPa, the practical interpretation is incomplete powder consolidation or an obstruction at the die entry. This can produce axial weld lines, surface drag marks, or laminar delamination after machining.
Because the material is not processed by a screw, residence time distribution is determined primarily by piston dwell time and die length. Die land length is typically selected at 4 to 8 times the final profile diameter to provide sufficient backpressure for densification. Cooling after the die should be staged; quench cooling can create a frozen skin while the core remains above the crystalline melting range, producing residual tensile stress at the center. A controlled-rheology grade such as 4530 CR is specifically relevant in this heat-transfer-limited region because its lower elastic recovery reduces the tendency for core tearing during post-extrusion crystallization.
Pre-drying is generally not required when ambient relative humidity is below 60 %. At higher humidity, a desiccant dryer at 70 °C for 2 h to 4 h reduces the likelihood of steam-induced microporosity. The powder should not be blended with amine-based processing aids or flame-retardant additives that generate acidic decomposition products, as these accelerate chain scission at extended processing temperatures.
| Property | Test method | Unit | Representative controlled-rheology UHMW-PE family range |
|---|---|---|---|
| Density | ISO 1183-1 | g/cm³ | 0.93–0.94 |
| Tensile yield stress | ISO 527-2 | MPa | 20–23 |
| Elongation at break | ISO 527-2 | % | 300–450 |
| Charpy notched impact | ISO 11542-2 | — | no break |
| Shore D hardness | ISO 868 | — | 60–66 |
| Vicat softening temperature | ISO 306/A50 | °C | 78–84 |
| Average molecular weight by dilute solution viscosity | ISO 1628-3:2010 | g/mol | 4.5 × 10⁶–6.0 × 10⁶ |
The table values are representative of controlled-rheology UHMW-PE product families and are not to be used as commercial specification limits. Lot-release values for Celanese UHMW-PE 4530 CR are based on the certificate of analysis and may be tighter or broader depending on the production campaign. The tensile and impact figures assume compression-molded plaques prepared according to ISO 11542-2. Machined stock shapes may show direction-dependent differences because of chain orientation developed during ram extrusion.
Compression molding of UHMW-PE 4530 CR is normally carried out at 180 °C to 220 °C under press pressures of 10 MPa to 20 MPa. Heating rate is less important than pressure history during the melt densification stage. The powder must be allowed to fully compact before the final mold closure; otherwise, trapped air creates interfacial porosity that is not visible on the surface but appears as pitting after machining. Hold time is typically scaled to thickness, with press cycles commonly requiring 15 min to 30 min per 10 mm of final sheet thickness. Cooling should be controlled at a rate below 10 K/min through the crystallization region to minimize internal stress. If the press is opened too early, parts above 50 mm thickness can exhibit post-demolding warpage.
After demolding, dimensional stability is improved by stress-relief annealing. A typical cycle is 100 °C for 2 h per 25 mm of cross-section, followed by slow cooling inside the annealing chamber. Annealed stock shapes of UHMW-PE 4530 CR are used where post-machining flatness or runout is specified to within 0.1 mm per 100 mm. Compared with general-purpose grades, the controlled-rheology variant is reported to require less intermediate annealing for thick machined components, but published data for this specific configuration is limited.
Hot-plate welding is technically possible but results in joint strengths below parent material. Welding at surface temperatures of 200 °C to 230 °C commonly produces tensile strengths of 50 % to 70 % of the base material, depending on pressure and alignment. Adhesive bonding is not recommended unless the surface is first activated by corona, plasma, or chemical etching. The grade should not be used as a structural load-bearing member in applications requiring high tensile creep resistance at temperatures above 80 °C.
Food-contact use of Celanese UHMW-PE 4530 CR must be confirmed against the applicable regulatory status of the specific additive package and the final article geometry. The base olefin polymer can be evaluated under FDA 21 CFR 177.1520 and EU Regulation No 10/2011, Annex I. Conformity is not automatic for all articles; overall migration testing must be completed on the finished component, including any machining lubricants, cleaning residues, or post-process surface treatments. In wet food-processing environments, the surfaces of ram-extruded or compression-molded parts should be finish-machined to a surface roughness of Ra 0.8 μm or lower to reduce debris retention and biofilm adhesion. The material is not intended for hot-fill applications above 80 °C or for repeated steam sterilization above 110 °C, because dimensional change accelerates near the Vicat softening range.
| Standard or regulation | Scope | Relevance to UHMW-PE 4530 CR |
|---|---|---|
| ISO 11542-2 | Moulding and extrusion materials | Specimen preparation and property determination for PE-UHMW |
| ISO 1628-3:2010 | Viscosity number of polyethylene | Melt-flow-independent molecular characterization |
| FDA 21 CFR 177.1520 | Olefin polymers for food contact | Compliance evaluation for final food-contact articles |
| EU 10/2011, Annex I | Plastic food-contact materials | Overall migration and specific migration limits |
| REACH 1907/2006 | EU chemical safety | Substance registration and restriction screening |
| RoHS 2011/65/EU, Annex II | Restricted substances | Lead, cadmium, mercury, and hexavalent chromium limits |
Industrial applications for this grade are concentrated in material-handling, packaging-machinery, water-treatment, and food-processing wear components. Typical parts include chain guides, wear strips, star wheels, conveyor rails, hopper liners, scraper blades, and low-speed bearing housings that run against stainless steel or polymer counterfaces. The controlled-rheology characteristic is most valuable when the part has a thick cross-section above 40 mm and must retain flatness or roundness after final machining. In sliding-contact service, UHMW-PE exhibits low coefficient of friction and low moisture absorption, but the design must account for thermal expansion and creep under continuous load. The material is not recommended for exposure to concentrated nitric acid above 20 wt%, strong oxidizing environments at elevated temperatures, or continuous operation above 80 °C under high load.