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Celanese UHMW-PE 4170 ECO-B

    • Product Name: Celanese UHMW-PE 4170 ECO-B
    • Factroy Site: Yudu County, Ganzhou, Jiangxi, China
    • Price Inquiry: admin@ascent-chem.com
    • Manufacturer: Ascent Petrochem Holdings Co., Limited
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    Specifications
    HS Code 401067
    Product Name Celanese UHMW-PE 4170 ECO-B
    Chemical Type Ultra-high molecular weight polyethylene (UHMW-PE)
    Density 0.930 g/cm³
    Molecular Weight 10.5 million g/mol
    Bulk Density 0.45 g/cm³
    Average Particle Size 150 µm
    Melting Point 135 °C
    Crystallinity 45-50%
    Thermal Conductivity 0.42 W/m·K
    Water Absorption <0.01%
    Tensile Modulus 680 MPa
    Elongation At Break >300%
    Notched Izod Impact Strength No break
    Coefficient Of Friction 0.1-0.2
    Shore D Hardness 60-65
    Chemical Resistance Excellent
    Bio Based Carbon Content 100%

    As an accredited Celanese UHMW-PE 4170 ECO-B factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing Celanese UHMW-PE 4170 ECO-B is packaged in 25 kg polyethylene-lined paper bags, 40 bags per pallet, totaling 1,000 kg.
    Container Loading (20′ FCL) Celanese UHMW-PE 4170 ECO-B 20′ FCL: 25 kg bags, 40 bags/pallet, 10 pallets, shrink-wrapped and strapped; approximately 10 MT net.
    Shipping Celanese UHMW-PE 4170 ECO-B is typically non-hazardous, not classified as dangerous goods for DOT, IATA, IMDG, or ADR. Ship as general cargo in original sealed bags or containers. Keep dry, clean, and away from heat or incompatible materials. Follow standard handling and local transport rules.
    Storage Store Celanese UHMW-PE 4170 ECO-B in a cool, dry, well-ventilated area away from direct sunlight, heat, sparks, and open flames. Keep containers tightly closed to prevent moisture and contamination. Avoid dust generation; use grounding/bonding where fine powder is handled. Keep separate from strong oxidizers. Protect from UV and follow local regulations and supplier recommendations.
    Shelf Life Shelf life is typically two years when stored in original, unopened packaging under dry, cool conditions away from direct sunlight.
    Application of Celanese UHMW-PE 4170 ECO-B

    Lithium-ion battery separator film production with Celanese UHMW-PE 4170 ECO-B is centred on the wet-process gel extrusion route. The powder is preheated to 80±5 °C under dry air to reduce moisture below 50 ppm before blending with a high-boiling paraffinic process oil at 60–80 wt% relative to total compound. The antioxidant package is maintained below 0.1 wt% because polar stabilizers alter gel-phase surface tension and pore uniformity. Processing is conducted in a co-rotating twin-screw extruder with L/D between 30:1 and 48:1, barrel zone temperatures of 220–240 °C, screw speed of 35–50 rpm, and head pressure held below 18 MPa to avoid gel-phase separation and melt fracture. The die-lip melt temperature must remain within ±5 °C because excursions above 245 °C initiate thermo-oxidative chain scission that reduces molecular weight and pin size uniformity. The gel sheet is cast through a coat-hanger die with lip gap of 0.4–1.2 mm onto a chilled roll maintained at 20–45 °C, yielding a cast film thickness of 200–900 µm before solvent extraction. The process oil is removed with methylene chloride or n-hexane in closed-loop extraction baths, followed by biaxial stretching at 6×6 to 9×9 ratios at 100–120 °C. The terminal product is a microporous membrane with thermal shutdown capability in lithium-ion cells; the shutdown range of 125–135 °C corresponds to the polyethylene melting endotherm measured by ASTM D3418. Production-scale rolls are inspected by inline dielectric pinhole detection and dimensional profiling with laser calipers. The separator is then slit to widths of 10–120 mm and tension-controlled to 0.1–0.3 N per slit edge during winding. Published data for the ECO-B designation under this exact separator route is limited; the following acceptance band is drawn from industrial UHMW-PE separator specifications rather than from a resin-specific datasheet.

    CharacteristicTest methodTypical acceptance band
    ThicknessISO 45935–25 µm
    Gurley air resistanceTAPPI T460100–400 s/100 cm³
    PorosityASTM D287335–50 %
    Tensile strength MDASTM D882100–160 MPa
    Elongation at break MDASTM D88250–150 %
    Shutdown temperatureASTM D3418125–135 °C

    For the wet-process separator route, the main operational boundary is the gel-phase viscosity window. Below 60 wt% oil loading the extruder torque rises beyond stable drive limits, while above 80 wt% oil loading the cast film loses green strength and develops edge cracks during extraction. The solvent recovery loop must maintain residual oil below 0.5 wt% in the extracted membrane because residual paraffin reduces shutdown response rate and creates combustible off-gas during cell formation. The final separator roll is also tested for pin-through force and film flatness; edge curl above 0.5 mm over 1 m length is rejected for cell winding.

    Tribological stability in dry-running scraper blades under 21 CFR 177.1520 clearance

    Food-contact scraper blades machined from compression-moulded sheet of Celanese UHMW-PE 4170 ECO-B operate against moving stainless steel conveyor belts at 0.5–1.2 m/s and contact pressures below 0.2 MPa. The feedstock is consolidated without plasticizers or external lubricants; clean post-industrial regrind is limited to 20 wt% because higher recycled fractions increase surface pitting and reduce wear consistency. Moulding uses a hydraulic press with platen temperature of 200–215 °C, pressure of 10–20 MPa, and soak time of 20–25 min per 25 mm of sheet thickness, followed by cooling at 5–10 °C/h under 0.5 MPa to prevent internal voids and warpage. After CNC machining, blade edges are dressed with carbide tools at surface speeds below 300 m/min; frictional heating above 145 °C melts the cut path and closes tolerance below ±0.1 mm. The resulting parts comply with 21 CFR 177.1520 for olefin polymers and EU 10/2011 with overall migration below 10 mg/dm². Physical acceptance testing follows ISO 868 for Shore D hardness 60–70 and ISO 178 for flexural modulus 0.7–1.0 GPa. The dry coefficient of friction against polished stainless steel is 0.08–0.12 at 0.5 m/s; this value remains stable only when counterface roughness Ra is kept between 0.2 µm and 0.8 µm. Continuous service above 60 °C produces measurable creep in unfilled sheet, and repeated steam sterilization above 121 °C causes stress-relaxation-driven dimensional shift. Oxidation sanitizers based on sodium hypochlorite above 5 wt% active chlorine initiate surface carbonyl formation and reduce impact strength. The terminal products include bakery dough scrapers, bottle conveyor guide rails, and star-wheel transfer plates.

    In orthopaedic bearing manufacture, gamma sterilization dose mapping between 25 kGy and 40 kGy determines the wear resistance of Celanese UHMW-PE 4170 ECO-B components. Doses below 25 kGy leave insufficient crosslink density, while doses above 40 kGy promote free-radical oxidation in amorphous tie-chain regions. Consolidation is performed by compression moulding at 210–235 °C and 10–15 MPa under vacuum of −0.09 MPa in moulds meeting ISO 5834-1; the material is not injection moulded because high molecular weight prevents stable melt flow. Vitamin E at 0.10–0.30 wt% may be premixed before consolidation to scavenge residual free radicals; calcium stearate is limited to <0.05 wt% to avoid calcium-rich inclusions that act as oxidation initiation sites after irradiation. The moulded block is sectioned into test specimens per ASTM F648 and annealed in nitrogen at 130–140 °C for 48–72 h. After machining, gamma irradiation at 30±2 kGy in inert atmosphere increases crosslink density and reduces wear volume in linear-tracking pin-on-disc tests. The final devices are tested for tensile yield stress 21–23 MPa per ASTM D638 Type V, elongation at break 300–400%, and oxidation index below 1.0 per ASTM F2102. The material meets ASTM F648 and ISO 5834-2 requirements for surgical implant bearing surfaces. Operational limits include sensitivity to repeated gamma resterilization beyond 3 cycles, where subsurface embrittlement can occur, and incompatibility with autoclave steam above 134 °C that causes dimensional compromise. The terminal products are tibial inserts, acetabular liners, and patellar components.

    When Slurry Pump Liners Exceed 80°C Continuous Service, Creep Modulus Governs Replacement Intervals

    Compression-moulded Celanese UHMW-PE 4170 ECO-B slurry pump liners are installed in centrifugal pumps transferring ore slurries with solids loading of 15–35 wt% and particle diameter d50 < 5 mm. The powder is consolidated in a cylindrical steel mould at 215±5 °C and 12–18 MPa; for wall sections above 50 mm, the cooling rate is controlled at 2–5 °C/h under pressure to prevent shrinkage voids at the mould core. The liner is then machined on a vertical boring mill with carbide inserts; dimensional tolerance across the casing register is held at ±0.25 mm. In this application, the material replaces cast elastomer or hard metal and provides a dry coefficient of friction below 0.10 against hard-chrome impeller hubs. Compliance testing follows ISO 11542 for UHMW-PE moulding materials, ASTM D4020 for solution viscosity, and ASTM D2240 for Shore D hardness 60–70. The continuous service ceiling is governed by creep; above 80 °C the tensile creep modulus falls below 0.1 GPa, causing liner deformation and bolt-hole elongation. Aromatic solvents, strong oxidizing acids, and ultraviolet exposure without 2.0–2.5 wt% carbon black increase environmental stress cracking and surface degradation. The terminal product is installed in mine tailings, flue gas desulfurization, and chemical plant transfer pumps. The liner must also be relieved for thermal expansion because linear thermal expansion is approximately 1.5×10⁻⁴ K⁻¹, which creates bolt notching if rigidly constrained.

    For press-and-sinter porous filter elements made from Celanese UHMW-PE 4170 ECO-B powder, narrow particle size cuts between 150 µm and 300 µm produce interconnected pores in the 10–40 µm range without fugitive pore formers. The powder is screened to remove fines below 100 µm, then filled into matched metal moulds and sintered at 190–205 °C for 30–60 min under no external pressure or under contact pressure of 0.1–0.3 MPa. The sintered preform is machined into filter cartridges, sparger discs, and water treatment diffusers; porous wall thickness is fixed at 5–15 mm to balance bubble-point pressure and permeability. The material is non-hydrophilic but can be surface-treated with oxygen plasma to reduce water contact angle below 60° for aeration duty. Compliance for liquid filtration follows ISO 16889 multipass beta rating; for drinking-water contact the component must meet NSF/ANSI 61 and EU 10/2011. Tensile strength of the sintered body is lower than solid sheet, typically 8–15 MPa per ISO 527-2, and must be derated by 30–50% when hot water exceeds 60 °C. The porous parts cannot be melt welded without collapsing the pore network; sealing is achieved with O-ring grooves and backing plates. Terminal uses include aeration pads, chemical-process liquid clarification, and pneumatic conveyance diffusers.

    Abrasion loss in marine fender facing pads falls outside linear wear models when moulded sheet density drops below 930 kg/m³

    Marine fender facing pads made from Celanese UHMW-PE 4170 ECO-B sheet are compression moulded in large-format presses with platen dimensions above 3 m × 2 m and clamp force of 2,000 t. The powder is charged to a mould thickness oversize of 12–15% to compensate for consolidation shrinkage; the heating cycle raises platen temperature from 80 °C to 230 °C at 2–4 °C/min, holds at 230±3 °C for 45–60 min, and cools under 0.5 MPa to ambient. Density is measured per ASTM D792 and kept at 0.930–0.935 g/cm³; a local density below 930 kg/m³ indicates fusion defects or trapped volatiles that increase wear rate disproportionately. The finished facing pad is bolted to steel fender panels and operates as a sliding surface against hull structures under contact pressures up to 1.0 MPa. Sand-slurry abrasion resistance is evaluated by ASTM G65 procedure A, with typical UHMW-PE volume loss below 3 mm³ after 6,000 wheel revolutions; published data specific to ECO-B under this test is limited, but sheet density and molecular weight remain the primary material variables controlling loss rate. Taber abrasion per ASTM D4060 with CS-17 wheels and 1,000 g load gives mass loss below 2 mg/1,000 cycles. Outdoor exposure requires 2.0–2.5 wt% carbon black or UV stabilizer masterbatch; without this, ultraviolet embrittlement occurs within 12–18 months in tropical marine conditions. Terminal products include berthing pads, lock gate surfaces, and vessel guide liners.

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    Certification & Compliance
    More Introduction

    Celanese UHMW-PE 4170 ECO-B is a granular ultra-high-molecular-weight polyethylene specified for compression moulding and ram extrusion. The viscosity-average molecular weight is in the 10.5 × 10⁶ g/mol class, and the moulded density is reported as 0.930 g/cm³ under ISO 1183-1. The ECO-B suffix reflects a mass-balance attribution of bio-derived ethylene; it does not introduce a different comonomer or stabilisation route that would alter the polymer backbone from the fossil-derived GUR 4170 reference.

    As a powder, the material shows bulk-density variability from 0.42 g/cm³ to 0.50 g/cm³ depending on particle size distribution and transport compaction. This variability affects compression-ratio settings in mould charging; a filling ratio of 2.5:1 to 3.5:1 is used to achieve a void-free moulded slab. The supplier’s certificate should be consulted for lot-specific particle size and bulk density, because the ECO-B mass-balance route does not alter these physical specifications.

    Material Architecture and Specification Layer

    For lot acceptance, solution viscosity is used instead of a conventional melt-flow index. At processing shear rates, the melt viscosity of the 10.5 × 10⁶ g/mol class is above 10⁸ Pa·s, and a stable ISO 1133 extrudate is not obtained. The representative property envelope in Table 1 derives from published UHMW-PE data for the 10 × 10⁶ g/mol molecular-weight class; product-specific batch values may differ within the supplier certificate.

    PropertyTest standardRepresentative envelopeNotes
    Viscosity-average molecular weightISO 1628-3, ASTM D40209.5–11.5 × 10⁶ g/molSolution viscosity in decalin at 135°C; converted by Margolies relation
    Moulded densityISO 1183-10.925–0.940 g/cm³Compression-moulded specimen; no filler
    Tensile stress at yieldISO 527-217–23 MPaTest speed 50 mm/min, type 1B specimen
    Elongation at breakISO 527-2≥300%Gauge length 25 mm; surface defects affect reproducibility
    Shore D hardnessISO 86860–6815 s reading; specimen thickness 6 mm
    Vicat softening temperature A50ISO 30675–85°C10 N load, 50 K/h heating rate
    Charpy impact strength, notchedISO 179-1/1eANo break at 23°CAt -20°C, partial break may appear
    Water absorption, 24 hISO 62<0.01%Immersion in distilled water at 23°C

    These values are representative of the molecular-weight class and should not be used as a substitute for the lot-specific certificate of analysis. The ECO-B designation does not alter the test methods or typical mechanical values; any variation arises from normal polymerisation and milling lot variability.

    The high entanglement density of the 10.5 × 10⁶ g/mol chain length produces a plateau modulus and a zero-shear viscosity that cannot be measured in conventional rotational rheometers at 190°C without edge fracture. Capillary rheometry at low shear rates is used to confirm the absence of melt fracture. The lack of flow under ISO 1133 is a deliberate specification marker, not a defect. Compared with lower-viscosity UHMW-PE grades such as GUR 4120 and GUR 4130, the 4170 class raises ram extrusion pressure and improves abrasion resistance, but it also narrows the practical processing window because the higher melt viscosity reduces heat transfer and increases the residence time required for full fusion.

    How Does the ECO-B Mass-Balance Designation Alter Processing or Registration Requirements?

    From a thermal and rheological standpoint, the designation does not alter processing. The powder is charged under the same dry-blending and moulding conditions as the fossil-derived GUR 4170 grade. The relevant change is documentation-controlled: when a converter claims renewable content or reduced carbon footprint, the mass-balance attribution must be preserved in the enterprise resource planning system. Because the bio-derived ethylene is fully polymerised into polyethylene, the migration and extraction profile remains governed by the same high-molecular-weight paraffinic structure as conventional UHMW-PE.

    Food-contact compliance for olefin polymers is evaluated under FDA 21 CFR 177.1520 and EU 10/2011; but the specific migration limit for the finished article depends on the additive package and the geometry, not solely on the polymer base. A converter must obtain the grade-specific compliance certificate. Published data for the exact bio-carbon fraction in Celanese UHMW-PE 4170 ECO-B is limited at the product-page level; sustainability documentation is supplied through the vendor’s mass-balance certificate.

    Moisture uptake is below 0.01% under ISO 62, but surface condensation on powder stored in outdoor silos at relative humidity above 60% can introduce water into the ram extrusion feed. A dehumidified hopper or pre-drying step at 80°C for 2–4 h is applied when the powder has been stored in unheated warehouses during winter months.

    On a compression-moulding line comprising a 630 t downstroke press with 1,500 mm × 1,500 mm platens, a typical heating cycle reaches platen setpoints of 200–220°C. The powder bed is initially compacted at 5–10 MPa to remove entrapped air, then the mould is heated under a stepped pressure ramp. Once the core temperature reaches 180°C—measured by inserted thermocouples—the pressure is raised to 15–25 MPa and maintained during cooling at 10–15 K/min. Release of the mould before the core temperature falls below 60°C produces warpage and internal voids; parts thicker than 80 mm may require cooling cycles in excess of 8 h.

    Ram extrusion line behaviour differs from compression moulding because the material is consolidated in a heated barrel and moved by a hydraulic ram instead of a screw. Barrel zones are set from 190°C to 230°C, but the actual die-land temperature is controlled by ram speed, die resistance, and frictional heating. The practical die-temperature window is narrow—approximately 200–230°C—because oxidation accelerates above 230°C and gel bodies appear when local temperature exceeds 260°C. Screw extrusion is not a viable conversion route for this grade; a single-screw extruder with L/D 30:1 cannot maintain a stable melt plug, and local shear heating raises the melt above 260°C, causing chain scission and gel particles. The resulting surface defects cannot be removed by melt filtration due to the ultra-high viscosity.

    When Wear Components Exceed Acceptable Surface Roughness on Conventional HDPE Lines

    Substitution of conventional PE-HD by UHMW-PE 4170 ECO-B is justified when the failure mode is abrasion, gouging, or impact-induced delamination in moving line components. In bottle-filling and packaging conveyors, polymer guide rails and star wheels are exposed to repeated sliding contact with glass and PET surfaces under low-speed sliding and high contact pressure. Under sand-slurry abrasion testing to ISO 15527, UHMW-PE of the 10 × 10⁶ g/mol class exhibits lower wear loss than lower-molecular-weight polyethylene when the counterface and slurry concentration are held constant; however, the absolute wear rate is system-dependent. Published data for this specific ECO-B configuration in those wear tests is limited; comparative wear evaluations should use the same moisture content and counterface roughness.

    For chain guides and scraper blades in dry bulk handling, the specification threshold is the maximum allowable linear wear before the guide loses dimensional support. With UHMW-PE 4170 ECO-B, the coefficient of friction measured under ASTM D1894 is approximately 0.10–0.15 against polished steel. This reduces drive torque relative to nylon and acetal alternatives, but the material has a lower compressive modulus than filled engineering thermoplastics. Continuous service above 80°C is not recommended because the Vicat softening point imposes a creep limit; under heavy loads, the maximum long-term service temperature is typically 60–70°C unless the part is supported by a steel substructure.

    A converter seeking to substitute 4170 ECO-B for a lower-viscosity UHMW-PE grade or for HDPE must first resolve three differences: melt rheology, powder flow, and documentation. Table 2 summarises the comparative platform.

    VariableCelanese UHMW-PE 4170 ECO-BFossil-derived GUR 4170 referenceConventional PE-HD
    Viscosity-average molecular weight≈10.5 × 10⁶ g/mol≈10.5 × 10⁶ g/mol0.05–0.25 × 10⁶ g/mol
    Melt flow rateNo stable extrudate under ISO 1133 at 190°C/21.6 kgNo stable extrudate under ISO 11332–20 g/10 min under ISO 1133
    Primary conversion routesCompression moulding, ram extrusionCompression moulding, ram extrusionInjection moulding, screw extrusion, blow moulding, film
    Feedstock attributionMass-balance bio-derived ethylene under ECO-B designationFossil-derived ethyleneTypically fossil-derived; renewable grades available under separate designations
    Wear performance in sliding contactHigher abrasion resistance than HDPE; test-method dependentEquivalent polymer network, no ECO-B documentationLower wear threshold under identical sand-slurry loading
    Moisture uptake<0.01% ISO 62<0.01% ISO 62<0.01% ISO 62

    The equivalence in mechanical properties between 4170 ECO-B and its fossil-derived GUR 4170 reference is a mass-balance consequence, not a new polymerisation route. Differences in lot-to-lot powder flow and particle size distribution may exceed any differences introduced by feedstock origin, making incoming powder rheology and bulk-density checks more meaningful than the ECO-B label for day-to-day process control.

    Warehouse handling of 4170 ECO-B should avoid open flame and high dust concentrations because polyethylene powder can form combustible dust suspensions. The product contains no hazardous fillers under Regulation (EC) No 1272/2008 as normally supplied; however, the powder creates a slipping hazard. Contact with strong oxidising agents and halogenated solvents at elevated temperature can embrittle the surface and reduce molecular weight. For machining, carbide-tipped tools with positive rake angles and low cutting speeds are used because the high molecular weight causes smearing and burr formation on heat-generating edges.

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