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Celanese UHMW-PE 402M13

    • Product Name: Celanese UHMW-PE 402M13
    • Factroy Site: Yudu County, Ganzhou, Jiangxi, China
    • Price Inquiry: admin@ascent-chem.com
    • Manufacturer: Ascent Petrochem Holdings Co., Limited
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    Specifications
    HS Code 639718
    Chemical Family Ultra-high molecular weight polyethylene (UHMW-PE)
    Molecular Weight 4.0 million g/mol
    Density 0.930 g/cm³
    Bulk Density 0.43 g/cm³
    Particle Size 130 µm
    Melting Point 135 °C
    Crystallinity 45%
    Tensile Modulus 700 MPa
    Tensile Strength At Yield 20 MPa
    Elongation At Break 300%
    Charpy Notched Impact Strength 100 kJ/m²
    Shore D Hardness 62
    Water Absorption <0.01%
    Thermal Conductivity 0.4 W/mK
    Coefficient Of Linear Thermal Expansion 200 µm/m°C
    Dielectric Constant 2.3
    Volume Resistivity >10^15 ohm·cm
    Flammability UL 94 HB

    As an accredited Celanese UHMW-PE 402M13 factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing Celanese UHMW-PE 402M13 is typically packaged in 25 kg multiwall paper bags, palletized, or 1,000 kg bulk bags for shipment.
    Container Loading (20′ FCL) Celanese UHMW-PE 402M13, 20′ FCL loading: palletized bags, securely stowed in a dry container for safe ocean transport.
    Shipping Celanese UHMW-PE 402M13 is a non-hazardous ultra-high molecular weight polyethylene powder. It is typically shipped in sealed, moisture-resistant 20–25 kg bags or drums, palletized and shrink-wrapped. Transport is not regulated as dangerous goods under DOT, IMDG, IATA, or ADR/RID; keep dry and away from heat and oxidizers.
    Storage Store Celanese UHMW-PE 402M13 in a cool, dry, well-ventilated area, away from heat, sparks, flames, and strong oxidizers. Keep containers tightly closed when not in use. Protect from moisture, direct sunlight, and contamination. Use original packaging, minimize dust generation, and maintain good housekeeping. Avoid excessive stacking or physical damage to containers. Store at ambient temperature. Follow local regulations.
    Shelf Life Celanese UHMW-PE 402M13 shelf life: two years if stored unopened in a cool, dry, ventilated area away from direct sunlight and heat.
    Application of Celanese UHMW-PE 402M13

    Direct conversion of 402M13 into orthopaedic bearing stock begins with incoming-lot verification against ISO 5834-2 and ASTM F648 before any compression-moulding cycle is released. The powder is consolidated in a compression mould rather than by conventional screw extrusion because the high melt viscosity of UHMWPE does not produce a measurable melt flow index under ISO 1133-1. Typical moulding envelopes for this molecular-weight class use platen temperatures of 190–220°C, consolidation pressure of 10–15 MPa, and hold time scaled to 10–15 min per 10 mm of final slab thickness. The mould cavity is blanketed with nitrogen or vacuum; oxygen concentration is held below 0.5 vol% during heating and consolidation to limit oxidation index development measured later by ASTM F2102. The consolidated slab is cooled under pressure at a controlled rate, usually below 10 K/min through the crystallisation plateau, to reduce density gradients and trapped volatile pockets. After demoulding, slabs are stress-relieved and machined into acetabular liners, tibial inserts, and patellar components on CNC lathes with carbide or polycrystalline diamond tooling; machining feeds and speeds are kept low because the low thermal conductivity of UHMWPE can produce melt streaks and surface oxidation on the cut face. Gamma sterilization at 25–40 kGy in vacuum or inert-gas packaging remains the standard terminal sterilization route for this polymer class, but the radiation dose generates residual free radicals that accelerate oxidative embrittlement over implant shelf life unless packaging oxygen levels are controlled and post-irradiation annealing or vitamin E blending is specified. Because 402M13 is supplied as a virgin UHMWPE powder grade, any alpha-tocopherol-stabilised formulation must be produced through validated secondary blending under ISO 5834-2 qualification unless the supplier certificate indicates otherwise. Published data for the specific 402M13 configuration with vitamin E is limited and must be generated for the intended implant design.

    What Restricts Ram Extrusion Throughput When 402M13 Is Formed into Wear Strips and Chain Guides?

    Ram extrusion of 402M13 into solid profiles is used for chain guides, wear strips, scraper blades, and spiral conveyor rails because the powder can be fed into a heated barrel without imposing screw shear. The process is thermally limited; UHMWPE exhibits a thermal conductivity of approximately 0.4 W/(m·K), so wall heat transfer controls the sintering front. Barrel temperatures are typically maintained at 200–230°C while the die is held 10–20 K lower to retain profile shape during cooling. The reciprocating ram compresses the powder into a solid plug that is sintered under pressure and advanced in discrete increments. Published production-rate data for 402M13 profiles is limited, but commercial ram extrusion of this molecular-weight class is substantially slower than single-screw extrusion of lower-molecular-weight HDPE, with output governed by cross-sectional area and cooling length rather than drive power. Operators monitor the die exit for surface defects associated with insufficient fusion or excessive die temperature; centreline porosity and transverse cracking indicate that the sintering front has not fully penetrated the profile before it enters the cooling zone. The process is incompatible with screw-based reclaim compounding unless the molecular weight is deliberately degraded, which defeats wear and abrasion resistance in the terminal part. Extruded profiles are cut and machined to final dimensions; because UHMWPE has high specific heat and low thermal diffusivity, dimensional inspection after 24 h at 23°C under ISO 291 is required. ASTM D4020 molecular-weight verification on the incoming powder and ISO 11542-2 tensile property checks on representative compression-moulded plaques are the usual release tests. This segment does not require food-contact or implant certification unless the profile is sold into food or pharmaceutical material-handling lines, in which case FDA 21 CFR 177.1520 and EU 10/2011 migration documentation must be added.

    In wet-process lithium-ion battery separator production, 402M13 powder is blended with high-density polyethylene and a high-boiling paraffin plasticizer before gel extrusion through a flat die. The UHMWPE fraction raises the viscosity of the polymer-plasticizer gel and modifies crystalline morphology after biaxial stretching; published literature on UHMWPE/HDPE separator compounds generally reports UHMWPE additions below 20 wt% because higher loadings reduce cast-film throughput and can destabilize the tentering stage. 402M13 enters the dry-blend or masterbatch feed as a powder with no measurable melt-flow index; adequate dispersion requires high-shear mixing upstream of the extruder because the UHMWPE domains do not molecularly dissolve into the HDPE melt at separator extrusion temperatures. After the gel film is quenched, solvent extraction removes the paraffin and biaxial orientation creates microporosity, followed by heat-setting to stabilise pore dimensions. The resulting membrane is evaluated for puncture resistance and tensile strength under the converter’s internal test methods; standardised published protocols vary, with ASTM D882 used for thin-film tensile and pore-size characterisation via gas-liquid porometry or mercury porosimetry. The functional contribution of 402M13 in this application is retention of melt integrity and formation of fine fibrils across the pore walls rather than a direct load-bearing role. Converters must verify foreign-body cleanliness and metal content because separator film thickness is typically below 20 µm and defects above 10 µm can trigger dielectric breakdown during cell formation. The powder should be stored below 50°C and kept dry; although UHMWPE has low moisture uptake, condensation on cold powder can create paper-like agglomerates that disturb gravimetric feeding. This application has no implant or food-contact compliance requirement, but REACH and RoHS documentation is commonly requested by cell manufacturers.

    Compression-Moulded Sheet Complies with FDA 21 CFR 177.1520 for Food-Contact Conveyor Liners

    In food processing and packaging lines, compression-moulded sheet converted from 402M13 is used as chain-track wear strips, chute liners, guide rails, and conveyor bed components where repeated sliding contact and washdown exposure are present. The powder is consolidated into 2–100 mm sheet, then planed or skived to final thickness; because UHMWPE cannot be hot-air welded with structural reliability, assemblies rely on mechanical fastening, dovetail routing, or manufactured tongue-and-groove joints. Food-contact status is based on the olefin polymer provisions of FDA 21 CFR 177.1520, with condition-of-use limitations derived from the intended food type and temperature; EU conversion requires overall migration testing under Regulation (EU) No 10/2011 against the 10 mg/dm² limit. Continuous service temperature for UHMWPE sheet under load is generally below 80°C based on ASTM D648 heat deflection temperature and creep considerations; short-term contact with hot washdown above 80°C is not recommended where dimensional stability or load-bearing retention is critical. Wear performance in dry or wet sliding against steel or stainless-steel counterfaces is evaluated by thrust-washer or block-on-ring procedures such as ASTM D3702; published wear-rate data for 402M13 in specific food-contact configurations is limited and should be generated on the actual counterface and sanitizer exposure cycle. The sheet should not be sterilized by steam autoclave because the 121°C cycle exceeds the crystalline softening region and can induce distortion, surface whitening, and release locked-in stress. Terminals include poultry processing slats, bakery dough guides, bottling conveyor wear strips, and fish-filleting table liners; any use above 80°C or involving high load-bearing structural support requires a lower-modulus, higher-creep design review.

    Compliance and test matrix across 402M13 application segments
    SegmentStandard/CodeTest/ParameterNotes
    Orthopaedic bearing stockISO 5834-2, ASTM F648Oxidation index via ASTM F2102; tensile via ISO 527-2; density via ISO 1183-1Gamma dose 25–40 kGy; inert gas packaging required
    Ram-extruded wear profilesASTM D4020, ISO 11542-2Molecular weight; tensile on compression-moulded plaqueBarrel 200–230°C; die 10–20 K lower
    Battery separator compoundREACH, RoHSFilm tensile via ASTM D882; pore size via gas-liquid porometryFilm thickness below 20 µm; defects above 10 µm unacceptable
    Food-contact conveyor linerFDA 21 CFR 177.1520, EU 10/2011Overall migration limit 10 mg/dm²; HDT via ASTM D648Continuous use below 80°C
    Sintered porous filtrationASTM F316Bubble point; pore-size distributionSintering 180–220°C
    PA/POM wear compoundISO 527-2, ASTM D3702Tensile; wear factorAddition 5–20 wt%; L/D 40:1–52:1

    For porosity-controlled filtration plates, venting discs, and pneumatic silencers, 402M13 powder can be free-sintered in a closed mould without full densification. The particle boundaries fuse at contact points when the mould is held between 180°C and 220°C, producing a porous body whose void volume and throat size are set by powder particle-size distribution, filling density, and sintering time rather than by compaction pressure. Unlike compression-moulded solid sheet, the resulting porous stock is not intended for high-tensile or high-impact service; its function is controlled permeability, hydrophobicity, and chemical inertness. Bubble point and pore-size measurements are performed according to ASTM F316 or equivalent gas-liquid porometry, while air permeability is stated under the fabricator’s internal standard. Published data for 402M13 in specific sintered filter grades is limited because final pore diameter depends more on sieve cuts and mould fill than on the base resin itself. Cleanliness requirements are tight: loose powder fines must be removed after sintering because retained particles can detach in service and block downstream instrument orifices. The material is not suitable for sterilizing-grade filtration or pharmaceutical final filters unless validated in the fully assembled device under the applicable bacterial challenge standard. Terminal components are found in compressed-air exhaust silencers, gas sensor vents, water treatment diffusion plates, and laboratory filter supports. Chemical compatibility with acids and alkalis follows general UHMWPE resistance data, but organic solvents and strong oxidizers require specific immersion testing before production release.

    When 402M13 Powder Is Dispersed into Injection-Moulded PA and POM Compounds for Low-Speed Sliding Wear

    Thermoplastic compounders add 402M13 to polyamide, polyoxymethylene, or polypropylene matrices to reduce coefficient of friction and improve wear resistance in injection-moulded sliding elements. The processing window is narrow: UHMWPE domains remain as discrete solid particles at the processing temperatures of PA and POM because the molecular weight of 402M13 prevents complete chain interdiffusion. Twin-screw extruders with L/D ratios of 40:1 to 52:1 and downstream side feeding are used to limit shear heating and prevent the UHMWPE particles from matting into agglomerates; barrel temperatures are set according to the carrier resin, not the UHMWPE melting range. Addition levels commonly range from 5 wt% to 20 wt%; above 15 wt% the weld-line strength and tensile modulus of the compound can decline because UHMWPE particles act as stress concentrators rather than reinforcing fillers. The compound is tested for tensile properties under ISO 527-2 and for wear factor by a thrust-washer method such as ASTM D3702, with counterface roughness and pressure-velocity conditions reported because UHMWPE-modified compounds are sensitive to frictional heat. Terminal parts include low-speed pulleys, gear blanks, bearing cages, and conveyor roller inserts where external lubrication is not desired. This application should not be confused with cross-linked or fiber-spun UHMWPE; 402M13 is an uncompounded powder and does not provide ballistic fiber tenacity unless it is processed through a dedicated gel-spinning line. Compounders must verify metal contamination and powder flowability because variance in particle-size distribution can alter feeding accuracy and produce batch-to-batch variation in the dispersion index. Published data for 402M13 in specific PA or POM matrices is limited; each carrier resin and additive package requires a designed experiment to map torque, melt temperature, and Izod impact retention.

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